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1. 发明授权

US08153756B2 Fluorine-containing monomer, fluorine-containing polymer and surface treating agent 有权
标题翻译：含氟单体，含氟聚合物和表面处理剂
公开(公告)号：US08153756B2
公开(公告)日：2012-04-10
申请号：US12236416
申请日：2008-09-23
申请人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami , Ginjiro Tomizawa
发明人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami , Ginjiro Tomizawa
IPC分类号： C08G73/24 , C08F214/16 , C08F214/18 , A61K31/195 , C07C61/08 , C07C229/08
CPC分类号： C07C317/18 , C07C229/30 , C07C255/23 , C07C323/12 , C08F214/18 , Y10T428/23986 , Y10T442/20 , Y10T442/2287
摘要： Disclosed is a fluorine-containing polymer having:(A) a repeating unit derived from a fluorine-containing monomer which is represented by the following formula: CH2═C(—X)—C(═O)—Y—[—(CH2)m—Z—]p—(CH2)n—Rf (I) (B) a repeating unit derived from a monomer containing no fluorine atom, and if necessary (C) a repeating unit derived from a crosslinkable monomer. This fluorine containing polymer has excellent water repellency, oil repellency and antifouling property.
摘要翻译：公开了一种含氟聚合物，其具有：（A）由下式表示的含氟单体的重复单元：CH 2 = C（-X）-C（= O）-Y - [ - （CH 2 ）m-Z-] p-（CH2）n-Rf（I）（B）衍生自不含氟原子的单体的重复单元，如果需要（C）衍生自可交联单体的重复单元。该含氟聚合物具有优异的防水性，拒油性和防污性。

2. 发明申请

US20070173148A1 Surface treating agent, fluorine-containing monomer and fluorine-containing polymer 有权
标题翻译：表面处理剂，含氟单体和含氟聚合物
公开(公告)号：US20070173148A1
公开(公告)日：2007-07-26
申请号：US10594011
申请日：2005-03-25
申请人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami
发明人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami
IPC分类号： B32B27/04 , C08F114/18 , C07C323/39
CPC分类号： C08F214/18 , C07C323/12 , C08F120/24 , C08F120/38 , C08F220/24 , C08F220/38 , C09D5/1668 , C09D133/16 , C09K3/18 , D06M15/277 , D06M15/295 , D06M2200/10 , D06M2200/11 , D06M2200/12 , D21H17/11 , D21H21/16 , Y10T442/2287
摘要： Disclosed is a surface treating agent containing fluorine-containing polymer having: (A) a repeating unit derived from a fluorine-containing compound which is represented by the following formula: CH2═C(—X)—C(═O)—Y—[—(CH2)m-Z-]p—(CH2)n—Rf (I) (wherein X is a hydrogen atom or a methyl group), (B) a repeating unit derived from a monomer containing no fluorine atom, if necessary and (C) a repeating unit derived from a crosslinkable monomer, if necessary. This surface treating agent has excellent water repellency, oil repellency and antifouling property.
摘要翻译：公开了含有含氟聚合物的表面处理剂，其具有：（A）由下式表示的含氟化合物的重复单元：＆lt;＆lt;直列式说明=“在线式”末端 =“铅”→CH 2 -C（-X）-C（-O）-Y - [ - （CH 2 CH 2）m

3. 发明授权

US07638575B2 Surface treating agent, fluorine-containing monomer and fluorine-containing polymer 有权
标题翻译：表面处理剂，含氟单体和含氟聚合物
公开(公告)号：US07638575B2
公开(公告)日：2009-12-29
申请号：US10594011
申请日：2005-03-25
申请人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami
发明人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami
IPC分类号： C08L27/12
CPC分类号： C08F214/18 , C07C323/12 , C08F120/24 , C08F120/38 , C08F220/24 , C08F220/38 , C09D5/1668 , C09D133/16 , C09K3/18 , D06M15/277 , D06M15/295 , D06M2200/10 , D06M2200/11 , D06M2200/12 , D21H17/11 , D21H21/16 , Y10T442/2287
摘要： Disclosed is a surface treating agent containing fluorine-containing polymer having: (A) a repeating unit derived from a fluorine-containing compound which is represented by the following formula: CH2═C(—X)—C(═O)—Y—[—(CH2)m-Z-]p—(CH2)n-Rf (I) (wherein X is a hydrogen atom or a methyl group), (B) a repeating unit derived from a monomer containing no fluorine atom, if necessary and (C) a repeating unit derived from a crosslinkable monomer, if necessary. This surface treating agent has excellent water repellency, oil repellency and antifouling property.
摘要翻译：公开了含有含氟聚合物的表面处理剂，其具有：（A）由下式表示的含氟化合物的重复单元：CH2-C（-X）-C（-O）-Y- [ - （CH 2）m Z-] p-（CH 2）n -R f（I）（其中X为氢原子或甲基），（B）衍生自不含氟原子的单体的重复单元，如果需要，（C）衍生自交联性单体的重复单元。该表面处理剂具有优异的防水性，防油性和防污性。

4. 发明授权

US07442829B2 Fluorine-containing monomer, fluorine-containing polymer and surface treating agent 有权
标题翻译：含氟单体，含氟聚合物和表面处理剂
公开(公告)号：US07442829B2
公开(公告)日：2008-10-28
申请号：US10594148
申请日：2005-03-25
申请人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami , Ginjiro Tomizawa
发明人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami , Ginjiro Tomizawa
IPC分类号： A61K31/195 , C07C229/48 , C07C61/08
CPC分类号： C07C317/18 , C07C229/30 , C07C255/23 , C07C323/12 , C08F214/18 , Y10T428/23986 , Y10T442/20 , Y10T442/2287
摘要： Disclosed is a fluorine-containing polymer having: (A) a repeating unit derived from a fluorine-containing monomer which is represented by the following formula: CH2═C(—X)—C(═O)—Y—[—(CH2)m-Z-]p—(CH2)n—Rf (I) (B) a repeating unit derived from a monomer containing no fluorine atom, and if necessary (C) a repeating unit derived from a crosslinkable monomer. This fluorine containing polymer has excellent water repellency, oil repellency and antifouling property.
摘要翻译：公开了一种含氟聚合物，其具有：（A）由下式表示的含氟单体衍生的重复单元：＆lt;线内配方说明=“在线式”末端=“铅” -C（ - ） - （ - O）-Y - [ - （CH 2）2） - [ （I）<βin-line-formula description =“In-line Formulas”end =“尾”→（B）衍生自不含氟原子的单体的重复单元，必要时（C）来自交联性单体的重复单元。该含氟聚合物具有优异的防水性，拒油性和防污性。

5. 发明申请

US20070202761A1 Fluorine-Containing Monomer, Fluorine-Containing Polymer And Surface Treating Agent 有权
标题翻译：含氟单体，含氟聚合物和表面处理剂
公开(公告)号：US20070202761A1
公开(公告)日：2007-08-30
申请号：US10594148
申请日：2005-03-25
申请人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami , Ginjiro Tomizawa
发明人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami , Ginjiro Tomizawa
IPC分类号： B32B27/04 , C08F14/18
CPC分类号： C07C317/18 , C07C229/30 , C07C255/23 , C07C323/12 , C08F214/18 , Y10T428/23986 , Y10T442/20 , Y10T442/2287
摘要： Disclosed is a fluorine-containing polymer having: (A) a repeating unit derived from a fluorine-containing monomer which is represented by the following formula: CH2═C(-X)-C(═O)-Y-[-(CH2)m-Z-]p-(CH2)n—Rf (I) (B) a repeating unit derived from a monomer containing no fluorine atom, and if necessary (C) a repeating unit derived from a crosslinkable monomer. This fluorine containing polymer has excellent water repellency, oil repellency and antifouling property.
摘要翻译：公开了一种含氟聚合物，其具有：（A）由下式表示的含氟单体衍生的重复单元：＆lt;线内配方说明=“在线式”末端=“铅” -C（ - ） - （ - O）-Y - [ - （CH 2）2） - [ （I）<βin-line-formula description =“In-line Formulas”end =“尾”→（B）衍生自不含氟原子的单体的重复单元，必要时（C）来自交联性单体的重复单元。该含氟聚合物具有优异的防水性，拒油性和防污性。

6. 发明授权

US07914589B2 Fluorine-containing urethanes 有权
标题翻译：含氟氨基甲酸酯
公开(公告)号：US07914589B2
公开(公告)日：2011-03-29
申请号：US11659229
申请日：2005-07-29
申请人： Ikuo Yamamoto , Yutaka Ohira , Shinichi Minami
发明人： Ikuo Yamamoto , Yutaka Ohira , Shinichi Minami
IPC分类号： C11D3/00 , D06M15/263 , C09J11/06 , C08J5/12 , C04B28/36 , C07C69/63 , B29D22/00 , B29D23/00 , B31B45/00 , B32B1/08 , B28B23/00 , B28B21/00 , B60R21/16 , A47G19/22
CPC分类号： C07D251/34 , Y10T428/1303 , Y10T428/1314 , Y10T428/1362
摘要： Fluorine-containing urethanes represented by the general formula: [Rf-A1-Z—X1—OC(═O)NH—]mI[—NHC(═O)O—Y1]n[—NHC(═O)O—(ClCH2—)X2O)a—R1]k (1) wherein I is a group derived from a polyisocyanate by removal of the isocyanato groups; Rf is perfluoroalkyl of 1 to 21 carbon atoms; A1 is a direct bond or an organic group of 1 to 21 carbon atoms; Z —SO2—; X1 is a divalent, straight-chain or branched, C1-5 aliphatic group which may have at least one hydroxyl group; X2 is a trivalent, straight-chain or branched, C2-5 aliphatic group; Y1 is a monovalent organic group which is optionally hydroxylated; and R1 is hydrogen or alkyl of 1 to 10 carbon atoms.
摘要翻译：由以下通式表示的含氟聚氨酯：[Rf-Al-Z-X1-OC（= O）NH-] mI [-NHC（= O）O-Y1] n [-NHC（= O）O- ClCH 2 - ）X 2 O）a-R 1] k（1）其中I是通过除去异氰酸酯基团而衍生自多异氰酸酯的基团; Rf是1至21个碳原子的全氟烷基; A1是直接键或1〜21个碳原子的有机基团; Z -SO 2 - ; X1是可以具有至少一个羟基的二价，直链或支链的C 1-5脂族基团; X2是三价直链或支链的C 2-5脂族基团; Y1是任选羟基化的一价有机基团; 并且R 1是氢或1-10个碳原子的烷基。

7. 发明申请

US20070245499A1 Fluorine-Containing Urethanes 有权
标题翻译：含氟聚氨酯
公开(公告)号：US20070245499A1
公开(公告)日：2007-10-25
申请号：US11659229
申请日：2005-07-29
申请人： Ikuo Yamamoto , Yutaka Ohira , Shinichi Minami
发明人： Ikuo Yamamoto , Yutaka Ohira , Shinichi Minami
IPC分类号： C07D251/34
CPC分类号： C07D251/34 , Y10T428/1303 , Y10T428/1314 , Y10T428/1362
摘要： Fluorine-containing urethanes represented by the general formula: [Rf-A1-Z-X1—OC(═O)NH—]mI[—NHC(═O)O—Y1]n[—NHC(═O)O—(ClCH2—)X2O)a—R1]k (1) wherein I is a group derived from a polyisocyanate by removal of the isocyanato groups; Rf is perfluoroalkyl of 1 to 21 carbon atoms; A1 is a direct bond or an organic group of 1 to 21 carbon atoms; Z is —S— or —SO2—; X1 is a divalent, straight-chain or branched, C1-5 aliphatic group which may have at least one hydroxyl group; X2 is a trivalent, straight-chain or branched, C2-5 aliphatic group; Y1 is a monovalent organic group which is optionally hydroxylated; and R1 is hydrogen or alkyl of 1 to 10 carbon atoms.
摘要翻译：由以下通式表示的含氟聚氨酯：<？in-line-formula description =“In-line formula”end =“lead”？> [Rf-A 1 -ZX 1 -OC（-O）NH - ] m I [-NHC（-O）O] 1 - [NHC （-O）O-（ClCH 2 - ）X 2 O）a （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中I是通过除去异氰酸酯基团而衍生自多异氰酸酯的基团; Rf是1至21个碳原子的全氟烷基; A 1是直接键或1至21个碳原子的有机基团; Z是-S-或-SO 2 - ; X 1是可以具有至少一个羟基的二价直链或支链C 1-5脂族基团; X 2是三价直链或支链C 2-5脂肪族基团; Y 1是任选羟基化的一价有机基团; 且R 1是氢或1至10个碳原子的烷基。

8. 发明申请

US20110220833A1 FLUOROSILICONES AND FLUORINE- AND SILICON-CONTAINING SURFACE TREATMENT AGENT 有权
标题翻译：氟代氟化物和含氟和含硅表面处理剂
公开(公告)号：US20110220833A1
公开(公告)日：2011-09-15
申请号：US13115572
申请日：2011-05-25
申请人： Ikuo Yamamoto , Shinichi Minami , Tetsuya Masutani , Peter C. Hupfield , Avril E. Surgenor
发明人： Ikuo Yamamoto , Shinichi Minami , Tetsuya Masutani , Peter C. Hupfield , Avril E. Surgenor
IPC分类号： D06M15/657 , C08G77/28
CPC分类号： D06M15/277 , C08F283/122 , C08G77/26 , C08G77/28 , C08G77/442 , D06M15/6436 , D06M15/657 , D06M2200/11 , Y10T428/31663 , Y10T442/60 , C08F220/24 , C08F214/18
摘要： A fluorosilicone reaction product of a mercapto functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a mercapto functional organopolysiloxane.
摘要翻译：公开了巯基官能化有机聚硅氧烷和含氟单体的氟硅酮反应产物及氟硅氧烷的制备方法。氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。氟代硅氧烷反应产物由（A）式CH 2 = C（X）COOYRf的含氟单体和（B）巯基官能的有机聚硅氧烷制备。

9. 发明授权

US09988759B2 Fluorosilicone polymers and surface treatment agent 有权
公开(公告)号：US09988759B2
公开(公告)日：2018-06-05
申请号：US13063809
申请日：2009-09-11
申请人： Shinichi Minami , Takashi Enomoto , Tetsuya Masutani , Masahiro Miyahara , Mitsuhiro Usugaya , Rumi Takeuchi , Ikuo Yamamoto , Peter Cheshire Hupfield
发明人： Shinichi Minami , Takashi Enomoto , Tetsuya Masutani , Masahiro Miyahara , Mitsuhiro Usugaya , Rumi Takeuchi , Ikuo Yamamoto , Peter Cheshire Hupfield
IPC分类号： B32B27/04 , D06M15/643 , C08F283/12 , C08F290/06 , D06M15/277 , D06M15/356
CPC分类号： D06M15/6436 , C08F283/122 , C08F290/068 , D06M15/277 , D06M15/3568 , Y10T442/2172 , C08F220/24 , C08F220/68
摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2═C(—X)—C(═O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.

10. 发明授权

US08197590B2 Fluorine-containing treatment composition 有权
标题翻译：含氟处理组合物
公开(公告)号：US08197590B2
公开(公告)日：2012-06-12
申请号：US11666428
申请日：2005-10-27
申请人： Ikuo Yamamoto , Shinichi Minami
发明人： Ikuo Yamamoto , Shinichi Minami
IPC分类号： C08K5/00 , C08G18/30
CPC分类号： C09K3/18 , C08F220/22 , C08F220/24 , C08F2220/185 , C08G18/2885 , C08G18/792 , C08K5/34924 , C09D133/16 , C09D175/04 , D06M15/277 , D06M15/576 , C08L33/16 , C08L2666/20
摘要： Disclosed is a composition containing a fluorine-containing urethane compound (A) and a fluorine-containing polymer (B) having a repeating unit derived from a fluorine-containing monomer represented by the following formula (I): CH2═C(—X)—C(═O)-A-Rf (I) (wherein X represents a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a CFX1X2 group (wherein X1 and X2 respectively represent a hydrogen atom, a fluorine atom or a chlorine atom), a cyano group, a straight or branched chain fluoroalkyl group having 1-20 carbon atoms, a substituted or unsubstituted benzyl group, or a substituted or unsubstituted phenyl group; A represents a divalent group; and Rf represents a straight or branched chain perfluoroalkyl group having 1-6 carbon atoms).
摘要翻译：公开了含有由下式（I）表示的含氟单体衍生的重复单元的含氟氨基甲酸酯化合物（A）和含氟聚合物（B）的组合物：CH 2 = C（-X） -C（= O）-A-Rf（I）（其中X表示氟原子，氯原子，溴原子，碘原子，CFX1X2基团（其中X1和X2分别表示氢原子，氟原子或氯原子），氰基，具有1-20个碳原子的直链或支链氟代烷基，取代或未取代的苄基或取代或未取代的苯基; A表示二价基团; Rf表示直链或具有1-6个碳原子的支链全氟烷基）。

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