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    • 4. 发明申请
    • Conversion of Alkylhalides Into Alcohol Alkoxylates
    • 烷基卤转化为醇烷氧基化物
    • US20090270655A1
    • 2009-10-29
    • US11887194
    • 2006-03-24
    • Howard Lam-Ho FongThomas Howard JohnsonThomas Carl Semple
    • Howard Lam-Ho FongThomas Howard JohnsonThomas Carl Semple
    • C07C41/01
    • A61Q17/04A61K8/39C07C41/16C11D1/72C11D11/04C07C43/15C07C43/11
    • A process for converting alkyl halides to alkyl alcohol alkoxylates is described. This is a direct alkoxylation because the alkyl alcohol alkoxylates are made without going through an alkyl alcohol intermediate. The process comprises direct alkoxylation coupling of alkyl halides with a nucleophilic material in the presence of a homogeneous catalyst system to produce alkyl alcohol alkoxylates, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds. A process for converting alkanes (paraffins) to alkyl alcohol alkoxylates is also described. This method comprises a) halogenation of at least one alkane to produce at least one alkyl halide; and b) direct alkoxylation coupling of at least a portion of the alkyl halide with a nucleophilic material in the presence of a homogeneous catalyst system to produce alkyl alcohol alkoxylates, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds.
    • 描述了将烷基卤转化为烷基醇烷氧基化物的方法。 这是直接烷氧基化,因为烷基醇烷氧基化物不经过烷基醇中间体而制备。 该方法包括在均相催化剂体系存在下烷基卤与亲核材料的直接烷氧基化偶合以产生烷基醇烷氧基化物,其中均相催化剂体系包含至少一种具有形成金属 - 卤素键的能力的金属或金属化合物 。 还描述了将烷烃(链烷烃)转化成烷基醇烷氧基化物的方法。 该方法包括a)至少一种烷烃的卤化以产生至少一种烷基卤; 和b)在均相催化剂体系存在下,烷基卤化物与亲核材料的至少一部分直接烷氧基化偶联以产生烷基醇烷氧基化物,其中均相催化剂体系包含至少一种具有能力的金属或金属化合物 以形成金属 - 卤素键。
    • 7. 发明申请
    • METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY
    • 增强烃回收方法与组合
    • US20110021389A1
    • 2011-01-27
    • US12866245
    • 2009-02-06
    • Kirk Herbert RaneyThomas Carl Semple
    • Kirk Herbert RaneyThomas Carl Semple
    • C09K8/58
    • C09K8/584
    • A method of treating a hydrocarbon containing formation, comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the hydrocarbon recovery composition comprises a propoxylated composition which comprises (1) a glycerol sulfonate of a propoxylated primary alcohol having a branched aliphatic group with an average carbon number from 10 to 24 and having an average number of branches per aliphatic group of from 0.7 to 2.5 and having at least 0.5, preferably from 3 to 12, moles of propylene oxide per mole of primary alcohol and (2) polypropylene glycol; provided that the primary alcohol is propoxylated by contacting the alcohol with propylene oxide in the presence of a catalytically effective amount of one or more of the phosphate salts of lanthanum series elements or the rare earth elements, preferably a carbonate salt thereof, wherein the propoxylated composition comprising the propoxylated alcohol and from 1 to 30 wt % of polypropylene glycol is produced; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
    • 一种处理含烃地层的方法,包括(a)向所述含烃地层的至少一部分提供烃回收组合物,其中所述烃回收组合物包含丙氧基化组合物,其包含(1)丙氧基化初级的甘油磺酸盐 具有平均碳数为10至24并且每个脂族基团的平均分支数为0.7至2.5并且每摩尔初级粒子具有至少0.5,优选3至12摩尔环氧丙烷的支链脂族基团的醇的醇, 醇和(2)聚丙二醇; 条件是通过在催化有效量的一种或多种镧系元素的磷酸盐或稀土元素,优选其碳酸盐的存在下,使醇与环氧丙烷接触,将伯醇丙氧基化,其中丙氧基化组合物 包括丙氧基化醇和1至30wt%的聚丙二醇; 和(b)允许组合物与含烃地层中的烃相互作用。