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    • 1. 发明授权
    • Oxygen-generating electrode and method for the preparation thereof
    • 产氧电极及其制备方法
    • US5156726A
    • 1992-10-20
    • US581417
    • 1990-09-12
    • Hiroyuki NakadaYukio KawashimaKazuhide Ohe
    • Hiroyuki NakadaYukio KawashimaKazuhide Ohe
    • C25B11/04C25B11/08C25C7/02
    • C25B11/0484C25C7/02
    • The electrode of the invention suitable for use in an oxygen-generating electrolytic process with durability comprises (A) a substrate of, e.g., titanium metal; (B) an undercoating layer thereon which is formed of a mixture of an iridium oxide and tantalum oxide in a limited molar proportion and (C) an overcoating layer formed of an iridium oxide. The undercoating layer can be formed by coating the substrate surface with a solution containing an iridium compound and tantalum compound each having thermal decomposability and then subjecting the coated substrate body to a heat treatment in an oxidizing atmosphere. Similarly, the overcoating layer can be formed by coating with a solution containing a thermally decomposable iridium compound followed by an oxidative heat treatment in an oxidizing atmosphere.
    • 适用于具有耐久性的产氧电解方法的本发明的电极包括(A)例如钛金属的基材; (B)由氧化铱和氧化钽的混合物以有限的摩尔比例形成的底涂层,(C)由氧化铱形成的外涂层。 底涂层可以通过用含有具有热分解性的铱化合物和钽化合物的溶液涂布基板表面,然后使涂覆的基板体在氧化气氛中进行热处理而形成。 类似地,外涂层可以通过用含有可热分解的铱化合物的溶液涂覆,然后在氧化气氛中进行氧化热处理来形成。
    • 2. 发明授权
    • Electroplating method and apparatus for the preparation of metal foil
and split insoluble electrode used therein
    • 用于制备金属箔和其中使用的裂解不溶性电极的电镀方法和装置
    • US5628892A
    • 1997-05-13
    • US245076
    • 1994-05-17
    • Yukio KawashimaKazuhide OheHiroyuki Nakada
    • Yukio KawashimaKazuhide OheHiroyuki Nakada
    • C25D1/04C25D17/10C25D17/12C25D1/20C25D7/06C25D17/00
    • C25D17/12C25D1/04
    • A length of electroplated metal foil, typically copper foil is prepared by placing a stationary arcuate anode concentrically with a rotating cathode drum to define a channel therebetween, passing a plating solution through the channel, conducting electricity across the channel for depositing metal on the cathode drum, and separating the metal deposit from the cathode drum. The anode includes a plurality of circumferentially arranged electrode segments formed of a valve metal material and coated with a platinum group metal or oxide thereof. The electrode segments are removably attached and electrically connected to a back plate. The split anode is easy in assembly and disassembly and, hence, in maintenance and repair, has a high degree of precision in configuration and dimensions, and ensures manufacture of copper foil of quality with a minimized variation in thickness during continuous operation.
    • 电镀金属箔(通常为铜箔)的长度通过将静止的弓形阳极与旋转阴极鼓同心地放置以在其间限定通道来制备,使电镀溶液通过通道,将电穿过该通道导电以在阴极鼓上沉积金属 并且将金属沉积物与阴极鼓分离。 阳极包括由阀金属材料形成并涂覆有铂族金属或其氧化物的多个周向布置的电极段。 电极段可移除地附接并电连接到背板。 分离阳极易于组装和拆卸,因此在维护和修理中具有高度的结构和尺寸精度,并且确保在连续操作期间具有最小的厚度变化的质量的铜箔的制造。
    • 3. 发明授权
    • Oxygen-generating electrode
    • 氧气发生电极
    • US5098546A
    • 1992-03-24
    • US626997
    • 1990-12-13
    • Yukio KawashimaKazuhide OheHiroyuki Nakada
    • Yukio KawashimaKazuhide OheHiroyuki Nakada
    • C23C18/12C23C28/04C25B11/04C25B11/06C25B11/10C25D17/10
    • C25D17/10C25B11/0484
    • Proposal is made for providing a high-performance electrode suitable for use in an oxygen-generating electrolytic process having an outstandingly low oxygen overvoltage and exhibiting high durability in a prolonged run of electrolysis. The electrode consists of an electroconductive substrate of a metal, e.g., titanium, and a multiple composite oxide coating layer thereon consisting of at least one layer of type A composed of iridium oxide and tantalum oxide in an Ir:Ta molar ratio of 40:60 to 79.9:20.1 and at least one layer of type B formed on the type A layer composed of iridium oxide and tantalum oxide in an Ir:Ta molar ratio of 80:20 to 99.9:0.1. A plural number of type A layers and a plural number of type B layers can be alternately laid one on the other so as to improve the mechanical stability of the coating layer on the substrate surface.
    • 提出了用于提供具有极低的氧过电压并且在长时间电解中表现出高耐久性的氧发生电解方法中使用的高性能电极。 电极由金属的导电基底(例如钛)和多层复合氧化物涂层组成,其中由氧化铱和氧化钽组成的至少一层由氧化铱和氧化钽构成的至少一层,其摩尔比为40:60 至79.9:20.1,并且形成在由氧化铱和氧化钽组成的A层的Ir:Ta摩尔比为80:20至99.9:0.1的至少一层B型。 可以将多个A层和多个B层交替放置,以提高基板表面上的涂层的机械稳定性。
    • 6. 发明授权
    • Electrolyzing electrode and process for the production thereof
    • 电解电极及其制造方法
    • US06231731B1
    • 2001-05-15
    • US09292841
    • 1999-04-16
    • Makoto KondoHiroyuki NakadaYukio Kawashima
    • Makoto KondoHiroyuki NakadaYukio Kawashima
    • C25B1100
    • C25B11/0484
    • An electrolyzing electrode which is for electrolyzing a metal electrolytic solution, shows a long lifetime in use as an ordinary anode and has sufficient durability even when in a poor potential region, and a process for the production thereof. The electrolyzing electrode of the present invention has an undercoating layer which is formed of platinum metal and tantalum oxide and contains, as metals, 1 to 20 at % of platinum and 80 to 99 at % of tantalum, on an electrically conductive electrode substrate, has an intermediate layer which is formed of iridium oxide and tantalum oxide and contains, as metals, 70 to 99.9 at % of iridium and 0.1 to 30 at % of tantalum, on the undercoating layer, and further has an overcoating layer which is formed of platinum metal and iridium oxide and contains, as metals, 60 to 99.9 at % of platinum and 0.1 to 40 at % of iridium, on the intermediate layer.
    • 用于电解金属电解液的电解电极在作为普通阳极的使用中具有长的使用寿命,即使在较差的电势区域中也具有足够的耐久性及其制造方法。 本发明的电解电极具有由铂金属和氧化钽形成的底涂层,在导电电极基板上含有1〜20原子%的铂和80〜99at%的钽作为金属,具有 由氧化铱和氧化钽形成的中间层,在底涂层上含有作为金属,70〜99.9at%的铱和0.1〜30at%的钽,并且还具有由铂形成的外涂层 金属和氧化铱,并且在中间层上含有金属为60〜99.9at%的铂和0.1〜40at%的铱。
    • 8. 发明申请
    • MAGNETIC DETECTION DEVICE INCLUDING RESISTANCE ADJUSTING UNIT
    • 磁阻检测装置,包括电阻调节单元
    • US20080061777A1
    • 2008-03-13
    • US11678846
    • 2007-02-26
    • Hideto AndoKiyoshi SatoHiroyuki Nakada
    • Hideto AndoKiyoshi SatoHiroyuki Nakada
    • G01R33/02H01L43/08
    • G01R33/093B82Y25/00H01L43/08
    • In a magnetic detection device for obtaining an output from between a variable resistance element using the magnetoresistance effect and a reference resistance element, a balance between resistance values in the device can be easily adjusted in a wide range. A voltage is applied to a resistance adjusting unit, a reference resistance element, and a variable resistance element, which are serially connected, and is also applied to another variable resistance element, another reference resistance element, and another resistance adjusting unit, which are serially connected. When subjected to a magnetic field of a predetermined size, resistance values of the variable resistance elements change, and as a result, the potentials of output terminals change. Each of the resistance adjusting units includes serially connected parallel portions each including a plurality of parallel connected resistance elements. The resistance value of the resistance adjusting unit can be changed by bringing one of the parallel connected resistance elements into a non-conduction state.
    • 在用于获得使用磁阻效应的可变电阻元件的输出与参考电阻元件之间的输出的磁性检测装置中,可以容易地在宽范围内调节器件中的电阻值之间的平衡。 电压被施加到串联连接的电阻调节单元,参考电阻元件和可变电阻元件,并且也被施加到串联的另一个可变电阻元件,另一个参考电阻元件和另一个电阻调节单元 连接的。 当受到预定尺寸的磁场时,可变电阻元件的电阻值改变,结果导致输出端子的电位变化。 每个电阻调节单元包括串联连接的并联部分,每个并联部分包括多个平行连接的电阻元件。 可以通过使并联的电阻元件中的一个成为非导通状态来改变电阻调节单元的电阻值。
    • 10. 发明授权
    • Magnetic detection device including resistance adjusting unit
    • 磁检测装置包括电阻调节单元
    • US07345477B1
    • 2008-03-18
    • US11678846
    • 2007-02-26
    • Hideto AndoKiyoshi SatoHiroyuki Nakada
    • Hideto AndoKiyoshi SatoHiroyuki Nakada
    • G01R33/02H01L29/82
    • G01R33/093B82Y25/00H01L43/08
    • In a magnetic detection device for obtaining an output from between a variable resistance element using the magnetoresistance effect and a reference resistance element, a balance between resistance values in the device can be easily adjusted in a wide range. A voltage is applied to a resistance adjusting unit, a reference resistance element, and a variable resistance element, which are serially connected, and is also applied to another variable resistance element, another reference resistance element, and another resistance adjusting unit, which are serially connected. When subjected to a magnetic field of a predetermined size, resistance values of the variable resistance elements change, and as a result, the potentials of output terminals change. Each of the resistance adjusting units includes serially connected parallel portions each including a plurality of parallel connected resistance elements. The resistance value of the resistance adjusting unit can be changed by bringing one of the parallel connected resistance elements into a non-conduction state.
    • 在用于获得使用磁阻效应的可变电阻元件的输出与参考电阻元件之间的输出的磁性检测装置中,可以容易地在宽范围内调节器件中的电阻值之间的平衡。 电压被施加到串联连接的电阻调节单元,参考电阻元件和可变电阻元件,并且还被施加到串联的另一个可变电阻元件,另一个参考电阻元件和另一个电阻调节单元 连接的。 当受到预定尺寸的磁场时,可变电阻元件的电阻值改变,结果导致输出端子的电位变化。 每个电阻调节单元包括串联连接的并联部分,每个并联部分包括多个平行连接的电阻元件。 可以通过使并联的电阻元件中的一个成为非导通状态来改变电阻调节单元的电阻值。