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1. 发明授权

US06733948B2 Negative image-recording material 有权
标题翻译：负图像记录材料
公开(公告)号：US06733948B2
公开(公告)日：2004-05-11
申请号：US09928447
申请日：2001-08-14
申请人： Ippei Nakamura , Tadahiro Sorori
发明人： Ippei Nakamura , Tadahiro Sorori
IPC分类号： G03C152
CPC分类号： B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41M5/465
摘要： A negative image-recording material which can be imagewise exposed to IR radiation from IR lasers and ensures direct image formation from digital data of a computer or the like. The material, when used in a lithographic printing plate, ensures good hardenability in an image area and exhibits good printing durability, even if not heated for image formation, and ensures a large number of good prints from the printing plate. The recording material contains (A) an IR absorber, (B) a radical generator having an onium salt structure, (C) a radical-polymerizing compound, and (D) a reducing additive, and this is imagewise exposed to IR radiation for image formation. Preferably, the reducing additive (D) is highly reactive with radicals and a reaction product with a radical has high reductivity. Preferred examples of the reducing additive are ether-type hydrogen donors, alcohol-type hydrogen donors, vinyl ethers and phosphine-type compounds.
摘要翻译：可以从IR激光器成像曝光到IR辐射的负图像记录材料，并确保从计算机等的数字数据直接形成图像。该材料在平版印刷版中使用时，确保图像区域的良好的淬透性，并且即使不加热成像，也能保证印刷品的良好印刷，因此具有良好的印刷耐久性。记录材料包含（A）IR吸收剂，（B）具有鎓盐结构的自由基发生剂，（C）自由基聚合化合物和（D）还原添加剂，并且其成像暴露于IR辐射图像形成。优选地，还原添加剂（D）与自由基具有高反应性，并且与基团的反应产物具有高的还原性。还原添加剂的优选实例是醚型氢供体，醇型氢供体，乙烯基醚和膦类化合物。

2. 发明授权

US06797449B2 Negative image-recording material and cyanine dye 有权
标题翻译：负图像记录材料和花青染料
公开(公告)号：US06797449B2
公开(公告)日：2004-09-28
申请号：US10044959
申请日：2002-01-15
申请人： Ippei Nakamura , Tadahiro Sorori
发明人： Ippei Nakamura , Tadahiro Sorori
IPC分类号： G03F7021
CPC分类号： C09B23/0066 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , C07D209/10 , C09B67/0034 , Y10S430/121 , Y10S430/122
摘要： The invention provides a negative image-recording material for heat-mode exposure systems, which comprises (A) an IR absorbent including cyanine dye having a substituent that contains an atom having an atomic weight of at least 28 such as halogen atom, or a substituent that contains a non-covalent electron pair such as carbonyl group, (B) a radical generator and (C) a radically-polymerable compound, and which is imagewise exposed to IR rays for image formation thereon.
摘要翻译：本发明提供一种用于热模式曝光系统的负型图像记录材料，其包括（A）包含具有取代基的花青染料的IR吸收剂，所述染料含有原子量至少为28的原子，例如卤素原子，或取代基其包含非共价电子对如羰基，（B）自由基发生剂和（C）可自由基聚合的化合物，并且其成像暴露于IR光线以在其上形成图像。

3. 发明授权

US06958206B2 Image recording material and lithographic printing plate precursor 有权
标题翻译：图像记录材料和平版印刷版前体
公开(公告)号：US06958206B2
公开(公告)日：2005-10-25
申请号：US10359711
申请日：2003-02-07
申请人： Tomotaka Tsuchimura , Ippei Nakamura , Tadahiro Sorori , Akihiro Endo , Tomoo Murakami
发明人： Tomotaka Tsuchimura , Ippei Nakamura , Tadahiro Sorori , Akihiro Endo , Tomoo Murakami
IPC分类号： B41C1/10 , B41M5/36 , G03F7/039
CPC分类号： B41C1/1008 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262 , B41M5/368 , Y10S430/145 , Y10S430/146
摘要： An image recording material comprising (a) an infrared ray absorber and (b) a polymer to lower a dynamic coefficient of friction to from 0.38 to 0.60, which can undergo image formation upon exposure with infrared laser; or a long-chain alkyl group-containing polymer having a reduction rate of coefficient of friction to a base polymer of from 0.5 to 0.97, the polymer being a copolymer of a long-chain alkyl group-containing monomer having 6 or more carbon atoms and a hydrophilic monomer.
摘要翻译：一种图像记录材料，包括（a）红外线吸收剂和（b）将动态摩擦系数降至0.38至0.60的聚合物，其可以在用红外激光曝光时进行图像形成; 或具有0.5〜0.97摩尔的摩擦系数的缩合率为0.5〜0.97的长链烷基的聚合物，所述聚合物为具有6个或更多个碳原子的长链烷基单体和亲水单体。

4. 发明授权

US06770422B2 Negative image-recording material and method of image formation 有权
标题翻译：负图像记录材料和图像形成方法
公开(公告)号：US06770422B2
公开(公告)日：2004-08-03
申请号：US09899123
申请日：2001-07-06
申请人： Ippei Nakamura , Tadahiro Sorori
发明人： Ippei Nakamura , Tadahiro Sorori
IPC分类号： G03F7029
CPC分类号： B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , G03F7/322 , Y10S430/145
摘要： A negative image-recording material which can be imagewise-exposed by IR radiation from IR lasers and enables direct image formation from digital data of a computer or the like. The material, when used in a lithographic printing plate, ensures good hardenability in an image area, exhibits good printing durability, even if not heated for image-formation, and ensures a large number of good prints from the printing plate. The material includes (A) an IR absorber having an oxidation potential of at most 0.35 V (vs. SCE), (B) a thermal radical generator and (C) a radical-polymerizing compound. The material is imagewise-exposed to IR radiation for image formation. Preferably, the IR absorber (A) has, in a chromophoric group, an electron-donating substituent having a Hammett's &sgr;para value of at most −0.10, and the thermal radical generator (B) is an onium salt.
摘要翻译：可以通过来自IR激光器的IR辐射成像曝光的负图像记录材料，并且能够通过计算机等的数字数据进行直接图像形成。该材料在平版印刷版中使用时，确保图像区域的良好的淬透性，即使不进行图像形成加热也能显示出良好的印刷耐久性，并且确保了印刷版的大量良好的印刷。该材料包括（A）具有至多0.35V（相对于SCE）的氧化电位的IR吸收剂，（B）热自由基产生剂和（C）自由基聚合化合物。该材料成像暴露于IR辐射用于图像形成。优选地，IR吸收剂（A）在发色基团中具有至多为-0.10的哈米特sigmapara值的给电子取代基，并且热自由基产生剂（B）为鎓盐。

5. 发明授权

US07105276B2 Image recording material 有权
公开(公告)号：US07105276B2
公开(公告)日：2006-09-12
申请号：US11067698
申请日：2005-03-01
申请人： Kazuhiro Fujimaki , Tadahiro Sorori , Keitaro Aoshima
发明人： Kazuhiro Fujimaki , Tadahiro Sorori , Keitaro Aoshima
IPC分类号： G03F7/027 , G03F7/029
CPC分类号： B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/266 , Y10S430/145 , Y10S430/146 , Y10S430/165
摘要： A heat mode type negative image recording material is provided which comprises (A) a polymer compound that is insoluble in water but is soluble in an alkali aqueous solution and has at least one of groups represented by general formulae (1) to (3) on a side chain; (B) a photothermal conversion agent; and (C) an onium salt compound forming radicals by heat mode exposure with light that is capable of being absorbed by said photothermal conversion agent (B), said heat mode type negative image recording material being capable of recording an image by heat mode exposure. The general formulae are defined in the specification.

6. 发明授权

US06468711B1 Photosensitive composition and method for manufacturing lithographic printing plate 失效
标题翻译：光敏组合物和制造平版印刷版的方法
公开(公告)号：US06468711B1
公开(公告)日：2002-10-22
申请号：US09392259
申请日：1999-09-09
申请人： Tadahiro Sorori , Tatsuji Higashi , Koichi Kawamura
发明人： Tadahiro Sorori , Tatsuji Higashi , Koichi Kawamura
IPC分类号： G03F7004
CPC分类号： C08F2/50 , G03F7/029
摘要： A photosensitive composition comprising: a titanocene compound; and at least one dye selected from: carbonyl compounds represented by formula (I): wherein Y represents a nonmetallic atom group for forming a nitrogen-containing heterocyclic ring together with the adjacent N and carbon atom, and X represents a monovalent nonmetallic atom group; and merocyanine compounds represented by formula (II): wherein A represents S atom or NR1, R1 represents an alkyl group or an aryl group, Y represents a nonmetallic atom group for forming a basic nucleus of the dye together with the adjacent A and carbon atom, X1 and X2 each independently represents a monovalent nonmetallic atom group, and X1 and X2 may be combined with each other to form the acidic nucleus of a dye. Also disclosed is a method for manufacturing a lithographic printing plate using the photosensitive composition.
摘要翻译：一种光敏组合物，其包含：二茂钛化合物; 和选自由式（I）表示的羰基化合物的至少一种染料：其中Y表示与相邻的N和碳原子一起形成含氮杂环的非金属原子，X表示一价非金属原子团; 和由式（II）表示的部花菁化合物：其中A表示S原子或NR 1，R 1表示烷基或芳基，Y表示与相邻的A和碳原子一起形成染料的碱性核的非金属原子，X1和X2各自独立地表示一价非金属原子，X1和X2可以相互结合形成染料的酸性核。还公开了使用该光敏组合物制造平版印刷版的方法。

7. 发明授权

US06423471B1 Photosensitive composition and method of making lithographic printing plate 失效
标题翻译：光敏组合物和制备平版印刷版的方法
公开(公告)号：US06423471B1
公开(公告)日：2002-07-23
申请号：US09620990
申请日：2000-07-20
申请人： Tadahiro Sorori , Yasufumi Murota
发明人： Tadahiro Sorori , Yasufumi Murota
IPC分类号： B03F7027
CPC分类号： G03F7/029
摘要： A photosensitive composition comprising (i) at least one titanocene compound (ii) an addition polymerizable compound containing at least one ethylenically unsaturated double bond and (iii) at least one pigment having an optical characteristic such that the transmittance at 500 nm is relatively smaller than the transmittance at 400 nm. Also disclosed is a method of producing a lithographic printing plate using a lithographic printing plate precursor comprising the photosensitive composition.
摘要翻译：一种光敏组合物，其包含（i）至少一种二茂钛化合物（ii）含有至少一个烯属不饱和双键的加成聚合化合物和（iii）至少一种具有光学特性的颜料，使得在500nm处的透射率相对小于在400 nm处的透射率。还公开了使用包含感光性组合物的平版印刷版原版来制造平版印刷版的方法。

8. 发明授权

US06335144B1 Photopolymerizable composition for short wavelength semiconductor laser exposure 失效
标题翻译：用于短波长半导体激光曝光的光聚合组合物
公开(公告)号：US06335144B1
公开(公告)日：2002-01-01
申请号：US09557321
申请日：2000-04-25
申请人： Yasufumi Murota , Tadahiro Sorori
发明人： Yasufumi Murota , Tadahiro Sorori
IPC分类号： G03F7027
CPC分类号： G03F7/031 , C08F2/50 , G03F7/029 , Y10S430/114 , Y10S430/127
摘要： Disclosed is a photopolymerizable composition which comprises (i) a sensitizing dye represented by the following formula (I-1), (ii) a titanocene compound, and (iii) an addition polymerizable compound having at least one ethylenically unsaturated double bond: wherein A and B each represents —S—, NR3, or NR4; R3 and R4 each represents a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; Y1 and Y2 each represents a non-metallic atomic group to form a basic nucleus of a dye together with the adjacent A or B, and the adjacent carbon atoms; R1 and R2 each represents a monovalent non-metallic atomic group, or they may be bonded to each other to form an aliphatic or aromatic ring.
摘要翻译：公开了一种可光聚合组合物，其包含（i）由下式（I-1）表示的增感染料，（ii）二茂钛化合物和（iii）具有至少一个烯键式不饱和双键的加成聚合化合物：其中A 和B各自表示-S-，NR 3或NR 4; R 3和R 4各自表示取代或未取代的烷基，或取代或未取代的芳基; Y1和Y2各自表示与相邻的A或B以及相邻碳原子一起形成染料的碱性核的非金属原子团; R1和R2各自表示一价非金属原子团，或者它们可以彼此键合以形成脂族或芳族环。

9. 发明授权

US5049481A Sensitizers for photopolymerizable compositions 失效
标题翻译：可光聚合组合物的敏化剂
公开(公告)号：US5049481A
公开(公告)日：1991-09-17
申请号：US456968
申请日：1989-12-26
申请人： Yasuo Okamoto , Tadahiro Sorori
发明人： Yasuo Okamoto , Tadahiro Sorori
IPC分类号： G03F7/028 , C08F2/50 , G03F7/029 , G03F7/031
CPC分类号： G03F7/029 , G03F7/031 , Y10S430/115 , Y10S430/116 , Y10S430/121 , Y10S430/123 , Y10S430/127 , Y10S430/146 , Y10S522/913
摘要： A photopolymerizable composition comprising (i) a polymerizable compound having an addition polymerizable unsaturated bond, (ii) a compound represented by formula (Ia): ##STR1## a compound represented by formula (Ib): ##STR2## or a compound represented by formula (Ic): ##STR3## wherein A represents an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, an alkyl- or aryl-substituted nitrogen atom, or a dialkyl-substituted carbon atom; Y.sup.1 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an aralkyl group, an acyl group, an alkoxycarbonyl group, or a substituted alkoxycarbonyl group; R.sup.1 and R.sup.2 each represents a hydrogen atom, an alkyl group having from 1 to 18 carbon atoms, or an alkyl group having from 1 to 18 carbon atoms which is substituted with R.sup.3 O--, ##STR4## or a halogen atom (i.e., F, Cl, Br, and I), wherein R.sup.3 represents a hydrogen atom or an alkyl group having from 1 to 10 carbon atoms, and B represents a dialkylamino group, a hydroxyl group, an acyloxy group, a halogen atom, or a nitro group; n represents 0 or an integer of from 1 to 4; and m represents an integer of from 1 to 20, and (iii) at least one compound selected from the group consisting of (a) a compound having a carbon-halogen bond, (b) an aromatic onium salt, (c) an organic peroxide, (d) a thio compound represented by formula (II): ##STR5## wherein R.sup.4 represents an alkyl group, an aryl group, or a substituted aryl group; and R.sup.5 represents a hydrogen atom or an alkyl group; or R.sup.4 and R.sup.5 are taken together to represent a non-metallic atom group necessary to form a 5- to 7-membered ring which may contain a hetero atom selected from oxygen, sulfur and nitrogen atoms, (e) a hexaarylbiimidazole, and (f) a ketoxime ester. The composition has high sensitivity in a broadened range of light of from the ultraviolet region to the visible region.

10. 发明申请

US20050187103A1 Image recording material 有权
公开(公告)号：US20050187103A1
公开(公告)日：2005-08-25
申请号：US11067698
申请日：2005-03-01
申请人： Kazuhiro Fujimaki , Tadahiro Sorori , Keitaro Aoshima
发明人： Kazuhiro Fujimaki , Tadahiro Sorori , Keitaro Aoshima
IPC分类号： B41C1/10 , B41M5/36 , B41M5/20
CPC分类号： B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/266 , Y10S430/145 , Y10S430/146 , Y10S430/165
摘要： A heat mode type negative image recording material is provided which comprises (A) a polymer compound that is insoluble in water but is soluble in an alkali aqueous solution and has at least one of groups represented by general formulae (1) to (3) on a side chain; (B) a photothermal conversion agent; and (C) an onium salt compound forming radicals by heat mode exposure with light that is capable of being absorbed by said photothermal conversion agent (B), said heat mode type negative image recording material being capable of recording an image by heat mode exposure. The general formulae are defined in the specification.

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