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    • 6. 发明授权
    • Production of monoolefin oligomer
    • 单烯烃低聚物的生产
    • US5877375A
    • 1999-03-02
    • US659661
    • 1996-06-06
    • Michel Clarembeau
    • Michel Clarembeau
    • C07C2/20C07C2/08
    • C07C2/20C07C2527/1213C07C2531/02
    • A monoolefin oligomerization process which gives high yields of dimer and trimer at high monoolefin conversions in a single stage reaction is described. The process involves contacting a C.sub.6-20 vinyl olefin with a catalyst comprising boron trifluoride and from 0.075 to 0.5 mol %, based on the total quantity of monoolefin being used, of an alcohol catalyst promoter. The oligomerization is performed at a temperature below about 40.degree. C. and under a pressurized atmosphere of boron trifluoride in the range of 2 to 4 bars gauge until the monoolefin conversion is at least 95% and the combined total of dimer and trimer in the liquid reaction mixture is at least 60% by weight.
    • 描述了在单阶段反应中在高单烯烃转化下提供高产率的二聚物和三聚体的单烯烃低聚方法。 该方法包括使C 6-20乙烯基烯烃与包含三氟化硼的催化剂和基于所使用的单烯烃的总量的0.075至0.5mol%的醇催化剂促进剂接触。 低聚反应在低于约40℃的温度下进行,并在三氟化硼的压力气氛下在2至4巴的规格范围内进行,直到单烯烃转化率至少为95%,液体中二聚体和三聚体的总和 反应混合物为至少60重量%。