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1. 发明授权

US07091387B2 Process to convert alkanes into primary alcohols 有权
标题翻译：将烷烃转化成伯醇的方法
公开(公告)号：US07091387B2
公开(公告)日：2006-08-15
申请号：US11109552
申请日：2005-04-19
申请人： Howard Lam-Ho Fong , Lizbeth Olivia Cisneros Trevino , Brendan Dermot Murray , Manuel Luis Cano
发明人： Howard Lam-Ho Fong , Lizbeth Olivia Cisneros Trevino , Brendan Dermot Murray , Manuel Luis Cano
IPC分类号： C07C29/48 , C07C29/62 , C07C29/68
CPC分类号： C07C17/358 , B01J23/42 , B01J23/56 , B01J23/626 , B01J23/6447 , B01J23/745 , C01B7/01 , C01B7/096 , C07C17/10 , C07C17/23 , C07C29/124 , C12C11/02 , C07C19/01 , C07C19/075 , C07C31/125
摘要： This invention provides a process to convert alkanes to primary alcohols of the same carbon number. Carbon numbers of particular interest are C8 to C18. The process comprises the steps of: a) halogenating a linear or branched (or mixture of linear and branched) alkane to produce a mixture of primary mono-haloalkanes, internal mono-haloalkanes, unreacted alkanes, hydrogen halide, and possibly multi-haloalkanes in the presence of a catalyst and/or by heating the reaction mixture; b) separating the hydrogen halide from the mixture and optionally neutralizing it with a metal oxide to produce a partially halogenated metal oxide and/or metal halide which may be regenerated; c) separating the primary mono-haloalkanes from the mixture; d) reacting the separated primary mono-haloalkanes in a reactor with a metal oxide or combination of metal oxides and water to convert the aforesaid primary mono-haloalkane to a mixture of products that contains primary alcohols, unconverted primary mono-haloalkanes, and possibly other reaction products, and a partially halogenated metal oxide and/or metal halide which may be regenerated; e) regenerating the partially halogenated metal oxide and/or metal halide to halogen (such as Cl2) and/or acid and a metal oxide for recycle by reaction with air or oxygen; and f) removing the unreacted primary mono-haloalkane from the reaction mixture and then purifying the primary alcohol.
摘要翻译：本发明提供了将烷烃转化为相同碳数的伯醇的方法。特别感兴趣的碳数为C 8至C 18。该方法包括以下步骤：a）将直链或支链（或直链和支链的）混合物卤化以产生主要单卤代烷烃，内部单卤代烷烃，未反应的烷烃，卤化氢和可能的多卤代烷烃的混合物催化剂的存在和/或通过加热反应混合物; b）从混合物中分离卤化氢并任选地用金属氧化物中和它以产生可再生的部分卤化的金属氧化物和/或金属卤化物; c）从混合物中分离初级单卤代烷烃; d）将反应器中分离的主要单卤代烷烃与金属氧化物或金属氧化物和水的组合反应，将上述初级单卤代链烷烃转化为含有伯醇，未转化的主要单卤代烷烃和可能的其它产物的混合物反应产物和可再生的部分卤化的金属氧化物和/或金属卤化物; e）将部分卤化的金属氧化物和/或金属卤化物再生成卤素（例如Cl 2 H 2）和/或酸和金属氧化物，以通过与空气或氧气反应再循环; 和f）从反应混合物中除去未反应的主要单卤代链烷烃，然后纯化伯醇。

2. 发明授权

US07462752B2 Process to convert linear alkanes into alpha olefins 失效
标题翻译：将线性烷烃转化为α-烯烃的方法
公开(公告)号：US07462752B2
公开(公告)日：2008-12-09
申请号：US11109551
申请日：2005-04-19
申请人： Howard Lam-Ho Fong , Lizbeth Olivia Cisneros Trevino , Brendan Dermot Murray , Manuel Luis Cano
发明人： Howard Lam-Ho Fong , Lizbeth Olivia Cisneros Trevino , Brendan Dermot Murray , Manuel Luis Cano
IPC分类号： C07C1/26
CPC分类号： C07C29/124 , C07C1/30 , C07C11/02 , C07C17/10 , C07C17/358 , C07C17/37 , C07C2521/10 , C07C2521/14 , C07C2523/14 , C07C2523/44 , C07C2523/745 , C07C2523/78 , C07C19/075 , C07C19/01 , C07C31/125
摘要： This invention provides for a process to convert branched or linear alkanes to branched or linear alpha olefins (AO) of the same carbon number. The process comprises the steps of: a) halogenating linear alkanes, branched alkanes, or a mixture of linear and branched alkane to produce a mixture containing primary mono-haloalkanes and hydrogen halide; b) separating the hydrogen halide from the mixture and optionally neutralizing it with a metal oxide to produce a partially halogenated metal oxide and/or metal halide which may be regenerated; c) separating the primary mono-haloalkanes from the mixture; d) reacting the separated primary mono-haloalkanes with a metal oxide to produce a mixture of products that contains alpha olefins, unconverted primary mono-haloalkanes, possibly other reaction products, and a partially halogenated metal oxide and/or metal halide which may be regenerated; e) regenerating the partially halogenated metal oxide and/or metal halide to halogen and/or acid and a metal oxide (such as Cl2) for recycle by reaction with air or oxygen ; and f) removing the unreacted primary mono-haloalkane from the reaction mixture and then purifying the alpha olefin.
摘要翻译：本发明提供将支链或直链烷烃转化为相同碳数的支链或直链α-烯烃（AO）的方法。该方法包括以下步骤：a）将直链烷烃，支链烷烃或直链和支链烷烃的混合物卤化以产生含有主要单卤代烷烃和卤化氢的混合物; b）从混合物中分离卤化氢并任选地用金属氧化物中和它以产生可再生的部分卤化的金属氧化物和/或金属卤化物; c）从混合物中分离初级单卤代烷烃; d）使分离的初级单卤代烷烃与金属氧化物反应以产生含有α-烯烃，未转化的初级单卤代烷烃，可能的其它反应产物和可再生的部分卤化的金属氧化物和/或金属卤化物的产物的混合物 ; e）将部分卤化的金属氧化物和/或金属卤化物再生成卤素和/或酸和金属氧化物（例如Cl 2），以通过与空气或氧气反应再循环; 和f）从反应混合物中除去未反应的主要单卤代烷烃，然后纯化α-烯烃。

3. 发明授权

US08115039B2 Catalytic distillation process for primary haloalkanes 失效
标题翻译：主要卤代烷烃的催化蒸馏方法
公开(公告)号：US08115039B2
公开(公告)日：2012-02-14
申请号：US11887195
申请日：2006-03-24
申请人： Howard Lam-Ho Fong , Brendan Dermot Murray , Thomas Carl Semple
发明人： Howard Lam-Ho Fong , Brendan Dermot Murray , Thomas Carl Semple
IPC分类号： C07C21/00
CPC分类号： C07C17/23 , A61K8/20 , A61Q17/04 , C07C17/10 , C07C17/358 , C07C17/383 , C07C41/16 , C11D1/72 , C11D11/0082 , Y02P20/127 , C07C19/075 , C07C43/04
摘要： A process for making primary haloalkanes by catalytic distillation of internal haloalkanes which comprises a) introducing an internal haloalkane feed into a catalytic distillation column; b) isomerizing at least a portion of the internal haloalkane feed in the presence of an internal haloalkane isomerization catalyst at a temperature at or above the boiling point of the internal haloalkanes and below the temperature and pressure at which hydrogen halide is formed to form primary haloalkanes; and removing the primary haloalkanes from the catalytic distillation column.
摘要翻译：通过内部卤代烷烃的催化蒸馏制备主要卤代烷烃的方法，其包括：a）将内部卤代烷烃进料引入催化蒸馏塔; b）在内部卤代烷烃异构化催化剂的存在下，在内部卤代烷烃的沸点或高于内部卤代烷的沸点的温度和低于形成卤化氢的温度和压力下形成主要的卤代烷烃，异构化内部卤代烷烃进料的至少一部分 ; 并从催化蒸馏塔中除去主卤代烷烃。

4. 发明申请

US20090032437A1 Catalytic Distillation Process for Primary Haloalkanes 失效
标题翻译：主要卤代烷烃的催化蒸馏工艺
公开(公告)号：US20090032437A1
公开(公告)日：2009-02-05
申请号：US11887195
申请日：2006-03-24
申请人： Howard Lam-Ho Fong , Brendan Dermot Murray , Thomas Carl Semple
发明人： Howard Lam-Ho Fong , Brendan Dermot Murray , Thomas Carl Semple
IPC分类号： C10G65/02 , C07C19/075
CPC分类号： C07C17/23 , A61K8/20 , A61Q17/04 , C07C17/10 , C07C17/358 , C07C17/383 , C07C41/16 , C11D1/72 , C11D11/0082 , Y02P20/127 , C07C19/075 , C07C43/04
摘要： A process for making primary haloalkanes by catalytic distillation of internal haloalkanes which comprises a) introducing an internal haloalkane feed into a catalytic distillation column; b) isomerizing at least a portion of the internal haloalkane feed in the presence of an internal haloalkane isomerization catalyst at a temperature at or above the boiling point of the internal haloalkanes and below the temperature and pressure at which hydrogen halide is formed to form primary haloalkanes; and removing the primary haloalkanes from the catalytic distillation column.
摘要翻译：通过内部卤代烷烃的催化蒸馏制备主要卤代烷烃的方法，其包括：a）将内部卤代烷烃进料引入催化蒸馏塔; b）在内部卤代烷烃异构化催化剂的存在下，在内部卤代烷烃的沸点或高于内部卤代烷的沸点的温度和低于形成卤化氢的温度和压力下形成主要的卤代烷烃，异构化内部卤代烷烃进料的至少一部分 ; 并从催化蒸馏塔中除去主卤代烷烃。

5. 发明授权

US06271434B1 Process for separating linear alpha olefins from a crude stream containing saturated hydrocarbons, internal olefins, branched olefins, and linear alpha olefins 失效
标题翻译：从含有饱和烃，内烯烃，支链烯烃和直链α-烯烃的粗流中分离线性α-烯烃的方法
公开(公告)号：US06271434B1
公开(公告)日：2001-08-07
申请号：US09379090
申请日：1999-08-23
申请人： Lynn Henry Slaugh , Howard Lam-Ho Fong , Laurent Alain Fenouil
发明人： Lynn Henry Slaugh , Howard Lam-Ho Fong , Laurent Alain Fenouil
IPC分类号： C07C700
CPC分类号： C07C7/152 , C07C1/0485
摘要： This invention relates to a process for separating and isolating saturated hydrocarbons from olefins, and in particular, to a process for separating and isolating saturated hydrocarbons from olefins in a Fisher-Tropsch stream, and thereafter treating the olefins to separate linear alpha olefins from internal olefins. There is provided a process for separating olefins from saturated hydrocarbons in a feedstock, comprising: a) contacting a feedstock comprising olefins and saturated hydrocarbons, such as paraffins, with a linear polyaromatic compound under conditions effective to form a reaction mixture comprising linear polyaromatic compound-olefin adducts and saturated hydrocarbons; b) separating the linear polyaromatic compound-olefin adducts from the saturated hydrocarbons in the reaction mixture to form a saturated hydrocarbon stream and an adducted olefin stream; c) dissociating the linear polyaromatic compound-olefin adducts to form linear polyaromatic compounds and an olefin composition; and optionally d) separating the linear polyaromatic compound formed in step c) from the olefin composition; whereby the olefin composition is enriched in the concentration of olefins over the concentration of olefins in the feedstock and the saturated hydrocarbon stream is enriched in saturated hydrocarbons over the concentration of saturated hydrocarbons in the feedstock.
摘要翻译：本发明涉及从烯烃中分离和分离饱和烃的方法，特别涉及在费 - 托流中从烯烃中分离和分离饱和烃的方法，然后处理烯烃以从烯烃中分离出直链α-烯烃。提供了一种用于在原料中从饱和烃分离烯烃的方法，其包括：a）在有效形成包含线型多芳族化合物的反应混合物的条件下，将包含烯烃和饱和烃（如链烷烃）的原料与线性多芳族化合物接触，烯烃加合物和饱和烃; b）从反应混合物中的饱和烃中分离线性多芳族化合物 - 烯烃加合物以形成饱和烃流和加合烯烃流; c）使线性多芳族化合物 - 烯烃加合物解离以形成线性多芳族化合物和烯烃组合物; 和任选地）将步骤c）中形成的线型多芳族化合物与烯烃组合物分离;由此烯烃组合物富含烯烃浓度超过原料中烯烃的浓度，饱和烃流富含饱和烃浓度超过浓度的原料中的饱和烃。

6. 发明授权

US5777182A Cobalt-catalyzed process for preparing 1,3-propanidiol 失效
标题翻译：用于制备1,3-丙二醇的钴催化方法
公开(公告)号：US5777182A
公开(公告)日：1998-07-07
申请号：US703295
申请日：1996-08-26
申请人： Joseph Broun Powell , Lynn Henry Slaugh , Thomas Clayton Forschner , Jiang-Jen Lin , Terry Blane Thomason , Paul Richard Weider , Thomas Carl Semple , Juan Pedro Arhancet , Howard Lam-Ho Fong , Stephen Blake Mullin , Kevin Dale Allen , David Cleve Eubanks , David William Johnson
发明人： Joseph Broun Powell , Lynn Henry Slaugh , Thomas Clayton Forschner , Jiang-Jen Lin , Terry Blane Thomason , Paul Richard Weider , Thomas Carl Semple , Juan Pedro Arhancet , Howard Lam-Ho Fong , Stephen Blake Mullin , Kevin Dale Allen , David Cleve Eubanks , David William Johnson
IPC分类号： C07C29/141 , C07C45/58 , C07C45/80 , C07C27/04
CPC分类号： C07C45/58 , C07C29/141 , C07C45/80
摘要： 1,3-propanediol is prepared in a process which involves hydroformylating ethylene oxide: (a) in an essentially non-water-miscible solvent in the presence of a non-ligated cobalt catalyst and a catalyst promoter at a temperature within the range of about 50.degree. to about 100.degree. C. and a pressure within the range of about 500 to about 5000 psig, to produce an intermediate product mixture comprising less than about 15 wt % 3-hydroxypropanal; (b) adding an aqueous liquid and extracting at a temperature less than about 100.degree. C. the 3-hydroxypropanal to provide an aqueous phase comprising 3-hydroxypropanal in greater concentration than the concentration of 3-hydroxypropanal in said intermediate product mixture, and an organic phase comprising the cobalt catalyst; (c) separating the aqueous phase from the organic phase; (d) hydrogenating the 3-hydroxypropanal to provide a hydrogenation product mixture comprising 1,3-propanediol; and (e) recovering 1,3-propanediol from said hydrogenation product mixture. The process enables the production of 1,3-propanediol in high yields and selectivity without the use of a phosphine ligand-modified cobalt catalyst.
摘要翻译： 1,3-丙二醇的制备方法包括在环氧乙烷中加氢甲酰化：（a）在非连接的钴催化剂和催化剂助催化剂存在下，在基本上与水不混溶的溶剂中，温度范围为约 50℃至约100℃，压力范围为约500至约5000psig，以产生包含小于约15重量％的3-羟基丙醛的中间产物混合物; （b）加入水性液体并在低于约100℃的温度下提取3-羟基丙醛，以提供比所述中间产物混合物中3-羟基丙醛浓度更高浓度的3-羟基丙醛的水相，以及包含钴催化剂的有机相; （c）将水相与有机相分离; （d）氢化3-羟基丙醛以提供包含1,3-丙二醇的氢化产物混合物; 和（e）从所述氢化产物混合物中回收1,3-丙二醇。该方法能够以高产率和选择性生产1,3-丙二醇，而不需要使用膦配体改性的钴催化剂。

7. 发明授权

US06175050B1 Process for separating functionalized alpha olefins from functionalized internal olefins 失效
标题翻译：从功能化内烯中分离官能化的α-烯烃的方法
公开(公告)号：US06175050B1
公开(公告)日：2001-01-16
申请号：US09310054
申请日：1999-05-11
申请人： Lynn Henry Slaugh , Laurent Alain Fenouil , Howard Lam-Ho Fong
发明人： Lynn Henry Slaugh , Laurent Alain Fenouil , Howard Lam-Ho Fong
IPC分类号： C07C700
CPC分类号： C07C45/85 , C07C29/92 , C07C49/203 , C07C31/125 , C07C33/025
摘要： This invention relates to a process for separating functionalized alpha olefins from functionalized internal olefins. The process achieves by a step of contacting a feedstock containing functionalized alpha olefins and functionalized internal olefins with a linear polyaromatic compound to form a linear polyaromatic compound-functionalized alpha olefin adduct and a step of dissociating the linear polyaromatic compound-functionalized alpha olefin adduct to form linear polyaromatic compounds and a functionalized alpha olefin composition.
摘要翻译：本发明涉及从功能化内烯中分离官能化的α-烯烃的方法。该方法通过使包含官能化的α-烯烃和官能化的内烯烃的原料与线性聚芳族化合物接触以形成线性聚芳香族化合物官能化的α-烯烃加合物的步骤和将线性多芳族化合物官能化的α-烯烃加合物解离形成的步骤线性聚芳族化合物和官能化的α-烯烃组合物。

8. 发明授权

US5936136A Process for separating linear alpha olefins from 2 branched and/or3-branched alpha olefins 失效
标题翻译：从2支支链和/或3-支链α-烯烃分离线性α-烯烃的方法
公开(公告)号：US5936136A
公开(公告)日：1999-08-10
申请号：US876822
申请日：1997-06-16
申请人： Lynn Henry Slaugh , Howard Lam-Ho Fong , Laurent Alain Fenouil
发明人： Lynn Henry Slaugh , Howard Lam-Ho Fong , Laurent Alain Fenouil
IPC分类号： C07C7/152 , C07C7/00
CPC分类号： C07C7/152
摘要： Linear alpha olefins are separated from 2-branched alpha olefins and/or 3-branched alpha olefins. A feedstock of linear alpha olefins, branched alpha olefins, and internal olefins is converted to a linear alpha olefin composition having a lower concentration of branched alpha olefins than present in the feedstock bya) contacting the feedstock with anthracene under conditions effective to form a reaction mixture comprising an anthracene-linear alpha olefin adduct;b) separating the anthracene-linear alpha olefin adduct from the reaction mixture;c) disassociating the anthracene-linear alpha olefin adduct to form anthracene and a linear alpha olefin composition, andd) separating the anthracene formed in step c) from a linear alpha olefin composition.
摘要翻译：线性α-烯烃与2-支链α-烯烃和/或3-支链α-烯烃分离。直链α-烯烃，支链α-烯烃和内烯烃的原料转化为具有比原料中存在的较低浓度的支链α-烯烃的直链α-烯烃组合物，其方法是：a）在有效形成反应的条件下使原料与蒽接触包含蒽 - 线性α-烯烃加合物的混合物; b）从反应混合物中分离出蒽 - 线性α-烯烃加合物; c）使所述蒽 - 线性α-烯烃加合物分离形成蒽和线性α-烯烃组合物，和d）将步骤c）中形成的蒽与直链α-烯烃组合物分离。

9. 发明申请

US20090270655A1 Conversion of Alkylhalides Into Alcohol Alkoxylates 审中-公开
标题翻译：烷基卤转化为醇烷氧基化物
公开(公告)号：US20090270655A1
公开(公告)日：2009-10-29
申请号：US11887194
申请日：2006-03-24
申请人： Howard Lam-Ho Fong , Thomas Howard Johnson , Thomas Carl Semple
发明人： Howard Lam-Ho Fong , Thomas Howard Johnson , Thomas Carl Semple
IPC分类号： C07C41/01
CPC分类号： A61Q17/04 , A61K8/39 , C07C41/16 , C11D1/72 , C11D11/04 , C07C43/15 , C07C43/11
摘要： A process for converting alkyl halides to alkyl alcohol alkoxylates is described. This is a direct alkoxylation because the alkyl alcohol alkoxylates are made without going through an alkyl alcohol intermediate. The process comprises direct alkoxylation coupling of alkyl halides with a nucleophilic material in the presence of a homogeneous catalyst system to produce alkyl alcohol alkoxylates, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds. A process for converting alkanes (paraffins) to alkyl alcohol alkoxylates is also described. This method comprises a) halogenation of at least one alkane to produce at least one alkyl halide; and b) direct alkoxylation coupling of at least a portion of the alkyl halide with a nucleophilic material in the presence of a homogeneous catalyst system to produce alkyl alcohol alkoxylates, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds.
摘要翻译：描述了将烷基卤转化为烷基醇烷氧基化物的方法。这是直接烷氧基化，因为烷基醇烷氧基化物不经过烷基醇中间体而制备。该方法包括在均相催化剂体系存在下烷基卤与亲核材料的直接烷氧基化偶合以产生烷基醇烷氧基化物，其中均相催化剂体系包含至少一种具有形成金属 - 卤素键的能力的金属或金属化合物。还描述了将烷烃（链烷烃）转化成烷基醇烷氧基化物的方法。该方法包括a）至少一种烷烃的卤化以产生至少一种烷基卤; 和b）在均相催化剂体系存在下，烷基卤化物与亲核材料的至少一部分直接烷氧基化偶联以产生烷基醇烷氧基化物，其中均相催化剂体系包含至少一种具有能力的金属或金属化合物以形成金属 - 卤素键。

10. 发明申请

US20090054274A1 Formation of Heteroatom Containing Derivatives of Paraffins 审中-公开
标题翻译：含有衍生物的杂原子的形成
公开(公告)号：US20090054274A1
公开(公告)日：2009-02-26
申请号：US11887169
申请日：2006-03-24
申请人： Howard Lam-Ho Fong , Thomas Howard Johnson , Thomas Carl Semple
发明人： Howard Lam-Ho Fong , Thomas Howard Johnson , Thomas Carl Semple
IPC分类号： E21B43/25 , C07C17/23 , C07C43/10
CPC分类号： C07C41/16 , C07C17/23 , C07C17/38 , C07C19/075 , C07C43/11 , C07C43/15
摘要： A process by which alkyl halides may be reacted (coupled) with nucleophilic materials in the presence of a homogeneous catalyst system. The process comprises reacting (coupling) alkyl halides with a nucleophilic material in the presence of a homogeneous catalyst system to produce derivatives of alkyl halides, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds.
摘要翻译：在均相催化剂体系存在下，烷基卤化物可与亲核材料反应（偶联）的方法。该方法包括在均相催化剂体系的存在下使烷基卤与亲核材料反应（偶合）以产生烷基卤化物的衍生物，其中均相催化剂体系包含至少一种具有形成金属卤素的能力的金属或金属化合物债券。

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