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    • 3. 发明申请
    • Membrane electrode assembly for polymer electrolyte fuel cell
    • 用于聚合物电解质燃料电池的膜电极组件
    • US20050008920A1
    • 2005-01-13
    • US10844583
    • 2004-05-13
    • Katsuhiko KohyamaHiroshi ShinkaiMasaki Tani
    • Katsuhiko KohyamaHiroshi ShinkaiMasaki Tani
    • H01M8/02H01M2/00H01M2/02H01M4/86H01M8/04H01M8/10H01M8/12
    • H01M4/8605H01M4/8657H01M8/1004
    • A membrane electrode assembly for a polymer electrolyte fuel cell has, as basic components, a polymer electrolyte membrane, a pair of electrode layers which sandwich the polymer electrolyte membrane, and a pair of gas-diffusion layers disposed outside the respective electrode layers. Electric medium layers are respectively provided between the electrode layer and the gas-diffusion layer at one side and between the electric layer and the gas-diffusion layer at the other side. Each of the electric medium layers is constituted of a plurality of carbon whiskers, a plurality of carbon particles and a binder including an electrolyte material. A content GW of the carbon whiskers in each of the electric medium layers is set at 10 wt %≦GW≦25 wt %. Thus, the membrane electrode assembly for the polymer electrolyte fuel cell can keep a high power generating performance by reducing the contact resistance between the gas-diffusion layers and the electrode layers.
    • 固体高分子型燃料电池用的膜电极组件作为基本成分,具有高分子电解质膜,夹着聚合物电解质膜的一对电极层和配置在各电极层的外侧的一对气体扩散层。 电介质层分别设置在电极层和气体扩散层之间的一侧以及电层和另一侧的气体扩散层之间。 每个电介质层由多个碳晶须,多个碳颗粒和包含电解质材料的粘合剂构成。 每个电介质层中的碳晶须的含量GW被设定为10重量%<= GW <= 25重量%。 因此,通过降低气体扩散层和电极层之间的接触电阻,用于聚合物电解质燃料电池的膜电极组件可以保持高发电性能。
    • 6. 发明授权
    • Solid polymer cell assembly
    • 固体聚合物电池组件
    • US07566511B2
    • 2009-07-28
    • US10521059
    • 2003-06-26
    • Yoshinori WariishiNaoyuki EnjojiYoichi AsanoHiroshi Shinkai
    • Yoshinori WariishiNaoyuki EnjojiYoichi AsanoHiroshi Shinkai
    • H01M2/00H01M8/10
    • H01M8/04089H01M8/04291H01M8/241H01M8/2484H01M8/249
    • A cell assembly (10) includes a first unit cell (12) and a second unit cell (14). The first unit cell (12) and the second unit cell (14) are juxtaposed such that electrode surfaces of the first unit cell (12) and electrode surfaces of the second unit cell (14) are aligned in parallel with each other. An oxygen-containing gas flow passage (32) includes a first oxygen-containing gas passage (38) in the first unit cell (12), an oxygen-containing gas connection passage (40) in a connection passage member (16), and a second oxygen-containing gas passage (42) in the second unit cell (14). The first oxygen-containing gas passage (38), the oxygen-containing gas connection passage (40), and the second oxygen-containing gas passage (42) are connected serially from the first unit cell (12) to the second unit cell (14).
    • 电池组件(10)包括第一单电池(12)和第二单电池(14)。 第一单电池(12)和第二单电池(14)并置,使得第一单电池(12)的电极表面和第二单电池(14)的电极表面彼此平行排列。 含氧气体流路(32)包括第一单元电池(12)中的第一含氧气体通路(38),连接通路部件(16)中的含氧气体连接通路(40),以及 第二单元电池(14)中的第二含氧气体通道(42)。 第一含氧气体通道(38),含氧气体连接通道(40)和第二含氧气体通道(42)从第一单元电池(12)串联连接到第二单元电池 14)。
    • 7. 发明申请
    • ELECTRODE ELECTROLYTE FOR USE IN SOLID POLYMER FUEL CELL
    • 用于固体聚合物燃料电池的电极电解质
    • US20090130526A1
    • 2009-05-21
    • US11995701
    • 2006-06-30
    • Makoto HigamiIgor RozhanskiiYoshitaka YamakawaNagayuki KanaokaKaoru FukudaRyoichiro TakahashiHiroshi Shinkai
    • Makoto HigamiIgor RozhanskiiYoshitaka YamakawaNagayuki KanaokaKaoru FukudaRyoichiro TakahashiHiroshi Shinkai
    • H01M8/10
    • C08G61/02C08G73/028C08J5/2256C08J2371/12H01M4/8652H01M4/8807H01M4/92H01M4/926H01M8/0239H01M8/1023H01M8/1025H01M8/1027H01M8/103H01M8/1032H01M8/1048H01M8/106
    • This invention provides an electrode electrolyte for a solid polymer-type fuel cell, in which a cost problem and a problem related to recovery of catalyst metals are solved, having excellent proton conductivity, dimensional stability and heat resistance.An electrode electrolyte for a solid polymer electrolyte-type fuel cell contains a polymer, which has a polyphenylene structure as a main chain and both a sulfonic acid group and a nitrogen-containing heterocyclic group as a side chain. A side chain having the nitrogen-containing heterocyclic group has a structure represented by the following general formula (D). (In formula, Z represents at least one kind of structures selected from a group consisting of a direct bond, —O— and —S—, Y represents at least one kind of structures selected from a group consisting of —CO—, —SO2—, —SO—, —CONH—, —COO—, —(CF2)1— (1 is an integer of 1 to 10) and —C(CF3)2— and R20 represents a nitrogen-containing heterocyclic group. q represents an integer of 1 to 5 and p represents an integer of 0 to 4.)The above nitrogen-containing heterocyclic group is at least one kind of group derived from a compound selected from the group consisting of nitrogen-containing heterocyclic compounds including pyrrole, thiazole, isothiazole, oxazole, isoxazole, pyridine, imidazole, imidazoline, pyrazole, 1,3,5-triazine, pyrimidine, pyridazine, pyrazine, indole, quinoline, isoquinoline, purine, benzimidazole, benzoxazole, benzothiazole, tetrazole, tetrazine, triazole, carbazole, acridine, quinoxaline and quinazoline and derivatives thereof.
    • 本发明提供一种固体聚合物型燃料电池用电极电解质,其中解决了成本问题和与催化剂金属的回收相关的问题,具有优异的质子传导性,尺寸稳定性和耐热性。 固体高分子电解质型燃料电池用电极电解质含有作为主链的聚亚苯基结构和磺酸基和含氮杂环基作为侧链的聚合物。 具有含氮杂环基的侧链具有由以下通式(D)表示的结构。 (式中,Z表示选自由直链,-O-和-S-组成的组中的至少一种结构,Y表示选自-CO - , - SO 2的至少一种结构 - , - SO - , - CONH - , - COO - , - (CF 2)1 - (1为1〜10的整数)和-C(CF 3)2 - ,R 20为含氮杂环基 1〜5的整数,p表示0〜4的整数。)上述含氮杂环基是选自包含吡咯,噻唑等含氮杂环化合物的化合物中的至少一种 异噻唑,恶唑,异恶唑,吡啶,咪唑,咪唑啉,吡唑,1,3,5-三嗪,嘧啶,哒嗪,吡嗪,吲哚,喹啉,异喹啉,嘌呤,苯并咪唑,苯并恶唑,苯并噻唑四唑,四嗪,三唑, ,吖啶,喹喔啉和喹唑啉及其衍生物。