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1. 发明申请

US20190284329A1 Thermoplastic Polyurethane Matrix Resin 审中-公开
公开(公告)号：US20190284329A1
公开(公告)日：2019-09-19
申请号：US16429546
申请日：2019-06-03
申请人： Henkel AG & Co. KGaA
发明人： Andreas Niegemeier , Andreas Ferencz , Tamara Schmidt , Wolfgang Lupp
IPC分类号： C08G18/32 , C08G18/76 , B29C45/00 , B29C70/48
摘要： The invention relates to a thermoplastic polyurethane matrix resin composition, comprising at least one C3-8 alkane diol, at least one alkoxylated aromatic diol and at least one polyisocyanate. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermoplastic polyurethane polymer matrix according to the present invention and a fiber material. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.

2. 发明申请

US20190202965A1 THERMOPLASTIC PUR WITH HIGH TG FOR REACTION TRANSFER MOLDING (RTM) 审中-公开
公开(公告)号：US20190202965A1
公开(公告)日：2019-07-04
申请号：US16298456
申请日：2019-03-11
申请人： Henkel AG & Co. KGaA
发明人： Andreas Ferencz , Tamara Schmidt , Andreas Niegemeier , Olaf Lammerschop
IPC分类号： C08G18/32 , C08G18/76 , B29C70/48 , B29C70/18
CPC分类号： C08G18/3212 , B29C70/18 , B29C70/48 , B29K2075/00 , C08G18/3206 , C08G18/7664 , C08G18/7671 , C08J5/04 , C08J2375/04
摘要： The invention relates to a thermoplastic polyurethane matrix resin composition, comprising (i) at least one bridged and/or fused and/or Spiro polycyclic alcohol compound; (ii) at least one polyisocyanate; and (iii) at least one diol, which is different from the at least one bridged and/or fused and/or spiro polycyclic alcohol compound (i). The at least one bridged and/or fused and/or Spiro polycyclic alcohol compound (i) is present in the thermoplastic polyurethane matrix resin composition in an amount of at least 10 wt.-% by weight, preferably at least 20 wt-%, most preferably at least 25 wt.-%. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermoplastic polyurethane polymer matrix according to the present invention and a fiber material. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, e.g., skis, snowboards, rackets, golf clubs, fishing rods, baseball bats, hockey sticks, arrows, archery bows, surfboards, javelins, exercise equipment, cell phone and laptop housings, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.

3. 发明申请

US20170002106A1 Aqueous Primary Dispersions, Process Of Their Production And Use Thereof 审中-公开
标题翻译：水性主要分散体，其生产和使用过程
公开(公告)号：US20170002106A1
公开(公告)日：2017-01-05
申请号：US15105164
申请日：2013-12-20
申请人： BASF COATINGS GMBH , HENKEL AG & CO. KGAA
发明人： Konstantinos Markou , Andreas Niegemeier , Sabine Holtschulte
IPC分类号： C08F2/28 , C09D5/44 , C25D7/00 , C08K5/17 , C25D9/02 , B01F17/00 , C09D7/12
CPC分类号： C08F2/28 , B01F17/0042 , C08K5/17 , C09D4/00 , C09D5/44 , C09D5/4438 , C09D5/4476 , C09D5/4492 , C09D7/63 , C09D7/66 , C09D7/67 , C09D7/68 , C25D7/00 , C25D9/02 , C25D13/06
摘要： The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles having a Z-average particle diameter of 5 to 500 nm and which are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A). The emulsion polymerization takes place in the presence of one or more emulsifiers (EQ) having the following general formula: R1—N−(R2)(R3)(R4)X⊖, where R1 is a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one functional group selected from hydroxyl groups, thiol groups, and primary or secondary amino groups, and/or has at least one carbon-carbon multiple bond, R2, R3, and R4, independently of one another, are the same or different aliphatic moieties containing 1 to 14 carbon atoms, and X stands for the acid anion of an organic or inorganic acid. The invention further relates to a method for producing the primary dispersions, and to coating agents which include the primary dispersions, and to the use of the primary dispersions for producing electrodeposition coatings, and also to conductive substrates coated with the coating compositions. The invention further relates to emulsifiers which are used for producing the primary dispersions according to the invention.
摘要翻译：本发明涉及包含Z平均粒径为5〜500nm的分散的聚合物颗粒的水性阳离子稳定的一级分散体，其可通过至少一种烯属不饱和单体（A）的乳液聚合获得。在具有以下通式的一种或多种乳化剂（EQ）的存在下进行乳液聚合：R1-N-（R2）（R3）（R4）X⊖，其中R1是具有15至40个碳原子的部分，含有至少一个芳族基团和至少一个脂族基团，并且其含有至少一个选自羟基，硫醇基团和伯或仲氨基的官能团，和/或具有至少一个碳 - 碳多键R2 R 3和R 4彼此独立地是含有1至14个碳原子的相同或不同的脂肪族部分，X表示有机酸或无机酸的酸性阴离子。本发明还涉及一次分散体的制备方法，以及包括一次分散体的包衣剂，以及使用一次分散体用于制备电沉积涂料的方法，以及涂覆有涂料组合物的导电基材。本发明还涉及用于生产根据本发明的初级分散体的乳化剂。

4. 发明申请

US20190292335A1 Compositions Comprising a Fiber Material and a Thermoplastic Binder 审中-公开
公开(公告)号：US20190292335A1
公开(公告)日：2019-09-26
申请号：US16441177
申请日：2019-06-14
申请人： Henkel AG & Co. KGaA
发明人： Andreas Niegemeier , Andreas Ferencz , Tamara Schmidt , Wolfgang Lupp , Tim Weinhausen
IPC分类号： C08J5/04 , C08G18/76 , C08G18/75 , C08G18/72 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/66 , B29C70/30
摘要： The invention relates to compositions comprising a fiber material and a specific thermoplastic binder. The thermoplastic binder comprises at least one thermoplastic polyurethane polymer, wherein said thermoplastic polyurethane polymer comprises a reaction product of (i) at least one semi-crystalline polyester polyol, and (ii) at least one polyisocyanate. The molar ratio of the NCO groups of said polyisocyanate (ii) to the sum of OH groups of said polyester polyol (i) is less than 1.00:1 and the thermoplastic polyurethane polymer has (a) a melting enthalpy of at least 20 J/g, (b) a melting point (Tm) of >70° C., and (c) an average number molecular weight (Mn) of 5,000 to 80,000 g/mol. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermosetting polyurethane polymer matrix reinforced by the composition according to the present invention. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.

5. 发明授权

US09920140B2 Aqueous primary dispersions, process of their production and use thereof 有权
公开(公告)号：US09920140B2
公开(公告)日：2018-03-20
申请号：US15105164
申请日：2013-12-20
申请人： BASF COATINGS GMBH , HENKEL AG & CO. KGAA
发明人： Konstantinos Markou , Andreas Niegemeier , Sabine Holtschulte
IPC分类号： C08F2/28 , C09D4/00 , C25D13/06 , C09D5/44 , C09D7/12 , B01F17/00 , C08K5/17 , C25D7/00 , C25D9/02
CPC分类号： C08F2/28 , B01F17/0042 , C08K5/17 , C09D4/00 , C09D5/44 , C09D5/4438 , C09D5/4476 , C09D5/4492 , C09D7/63 , C09D7/66 , C09D7/67 , C09D7/68 , C25D7/00 , C25D9/02 , C25D13/06
摘要： The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles having a Z-average particle diameter of 5 to 500 nm and which are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A). The emulsion polymerization takes place in the presence of one or more emulsifiers (EQ) having the following general formula: R1—N−(R2)(R3)(R4)X⊖, where R1 is a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one functional group selected from hydroxyl groups, thiol groups, and primary or secondary amino groups, and/or has at least one carbon-carbon multiple bond, R2, R3, and R4, independently of one another, are the same or different aliphatic moieties containing 1 to 14 carbon atoms, and X stands for the acid anion of an organic or inorganic acid. The invention further relates to a method for producing the primary dispersions, and to coating agents which include the primary dispersions, and to the use of the primary dispersions for producing electrodeposition coatings, and also to conductive substrates coated with the coating compositions. The invention further relates to emulsifiers which are used for producing the primary dispersions according to the invention.

6. 发明授权

US09914840B2 Process for preparing pigment and filler containing formulations 有权
公开(公告)号：US09914840B2
公开(公告)日：2018-03-13
申请号：US15105069
申请日：2013-12-20
申请人： BASF COATINGS GMBH , HENKEL AG & CO. KGAA
发明人： Konstantinos Markou , Andreas Niegemeier , Sabine Holtschulte , Jerome Moebius
IPC分类号： C09D5/44 , C09D17/00 , C09D5/08 , C25D13/06
CPC分类号： C09D5/4457 , C09D5/08 , C09D5/4438 , C09D5/4492 , C09D17/004 , C09D17/005 , C09D17/006 , C09D17/007 , C09D17/008 , C25D13/06
摘要： The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles that have a Z-average particle diameter of 5 to 500 nm and are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A), wherein the emulsion polymerization takes place in the presence of one or more emulsifiers (E) having the following general formula: R1—(R2)(R3), where: R is a moiety that contains at least one aromatic group and at least one aliphatic group, has 15 to 40 carbon atoms, and contains at least one functional group selected from hydroxy groups, thiol groups, and primary or secondary amino groups and/or comprises at least one carbon-carbon multiple bond; and R1, R2, and R3 are, independently of each other, identical or different aliphatic moieties having 1 to 14 carbon atoms. The invention also relates to a method for producing the primary dispersions, coating agents comprising the primary dispersions, use of the primary dispersions to produce electrocoats, and conductive substrates that have been coated with the coating agent compositions.

7. 发明申请

US20220251370A1 PEO-PPO-PEO TRIBLOCK COPOLYMERS AS ADDITIVES FOR EPOXIDE-ANHYDRIDE SYSTEMS 有权
公开(公告)号：US20220251370A1
公开(公告)日：2022-08-11
申请号：US17660948
申请日：2022-04-27
申请人： Henkel AG & Co. KGaA
发明人： Andreas Niegemeier , Andreas Ferencz , Tamara Schmidt , Mustapha Benomar , Wolfgang Lupp
IPC分类号： C08L63/00
摘要： The present invention relates to curable resin compositions, to methods for producing a cured composition using said curable resin compositions, and articles, in particular molded parts, produced by such methods.

8. 发明授权

US11312810B2 Thermoplastic polyurethane matrix resin 有权
公开(公告)号：US11312810B2
公开(公告)日：2022-04-26
申请号：US16429546
申请日：2019-06-03
申请人： Henkel AG & Co. KGaA
发明人： Andreas Niegemeier , Andreas Ferencz , Tamara Schmidt , Wolfgang Lupp
IPC分类号： C08G18/32 , C08G18/65 , B29C45/00 , B29C70/48 , C08G18/76 , C08G18/48 , C08G18/66 , C08K3/013 , B29K75/00 , C08K3/04 , C08K3/34 , B29C70/06
摘要： The invention relates to a thermoplastic polyurethane matrix resin composition, comprising at least one C3-8 alkane diol, at least one alkoxylated aromatic diol and at least one polyisocyanate. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermoplastic polyurethane polymer matrix according to the present invention and a fiber material. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.

9. 发明授权

US10519287B2 Compositions comprising a fiber material and a thermoplastic binder 有权
公开(公告)号：US10519287B2
公开(公告)日：2019-12-31
申请号：US16441177
申请日：2019-06-14
申请人： Henkel AG & Co. KGaA
发明人： Andreas Niegemeier , Andreas Ferencz , Tamara Schmidt , Wolfgang Lupp , Tim Maeling
IPC分类号： B32B27/40 , B32B27/04 , C08L75/06 , C08G18/42 , C08J5/04 , C08G18/76 , C08G18/75 , C08G18/72 , C08G18/40 , C08G18/66 , B29C70/30 , C08G18/48 , B29K75/00
摘要： The invention relates to compositions comprising a fiber material and a specific thermoplastic binder. The thermoplastic binder comprises at least one thermoplastic polyurethane polymer, wherein said thermoplastic polyurethane polymer comprises a reaction product of (i) at least one semi-crystalline polyester polyol, and (ii) at least one polyisocyanate. The molar ratio of the NCO groups of said polyisocyanate (ii) to the sum of OH groups of said polyester polyol (i) is less than 1.00:1 and the thermoplastic polyurethane polymer has (a) a melting enthalpy of at least 20 J/g, (b) a melting point (Tm) of >70° C., and (c) an average number molecular weight (Mn) of 5,000 to 80,000 g/mol. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermosetting polyurethane polymer matrix reinforced by the composition according to the present invention. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.

10. 发明授权

US10208134B2 Aqueous primary dispersions, method for producing same, and use thereof 有权
公开(公告)号：US10208134B2
公开(公告)日：2019-02-19
申请号：US15105631
申请日：2013-12-20
申请人： BASF COATINGS GMBH , HENKEL AG & CO. KGAA
发明人： Konstantinos Markou , Andreas Niegemeier
IPC分类号： C08F2/28 , C08F2/30 , C09D4/00 , C08K5/17 , C09D5/44 , C25D7/00 , C25D9/02 , C09D7/63 , C09D7/40
摘要： The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles having a Z-average particle diameter of 5 to 500 nm and which are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A). The emulsion polymerization takes place in the presence of one or more emulsifiers (E) having the following general formula: R1—N(R2)(R3), where R1 is a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one functional group selected from hydroxyl groups, thiol groups, and primary or secondary amino groups, and/or has at least one carbon-carbon multiple bond, and R2 and R3, independently of one another, are the same or different aliphatic moieties containing 1 to 14 carbon atoms. The invention further relates to a method for producing the primary dispersions, and to coating agents which include the primary dispersions, and to the use of the primary dispersions for producing electrodeposition coatings, and also to conductive substrates coated with the coating compositions.

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