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1. 发明授权

US4072726A Hydrogenation of fluorinated esters 失效
标题翻译：氟化酯的氢化
公开(公告)号：US4072726A
公开(公告)日：1978-02-07
申请号：US761160
申请日：1977-01-21
申请人： Henry R. Nychka , Richard E. Eibeck , Martin A. Robinson , Edward S. Jones
发明人： Henry R. Nychka , Richard E. Eibeck , Martin A. Robinson , Edward S. Jones
IPC分类号： C07C29/149 , C07C31/34 , C07C29/00
CPC分类号： C07C29/149
摘要： Fluorinated esters of the formula C.sub.n H.sub.x F.sub.2n+1-x CO.sub.2 CH.sub.2 C.sub.m H.sub.y F.sub.2m+1-y such as CF.sub.3 CO.sub.2 CH.sub.2 CF.sub.3 are hydrogenated to fluorinated alcohols such as CF.sub.3 CH.sub.2 OH using a catalyst having between 50 and 100 percent, and preferably 75-95 percent CuO by weight. In the above formula n= 1 to 13, m= 1 to 13, x= 0 to 3 and y= 0 to 3. In the most preferred esters, n= m and x= y= 0. The catalyst may also contain 0-50 percent and preferably 5-25 percent by weight of a filler or binder such as a silicate salt. The reaction produces greater yields of alcohol and longer catalyst life than with chromite catalysts, and may proceed at substantially atmospheric pressures.
摘要翻译：使用具有50至100重量％，优选75-95重量％的CuO的催化剂将式CnH x F 2n + 1-x CO 2 CH 2 CmHyF 2 m + 1-y的氟化酯如CF 3 CO 2 CH 2 CF 3氢化成氟化醇如CF 3 CH 2 OH。在上式中，n = 1至13，m = 1至13，x = 0至3，y = 0至3.在最优选的酯中，n = m且x = y = 0。催化剂还可以含有0 -50％，优选5-25％重量的填料或粘合剂如硅酸盐。与铬铁矿催化剂相比，反应产生更高的醇产率和更长的催化剂寿命，并且可以在基本上大气压下进行。

2. 发明授权

US4377715A Production of perfluoropropane 失效
标题翻译：生产全氟丙烷
公开(公告)号：US4377715A
公开(公告)日：1983-03-22
申请号：US107123
申请日：1979-12-26
申请人： Henry R. Nychka , John B. Hino , Richard E. Eibeck , Martin A. Robinson
发明人： Henry R. Nychka , John B. Hino , Richard E. Eibeck , Martin A. Robinson
IPC分类号： B01J12/00 , B01J19/24 , C07B39/00 , C07C17/00 , C07C17/04 , C07C17/10 , C07C21/18 , C07C41/22 , C07C45/63 , C07C51/62 , C07C67/00 , C07C17/02
CPC分类号： C07C17/10 , B01J12/00 , B01J19/2415 , C07B39/00 , C07C17/04 , C07C45/63 , C07C51/62 , B01J2219/00063 , B01J2219/00069
摘要： Octafluoropropane or perfluoropropane is produced by introducing fluorine into an elongated inner zone surrounded by a porous member which is substantially resistant to fluorine corrosion and introducing a three carbon compound which is propane, a partially fluorinated propane, propene, a partially fluorinated propene, hexafluoropropene or mixtures thereof outside the porous member. When the porous member is metal, a perfluorinated diluent is used. When the porous member is fused alumina, conventional diluents such as nitrogen, or even no diluent may be employed.
摘要翻译：通过将氟引入到由多孔构件包围的细长的内部区域中产生，所述多孔构件基本上耐氟腐蚀，并引入三碳化合物，其是丙烷，部分氟化的丙烷，丙烯，部分氟化的丙烯，六氟丙烯或混合物在多孔构件外面。当多孔构件是金属时，使用全氟化稀释剂。当多孔构件是熔融氧化铝时，可以使用常规的稀释剂如氮气，甚至不使用稀释剂。

3. 发明授权

US4012453A Process for the production of chlorofluorinated aromatic hydrocarbons 失效
标题翻译：生产氯氟化芳烃的方法
公开(公告)号：US4012453A
公开(公告)日：1977-03-15
申请号：US642873
申请日：1975-12-22
申请人： Henry R. Nychka , Morris B. Berenbaum , Martin A. Robinson , Richard E. Eibeck
发明人： Henry R. Nychka , Morris B. Berenbaum , Martin A. Robinson , Richard E. Eibeck
IPC分类号： C07C17/15 , C07C17/156 , C07C25/18 , C07C25/04 , C07C25/13
CPC分类号： C07C17/15 , C07C17/156
摘要： Chlorofluorinated aromatic hydrocarbons may be effectively produced by an oxychlorofluorination process by reacting a gaseous mixture of a starting material selected from an aromatic hydrocarbon and an aromatic hydrohalocarbon in which the halo atoms are selected from chloro and fluoro, or mixtures thereof, an oxygen-containing gas, a chlorinating agent selected from the group consisting of HCl and Cl.sub.2 and mixtures thereof, and HF, in the presence of a Deacon catalyst supported by a stable, inert metal salt carrier.
摘要翻译：氯氟化芳烃可以通过氧氯氟化方法通过使选自芳族烃和卤素原子选自氯和氟的芳族氢卤烃的起始材料的气体混合物或其混合物，含氧气体，在由稳定的惰性金属盐载体负载的Deacon催化剂存在下，选自HCl和Cl 2的氯化剂及其混合物和HF。

4. 发明授权

US4227027A Recyclable boron trifluoride catalyst and method of using same 失效
标题翻译：可再利用的三氟化硼催化剂及其使用方法
公开(公告)号：US4227027A
公开(公告)日：1980-10-07
申请号：US96955
申请日：1979-11-23
申请人： Robert E. Booth , Francis E. Evans , Richard E. Eibeck , Martin A. Robinson
发明人： Robert E. Booth , Francis E. Evans , Richard E. Eibeck , Martin A. Robinson
IPC分类号： C07C2/20 , C07C2/68 , C07C3/56 , C07C3/18
CPC分类号： C07C2/20 , C07C2/68 , C07C2527/1213 , C07C2531/02 , Y02P20/584
摘要： When saturated with boron trifluoride, certain polyhydric alcohols form adducts which catalyze hydrocarbon alkyl transfer reactions for which boron trifluoride is catalytic. The adduct is recovered from the reaction mixture and recycled, greatly reducing boron and fluoride values in the product and in any effluent. Examples include propylation of toluene in the presence of a recycled adduct of boron trifluoride with mannitol or sorbitol, and the oligomerization of decene by a recycled adduct of boron trifluoride with mannitol or butanediol. Some of the catalysts become viscous on cooling and are thus more easily separated from the reaction products which remain in a separate liquid phase.
摘要翻译：当三氟化硼饱和时，某些多元醇形成催化三氟化硼催化的烃烷基转移反应的加合物。加合物从反应混合物中回收并循环使用，大大降低了产品和任何流出物中的硼和氟化物值。实例包括在三氟化硼与甘露糖醇或山梨糖醇的再循环加合物存在下甲苯的丙基化，以及通过三氟化硼与甘露糖醇或丁二醇的再循环加合物使癸烯低聚。一些催化剂在冷却时变得粘稠，因此更容易与保留在单独的液相中的反应产物分离。

5. 发明授权

US4371707A Process for the conversion of boron trifluoride dimethyl ether complex to the boron trifluoride dialkyl ether complex 失效
标题翻译：三氟化硼二甲醚络合物转化为三氟化硼二烷基醚络合物的方法
公开(公告)号：US4371707A
公开(公告)日：1983-02-01
申请号：US216045
申请日：1980-12-15
申请人： Richard E. Eibeck , Martin A. Robinson , Francis E. Evans , Eugene B. Recla
发明人： Richard E. Eibeck , Martin A. Robinson , Francis E. Evans , Eugene B. Recla
IPC分类号： C07F5/02
CPC分类号： C07F5/02
摘要： A process for the conversion of boron trifluoride dimethyl ether complex to boron trifluoride dialkyl ether complex substantially free of dimethyl ether impurities, which comprises reacting the boron trifluoride-dimethyl ether complex, in the liquid phase, in the presence of dialkyl ether wherein at least one of the alkyl groups contains at least two carbon atoms, in a restricted vapor equilibration region, while simultaneously sweeping the said vapor equilibration region with a substantially inert gas, and heating to distill off the dimethyl ether. High purity of the boron trifluoride dialkyl ether complex is attained with this method, with only minimal traces of the boron trifluoride dimethyl ether complex, dimethyl ether remaining. The preferred product is boron trifluoride diethyl ether.
摘要翻译：一种将三氟化硼二甲醚络合物转化为基本上不含二甲醚杂质的三氟化硼二烷基醚络合物的方法，其包括使三氟化硼 - 二甲醚络合物在液相中在二烷基醚存在下反应，其中至少一种的烷基在受限的蒸气平衡区域中含有至少两个碳原子，同时用基本上惰性的气体同时吹扫所述蒸气平衡区域，并加热以蒸馏除去二甲醚。通过该方法可以获得三氟化硼二烷基醚络合物的高纯度，只剩下少量的三氟化硼二甲醚络合物，二甲醚。优选的产物是三氟化硼二乙醚。

6. 发明授权

US4337361A Liquid phase synthesis of hexafluoroacetone 失效
标题翻译：六氟丙酮的液相合成
公开(公告)号：US4337361A
公开(公告)日：1982-06-29
申请号：US238920
申请日：1981-02-27
申请人： Louis G. Anello , Michael Van Der Puy , Martin A. Robinson , Richard E. Eibeck
发明人： Louis G. Anello , Michael Van Der Puy , Martin A. Robinson , Richard E. Eibeck
IPC分类号： C07C49/167 , B01J27/00 , B01J27/12 , C07B61/00 , C07C45/00 , C07C45/27 , C07C45/32 , C07C45/56 , C07C67/00
CPC分类号： C07C45/567
摘要： A process for the preparation of hexafluoroacetone which comprises contacting, in the liquid phase, hexafluorothioacetone dimer in the presence of an aprotic solvent containing a catalytic amount of an alkali metal fluoride with a gaseous oxidant selected from the group consisting of air, O.sub.2, O.sub.3, NO.sub.2 and NO is disclosed. The preferred aprotic solvent is dimethylformamide, and the preferred gaseous oxidant is O.sub.2.
摘要翻译：一种制备六氟丙酮的方法，该方法包括在含有催化量的碱金属氟化物的非质子溶剂存在下，在液相中与六氟硫代丙酮二聚物与选自空气，O 2，O 3，公开了NO2和NO。优选的非质子溶剂是二甲基甲酰胺，优选的气态氧化剂是O 2。

7. 发明授权

US4265871A Purification of boron-containing sulfuric acid 失效
标题翻译：含硼硫酸的纯化
公开(公告)号：US4265871A
公开(公告)日：1981-05-05
申请号：US36464
申请日：1979-05-07
申请人： Charles J. Felice, Jr. , Francis E. Evans , Martin A. Robinson , Richard E. Eibeck
发明人： Charles J. Felice, Jr. , Francis E. Evans , Martin A. Robinson , Richard E. Eibeck
IPC分类号： C01B35/00 , C01B17/90 , C01B35/06 , C01B7/00 , C01B9/08
CPC分类号： C01B17/90
摘要： Sulfuric acid contaminated with boron and fluoride values such as the waste acid of a boron trifluoride process is purified by contacting the contaminated acid with an inert gas to desorb boron trifluoride, and the inert gas is stripped by contacting with an absorbing liquid including concentrated sulfuric acid. Fluosulfonic acid is added to contaminated sulfuric acid at levels approximately three times the molar values of boric acid contaminant as an agent to spring non-volatile boron values. The absorption of boron trifluoride into the absorbing sulfuric acid is improved when it contains boric acid. Preferably the contaminated sulfuric acid to be purified is one portion of the waste liquid and the absorbing liquid is another portion of the waste liquid of a boron trifluoride manufacturing process. Boric acid is added to the absorbing liquid, then boron trifluoride is stripped from the inert gas and absorbed into the absorbing liquid. The absorbing liquid along with stripped boron trifluoride is recycled to a boron trifluoride manufacturing process. The inert gas can be recycled to the desorbing step.
摘要翻译：用硼污染的硫酸和三氟化硼处理的废酸等氟化物值通过使被污染的酸与惰性气体接触以解吸三氟化硼来净化，并且通过与包含浓硫酸的吸收液体接触来汽提惰性气体。将氟磺酸加入到污染硫酸中，其水平为硼酸污染物的摩尔值的三倍，作为弹性非挥发性硼值的试剂。当含有硼酸时，三氟化硼在吸收硫酸中的吸收得到改善。优选地，被净化的污染硫酸是废液的一部分，吸收液是三氟化硼制造方法的废液的另一部分。将硼酸加入到吸收液中，然后从惰性气体中汽提三氟化硼并吸收到吸收液中。将吸收液与汽提的三氟化硼一起再循环至三氟化硼制造方法。惰性气体可以再循环到解吸步骤。

8. 发明授权

US4209654A Recyclable boron trifluoride catalyst and method of using same 失效
标题翻译：可再利用的三氟化硼催化剂及其使用方法
公开(公告)号：US4209654A
公开(公告)日：1980-06-24
申请号：US951911
申请日：1978-10-16
申请人： Robert E. Booth , Francis E. Evans , Richard E. Eibeck , Martin A. Robinson
发明人： Robert E. Booth , Francis E. Evans , Richard E. Eibeck , Martin A. Robinson
IPC分类号： C07C2/32 , B01J27/12 , B01J31/22 , B01J31/26 , C07B61/00 , C07C1/00 , C07C2/20 , C07C2/22 , C07C2/68 , C07C11/02 , C07C67/00 , C07C3/56 , C07C3/18
CPC分类号： B01J31/2226 , B01J27/12 , C07C2/20 , C07C2/68 , B01J2231/4205 , B01J2531/30 , B01J31/0201 , B01J31/26 , C07C2527/1213 , C07C2531/02 , Y02P20/584
摘要： When saturated with boron trifluoride, certain polyhydric alcohols form adducts which catalyze reactions for which boron trifluoride is catalytic. The adduct is recovered from the reaction mixture and recycled, greatly reducing boron and fluoride values in the product and in any effluent. Examples include propylation of toluene in the presence of a recycled adduct of boron trifluoride with mannitol or sorbitol.
摘要翻译：当三氟化硼饱和时，某些多元醇形成催化三氟化硼催化反应的加合物。加合物从反应混合物中回收并循环使用，大大降低了产品和任何流出物中的硼和氟化物值。实例包括在三氟化硼与甘露糖醇或山梨糖醇的再循环加合物存在下丙烯化甲苯。

9. 发明授权

US4374782A Synthesis of trifluoroacetyl fluoride 失效
标题翻译：三氟乙酰氟的合成
公开(公告)号：US4374782A
公开(公告)日：1983-02-22
申请号：US275009
申请日：1981-06-18
申请人： Louis G. Anello , Michael Van Der Puy , Martin A. Robinson , Richard E. Eibeck
发明人： Louis G. Anello , Michael Van Der Puy , Martin A. Robinson , Richard E. Eibeck
IPC分类号： C07C51/58
CPC分类号： C07C51/58
摘要： A process for the preparation of trifluoroacetyl fluoride is disclosed, which comprises reacting, in the liquid phase, hexafluorothioacetone dimer in an aprotic solvent with at least a catalytic amount of an alkali metal fluoride in the presence of an oxidizing agent selected from the group consisting of Ag.sub.2 O, oxides of Pb, Sn, Ni, Co and Fe and M.sub.2 S.sub.2 O.sub.8 wherein M is an alkali metal. The preferred aprotic solvent is dimethylformamide; the preferred alkali metal fluoride is KF; and the preferred oxidizing agents are NiO, PbO.sub.2, and M.sub.2 S.sub.2 O.sub.8 wherein M is Na or K.
摘要翻译：公开了一种制备三氟乙酰氟的方法，其包括使液相中的六氟硫代丙酮二聚体在非质子传递溶剂中与至少一种催化量的碱金属氟化物在选自以下的氧化剂存在下反应： Ag2O，Pb，Sn，Ni，Co和Fe的氧化物和M2S2O8，其中M是碱金属。优选的非质子溶剂是二甲基甲酰胺; 优选的碱金属氟化物为KF; 优选的氧化剂是NiO，PbO2和M2S2O8，其中M是Na或K.

10. 发明授权

US4174349A Preparation of fluoroorganic compounds with calcium fluoride 失效
标题翻译：用氟化钙制备氟代有机化合物
公开(公告)号：US4174349A
公开(公告)日：1979-11-13
申请号：US955679
申请日：1978-10-30
申请人： Francis E. Evans , Morris B. Berenbaum , Richard E. Eibeck , Martin A. Robinson
发明人： Francis E. Evans , Morris B. Berenbaum , Richard E. Eibeck , Martin A. Robinson
IPC分类号： C07B39/00 , C07B31/00 , C07C17/20 , C07C45/63 , C07C51/58 , C07C67/00 , C07C17/10 , C07C17/12 , C07C17/14
CPC分类号： C07C45/63 , C07C17/208 , C07C51/58
摘要： Fluoroorganic compounds are prepared by reacting a haloorganic starting material in which at least one halo atom is replaceable with a fluorine atom by metathetical exchange, with calcium fluoride in the presence of a crown ether and an anhydrous, polar, basic organic solvent which complexes with the calcium ion and contains no --OH groups, at a temperature and for a period of time adequate to effect fluorination.
摘要翻译：通过在冠醚和无水极性的碱性有机溶剂的存在下，通过使其中至少一个卤原子可与氟原子进行元间交换的氟代氟化物与氟化钙反应来制备氟有机化合物，该有机溶剂与钙离子，并且在温度和时间足以实现氟化时不含-OH基团。

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