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1. 发明授权

US5891941A Fluororubber composition and molded article thereof 失效
标题翻译：氟橡胶组合物及其模塑制品
公开(公告)号：US5891941A
公开(公告)日：1999-04-06
申请号：US669287
申请日：1996-06-28
申请人： Hiroyuki Tanaka , Koji Matsumoto , Yutaka Ueta , Masayasu Tomoda
发明人： Hiroyuki Tanaka , Koji Matsumoto , Yutaka Ueta , Masayasu Tomoda
IPC分类号： C08K5/02 , C08K5/00 , C08K5/04 , C08K5/17 , C08K5/20 , C08L27/12
CPC分类号： C08K5/17
摘要： A fluororubber composition comprising a fluororubber, a vulcanizing agent and 0.1 to 5 wt. parts of a fatty acid monoamide per 100 wt. parts of said fluororubber. This fluororubber composition is excellent in mold releasability, and a molded article obtained by vulcanizing and molding the composition suffers less deterioration of mechanical properties caused by the addition of an internal mold release agent.
摘要翻译： PCT No.PCT / JP94 / 02180 Sec。 371日期：1996年6月28日 102（e）日期1996年6月28日PCT 1994年12月22日PCT公布。 WO95 / 18182 PCT出版物日期1995年7月6日一种氟橡胶组合物，其包含氟橡胶，硫化剂和0.1至5重量％每100重量份的脂肪酸单酰胺部分部分所述氟橡胶。这种氟橡胶组合物的脱模性优异，通过硫化和成型组合物得到的成型体的加入内部脱模剂引起的机械性能的劣化较少。

2. 发明授权

US4670328A Novel impregnated material of a copolymer of tetrafluoroethylene and perfluoroalkyl vinyl ether 失效
标题翻译：四氟乙烯和全氟烷基乙烯基醚共聚物的新型浸渍材料
公开(公告)号：US4670328A
公开(公告)日：1987-06-02
申请号：US834554
申请日：1986-02-28
申请人： Shoji Kawachi , Masayasu Tomoda , Yutaka Ueta , Masahiko Oka
发明人： Shoji Kawachi , Masayasu Tomoda , Yutaka Ueta , Masahiko Oka
IPC分类号： D06M15/353 , C08J9/40 , D06M15/256 , D06M101/00 , D06M101/02 , D06M101/16 , D06N3/04 , D21H19/14 , D21H19/20 , B32B27/00
CPC分类号： D06M15/256 , D06N3/047 , Y10T428/3154 , Y10T428/31544 , Y10T442/2172 , Y10T442/227 , Y10T442/2549
摘要： An impregnated material comprising an organic or inorganic material selected from the group consisting of a woven fabric, a non-woven fabric and an open cell porous material which is impregnated with a copolymer which comprises 50 to 95% by mole of repeating units derived from tetrafluoroethylene and 5 to 50% by mole of repeating units derived from perfluoroalkyl vinyl ether of the formula:CF.sub.2 .dbd.CFOR.sub.f (I)wherein R.sub.f is a C.sub.1 -C.sub.6 perfluoroalkyl group or a group of the formula:--(CF.sub.2 CFXO).sub.n --R.sub.f (II)wherein R.sub.f is the same as defined above, X is a fluorine atom or a trifluoromethyl group and n is an integer of 1 to 10, which has good chemical, corrosion, solvent and oil resistance as well as water- and oil-repellence.
摘要翻译：包含有机或无机材料的浸渍材料，该有机材料或无机材料选自织造织物，无纺织物和开孔细孔多孔材料，该共聚物浸渍有包含50-95％（摩尔）衍生自四氟乙烯的重复单元和5至50摩尔％的衍生自下式的全氟烷基乙烯基醚的重复单元：CF 2 = CFOR f（I）其中R f是C 1 -C 6全氟烷基或下式的基团： - （CF 2 CFXO）n -R f ）其中Rf与上述定义相同，X为氟原子或三氟甲基，n为1〜10的整数，具有良好的化学，腐蚀，溶剂和耐油性以及拒水拒油性。

3. 发明授权

US4260698A Co-crosslinkable blend composition comprising iodine-containing fluoroelastomer 失效
标题翻译：共可交联的共混组合物，其包含含碘的含氟弹性体
公开(公告)号：US4260698A
公开(公告)日：1981-04-07
申请号：US081895
申请日：1979-10-04
申请人： Masayoshi Tatemoto , Masayasu Tomoda , Yutaka Ueta
发明人： Masayoshi Tatemoto , Masayasu Tomoda , Yutaka Ueta
IPC分类号： C08J3/24 , C08K5/04 , C08K5/14 , C08L1/00 , C08L27/00 , C08L27/12 , C08L27/20 , C08L27/24 , C08L83/04 , C08L85/02 , C08L87/00 , C08L101/00 , C08L101/04
CPC分类号： C08L83/04 , C08L101/00 , C08L27/12 , C08L27/24 , C08L85/02 , C08G77/045 , C08G77/20 , C08G77/24 , C08L2205/02
摘要： A co-crosslinkable blend composition which comprises (1) an iodine-containing fluoroelastomer, (2) at least one of silicone oligomers, silicone elastomers, fluorosilicone elastomers, phosphonitrilic fluoroelastomers, tetrafluoroethylene/propylene copolymers and hexafluoropropylene/ethylene copolymers and (3) an organic peroxide.
摘要翻译：一种可共交联的共混组合物，其包含（1）含碘的含氟弹性体，（2）硅氧烷低聚物，硅氧烷弹性体，氟硅氧烷弹性体，膦腈基含氟弹性体，四氟乙烯/丙烯共聚物和六氟丙烯/乙烯共聚物中的至少一种和（3）有机过氧化物。

4. 发明授权

US4141874A Fluorine-containing elastomeric copolymers, process for preparing the same and composition containing the same 失效
标题翻译：含氟弹性体共聚物，其制备方法和含有该共聚物的组合物
公开(公告)号：US4141874A
公开(公告)日：1979-02-27
申请号：US740772
申请日：1976-11-10
申请人： Masahiko Oka , Singo Tanigawa , Takesi Suzuki , Masayasu Tomoda , Yutaka Ueta
发明人： Masahiko Oka , Singo Tanigawa , Takesi Suzuki , Masayasu Tomoda , Yutaka Ueta
IPC分类号： C08F2/16 , C08F259/08 , C08L27/16
CPC分类号： C08F259/08
摘要： Elastomeric copolymer of vinylidene fluoride and at least one other fluorine-containing monomer containing 28 to 92% by mole of the vinylidene fluoride unit and having an intrinsic viscosity of 0.4 to 1.3 at 35.degree. C. in methyl ethyl ketone, which is prepared by a two-stage polymerization process of vinylidene fluoride monomer and at least one other fluorine-containing monomer wherein monomers are copolymerized in an aqueous medium in the presence of a water-soluble radical polymerization initiator at a first stage to give a first stage-copolymer having an intrinsic viscosity of 0.01 to 3.0 at 35.degree. C. in methyl ethyl ketone and then copolymerized in an aqueous medium in the presence of the first stage-copolymer and an oil-soluble radical polymerization initiator at a second stage to give a second stage-copolymer, said elastomeric copolymer comprising 1 to 80% by weight of the first stage-copolymer and 20 to 99% by weight of the second stage-copolymer, process for preparing the same and composition containing the same. The elastomeric copolymer can be cured at satisfactory cure rate to give cured rubber having low compression set and high elongation.
摘要翻译：偏二氟乙烯与至少一种含有28-92％（摩尔）偏二氟乙烯单元的其它含氟单体的弹性共聚物，在35℃下在甲基乙基酮中的特性粘度为0.4〜1.3，其由偏二氟乙烯单体和至少一种其它含氟单体的两阶段聚合方法，其中单体在第一阶段在水溶性自由基聚合引发剂存在下在水性介质中共聚，得到第一阶段共聚物，其具有在35℃下在甲基乙基酮中的特性粘度为0.01〜3.0，然后在第一阶段共聚物和油溶性自由基聚合引发剂的存在下，在含水介质中共聚，得到第二级共聚物，所述弹性体共聚物包含1至80重量％的第一阶段共聚物和20至99重量％的第二阶段共聚物，其制备方法 nd组合物。弹性体共聚物可以以令人满意的固化速率固化，得到具有低压缩永久变形和高伸长率的固化橡胶。

5. 发明授权

US4501869A Cross linkable fluorine-containing polymer 失效
标题翻译：可交联的含氟聚合物
公开(公告)号：US4501869A
公开(公告)日：1985-02-26
申请号：US517334
申请日：1983-07-26
申请人： Masayoshi Tatemoto , Masahiko Oka , Hideo Kano , Masayasu Tomoda , Yutaka Ueta
发明人： Masayoshi Tatemoto , Masahiko Oka , Hideo Kano , Masayasu Tomoda , Yutaka Ueta
IPC分类号： C08L27/12 , C08F2/38 , C08F4/00 , C08F4/28 , C08F14/00 , C08F14/18 , C08K5/04 , C08K5/17 , C08L1/00 , C08L7/00 , C08L21/00 , C08L25/18 , C08L27/00 , C08L29/10 , C08L33/00 , C08L33/02 , C08L47/00 , C08F214/16
CPC分类号： C08F14/18 , C08F2438/01
摘要： An easily cross linkable fluorine-containing polymer comprising: (1) a polymeric chain comprising one or more polymer segments, at least one polymer segment of which consists of units of at least one fluorine-containing ethylenically unsaturated compound having 2 to 8 carbon atoms, or units of said fluorine-containing ethylenically unsaturated compound and at least one other monomer selected from the group consisting a fluorine-free ethylenically unsaturated compound having 2 to 4 carbon atoms and a fluorine-containing diene having 4 to 8 carbon atoms, (2) at least one bromine atom liberated from a brominated compound of the formula: RBr.sub.x (wherein R is a saturated hydrocarbon residue and x is a number corresponding to the bonding valency of the residue R) in an amount of 0.001 to 10% by weight based on the polymer weight and (3) a fragment of the brominated compound excluding the said liberated bromine atom therefrom, bonded to the polymeric chain, the polymer being prepared by polymerizing said fluorine-containing ethylenically unsaturated compound with or without said other monomer in the presence of a radical producing source and the brominated compound in at least one step.
摘要翻译：一种易交联的含氟聚合物，包括：（1）包含一个或多个聚合物链段的聚合物链，其至少一个聚合物链段由至少一个具有2-8个碳原子的含氟烯属不饱和化合物的单元组成，或所述含氟烯键式不饱和化合物的单元和选自具有2-4个碳原子的无氟烯键式不饱和化合物和具有4-8个碳原子的含氟二烯烃的至少一种其它单体，（2）从以下式的溴化化合物释放的至少一个溴原子：基于以下化学式的溴化化合物：RBrx（其中R是饱和烃残基，x是对应于残基R的键合化合价的数），其量为0.001至10重量％，基于聚合物重量和（3）除了结合到聚合物链上的所述释放的溴原子的溴化化合物的片段，聚合物由聚合物在自由基产生源和溴化化合物的存在下，在至少一个步骤中使含有或不含所述其它单体的含氟烯键式不饱和化合物的化学化。

6. 发明授权

US4188352A Elastomeric composition comprising fluoroelastomer and epicholorohydrin elastomer 失效
标题翻译：包含含氟弹性体和表氯醇弹性体的弹性组合物
公开(公告)号：US4188352A
公开(公告)日：1980-02-12
申请号：US974239
申请日：1978-12-29
申请人： Takeshi Suzuki , Yasuyoshi Furukawa , Masayasu Tomoda , Yutaka Ueta
发明人： Takeshi Suzuki , Yasuyoshi Furukawa , Masayasu Tomoda , Yutaka Ueta
IPC分类号： C08L27/12 , C08K3/22 , C08K5/04 , C08K5/05 , C08K5/13 , C08K5/17 , C08K5/34 , C08K5/49 , C08K5/50 , C08L1/00 , C08L27/00 , C08L27/14 , C08L27/16 , C08L71/00 , C08L71/03 , C08L87/00 , C08L27/20
CPC分类号： C08L27/16 , C08L71/03
摘要： An elastomeric composition comprising a fluoroelastomer, an epichlorohydrin elastomer, an acid-acceptor, a curing accelerator and a fluorine-containing polyhydroxy compound, which is handled without any difficulty and can afford, on crosslinking, a rubbery material excellent in physical and chemical properties at a wide range of temperatures.
摘要翻译：一种弹性体组合物，其包含含氟弹性体，表氯醇弹性体，酸受体，固化促进剂和含氟多羟基化合物，其在交联时无任何困难地处理，并且可以在交联时提供优异的物理和化学性质的橡胶材料范围广泛的温度。

7. 发明授权

US4133927A Composite material made of rubber elastomer and polytetrafluoroethylene resin 失效
标题翻译：复合材料由橡胶弹性体和聚四氟乙烯树脂制成
公开(公告)号：US4133927A
公开(公告)日：1979-01-09
申请号：US733124
申请日：1976-10-18
申请人： Masayasu Tomoda , Yutaka Ueta
发明人： Masayasu Tomoda , Yutaka Ueta
IPC分类号： C09K3/10 , B29C55/00 , B29C65/00 , B29C65/70 , B29C67/00 , B29D99/00 , B32B25/08 , C08J5/12 , F16J3/02 , F16J15/10 , B32B27/04 , B32B7/00 , B32B7/10
CPC分类号： B32B25/08 , C08J5/12 , Y10T29/49274 , Y10T428/24967 , Y10T428/24996 , Y10T428/249985 , Y10T428/249994 , Y10T428/259 , Y10T428/3154 , Y10T428/31544 , Y10T428/31826 , Y10T428/31924 , Y10T428/31928
摘要： A composite material including a rubber elastomer substrate and a polytetrafluoroethylene resin film or sheet having a porosity of 20 to 95% by volume and being laminated on at least one portion of the rubber elastomer substrate. In one preferred embodiment, a process for the production of the composite material includes the step of laminating a vulcanizable rubber elastomer with a porous film or sheet of polytetrafluoroethyle resin at a temperature and pressure sufficient to effect vulcanization of the rubber elastomer.
摘要翻译：一种复合材料，包括橡胶弹性体基材和具有20至95体积％的孔隙率的聚四氟乙烯树脂膜或片材，并且层压在橡胶弹性体基材的至少一部分上。在一个优选的实施方案中，制备复合材料的方法包括在足以实现橡胶弹性体硫化的温度和压力下将可硫化的橡胶弹性体与多孔膜或聚四氟乙基树脂片层压的步骤。

8. 发明授权

US4696989A Fluorine-containing elastomeric copolymer 失效
标题翻译：含氟弹性共聚物
公开(公告)号：US4696989A
公开(公告)日：1987-09-29
申请号：US849734
申请日：1986-04-09
申请人： Masahiko Oka , Yutaka Ueta , Hideo Kano , Masayasu Tomoda , Shoji Kawachi
发明人： Masahiko Oka , Yutaka Ueta , Hideo Kano , Masayasu Tomoda , Shoji Kawachi
IPC分类号： C08F14/28 , C08F214/18 , C08F214/22 , C08F214/26 , C08F214/28 , H01B3/44 , C08F14/18 , C08F14/22
CPC分类号： H01B3/445 , C08F214/18
摘要： A copolymer comprising repeating units derived from tetrafluoroethylene, vinylidene fluoride and hexafluoropropylene in a molar ratio within an area defined on a tetrafluoroethylene, vinylidene fluoride and hexafluoropropylene ternary composition diagram by a hexagon with its first vertex A at 34.0% by weight of tetrafluoroethylene, 8.5% by weight of vinylidene fluoride and 57.5% by weight of hexafluoropropylene; its second vertex B at 26.5% by weight of tetrafluoroethylene, 14.5% by weight of vinylidene fluoride and 59.0% by weight of hexafluoropropylene; its third vertex C at 31.0% by weight of tetrafluoroethylene, 24.0% by weight of vinylidene fluoride and 45.0% by weight of hexafluoropropylene; its fourth vertex D at 49.0% by weight of tetrafluoroethylene, 26.5% by weight of vinylidene fluoride and 24.5% by weight of hexafluoropropylene; its fifth vertex E at 49.0% by weight of tetrafluoroethylene, 11.0% by weight of vinylidene fluoride and 40.0% by weight of hexafluoropropylene; and its sixth vertex F at 50.0% by weight of tetrafluoroethylene, 9.0% by weight of vinylidene fluoride and 41.0% by weight of hexafluoropropylene having not only good flexibility, heat resistance and flame retardance but also good insulating performance and moldability.
摘要翻译：包含衍生自四氟乙烯，偏二氟乙烯和六氟丙烯的重复单元的摩尔比在四氟乙烯，偏二氟乙烯和六氟丙烯三元组成图中的四边形组成图中，其第一顶点A为34.0重量％的四氟乙烯，8.5重量％的偏二氟乙烯和57.5重量％的六氟丙烯; 其第二顶点B为26.5重量％的四氟乙烯，14.5重量％的偏二氟乙烯和59.0重量％的六氟丙烯; 其第三顶点C为31.0重量％的四氟乙烯，24.0重量％的偏二氟乙烯和45.0重量％的六氟丙烯; 其第四顶点D为49.0重量％的四氟乙烯，26.5重量％的偏二氟乙烯和24.5重量％的六氟丙烯; 其第五顶点E为49.0重量％的四氟乙烯，11.0重量％的偏二氟乙烯和40.0重量％的六氟丙烯; 其第四顶点F为40.0重量％的四氟乙烯，9.0重量％的偏二氟乙烯和41.0重量％的六氟丙烯，不仅具有良好的柔韧性，耐热性和阻燃性，而且具有良好的绝缘性能和成型性。

9. 发明授权

US4251399A Co-crosslinkable blend composition comprising iodine-containing fluoroelastomer 失效
标题翻译：共可交联的共混组合物，其包含含碘的含氟弹性体
公开(公告)号：US4251399A
公开(公告)日：1981-02-17
申请号：US82274
申请日：1979-10-05
申请人： Masayasu Tomoda , Yutaka Ueta
发明人： Masayasu Tomoda , Yutaka Ueta
IPC分类号： C08K5/04 , C08K5/14 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L27/12 , C08L27/24 , C08L33/00 , C08L33/02 , C08L57/00 , C08L71/03 , C08L83/04 , C08L101/00 , C08L9/00 , C08L27/16 , C08L27/22
CPC分类号： C08L71/03 , C08L101/00 , C08L21/00 , C08L27/12 , C08L27/24 , C08L83/04 , C08L23/16 , C08L23/22 , C08L7/00 , C08L9/02 , C08L9/06
摘要： A co-crosslinkable blend composition which comprises an iodine-containing fluoroelastomer, an elastomer crosslinkable in the presence of a peroxy radical and an organic peroxide.
摘要翻译：一种可共交联的共混组合物，其包含含碘的含氟弹性体，在过氧自由基和有机过氧化物的存在下可交联的弹性体。

10. 发明授权

US4243770A Cross linkable fluorine-containing polymer and its production 失效
标题翻译：可交联含氟聚合物及其生产
公开(公告)号：US4243770A
公开(公告)日：1981-01-06
申请号：US894256
申请日：1978-04-07
申请人： Masayoshi Tatemoto , Takeshi Suzuki , Masayasu Tomoda , Yasuyoshi Furukawa , Yutaka Ueta
发明人： Masayoshi Tatemoto , Takeshi Suzuki , Masayasu Tomoda , Yasuyoshi Furukawa , Yutaka Ueta
IPC分类号： C08F2/00 , C08F2/38 , C08F8/18 , C08F10/00 , C08F14/00 , C08F14/18 , C08F14/22 , C08F214/18 , C08K5/00 , C09K3/10 , C08F14/16
CPC分类号： C08F8/18 , C08F14/22 , C08F2438/01
摘要： An easily cross linkable fluorine-containing polymer substantially comprising: (1) a polymeric chain comprising one or more polymer segments, of which at least one polymer segment consisting of units of vinylidene fluoride alone or of units of vinylidene fluoride and one or more of other fluoroolefins, and (2) at least one iodine atom liberated from an iodinated compound of the formula: RI.sub.x (wherein R is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon residue having 1 to 8 carbon atoms and x is an integer of 1 or 2 corresponding to the bonding valency of the residue R) in an amount of 0.001 to 10% by weight based on the polymer and (3) a fragment of the iodinated compound excluding the said liberated iodine atom therefrom, which are bonded to the polymeric chain and being prepared by polymerizing vinylidene fluoride with or without one or more of the other fluoroolefins in the presence of a radical producing source and the iodinated compound or its reaction product with the said monomer(s) in one or more steps, the other fluoroolefins being selected from the group consisting of tetrafluoroethylene, chlorotrifluoroethylene, trifluoroethylene, vinyl fluoride, hexafluoropropylene, pentafluoropropylene, perfluoro(methyl vinyl ether), perfluoro(ethyl vinyl ether) and perfluoro(propyl vinyl ether).
摘要翻译：一种容易交联的含氟聚合物，其基本上包括：（1）包含一个或多个聚合物链段的聚合物链，其中至少一个聚合物链段由单偏氟乙烯单元或偏二氟乙烯单元和其它一个或多个单元组成氟化烯烃，和（2）从下式的碘化化合物释放的至少一个碘原子：其中R是具有1至8个碳原子的饱和或不饱和氟代烃或氯氟烃残基，x是1或2的整数，对应于残留物R的键合化合价）为0.001〜10重量％，（3）与该聚合物链结合的碘化合物不包括在内的碘化合物的片段，通过在自由基产生源和碘化化合物或其反应产物存在下聚合具有或不具有一种或多种其它氟代烯烃的偏二氟乙烯一个或多个步骤中的所述单体，其它氟烯烃选自四氟乙烯，三氟氯乙烯，三氟乙烯，氟乙烯，六氟丙烯，五氟丙烯，全氟（甲基乙烯基醚），全氟（乙基乙烯基醚）和全氟（丙基乙烯基醚）。

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