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1. 发明授权

US08790551B2 Electrolyte composition, photoelectric conversion element using the same, and dye-sensitized photovoltaic cell 有权
标题翻译：电解质组合物，使用其的光电转换元件和染料敏化光伏电池
公开(公告)号：US08790551B2
公开(公告)日：2014-07-29
申请号：US12485464
申请日：2009-06-16
申请人： Hiroki Usui , Nobuo Tanabe , Hiroshi Matsui , Tetsuya Ezure , Shozo Yanagida
发明人： Hiroki Usui , Nobuo Tanabe , Hiroshi Matsui , Tetsuya Ezure , Shozo Yanagida
IPC分类号： H01G9/032 , H01B1/16 , H01L31/00
CPC分类号： H01B1/04 , B82Y10/00 , B82Y30/00 , H01B1/122 , H01G9/2009 , H01G9/2013 , H01G9/2031 , H01G9/2036 , H01L51/444 , H01M14/005 , H01M2300/0091 , Y02E10/542 , Y10S977/742
摘要： An electrolyte composition containing an ionic liquid and conductive particles, an electrolyte composition containing an ionic liquid and oxide semiconductor particles and optionally containing conductive particles, and an electrolyte composition containing an ionic liquid and insulating particles are provided. Furthermore, a photoelectric conversion element comprising: a working electrode, the working electrode comprising an electrode substrate and an oxide semiconductor porous film formed on the electrode substrate and sensitized with a dye; a counter electrode disposed opposing the working electrode; and an electrolyte layer made of these electrolyte compositions is provided.
摘要翻译：提供含有离子液体和导电颗粒的电解质组合物，含有离子液体和氧化物半导体颗粒以及任选地含有导电颗粒的电解质组合物，以及含有离子液体和绝缘颗粒的电解质组合物。此外，一种光电转换元件，包括：工作电极，所述工作电极包括电极基板和形成在所述电极基板上并用染料敏化的氧化物半导体多孔膜; 与所述工作电极相对设置的对置电极; 并且提供由这些电解质组合物制成的电解质层。

2. 发明授权

US08785765B2 Electrolyte composition, photoelectric converter and dye-sensitized solar cell using same 有权
标题翻译：电解质组合物，光电转换器和染料敏化太阳能电池使用相同
公开(公告)号：US08785765B2
公开(公告)日：2014-07-22
申请号：US10564314
申请日：2004-07-12
申请人： Hiroki Usui , Nobuo Tanabe , Hiroshi Matsui , Tetsuya Ezure , Shozo Yanagida
发明人： Hiroki Usui , Nobuo Tanabe , Hiroshi Matsui , Tetsuya Ezure , Shozo Yanagida
IPC分类号： H01L31/00 , H01L31/04 , H01G9/20 , B82Y30/00 , H01M14/00 , H01B1/04 , H01B1/12 , B82Y10/00 , H01L51/44
CPC分类号： H01B1/04 , B82Y10/00 , B82Y30/00 , H01B1/122 , H01G9/2009 , H01G9/2013 , H01G9/2031 , H01G9/2036 , H01L51/444 , H01M14/005 , H01M2300/0091 , Y02E10/542 , Y10S977/742
摘要： An electrolyte composition containing an ionic liquid and conductive particles, an electrolyte composition containing an ionic liquid and oxide semiconductor particles and optionally containing conductive particles, and an electrolyte composition containing an ionic liquid and insulating particles are provided. Furthermore, a photoelectric conversion element comprising: a working electrode, the working electrode comprising an electrode substrate and an oxide semiconductor porous film formed on the electrode substrate and sensitized with a dye; a counter electrode disposed opposing the working electrode; and an electrolyte layer made of these electrolyte compositions is provided.
摘要翻译：提供含有离子液体和导电颗粒的电解质组合物，含有离子液体和氧化物半导体颗粒以及任选地含有导电颗粒的电解质组合物，以及含有离子液体和绝缘颗粒的电解质组合物。此外，一种光电转换元件，包括：工作电极，所述工作电极包括电极基板和形成在所述电极基板上并用染料敏化的氧化物半导体多孔膜; 与所述工作电极相对设置的对置电极; 并且提供由这些电解质组合物制成的电解质层。

3. 发明授权

US07872191B2 Electrolyte composition, photoelectric conversion element using the same, and dye-sensitized photovoltaic cell 有权
标题翻译：电解质组合物，使用其的光电转换元件和染料敏化光伏电池
公开(公告)号：US07872191B2
公开(公告)日：2011-01-18
申请号：US12486004
申请日：2009-06-17
申请人： Hiroki Usui , Nobuo Tanabe , Hiroshi Matsui , Tetsuya Ezure , Shozo Yanagida
发明人： Hiroki Usui , Nobuo Tanabe , Hiroshi Matsui , Tetsuya Ezure , Shozo Yanagida
IPC分类号： H01L25/00
CPC分类号： H01B1/04 , B82Y10/00 , B82Y30/00 , H01B1/122 , H01G9/2009 , H01G9/2013 , H01G9/2031 , H01G9/2036 , H01L51/444 , H01M14/005 , H01M2300/0091 , Y02E10/542 , Y10S977/742
摘要： An electrolyte composition containing an ionic liquid and conductive particles, an electrolyte composition containing an ionic liquid and oxide semiconductor particles and optionally containing conductive particles, and an electrolyte composition containing an ionic liquid and insulating particles are provided. Furthermore, a photoelectric conversion element comprising: a working electrode, the working electrode comprising an electrode substrate and an oxide semiconductor porous film formed on the electrode substrate and sensitized with a dye; a counter electrode disposed opposing the working electrode; and an electrolyte layer made of these electrolyte compositions is provided.
摘要翻译：提供含有离子液体和导电颗粒的电解质组合物，含有离子液体和氧化物半导体颗粒以及任选地含有导电颗粒的电解质组合物，以及含有离子液体和绝缘颗粒的电解质组合物。此外，一种光电转换元件，包括：工作电极，所述工作电极包括电极基板和形成在所述电极基板上并用染料敏化的氧化物半导体多孔膜; 与所述工作电极相对设置的对置电极; 并且提供由这些电解质组合物制成的电解质层。

4. 发明申请

US20060174932A1 Electrolyte compositon, photoelectric converter and dye-sensitized solar cell using same 有权
标题翻译：电解质组合物，光电转换器和使用其的染料敏化太阳能电池
公开(公告)号：US20060174932A1
公开(公告)日：2006-08-10
申请号：US10564314
申请日：2004-07-12
申请人： Hiroki Usui , Nobuo Tanabe , Hiroshi Matsui , Tetsuya Ezure , Shozo Yanagida
发明人： Hiroki Usui , Nobuo Tanabe , Hiroshi Matsui , Tetsuya Ezure , Shozo Yanagida
IPC分类号： H01L31/00 , H01G9/022
CPC分类号： H01B1/04 , B82Y10/00 , B82Y30/00 , H01B1/122 , H01G9/2009 , H01G9/2013 , H01G9/2031 , H01G9/2036 , H01L51/444 , H01M14/005 , H01M2300/0091 , Y02E10/542 , Y10S977/742
摘要： An electrolyte composition containing an ionic liquid and conductive particles as main components, an electrolyte composition containing an ionic liquid, and oxide semiconductor particles or oxide semiconductor particles, and conductive particles, and an electrolyte composition containing an ionic liquid and insulating particles are provided. Furthermore, a photoelectric conversion element comprising: a working electrode, the working electrode comprising an electrode substrate and an oxide semiconductor porous film formed on the electrode substrate and sensitized with a dye; a counter electrode disposed opposing the working electrode; and an electrolyte layer made of these electrolyte compositions is provided.
摘要翻译：提供了含有离子液体和导电性粒子作为主要成分的电解质组合物，含有离子性液体的电解质组合物，氧化物半导体粒子或氧化物半导体粒子以及导电粒子，以及含有离子液体和绝缘粒子的电解质组合物。此外，一种光电转换元件，包括：工作电极，所述工作电极包括电极基板和形成在所述电极基板上并用染料敏化的氧化物半导体多孔膜; 与所述工作电极相对设置的对置电极; 并且提供由这些电解质组合物制成的电解质层。

5. 发明申请

US20120126206A1 ORGANIC SEMICONDUCTOR DEVICE 有权
标题翻译：有机半导体器件
公开(公告)号：US20120126206A1
公开(公告)日：2012-05-24
申请号：US13131003
申请日：2009-11-25
申请人： Yasushi Morita , Masaaki Yokoyama , Shozo Yanagida , Yoshihisa Tawada , Kenji Yamamoto , Ryotaro Tsuji
发明人： Yasushi Morita , Masaaki Yokoyama , Shozo Yanagida , Yoshihisa Tawada , Kenji Yamamoto , Ryotaro Tsuji
IPC分类号： H01L51/30
CPC分类号： H01L51/0056 , H01L51/424 , H01L51/5012 , H01L51/5048 , H01L51/5088 , Y02E10/549 , Y10S428/917
摘要： An organic semiconductor device according to the present invention includes a semiconductor layer 14 interposed between two electrodes 12 and 15, and the semiconductor layer 14 contains a trioxotriangulene (TOT) derivative, which is a neutral radical compound, as a semiconductor material. The semiconductor layer 14 acts as an n-type semiconductor and coacts with a p-type semiconductor layer 13 to exhibit a photoelectric conversion effect. The organic semiconductor device is characterized as including a semiconductor layer that has a narrow band gap, has light absorption performance in an infrared region, and is high in carrier mobility.
摘要翻译：根据本发明的有机半导体器件包括插入在两个电极12和15之间的半导体层14，并且半导体层14包含作为半导体材料的作为中性自由基化合物的三氧化三三烯（TOT）衍生物。半导体层14用作n型半导体并与p型半导体层13共同显示光电转换效果。有机半导体器件的特征在于包括具有窄带隙的半导体层，在红外区域具有光吸收性能，并且载流子迁移率高。

6. 发明授权

US06300481B1 Rare earth complexes 失效
标题翻译：稀土配合物
公开(公告)号：US06300481B1
公开(公告)日：2001-10-09
申请号：US09380828
申请日：1999-09-10
申请人： Shozo Yanagida , Yasuchika Hasegawa , Yuji Wada , Tatsuhiko Yamanaka , Takashi Okubo
发明人： Shozo Yanagida , Yasuchika Hasegawa , Yuji Wada , Tatsuhiko Yamanaka , Takashi Okubo
IPC分类号： C07F500
CPC分类号： C07C309/06 , C07C311/48
摘要： The present invention provides an optically functional material comprising a rare-earth complex represented by the formula (I) wherein M is a rare-earth atom, n1 is 2 or 3, n2 is 2, 3 or 4, R is a C1-C20 group containing no H, X is a Group IVA atom, Group VA atom other than nitrogen or Group VIA atom other than oxygen, n3 is 0 or 1, and Y is C-Z′ (wherein Z′ is D, a halogen or C1-C20 group containing no H), N, P, As, Sb or Bi, or by the formula (II) wherein N, R, X, n1, n2 and n3 are as defined above.
摘要翻译：本发明提供一种光学功能材料，其包括由式（I）表示的稀土配合物，其中M为稀土原子，n1为2或3，n2为2,3或4，R为C1-C20 不含H的基团，X是除了氧以外的氮或VIA族的IVA族原子，VA族原子，n3为0或1，Y为CZ'（其中Z'为D，卤素或C1-C20 不含H），N，P，As，Sb或Bi的化合物，或其中N，R，X，n1，n2和n3如上定义的式（II）。

7. 发明授权

US08933437B2 Organic semiconductor material with neutral radical compound of a trioxotriangulene derivative as a semiconductor material 有权
标题翻译：具有作为半导体材料的三氧三三烯衍生物的中性自由基化合物的有机半导体器件
公开(公告)号：US08933437B2
公开(公告)日：2015-01-13
申请号：US13131003
申请日：2009-11-25
申请人： Yasushi Morita , Masaaki Yokoyama , Shozo Yanagida , Yoshihisa Tawada , Kenji Yamamoto , Ryotaro Tsuji
发明人： Yasushi Morita , Masaaki Yokoyama , Shozo Yanagida , Yoshihisa Tawada , Kenji Yamamoto , Ryotaro Tsuji
IPC分类号： H01L51/30 , H01L51/00 , H01L51/42 , H01L51/50
CPC分类号： H01L51/0056 , H01L51/424 , H01L51/5012 , H01L51/5048 , H01L51/5088 , Y02E10/549 , Y10S428/917
摘要： An organic semiconductor device according to the present invention includes a semiconductor layer 14 interposed between two electrodes 12 and 15, and the semiconductor layer 14 contains a trioxotriangulene (TOT) derivative, which is a neutral radical compound, as a semiconductor material. The semiconductor layer 14 acts as an n-type semiconductor and coacts with a p-type semiconductor layer 13 to exhibit a photoelectric conversion effect. The organic semiconductor device is characterized as including a semiconductor layer that has a narrow band gap, has light absorption performance in an infrared region, and is high in carrier mobility.
摘要翻译：根据本发明的有机半导体器件包括插入在两个电极12和15之间的半导体层14，并且半导体层14包含作为半导体材料的作为中性自由基化合物的三氧化三三烯（TOT）衍生物。半导体层14用作n型半导体并与p型半导体层13共同显示光电转换效果。有机半导体器件的特征在于包括具有窄带隙的半导体层，在红外区域具有光吸收性能，并且载流子迁移率高。

8. 发明申请

US20070166836A1 Rare earth complex excellent in thermal resistance 审中-公开
标题翻译：稀土复合材料具有优异的耐热性
公开(公告)号：US20070166836A1
公开(公告)日：2007-07-19
申请号：US10574778
申请日：2004-10-07
申请人： Kazuhiro Manseki , Yasuchika Hasegawa , Shozo Yanagida
发明人： Kazuhiro Manseki , Yasuchika Hasegawa , Shozo Yanagida
IPC分类号： C07F5/00 , G01N33/543
CPC分类号： C07F5/003 , C07C69/88 , C09K11/06 , C09K2211/1007 , C09K2211/182
摘要： The present invention provides a fluorescent substance excellent in thermal resistance, which can be uniformly dispersed into plastic materials, and has a high fluorescence intensity even after experienced heat history in plastic forming processes. More specifically, the present invention provides a fluorescent substance containing a rare earth complex having benzophenone or benzoyl substituted with an alkyl group, a cycloalkyl group, an acyl group or an alkoxy group having a carbon number of 1 to 20 as a skeletal structure, in which a plurality of rare earth ions are coordinated with one or more types of molecules having a photosensitizing function.
摘要翻译：本发明提供耐热性优异的荧光物质，其可以均匀分散在塑料材料中，并且即使在塑性成型工艺中经历了热历史之后也具有高的荧光强度。更具体地说，本发明提供了含有具有二苯甲酮或被烷基，环烷基，酰基或碳数为1〜20的烷氧基取代的苯甲酰基作为骨架结构的稀土配合物的荧光物质，其中多个稀土离子与具有光敏功能的一种或多种类型的分子配位。

9. 发明授权

US06822159B2 Dye-sensitized photoelectric conversion device 失效
标题翻译：染料敏化光电转换装置
公开(公告)号：US06822159B2
公开(公告)日：2004-11-23
申请号：US10311036
申请日：2002-12-12
申请人： Masaaki Ikeda , Koichiro Shigaki , Teruhisa Inoue , Shozo Yanagida
发明人： Masaaki Ikeda , Koichiro Shigaki , Teruhisa Inoue , Shozo Yanagida
IPC分类号： H01M1400
CPC分类号： H01L51/0052 , H01G9/2031 , H01G9/2059 , H01L51/005 , H01L51/0058 , H01L51/0086 , H01L51/4226 , Y02E10/542 , Y02E10/549
摘要： The present invention aims at developing a low-cost photoelectric conversion device having favorable conversion efficiency and a solar cell and, accordingly, relates to a photoelectric conversion device of a semiconductor fine particles, being sensitized with an organic dye, which adsorbs thereon a specified azo dye expressed by the general formula 1: wherein Ar 1 represents an aromatic group having at least one substituent selected from the group consisting of a carboxylic acid group, a hydroxyl group, a phosphoric acid group, a phosphoric acid ester group and a mercapto group either directly or via a cross-linking group; and Ar 2 represents an aromatic group having at least one electron-donating group as a substituent, and also to a solar cell using the photoelectric conversion device.
摘要翻译：本发明的目的在于开发一种具有良好转换效率的低成本光电转换装置和太阳能电池，因此涉及一种用有机染料敏化的半导体细颗粒的光电转换装置，其上吸附有特定的偶氮由通式1表示的染料：其中Ar 1表示具有至少一个选自羧酸基，羟基，磷酸基，磷酸酯基和巯基的取代基的芳族基团直接或通过交联组; 并且Ar 2表示具有至少一个供电子基团作为取代基的芳族基团，也包括使用该光电转换装置的太阳能电池。

10. 发明授权

US08106198B2 Photosensitizer dye 有权
标题翻译：光敏剂染料
公开(公告)号：US08106198B2
公开(公告)日：2012-01-31
申请号：US12223601
申请日：2007-02-05
申请人： Ke-Jian Jiang , Shuji Noda , Shozo Yanagida
发明人： Ke-Jian Jiang , Shuji Noda , Shozo Yanagida
IPC分类号： C07F15/00 , H01L31/00
CPC分类号： C09B57/10 , C07D213/38 , C07D409/14 , H01G9/2031 , H01G9/2059 , H01L51/0086 , H01M14/005 , Y02E10/542 , Y02E10/549
摘要： A theme of the present invention is to provide a new transition metal complex, useful as a photosensitizer dye for a photoelectric conversion element having an excellent durability and a high photoelectric conversion characteristic. The present invention provides a bivalent transition metal complex constituted of (i) a bipyridyl polyacidic ligand, such as a dicarboxybipyridyl (dcbpy) ligand, as an adsorption site for adsorption onto titanium dioxide particle surfaces; (ii) a ligand, selected from the group consisting of an isothiocyanato group, an isocyanato group, and an isoselenocyanato group and enabling absorption and excitation at long wavelengths and charge transfer; and (iii) a bipyridyl (bpy) ligand, having an alkyl group or an alkoxy group, preferably a long-chain alkyl group, and a conjugately bonded thienylvinylene group, aminophenylenevinylene group, etc., and improving an absorbance of a transition metal complex and imparting stability against nucleophile to a sensitizer dye that improves an absorption bathochromic effect.
摘要翻译：本发明的主题是提供一种新的过渡金属络合物，其可用作具有优异耐久性和高光电转换特性的光电转换元件的光敏染料。本发明提供由（i）二吡啶基多酸配体如二羧基联吡啶（dcbpy）配体构成的二价过渡金属络合物作为吸附在二氧化钛颗粒表面上的吸附位点; （ii）选自异硫氰酸酯基，异氰酸基和异硒基异氰酸酯基的配体，并且能够在长波长和电荷转移下进行吸收和激发; 和（iii）具有烷基或烷氧基，优选长链烷基和共轭键合的噻吩基亚乙烯基，氨基亚苯基亚乙烯基等的联吡啶（bpy）配体，并改善过渡金属络合物的吸光度并赋予敏化剂染料对亲核试剂的稳定性，改善了吸收红细胞色素的作用。

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