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    • 2. 发明授权
    • Nanofiber sheet, process for producing the same, and fiber-reinforced composite material
    • 纳米纤维片,其制造方法和纤维增强复合材料
    • US09029275B2
    • 2015-05-12
    • US12374220
    • 2007-07-13
    • Hiroyuki YanoMasaya NogiShinsuke IfukuKentarou AbeKeishin Handa
    • Hiroyuki YanoMasaya NogiShinsuke IfukuKentarou AbeKeishin Handa
    • B32B23/02H05K1/03D21H11/08
    • H05K1/0366D21H11/08H05K2201/0251H05K2201/0284Y10T442/2869
    • Provided is a nanofiber sheet that sufficiently refined by fibrillation and has high crystallinity of cellulose fiber and can realize a fiber-reinforced composite material exhibiting high transparency, a high elastic modulus, a low coefficient of linear thermal expansion, and high heat resistance and being high in flatness and smoothness. This nanofiber sheet includes crystalline cellulose as the main component and a lignin in an amount of from 10 ppm to 10 wt %. When a fiber/resin composite material obtained by impregnating the nanofiber sheet with tricyclodecane dimethacrylate, subjecting the impregnated product to UV-curing at 20 J/cm2, and heating the cured product in vacuum at 160° C. for two hours includes 60 wt % of the cured tricyclodecane dimethacrylate and 40 wt % of nanofiber, the following physical characteristics (i) to (iii) are satisfied: (i) the parallel light transmittance of light of a wavelength of 600 nm at a sheet thickness of 100 μm is 70% or more; (ii) the Young's modulus is 5.0 GPa or more; and (iii) the coefficient of linear thermal expansion is 20 ppm/K or less.
    • 本发明提供一种纳米纤维片材,其通过原纤维化进行充分精制并具有高纤维素纤维素结晶度,并且可以实现具有高透明度,高弹性模量,低热膨胀系数和高耐热性的纤维增强复合材料,并且高 平坦度平滑。 该纳米纤维片包含结晶纤维素作为主要成分,木素含量为10〜10重量%。 当通过用三环癸烷二甲基丙烯酸酯浸渍纳米纤维片而获得的纤维/树脂复合材料,使浸渍产物以20J / cm 2进行UV固化,并且在160℃下真空加热固化产物2小时包括60重量% 的固化三环癸烷二甲基丙烯酸酯和40重量%的纳米纤维,满足以下物理特性(i)至(iii):(i)在100μm厚度下波长为600nm的光的平行光透射率为70 % 或者更多; (ii)杨氏模量为5.0GPa以上; 和(iii)线性热膨胀系数为20ppm / K以下。
    • 3. 发明申请
    • NANOFIBER SHEET, PROCESS FOR PRODUCING THE SAME, AND FIBER-REINFORCED COMPOSITE MATERIAL
    • 纳米纤维板,其制造方法和纤维增强复合材料
    • US20090264036A1
    • 2009-10-22
    • US12374220
    • 2007-07-13
    • Hiroyuki YanoMasaya NogiShinsuke IfukuKentarou AbeKeishin Handa
    • Hiroyuki YanoMasaya NogiShinsuke IfukuKentarou AbeKeishin Handa
    • B32B23/02D21C9/00D21B1/04D21C3/22D21C3/02
    • H05K1/0366D21H11/08H05K2201/0251H05K2201/0284Y10T442/2869
    • Provided is a nanofiber sheet that sufficiently refined by fibrillation and has high crystallinity of cellulose fiber and can realize a fiber-reinforced composite material exhibiting high transparency, a high elastic modulus, a low coefficient of linear thermal expansion, and high heat resistance and being high in flatness and smoothness. This nanofiber sheet includes crystalline cellulose as the main component and a lignin in an amount of from 10 ppm to 10 wt %. When a fiber/resin composite material obtained by impregnating the nanofiber sheet with tricyclodecane dimethacrylate, subjecting the impregnated product to UV-curing at 20 J/cm2, and heating the cured product in vacuum at 160° C. for two hours includes 60 wt % of the cured tricyclodecane dimethacrylate and 40 wt % of nanofiber, the following physical characteristics (i) to (iii) are satisfied: (i) the parallel light transmittance of light of a wavelength of 600 nm at a sheet thickness of 100 μm is 70% or more; (ii) the Young's modulus is 5.0 GPa or more; and (iii) the coefficient of linear thermal expansion is 20 ppm/K or less.
    • 本发明提供一种纳米纤维片,其通过原纤维化进行充分精制并具有高纤维素纤维素结晶度,并且可以实现具有高透明度,高弹性模量,低热膨胀系数和高耐热性的纤维增强复合材料,并且高 平坦度平滑。 该纳米纤维片包含结晶纤维素作为主要成分,木素含量为10〜10重量%。 当通过用三环癸烷二甲基丙烯酸酯浸渍纳米纤维片而获得的纤维/树脂复合材料,使浸渍产物以20J / cm 2进行UV固化,并且在160℃下真空加热固化产物2小时包括60重量% 的固化的三环癸烷二甲基丙烯酸酯和40重量%的纳米纤维,满足以下物理特性(i)至(iii):(i)100μm厚度的波长为600nm的光的平行光透射率为70 % 或者更多; (ii)杨氏模量为5.0GPa以上; 和(iii)线性热膨胀系数为20ppm / K以下。
    • 5. 发明申请
    • FIBER-REINFORCED COMPOSITE MATERIAL AND PROCESS FOR PRODUCING THE SAME
    • 纤维增强复合材料及其制造方法
    • US20090054552A1
    • 2009-02-26
    • US11815263
    • 2006-01-31
    • Hiroyuki YanoMasaya NogiFumiaki NakatsuboShinsuke Ifuku
    • Hiroyuki YanoMasaya NogiFumiaki NakatsuboShinsuke Ifuku
    • C08K9/04
    • C08J5/06H01L51/0081H01L51/0096H01L51/52Y10T428/249924Y10T428/26Y10T428/269
    • Disclosed is a highly transparent fiber-reinforced composite material including an assembly of cellulose fibers of 4 to 200 nm average fiber diameter impregnated with a matrix material so as to not only remedy the moisture absorbency attributed to cellulose fibers but also further improve transparency. There is provided a fiber-reinforced composite material including an assembly of cellulose fibers impregnated with a matrix material. In the fiber-reinforced composite material, hydroxyl groups of cellulose fibers are chemically modified through a reaction with one or more chemical modifiers selected from the group consisting of an acid, an alcohol, a halogenating reagent, an acid anhydride, and an isocyanate so that the ratio of a functional group introduced by the chemical modification is 5 to 40 percent by mole based on the hydroxyl groups of cellulose fibers before the chemical modification. The chemical modification of hydroxyl groups of cellulose fibers can reduce the hydrophilicity of cellulose fibers to thereby reduce the moisture absorbency of fiber-reinforced composite material. Further, the affinity between cellulose fibers and matrix material can be enhanced to thereby further improve transparency.
    • 公开了一种高透明度的纤维增强复合材料,其包括浸渍有基质材料的4〜200nm平均纤维直径的纤维素纤维的组合,不仅能够补偿归因于纤维素纤维的吸湿性,而且进一步提高透明性。 提供了一种纤维增强复合材料,其包括浸渍有基质材料的纤维素纤维的组合。 在纤维增强复合材料中,纤维素纤维的羟基通过与选自酸,醇,卤化试剂,酸酐和异氰酸酯的一种或多种化学改性剂的反应进行化学改性,使得 通过化学改性引入的官能团的比例相对于化学改性前的纤维素纤维的羟基为5〜40摩尔%。 纤维素纤维的羟基的化学改性可以降低纤维素纤维的亲水性,从而降低纤维增强复合材料的吸湿性。 此外,可以提高纤维素纤维与基质材料之间的亲和力,从而进一步提高透明度。
    • 7. 发明授权
    • Fiber-reinforced composite material and process for producing the same
    • 纤维增强复合材料及其制造方法
    • US08030375B2
    • 2011-10-04
    • US11815263
    • 2006-01-31
    • Hiroyuki YanoMasaya NogiFumiaki NakatsuboShinsuke Ifuku
    • Hiroyuki YanoMasaya NogiFumiaki NakatsuboShinsuke Ifuku
    • B32B27/38B32B27/12
    • C08J5/06H01L51/0081H01L51/0096H01L51/52Y10T428/249924Y10T428/26Y10T428/269
    • Disclosed is a highly transparent fiber-reinforced composite material including an assembly of cellulose fibers of 4 to 200 nm average fiber diameter impregnated with a matrix material so as to not only remedy the moisture absorbency attributed to cellulose fibers but also further improve transparency. There is provided a fiber-reinforced composite material including an assembly of cellulose fibers impregnated with a matrix material. In the fiber-reinforced composite material, hydroxyl groups of cellulose fibers are chemically modified through a reaction with one or more chemical modifiers selected from the group consisting of an acid, an alcohol, a halogenating reagent, an acid anhydride, and an isocyanate so that the ratio of a functional group introduced by the chemical modification is 5 to 40 percent by mole based on the hydroxyl groups of cellulose fibers before the chemical modification. The chemical modification of hydroxyl groups of cellulose fibers can reduce the hydrophilicity of cellulose fibers to thereby reduce the moisture absorbency of fiber-reinforced composite material. Further, the affinity between cellulose fibers and matrix material can be enhanced to thereby further improve transparency.
    • 公开了一种高透明度的纤维增强复合材料,其包括浸渍有基质材料的4〜200nm平均纤维直径的纤维素纤维的组合,不仅能够补偿归因于纤维素纤维的吸湿性,而且进一步提高透明性。 提供了一种纤维增强复合材料,其包括浸渍有基质材料的纤维素纤维的组合。 在纤维增强复合材料中,纤维素纤维的羟基通过与选自酸,醇,卤化试剂,酸酐和异氰酸酯的一种或多种化学改性剂的反应进行化学改性,使得 通过化学改性引入的官能团的比例相对于化学改性前的纤维素纤维的羟基为5〜40摩尔%。 纤维素纤维的羟基的化学改性可以降低纤维素纤维的亲水性,从而降低纤维增强复合材料的吸湿性。 此外,可以提高纤维素纤维与基质材料之间的亲和力,从而进一步提高透明度。