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    • 1. 发明授权
    • Method for producing light conducting fibers
    • 光导纤维的制造方法
    • US4141710A
    • 1979-02-27
    • US815911
    • 1977-07-15
    • Hubert AulichHans PinkJosef Grabmaier
    • Hubert AulichHans PinkJosef Grabmaier
    • C03B37/014C03B37/016C03B37/027C03B37/03C03C25/10G02B6/00C03C25/02
    • C03B37/016C03B37/02736C03B37/032C03C25/106
    • A method of producing a light conducting fiber comprises the steps of providing a base member of an optical material such as glass or a synthetic glass-like material, depositing at least one optical material forming layer such as a glass forming layer or a synthetic glass-like material forming layer from a liquid phase on a surface of the base member and subsequently transforming each of the layers into a film of optical material such as a glass film or a synthetic glass-like film. The base member may be a glass tube and the optical material forming layers may be deposited on an interior surface and after the layers have been transformed into a film, the tube is collapsed into a rod and then subsequently drawn into a cladded light conducting fiber. In one embodiment of the invention, the base member is a rod and the layers are deposited on a surface of the rod which is subsequently drawn into a cladded light conducting fiber. In yet another embodiment of the invention, the base member is provided by drawing a core of an optical fiber and the method includes depositing the optical material forming layers on the core so that as the layers are transformed into the film of optical material, a cladded light conducting fiber will be produced.
    • 制造导光纤维的方法包括以下步骤:提供诸如玻璃或合成玻璃状材料的光学材料的基底,沉积至少一种光学材料形成层,例如玻璃形成层或合成玻璃 - 并且随后将各层转化为诸如玻璃膜或合成玻璃状膜的光学材料的膜。 基底构件可以是玻璃管,并且光学材料形成层可以沉积在内表面上,并且在层已经变成膜之后,管被折叠成棒,然后被拉入包覆的导光纤维中。 在本发明的一个实施例中,基部构件是杆,并且这些层沉积在杆的表面上,随后将其拉制成包覆的导光纤维。 在本发明的另一个实施例中,通过拉制光纤的芯来提供基底构件,该方法包括在芯上沉积光学材料形成层,使得当层被转变成光学材料的膜时, 将生产光导纤维。
    • 2. 发明授权
    • Crucible for the production of single-material light-guiding fibers
    • 可用于生产单一材料导光纤维
    • US4131447A
    • 1978-12-26
    • US761267
    • 1977-01-21
    • Hubert AulichJosef Grabmaier
    • Hubert AulichJosef Grabmaier
    • C03B37/023C03B5/26C03B37/00
    • C03B37/023C03B2203/10C03B2203/12C03B2203/14
    • A method for the production of single-material light-guiding fibers which have a core supported in a glass sheath in a cantilever manner by glass webs characterized by providing a crucible having an exit nozzle with an opening having a configuration of the cross section of the light-guiding fiber with a core portion connected by web portions to a surrounding annular portion, providing molten material of the light-guiding fiber in the crucible, drawing the molten material from the crucible through the exit nozzle to form a continuous integral workpiece having a core portion supported in a glass sheath in a cantilever manner by integral glass webs and continuously drawing the integral workpiece into the single-material light-guiding fiber. The crucible is formed by a pair of hollow bodies supported in an outer cylindrical member in a cantilever manner so that the cylindrical member and the pair of hollow bodies form the exit nozzle with the desired configuration.
    • 一种用于生产单材料导光纤维的方法,其具有以悬臂方式由玻璃纤维网支撑在玻璃护套中的芯,其特征在于提供具有出口喷嘴的坩埚,所述出口具有开口,所述开口具有截面形状 导光纤维,其芯部通过腹板部分连接到周围的环形部分,将导光纤维的熔融材料提供在坩埚中,通过出口喷嘴从坩埚中抽出熔融材料,形成具有 芯部通过一体的玻璃腹板以悬臂方式支撑在玻璃护套中,并将整体工件连续地拉入单材料光导纤维中。 该坩埚由悬臂式支撑在外圆柱形构件中的一对中空体形成,使得圆柱形构件和一对中空体以期望的构造形成出口喷嘴。
    • 5. 发明授权
    • Device for drawing a group of cladded light conducting fibers
    • 用于绘制一组包覆光导纤维的装置
    • US4193782A
    • 1980-03-18
    • US924176
    • 1978-07-13
    • Hubert AulichJosef GrabmaierKarl-Heinz Eisenrith
    • Hubert AulichJosef GrabmaierKarl-Heinz Eisenrith
    • C03B37/023G02B6/00G02B6/44C03B37/02
    • C03B37/023G02B6/4486C03B2203/34Y02P40/57
    • A device for drawing a plurality of cladded light conducting fibers utilizing a double crucible having an inner crucible and an outer crucible with each of the crucibles having a bottom and receiving a melt of the respective material, and having nozzle pairs with the nozzle of the inner crucible being aligned axially with the nozzle of the outer crucible, the device including a device for gathering the pulled fibers to form a bundle and for coating the pulled cladded fibers characterized by the nozzles being exclusively arranged at points on the bottoms of their respective crucibles where the same temperature prevails for the glass melt present in the double crucibles. To accomplish this, the nozzles are located between and equal distance from the parallel boundary lines of the bottom of the inner crucible so that the melt drawn through the nozzle travels the same distance in all directions. The device for gathering is a coating cuvette, which is preferably formed of two longitudinal halves which can be moved transversely to the direction of movement of the fibers to facilitate threading the fibers into the cuvette.
    • 一种利用具有内坩埚和外坩埚的双坩埚绘制多个包层导光纤的装置,每个坩埚具有底部并接收各个材料的熔体,并且具有与内部的喷嘴的喷嘴对 坩埚与外坩埚的喷嘴轴向对准,该装置包括用于收集拉动的纤维以形成束并用于涂覆拉伸的包覆纤维的装置,其特征在于喷嘴专门设置在它们各自坩埚的底部的点处, 对于双坩埚中存在的玻璃熔体,温度相同。 为了实现这一点,喷嘴位于与内坩埚的底部的平行边界线之间等距离处,使得通过喷嘴拉出的熔体在所有方向上行进相同的距离。 用于聚集的装置是涂层试管,其优选地由两个纵向半部形成,其可以横向于纤维的运动方向移动,以便于将纤维穿入比色皿。
    • 8. 发明授权
    • Apparatus and method for producing light conducting fibers having a core
disposed in a loose fitting cladding tube
    • 用于制造具有设置在松配合包层管中的芯的导光纤维的装置和方法
    • US4133664A
    • 1979-01-09
    • US810760
    • 1977-06-28
    • Hubert AulichJosef GrabmaierKarl-Heinz Eisenrith
    • Hubert AulichJosef GrabmaierKarl-Heinz Eisenrith
    • C03B37/023C03B37/02
    • C03B37/023
    • A method and apparatus for producing a light conducting fiber having a core disposed in a loose fitting cladding tube characterized by a double crucible arrangement having a first crucible for a melt of the material for the cladding tube and a second crucible for the melt of the material of the core. The second crucible has an orifice of a given diameter and the first crucible has a ring-shaped orifice with an inner diameter greater than the given diameter of the orifice of the second crucible with the center of the ring-shaped orifice being arranged substantially on a central axis of the orifice of the second crucible so that a core drawn from the orifice of the second crucible is substantially concentrically disposed within the tube of material drawn from the ring-shaped orifice. In each embodiment of the apparatus, the first crucible is an annular crucible having a ring-shaped cross section and the second crucible is either disposed above the first crucible so that the core drawn from the second crucible passes through a hollow passage or is disposed in the central space either with spacing from the walls of the first crucible or with the inner wall of the first crucible forming the wall of the second crucible. Preferably, an inert gas is injected between the core and the tube to prevent collapsing of the tube during the drawing of the fiber.
    • 一种用于制造导光纤维的方法和装置,其具有设置在松配套包层管中的芯,其特征在于具有用于熔化包覆管的材料的第一坩埚和用于熔化材料的第二坩埚的双坩埚布置 的核心。 第二坩埚具有给定直径的孔,并且第一坩埚具有环形孔,其内径大于第二坩埚的孔的给定直径,其中环形孔的中心基本上设置在第二坩埚上 第二坩埚的孔口的中心轴线,使得从第二坩埚的孔口拉出的芯体基本上同心地设置在从环形孔口抽出的材料管内。 在装置的每个实施例中,第一坩埚是具有环形横截面的环形坩埚,第二坩埚被设置在第一坩埚上方,使得从第二坩埚抽出的芯通过中空通道或者设置在 中心空间与第一坩埚的壁间隔开,或与第一坩埚的内壁形成第二坩埚的壁。 优选地,在芯和管之间注入惰性气体,以防止在拉伸纤维期间管的塌缩。
    • 10. 发明授权
    • Method for producing high purity Si for solar cells
    • 生产太阳能电池高纯度硅的方法
    • US4460556A
    • 1984-07-17
    • US486685
    • 1983-04-20
    • Hubert AulichKarl-Heinz EisenrithFriedrich-Wilhelm SchulzeHans-Peter Urbach
    • Hubert AulichKarl-Heinz EisenrithFriedrich-Wilhelm SchulzeHans-Peter Urbach
    • C01B31/02C01B31/04C01B33/025C01B33/02
    • C01B33/025
    • Highly purified starting materials for the production of silicon suitable for fabrication of solar cells are produced via the carbo-thermal reduction process. A carbon-containing material with impurities therein, either by itself or admixed with glass bodies, which are attained from a melt of quartz sand and glass-forming additives formed into a fiber form and pulverized, is converted into a granulate form with the aid of a bonding agent. The resultant granulates are contacted with a hot inorganic acid, such as 3N HCl at about 90.degree. C., to extract substantially all impurities from the granulates, which can be in pellet or tablet form. The resultant purified pellets are then directly charged into an electrical arc furnace to yield solar-quality silicon. With this process, highly purified SiO.sub.2 and highly purified carbon are produced in a simple and cheap manner. The impurity level for boron, phosphorus and transition metal in these starting materials is less than about 10 ppm.
    • 通过碳热还原法生产用于制造适合太阳能电池制造的硅的高纯度原料。 其中具有杂质的含碳材料本身或与玻璃体混合,其由石英砂的熔体和形成纤维形式并粉碎的玻璃形成添加剂获得,借助于 粘合剂。 将得到的颗粒与热无机酸如3N HCl在约90℃下接触,以从颗粒中提取基本上所有的杂质,其可以是颗粒或片剂形式。 然后将所得纯化的颗粒直接装入电弧炉中以产生太阳质量的硅。 通过这种方法,以简单且便宜的方式生产高纯度的SiO 2和高度纯化的碳。 这些原料中硼,磷和过渡金属的杂质含量低于约10ppm。