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    • 2. 发明授权
    • Methods of adhesion promoter between low-K layer and underlying insulating layer
    • 低K层和下层绝缘层之间的粘附促进剂的方法
    • US06472335B1
    • 2002-10-29
    • US09175019
    • 1998-10-19
    • Chia-Shiung TsaiYao-Yi ChengHun-Jan Tao
    • Chia-Shiung TsaiYao-Yi ChengHun-Jan Tao
    • H01L2131
    • H01L21/0214H01L21/02118H01L21/022H01L21/02343H01L21/31111H01L21/312H01L21/3122H01L21/3124H01L21/3144H01L21/31629H01L21/3185H01L21/76801Y10S438/906Y10S438/958Y10S438/964
    • The present invention provides a method improving the adhesion between inter metal dielectric (IMD) layers by performing a HF dip etch to treat the surface of an oxide, silicon nitride or Silicon oxynitride insulating layer before an overlying low-K layer is formed. The present invention provides a method of fabricating a low-K IMD layer 20 over an oxide, Silicon oxynitride (SiON), or nitride IMD layer 14 with improved adhesion. First, a 1st inter metal dielectric (IMD) layer 14 is formed over a substrate. Next, the invention's novel HF dip etch is performed on the 1st IMD layer 14 to form a treated surface 16. Next, a 2nd BMD layer composed of a low-K material is formed over the rough surface 16 of the 1st IMD layer 14. The treated surface 16 improves the adhesion between a 1st IMD layer oxide (oxide, SiN or SiON) and a low k layer. Subsequent photoresist strip steps do not cause the 1st IMI layer 14 and the 2nd IMD layer 20 (low-K dielectric) to peel.
    • 本发明提供一种通过在形成上覆低K层之前进行HF浸渍蚀刻来处理氧化物,氮化硅或氮氧化硅绝缘层的表面来改善金属间电介质(IMD)层之间的粘合力的方法。 本发明提供了一种在氧化物,氮氧化硅(SiON)或氮化物IMD层14上制备低K IMD层20的方法,其具有改善的粘合性。 首先,在衬底上形成第一金属间介电层(IMD)层14。 接下来,在第一IMD层14上进行本发明的新型HF浸渍蚀刻以形成处理表面16.接下来,在第一IMD层14的粗糙表面16上形成由低K材料构成的第二BMD层。 经处理的表面16改善了第一IMD层氧化物(氧化物,SiN或SiON)和低k层之间的粘合性。 随后的光刻胶条步骤不会导致第一IMI层14和第二IMD层20(低K电介质)剥离。
    • 4. 发明授权
    • Method for cleaning silicon wafers with deep trenches
    • 用深沟槽清洗硅晶片的方法
    • US6129091A
    • 2000-10-10
    • US725804
    • 1996-10-04
    • Kuei-Ying LeeHun-Jan TaoChia-Shiung Tsai
    • Kuei-Ying LeeHun-Jan TaoChia-Shiung Tsai
    • H01L21/00B08B3/08B08B3/12
    • H01L21/67028
    • Current aqueous methods for removal of polymeric materials from the sidewalls of trenches etched into silicon wafers by reactive-ion-etching are inadequate for treating deep trenches having high aspect ratios. Spin-dry operations performed after the aqueous etching are incapable of completely removing rinse water and ionic species from these deep trenches, thereby leaving pockets of liquid. Subsequent evaporation of these pockets results in the concentration and eventual precipitation of residual ionic species creating watermarks. A two stage cleaning method is described in which the first stage dissolves the sidewall polymer and the second stage draws ionic species strongly chemisorbed onto the silicon surfaces into solution. A key feature of the method is that the wafer surface is not permitted to dry until after the final rinse.
    • 目前的用于通过反应离子蚀刻从蚀刻到硅晶片的沟槽的侧壁上去除聚合材料的水性方法不足以处理具有高纵横比的深沟槽。 在水蚀刻之后执行的旋转干燥操作不能从这些深沟槽中完全去除漂洗水和离子物质,从而留下一些液体。 随后蒸发这些口袋导致产生水印的残留离子物质的浓度和最终沉淀。 描述了两阶段清洗方法,其中第一阶段溶解侧壁聚合物,第二阶段将离子物质强吸附在硅表面上成溶液。 该方法的一个关键特征是晶片表面不允许干燥直到最后冲洗。
    • 5. 发明授权
    • Method for patterning a polysilicon gate with a thin gate oxide in a
polysilicon etcher
    • 在多晶硅蚀刻剂中用薄栅极氧化物图案化多晶硅栅极的方法
    • US6037266A
    • 2000-03-14
    • US161567
    • 1998-09-28
    • Hun-Jan TaoChia-Shiung Tsai
    • Hun-Jan TaoChia-Shiung Tsai
    • H01L21/3213H01L21/00
    • H01L21/32137
    • A method of patterning a polysilicon gate using an oxide hard mask using a novel 4 step insitu etch process. All 4 etch steps are performed insitu in a polysilicon high density plasma (TCP--transformer coupled plasma) etcher. A multi-layered semiconductor structure 35 (FIG. 1) is formed comprising: a substrate 10, a gate oxide layer 14, a polysilicon layer 18, a hard mask layer 22, and a bottom anti-reflective coating (BARC) layer 26 and a resist layer 30. The 4 step insitu etch process comprises:a) in STEP 1, etching the bottom anti-reflective coating (BARC) layer by flowing HBr and O.sub.2 gasses, and applying a first TCP Power and a first Bias power;b) in STEP 2, etching the hard mask by flowing a flouorocarbon gas; and applying a second TCP Power and second Bias power;c) in STEP 3--stripping the bottom anti-reflective coating (BARC) layer by flowing oxygen and applying a third TCP Power and a third Bias power;d) in STEP 4--etching the polysilicon layer by flowing chlorine species, oxygen species; Helium species and bromine gas species and applying a fourth TCP Power and a fourth Bias power.
    • 使用新的4步蚀刻工艺使用氧化物硬掩模图案化多晶硅栅极的方法。 所有4个蚀刻步骤都在多晶硅高密度等离子体(TCP-变压器耦合等离子体)蚀刻器中进行。 形成多层半导体结构35(图1),包括:基板10,栅极氧化物层14,多晶硅层18,硬掩模层22和底部抗反射涂层(BARC)层26和 4步蚀刻工艺包括:a)在步骤1中,通过流过HBr和O2气体并施加第一TCP功率和第一偏压功率蚀刻底部抗反射涂层(BARC)层; b)在步骤2中,通过流动氟碳化物气体来蚀刻硬掩模; 以及施加第二TCP功率和第二偏置功率; c)在步骤3中 - 通过流动氧气并施加第三TCP功率和第三偏压功率来剥离底部抗反射涂层(BARC)层; d)在步骤4中,通过流动氯物质,氧物种蚀刻多晶硅层; 氦物种和溴气物种,并应用第四个TCP电源和第四个偏置电源。
    • 7. 发明授权
    • Plasma etch method for forming patterned layer with enhanced critical dimension (CD) control
    • 用于形成具有增强的临界尺寸(CD)控制的图案层的等离子体蚀刻方法
    • US06620631B1
    • 2003-09-16
    • US09573807
    • 2000-05-18
    • Hun-Jan TaoChia-Shiung TsaiAnthony Yen
    • Hun-Jan TaoChia-Shiung TsaiAnthony Yen
    • H01L21302
    • H01L22/20H01J37/32935
    • Within a method for fabricating a microelectronic fabrication there is first provided a substrate. There is then formed over the substrate a blanket target layer. There is then formed over the blanket target layer a patterned mask layer. There is then measured, while employing an optical method, a linewidth of the patterned mask layer to determine a patterned mask layer measured linewidth. There is then determined a deviation of the patterned mask layer measured linewidth from a patterned mask layer target linewidth. There is then etched, while employing a plasma etch method, the blanket target layer to form a patterned target layer while employing the patterned mask layer as a etch mask layer. Within the method, in conjunction the deviation of the patterned mask layer measured linewidth from the patterned mask layer target linewidth there is adjusted within the plasma etch method at least one plasma etch parameter such that a patterned target layer measured linewidth more closely approximates a patterned target layer target linewidth. Similarly, within the method, the measuring of the patterned mask layer measured linewidth while employing the optical method and the adjusting within the plasma etch method of the at least one plasma etch parameter are undertaken in-situ for each substrate within a series of substrates fabricated while employing the plasma etch method. Within a second embodiment of the present invention a blanket target layer thickness is measured while employing an optical method rather than a patterned masking layer linewidth.
    • 在微电子制造的制造方法中,首先提供基板。 然后在衬底上形成覆盖目标层。 然后在毯状目标层上形成图案化的掩模层。 然后在采用光学方法时,测量图案化掩模层的线宽以确定图案化掩模层测量的线宽。 然后确定图案化掩模层测量的线宽与图案化掩模层目标线宽的偏差。 然后在采用等离子体蚀刻方法的同时蚀刻该覆盖层目标层以形成图案化目标层,同时采用图案化掩模层作为蚀刻掩模层。 在该方法中,结合图案化掩模层测量的线宽与图案化掩模层目标线宽的偏差,在等离子体蚀刻方法内调节至少一个等离子体蚀刻参数,使得图案化目标层测量的线宽更接近于图案化靶 层目标线宽。 类似地,在该方法中,在使用光学方法的同时测量线状图案测量线性以及等离子体蚀刻方法内的至少一种等离子体蚀刻参数的调整是在一系列衬底内的每个衬底的原位进行的 同时采用等离子体蚀刻方法。 在本发明的第二实施例中,使用光学方法而不是图案化掩蔽层线宽来测量覆盖目标层厚度。
    • 8. 发明授权
    • In situ dry etching procedure to form a borderless contact hole
    • 原位干蚀刻工艺形成无边界接触孔
    • US06497993B1
    • 2002-12-24
    • US09614010
    • 2000-07-11
    • Yuan-Hunh ChiuHun-Jan TaoChia-Shiung TsaiChu-Yun Fu
    • Yuan-Hunh ChiuHun-Jan TaoChia-Shiung TsaiChu-Yun Fu
    • G03F736
    • H01L21/76802H01L21/31116
    • A process for forming a contact hole opening, featuring the use in situ dry etching, and photoresist removal procedures, used to define the desired contact hole opening; in an overlying hard mask layer, in the dielectric layer, and in an underlying insulator stop layer, has been developed. The process features the initial definition of the contact hole opening, in an overlying hard mask insulator layer, accomplished in a chamber of a dry etch tool, followed by removal of an overlying, contact hole defining photoresist shape, performed in situ, in the same dry etch chamber. The contact hole opening is then transferred to the dielectric layer via a selective dry etch procedure, performed in situ, in the dry etch chamber, using the overlying hard mask insulator layer as an etch mask. A final dry etch procedure is then performed in situ, in the same dry etch chamber, to form the contact hole opening in the underlying insulator stop layer, with the final dry etch procedure also resulting in the removal of the exposed hard mask insulator layer, thus creating the desired contact hole opening in a dielectric layer, and in the underlying insulator stop layer.
    • 用于形成接触孔开口的方法,其特征在于使用原位干蚀刻和光致抗蚀剂去除程序,用于限定所需的接触孔开口; 在覆盖的硬掩模层,电介质层和下面的绝缘体停止层中已经开发出来。 该方法具有接触孔开口的初始定义,在覆盖的硬掩模绝缘体层中,在干蚀刻工具的腔室中完成,随后除去在相同的位置原位执行限定光致抗蚀剂形状的上覆接触孔 干蚀刻室。 接触孔开口然后通过选择性干蚀刻方法,在干蚀刻室中原位进行,使用覆盖的硬掩模绝缘体层作为蚀刻掩模转移到电介质层。 然后在相同的干蚀刻室中原位进行最终的干蚀刻工艺,以在下面的绝缘体停止层中形成接触孔开口,最终的干法蚀刻程序也导致暴露的硬掩模绝缘体层的去除, 从而在电介质层中和在下面的绝缘体停止层中产生所需的接触孔开口。
    • 10. 发明授权
    • Post photodevelopment isotropic radiation treatment method for forming patterned photoresist layer with attenuated linewidth
    • 用于形成具有衰减线宽的图案化光致抗蚀剂层的后期光致发展各向同性辐射处理方法
    • US06183937B2
    • 2001-02-06
    • US09072997
    • 1998-05-06
    • Chia-Shiung TsaiHun-Jan Tao
    • Chia-Shiung TsaiHun-Jan Tao
    • G03F700
    • G03F7/2024G03F7/0045G03F7/40
    • A method for forming a patterned photoresist layer. There is first provided a substrate employed within a microelectronics fabrication. There is then formed over the substrate a blanket photoresist layer. There is then photoexposed and developed the blanket photoresist layer to form a patterned photoresist layer having a first linewidth. There is then irradiated isotropically the patterned photoresist layer with an isotropic radiation source to decompose a conformal surface layer of the patterned photoresist layer while simultaneously forming a conformal surface layer decomposed patterned photoresist layer having a second linewidth narrower than first linewidth. The conformal surface layer decomposed patterned photoresist layer may then be employed as an etch mask layer when etching a blanket microelectronics layer formed interposed between the substrate and the conformal surface layer decomposed patterned photoresist layer. Through the method there may be formed a patterned microelectronics layer of narrow linewidth without employing an advanced photoexposure apparatus.
    • 一种形成图案化光致抗蚀剂层的方法。 首先提供了在微电子制造中使用的衬底。 然后在衬底上形成覆盖光致抗蚀剂层。 然后照射曝光并显影覆盖光致抗蚀剂层以形成具有第一线宽的图案化光致抗蚀剂层。 然后将具有各向同性辐射源的图案化光致抗蚀剂层各向同性地照射,以分解图案化光致抗蚀剂层的共形表面层,同时形成具有比第一线宽窄的第二线宽的共形表面层分解的图案化光致抗蚀剂层。 然后当蚀刻形成在介于基底和保形表面层分解的图案化光致抗蚀剂层之间的覆盖微电子层时,共形表面层分解的图案化光致抗蚀剂层可用作蚀刻掩模层。 通过该方法,可以形成窄线宽的图案化微电子学层,而不使用先进的曝光装置。