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1. 发明授权

US5453861A Chiral smectic liquid crystal device and display apparatus 失效
标题翻译：手性近晶体液晶装置及显示装置
公开(公告)号：US5453861A
公开(公告)日：1995-09-26
申请号：US252535
申请日：1994-06-01
申请人： Kenji Shinjo , Hiroyuki Kitayama , Masanobu Asaoka , Masahiro Terada , Syuji Yamada , Hiroshi Mizuno
发明人： Kenji Shinjo , Hiroyuki Kitayama , Masanobu Asaoka , Masahiro Terada , Syuji Yamada , Hiroshi Mizuno
IPC分类号： G02F1/1337 , G02F1/141 , G02F1/13 , G02F1/1343
CPC分类号： G02F1/1416 , G02F2001/133746
摘要： A liquid crystal device showing improved uniform alignment characteristic and switching characteristic is constituted by a pair of an upper substrate and a lower substrate, and a chiral smectic liquid crystal disposed between the upper and lower substrates. Each of the upper and lower substrates has thereon an electrode for applying a voltage to the liquid crystal and a uniaxial alignment film. The alignment films on the upper and lower substrates are provided with uniaxial alignment axes which cross each other so that the direction of crossing of the uniaxial alignment axes from the lower substrate to the upper substrate is identical to the direction of helical twist in cholesteric phase of the chiral smectic liquid crystal, and the chiral smectic liquid crystal is disposed in such an alignment state that the liquid crystal shows a pretilt angle .alpha., a cone angle H, an inclination angle .delta. of SmC.sup.* layer, and an apparent tilt angle .theta.a satisfying relationships of: H .theta.a>H/2. The crossing direction may preferably have a polarity (taken as "positive" in clockwise direction and "negative" in anticlockwise direction) which is the same as the polarity of the spontaneous polarization of the liquid crystal.
摘要翻译：显示出改善的均匀取向特性和切换特性的液晶装置由一对上基板和下基板以及设置在上基板和下基板之间的手性近晶液晶构成。上基板和下基板都具有用于向液晶施加电压的电极和单轴取向膜。上基板和下基板上的取向膜具有彼此交叉的单轴对准轴，使得单轴对准轴从下基板到上基板的交叉方向与胆甾醇相的螺旋扭转方向相同手性近晶液晶和手性近晶液晶以这样的取向状态设置，使得液晶显示预倾角α，锥角+ E，crc / H /，SmC *层的倾斜角度δ，以及满足以下关系的明显倾斜角θa：+ E，crc / H /α+δ和+ E，crc / H />θa> + E，crc / H / / 2。交叉方向可以优选地具有与液晶的自发极化的极性相同的极性（顺时针方向为“正”，逆时针方向为“负”）。

2. 发明授权

US5424004A Chiral smectic liquid crystal composition, liquid crystal device, display apparatus and display method 失效
标题翻译：手性近晶液晶组合物，液晶显示装置，显示装置及显示方法
公开(公告)号：US5424004A
公开(公告)日：1995-06-13
申请号：US45312
申请日：1993-04-13
申请人： Kenji Shinjo , Hiroyuki Kitayama , Toshiharu Uchimi , Syuji Yamada , Kazuharu Katagiri
发明人： Kenji Shinjo , Hiroyuki Kitayama , Toshiharu Uchimi , Syuji Yamada , Kazuharu Katagiri
IPC分类号： G02F1/13 , C09K19/34 , C09K19/42 , C09K19/46
CPC分类号： C09K19/3469 , C09K19/46
摘要： A chiral smectic liquid crystal composition is formed by including at least one species of a mesomorphic compound represented by the following formula (I): ##STR1## wherein X denotes F, Cl, Br, CF.sub.3, NO.sub.2 or CN; Y denotes a single bond, ##STR2## --CH.sub.2 O-- or --OCH.sub.2 --; and R denotes a linear or branched alkyl group having 1-20 carbon atoms optionally substituted. The composition shows improved switching characteristics and, when used in combination with an alignment film providing a high pre-tilt angle, provides an increased contrast at a large drive margin and with little tendency of monostabilization of a memory state.
摘要翻译：通过包含至少一种由下式（I）表示的介晶化合物形成手性近晶液晶组合物：其中X表示F，Cl，Br，CF 3，NO 2或CN; Y表示单键，图示-CH 2 O-或-OCH 2 - ; 并且R表示任选取代的具有1-20个碳原子的直链或支链烷基。该组合物显示改进的开关特性，并且当与提供高预倾角的取向膜组合使用时，在大的驱动裕度提供增加的对比度并且几乎没有记忆状态的单稳态化趋势。

3. 发明授权

US5583682A Liquid crystal device for gradational display 失效
标题翻译：液晶显示器
公开(公告)号：US5583682A
公开(公告)日：1996-12-10
申请号：US253160
申请日：1994-06-02
申请人： Hiroyuki Kitayama , Kenji Shinjo , Syuji Yamada
发明人： Hiroyuki Kitayama , Kenji Shinjo , Syuji Yamada
IPC分类号： G02F1/1337 , C09K19/02 , C09K19/34 , G02F1/141
CPC分类号： C09K19/34 , C09K19/0225 , G02F1/1416 , G02F2203/30
摘要： A liquid crystal device for gradational display, comprising: a pair of substrates each provided with an electrode, and a liquid crystal layer comprising a chiral smectic liquid crystal disposed between the substrates; the pair of substrates each having thereon alignment control layer provided with a uniaxial alignment axis, wherein aid liquid crystal layer comprises a striped region and a non-striped region where (1) the striped region and the non-striped region each assume a homogeneous alignment state, (2) the striped region extends in a direction perpendicular to the direction of the uniaxial alignment axis, and (3) each of liquid crystal molecules within the striped region and the non-striped region show bistability; and the liquid crystal molecules within the striped region have a threshold voltage, for switching between two stable states, different from that given by the liquid crystal molecules within the on-striped region. The above two regions (striped and non-striped region) having different threshold voltages each other are suitable as a display region for a liquid crystal device providing good gradation characteristic.
摘要翻译：一种用于梯度显示的液晶显示装置，包括：一对基板，每个基板均设置有电极;以及液晶层，其包括设置在所述基板之间的手性近晶液晶; 所述一对基板各自具有设置有单轴取向轴的取向控制层，其中辅助液晶层包括条纹区域和非条带区域，其中（1）所述条纹区域和所述非条纹区域各自呈均匀对准状态，（2）条纹区域沿垂直于单轴取向轴线方向的方向延伸，（3）条纹区域和非条纹区域中的每个液晶分子显示双稳态; 并且条纹区域内的液晶分子具有阈值电压，用于在两个稳定状态之间切换，不同于在条纹区域内的液晶分子给出的稳定状态。具有不同阈值电压的上述两个区域（条纹和非条纹区域）适合作为提供良好灰度特性的液晶装置的显示区域。

4. 发明授权

US5948317A Liquid crystal composition, liquid crystal device using the composition, liquid crystal apparatus and display method 失效
标题翻译：液晶组合物，使用组合物的液晶装置，液晶装置和显示方法
公开(公告)号：US5948317A
公开(公告)日：1999-09-07
申请号：US971163
申请日：1997-11-14
申请人： Koichi Sato , Hiroyuki Kitayama , Kenji Shinjo , Shinichi Nakamura , Katsutoshi Nakamura
发明人： Koichi Sato , Hiroyuki Kitayama , Kenji Shinjo , Shinichi Nakamura , Katsutoshi Nakamura
IPC分类号： C09K19/04 , C09K19/34 , C09K19/42 , C09K19/58 , G02F1/1337
CPC分类号： G02F1/133723 , C09K19/04 , C09K19/3469 , C09K19/42 , C09K19/588 , C09K2019/044
摘要： A liquid crystal composition includes at least one fluorine-containing mesomorphic compound (a) having a fluorocarbon terminal portion and a hydrocarbon terminal portion, and at least one optically active compound (b) having an optically active cyclic group and a terminal alkyl group free from a perfluorocarbon atom. The compound (a) and the compound (b) are mutually soluble readily to form a homogeneous liquid crystal composition. The liquid crystal composition shows a layer structure of so-called bookshelf or a layer structure having a small inclination angle (closer to bookshelf structure). The liquid crystal composition is useful in improving response characteristics and display characteristics, particularly a contrast ratio, of a liquid crystal device using the liquid crystal composition.
摘要翻译：液晶组合物包含至少一种具有碳氟化合物末端部分和烃末端部分的含氟介晶化合物（a）和至少一种光学活性化合物（b），其具有光学活性的环状基团和不具有全氟化碳原子。化合物（a）和化合物（b）易于溶解以形成均匀的液晶组合物。液晶组合物显示出所谓书架的层结构或具有较小倾斜角（更靠近书架结构）的层结构。液晶组合物可用于改善使用液晶组合物的液晶装置的响应特性和显示特性，特别是对比度。

5. 发明授权

US5405553A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5405553A
公开(公告)日：1995-04-11
申请号：US76931
申请日：1993-06-16
申请人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Takao Takiguchi , Masanobu Asaoka , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
发明人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Takao Takiguchi , Masanobu Asaoka , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
IPC分类号： C09K19/34 , C09K19/46 , C07D239/02 , G02F1/13
CPC分类号： C09K19/46 , C09K19/3441
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one optically active compound represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 respectively denote a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent, at least one of R.sub.1 and R.sub.2 being optically active; X.sub.1 denotes --O--, ##STR2## and X.sub.2 denotes a single bond, --O--, ##STR3## and at least one compound represented by the following formula (II): ##STR4## wherein R.sub.3 and R.sub.4 respectively denote a linear or branched optically inactive alkyl group having 1-18 carbon atoms capable of having an alkoxy group of 1-12 carbon atoms; X.sub.3 and X.sub.4 respectively denote a single bond, --O--, ##STR5## and m and n are respectively 0, 1 or 2 with proviso that both of m and n are not 0.
摘要翻译：包含至少一种由下式（I）表示的光学活性化合物的铁电手性近晶液晶组合物：具有能够具有取代基的具有1-18个碳原子的直链或支链烷基，R 1和R 2中的至少一个光学活性; X1表示-O-，，X2表示单键，-O-，和由下式（II）表示的至少一种化合物：其中R 3和R 4分别表示具有能够具有1-12个碳原子的烷氧基的具有1-18个碳原子的直链或支链的非光学惰性烷基; X3和X4分别表示单键，-O-，，m和n分别为0,1或2，条件是m和n均不为0。

6. 发明授权

US5240637A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5240637A
公开(公告)日：1993-08-31
申请号：US370808
申请日：1989-06-23
申请人： Kenji Shinjo , Takao Takiguchi , Hiroyuki Kitayama , Kazuharu Katagiri , Masahiro Terada , Takeshi Togano , Masataka Yamashita , Masanobu Asaoka
发明人： Kenji Shinjo , Takao Takiguchi , Hiroyuki Kitayama , Kazuharu Katagiri , Masahiro Terada , Takeshi Togano , Masataka Yamashita , Masanobu Asaoka
IPC分类号： C07D271/10 , C07D285/12 , C09K19/34 , C09K19/42 , C09K19/46
CPC分类号： C07D271/10 , C07D285/12 , C09K19/345 , C09K19/3455 , C09K19/3463 , C09K19/348 , C09K19/3497 , C09K19/42 , C09K19/46
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; X.sub.1 denotes a single bond, --O-- or ##STR2## Z denotes a single bond or ##STR3## denotes ##STR4## and n is an integer of 1-12; and at least one compound represented by the following formula (II): ##STR5## wherein R.sub.2 and R.sub.3 respectively denote a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent, at lease one of R.sub.2 and R.sub.3 being optically active; X.sub.2 and X.sub.3 respectively denote a single bond, --O--, ##STR6##
摘要翻译：一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的化合物：其中R 1表示可具有取代基的具有1-18个碳原子的直链或支链烷基; X1表示单键，-O-或 Z表示单键，或表示，n表示1-12的整数。和由下式（II）表示的至少一种化合物：其中R 2和R 3分别表示可以具有取代基的具有1-18个碳原子的直链或支链烷基，其中R2和 R3是光学活性的; X2和X3分别表示单键-O-，

7. 发明授权

US5173211A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5173211A
公开(公告)日：1992-12-22
申请号：US378824
申请日：1989-07-12
申请人： Masataka Yamashita , Takeshi Togano , Masahiro Terada , Akio Yoshida , Yoshiko Kimura , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
发明人： Masataka Yamashita , Takeshi Togano , Masahiro Terada , Akio Yoshida , Yoshiko Kimura , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
IPC分类号： C09K19/42
CPC分类号： C09K19/42
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one optically active compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; R.sub.2 denotes a linear or branched alkyl group having 1-14 carbon atoms capable of having a substituent; and X.sub.1 denotes a single bond, ##STR2## and at least one optically active compound represented by the following formula (II): ##STR3## wherein R.sub.3 denotes a linear alkyl group having 1-14 carbon atoms; R.sub.4 denotes a linear or branched alkyl group having 1-14 carbon atoms capable of having a substituent; and X.sub.2 denotes a single bond, ##STR4##
摘要翻译：一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的光学活性化合物：其中R 1表示具有1-18个碳原子的具有取代基的直链或支链烷基 ; R2表示可具有取代基的具有1-14个碳原子的直链或支链烷基; 并且X1表示单键，和下式（II）表示的至少一种光学活性化合物：其中R 3表示具有1-14个碳原子的直链烷基; R4表示可具有取代基的具有1-14个碳原子的直链或支链烷基; X2表示单键，

8. 发明授权

US5641427A Liquid crystal composition, liquid crystal device using the composition liquid crystal apparatus and display method 失效
标题翻译：液晶组合物，使用组合物的液晶装置，液晶装置和显示方法
公开(公告)号：US5641427A
公开(公告)日：1997-06-24
申请号：US506537
申请日：1995-07-25
申请人： Kenji Shinjo , Hiroyuki Kitayama , Koichi Sato
发明人： Kenji Shinjo , Hiroyuki Kitayama , Koichi Sato
IPC分类号： C09K19/34 , C09K19/42 , C09K19/52 , C09K19/20 , C09K19/32
CPC分类号： C09K19/42 , C09K19/3441 , C09K19/345
摘要： A liquid crystal composition includes at least one fluorine-containing mesomorphic compound (a) having a fluorocarbon terminal portion and a hydrocarbon terminal portion, and at least one optically active compound (b) having at least one substituted or unsubstituted terminal alkyl group containing an asymmetric carbon atom directly connected with F, CF.sub.3 or CH.sub.3. The liquid crystal composition shows a layer structure of so-called bookshelf or a layer structure having a small inclination angle (closer to bookshelf structure). The liquid crystal composition is useful in improving response characteristics and display characteristics, particularly a contrast ratio, of a liquid crystal device using the liquid crystal composition.
摘要翻译：液晶组合物包含至少一种含氟碳末端部分和烃末端部分的含氟介晶化合物（a）和至少一种具有至少一个取代或未取代的含有不对称的末端烷基的光学活性化合物（b）碳原子与F，CF3或CH3直接连接。液晶组合物显示出所谓书架的层结构或具有较小倾斜角（更靠近书架结构）的层结构。液晶组合物可用于改善使用液晶组合物的液晶装置的响应特性和显示特性，特别是对比度。

9. 发明授权

US5580489A Method of producing a liquid crystal composition 失效
标题翻译：液晶组合物的制造方法
公开(公告)号：US5580489A
公开(公告)日：1996-12-03
申请号：US377134
申请日：1995-01-23
申请人： Kenji Shinjo , Takao Takiguchi , Hiroyuki Kitayama , Kazuharu Katagiri , Masataka Yamashita , Takeshi Togano , Masahiro Terada , Junko Sato
发明人： Kenji Shinjo , Takao Takiguchi , Hiroyuki Kitayama , Kazuharu Katagiri , Masataka Yamashita , Takeshi Togano , Masahiro Terada , Junko Sato
IPC分类号： C07D271/10 , C07D285/12 , C09K19/34 , C09K19/42 , C09K19/46 , C07D239/02
CPC分类号： C07D271/10 , C07D285/12 , C09K19/345 , C09K19/3455 , C09K19/3463 , C09K19/348 , C09K19/3497 , C09K19/42 , C09K19/46
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent, R.sub.2 denotes a linear or branched alkyl group having 1-14 carbon atoms capable of having a substituent; X.sub.1 and X.sub.2 respectively denote a single bond, ##STR2## m is 0-7; and n is 0 or 1; and at least one compound represented by the following formula (II): ##STR3## wherein R.sub.3 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; R.sub.4 denotes a linear alkyl group having 1-10 carbon atoms; X.sub.3 denotes a single bond, ##STR4## Y denotes ##STR5## and ##STR6## respectively denote ##STR7##
摘要翻译：一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的化合物：其中R 1表示具有1-18个能够具有取代基的碳原子的直链或支链烷基，R2 表示具有能够具有取代基的具有1-14个碳原子的直链或支链烷基; X1和X2分别表示单键， m为0-7; 并且n为0或1; 和由下式（II）表示的至少一种化合物：其中R 3表示可具有取代基的具有1-18个碳原子的直链或支链烷基; R4表示具有1-10个碳原子的直链烷基; X3表示单键， Y表示

10. 发明授权

US5238601A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5238601A
公开(公告)日：1993-08-24
申请号：US370909
申请日：1989-06-23
申请人： Kenji Shinjo , Takao Takiguchi , Hiroyuki Kitayama , Kazuharu Katagiri , Masahiro Terada , Takeshi Togano , Masataka Yamashita
发明人： Kenji Shinjo , Takao Takiguchi , Hiroyuki Kitayama , Kazuharu Katagiri , Masahiro Terada , Takeshi Togano , Masataka Yamashita
IPC分类号： C07D271/10 , C07D285/12 , C09K19/30 , C09K19/34 , C09K19/42
CPC分类号： C07D271/10 , C07D285/12 , C09K19/3068 , C09K19/345 , C09K19/3455 , C09K19/3463 , C09K19/348 , C09K19/3497 , C09K19/42
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one optically active compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear alkyl group having 1-14 carbon atoms; R.sub.2 denotes a linear or branched alkyl group having 1-14 carbon atoms capable of having a subtituent; and X.sub.1 denotes a single bond, ##STR2## and at least one compound represented by the following formula (II): ##STR3## wherein R.sub.3 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; R.sub.4 denotes a linear alkyl group having 1-10 carbon atoms; X.sub.2 denotes a single bond, ##STR4##
摘要翻译：一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的光学活性化合物：其中R 1表示具有1-14个碳原子的直链烷基; R2表示能够具有取代基的具有1-14个碳原子的直链或支链烷基; X1表示单键，和下述式（II）表示的至少一种化合物：其中，R 3表示可具有取代基的具有1-18个碳原子的直链或支链烷基， ; R4表示具有1-10个碳原子的直链烷基; X2表示单键，

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