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    • 9. 发明授权
    • Ester-urethane derivatives of (meth)-acrylic acid for dental materials
    • 用于牙科材料的(甲基)丙烯酸的酯 - 氨基甲酸酯衍生物
    • US4904750A
    • 1990-02-27
    • US287424
    • 1988-12-20
    • Jurgen ReinersCarlhans SulingWalter SchaferHanns P. MullerWolfgang PodszunJens Winkel
    • Jurgen ReinersCarlhans SulingWalter SchaferHanns P. MullerWolfgang PodszunJens Winkel
    • A61K6/083A61K6/09C07C271/22C08F20/34C08F220/36C08F290/00C08F299/00C08G18/67C08G18/72
    • A61K6/0017A61K6/09C07C271/22C08G18/672C08G18/72
    • Dental fillings, coatings and teeth are formed of polymers and copolymers of a polyfunctional ester-urethane derivative of (meth)-acrylic acid of the formula ##STR1## in which A is a straight-chain or branched aliphatic radical which has 2 to 20 carbon atoms and optionally contains 1 to 3 oxygen bridges, an aromatic radical with 6 to 24 carbon atoms, an araliphatic radical with 7 to 26 carbon atoms or a cycloaliphatic radical with 6 to 26 carbon atoms,r denotes the number of chains starting from A and denotes a number from 2 to 6,R.sup.1 and R.sup.2 are identical and denote hydrogen or are different and denote hydrogen and methyl,n denotes a number from 0 to 5 independently for each chain starting from A,X stands for the group ##STR2## in which Y denotes a divalent (cyclo)aliphatic radical which has 2 to 15 carbon atoms and optionally contains ester, ether or urethane groups,Z denotes a divalent straight-chain or branched aliphatic hydrocarbon radical which has 3 to 15 carbon atoms and can optionally contain 1 to 3 oxygen bridges and can optionally be substituted by 1 to 4 additional (meth)-acrylate radicals andR.sup.3 denotes hydrogen or methyl independently for each chain starting from A.
    • 牙科填充物,涂料和牙齿由式(IMA)(I)的(甲基)丙烯酸的多官能酯 - 氨基甲酸酯衍生物的聚合物和共聚物形成,其中A是直链或支链脂族基团,其具有2 至20个碳原子,并且任选地含有1至3个氧桥,具有6至24个碳原子的芳族基团,具有7至26个碳原子的芳脂族基团或具有6至26个碳原子的脂环族基团,r表示链起始数 从A表示2至6的数,R1和R2相同并且表示氢或不同,表示氢和甲基,n表示从A开始独立地为0至5的数,X表示< IMAGE>其中Y表示具有2至15个碳原子并且任选地含有酯,醚或氨基甲酸酯基团的二价(环)脂族基团,Z表示具有3至15个碳原子的二价直链或支链脂族烃基, ca n任选地含有1至3个氧桥,并且可以任选地被1至4个另外的(甲基)丙烯酸酯基团取代,并且对于从A开始的每个链,R 3表示氢或甲基。