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1. 发明申请

US20170002106A1 Aqueous Primary Dispersions, Process Of Their Production And Use Thereof 审中-公开
标题翻译：水性主要分散体，其生产和使用过程
公开(公告)号：US20170002106A1
公开(公告)日：2017-01-05
申请号：US15105164
申请日：2013-12-20
申请人： BASF COATINGS GMBH , HENKEL AG & CO. KGAA
发明人： Konstantinos Markou , Andreas Niegemeier , Sabine Holtschulte
IPC分类号： C08F2/28 , C09D5/44 , C25D7/00 , C08K5/17 , C25D9/02 , B01F17/00 , C09D7/12
CPC分类号： C08F2/28 , B01F17/0042 , C08K5/17 , C09D4/00 , C09D5/44 , C09D5/4438 , C09D5/4476 , C09D5/4492 , C09D7/63 , C09D7/66 , C09D7/67 , C09D7/68 , C25D7/00 , C25D9/02 , C25D13/06
摘要： The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles having a Z-average particle diameter of 5 to 500 nm and which are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A). The emulsion polymerization takes place in the presence of one or more emulsifiers (EQ) having the following general formula: R1—N−(R2)(R3)(R4)X⊖, where R1 is a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one functional group selected from hydroxyl groups, thiol groups, and primary or secondary amino groups, and/or has at least one carbon-carbon multiple bond, R2, R3, and R4, independently of one another, are the same or different aliphatic moieties containing 1 to 14 carbon atoms, and X stands for the acid anion of an organic or inorganic acid. The invention further relates to a method for producing the primary dispersions, and to coating agents which include the primary dispersions, and to the use of the primary dispersions for producing electrodeposition coatings, and also to conductive substrates coated with the coating compositions. The invention further relates to emulsifiers which are used for producing the primary dispersions according to the invention.
摘要翻译：本发明涉及包含Z平均粒径为5〜500nm的分散的聚合物颗粒的水性阳离子稳定的一级分散体，其可通过至少一种烯属不饱和单体（A）的乳液聚合获得。在具有以下通式的一种或多种乳化剂（EQ）的存在下进行乳液聚合：R1-N-（R2）（R3）（R4）X⊖，其中R1是具有15至40个碳原子的部分，含有至少一个芳族基团和至少一个脂族基团，并且其含有至少一个选自羟基，硫醇基团和伯或仲氨基的官能团，和/或具有至少一个碳 - 碳多键R2 R 3和R 4彼此独立地是含有1至14个碳原子的相同或不同的脂肪族部分，X表示有机酸或无机酸的酸性阴离子。本发明还涉及一次分散体的制备方法，以及包括一次分散体的包衣剂，以及使用一次分散体用于制备电沉积涂料的方法，以及涂覆有涂料组合物的导电基材。本发明还涉及用于生产根据本发明的初级分散体的乳化剂。

2. 发明授权

US09920140B2 Aqueous primary dispersions, process of their production and use thereof 有权
公开(公告)号：US09920140B2
公开(公告)日：2018-03-20
申请号：US15105164
申请日：2013-12-20
申请人： BASF COATINGS GMBH , HENKEL AG & CO. KGAA
发明人： Konstantinos Markou , Andreas Niegemeier , Sabine Holtschulte
IPC分类号： C08F2/28 , C09D4/00 , C25D13/06 , C09D5/44 , C09D7/12 , B01F17/00 , C08K5/17 , C25D7/00 , C25D9/02
CPC分类号： C08F2/28 , B01F17/0042 , C08K5/17 , C09D4/00 , C09D5/44 , C09D5/4438 , C09D5/4476 , C09D5/4492 , C09D7/63 , C09D7/66 , C09D7/67 , C09D7/68 , C25D7/00 , C25D9/02 , C25D13/06
摘要： The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles having a Z-average particle diameter of 5 to 500 nm and which are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A). The emulsion polymerization takes place in the presence of one or more emulsifiers (EQ) having the following general formula: R1—N−(R2)(R3)(R4)X⊖, where R1 is a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one functional group selected from hydroxyl groups, thiol groups, and primary or secondary amino groups, and/or has at least one carbon-carbon multiple bond, R2, R3, and R4, independently of one another, are the same or different aliphatic moieties containing 1 to 14 carbon atoms, and X stands for the acid anion of an organic or inorganic acid. The invention further relates to a method for producing the primary dispersions, and to coating agents which include the primary dispersions, and to the use of the primary dispersions for producing electrodeposition coatings, and also to conductive substrates coated with the coating compositions. The invention further relates to emulsifiers which are used for producing the primary dispersions according to the invention.

3. 发明授权

US09914840B2 Process for preparing pigment and filler containing formulations 有权
公开(公告)号：US09914840B2
公开(公告)日：2018-03-13
申请号：US15105069
申请日：2013-12-20
申请人： BASF COATINGS GMBH , HENKEL AG & CO. KGAA
发明人： Konstantinos Markou , Andreas Niegemeier , Sabine Holtschulte , Jerome Moebius
IPC分类号： C09D5/44 , C09D17/00 , C09D5/08 , C25D13/06
CPC分类号： C09D5/4457 , C09D5/08 , C09D5/4438 , C09D5/4492 , C09D17/004 , C09D17/005 , C09D17/006 , C09D17/007 , C09D17/008 , C25D13/06
摘要： The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles that have a Z-average particle diameter of 5 to 500 nm and are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A), wherein the emulsion polymerization takes place in the presence of one or more emulsifiers (E) having the following general formula: R1—(R2)(R3), where: R is a moiety that contains at least one aromatic group and at least one aliphatic group, has 15 to 40 carbon atoms, and contains at least one functional group selected from hydroxy groups, thiol groups, and primary or secondary amino groups and/or comprises at least one carbon-carbon multiple bond; and R1, R2, and R3 are, independently of each other, identical or different aliphatic moieties having 1 to 14 carbon atoms. The invention also relates to a method for producing the primary dispersions, coating agents comprising the primary dispersions, use of the primary dispersions to produce electrocoats, and conductive substrates that have been coated with the coating agent compositions.

4. 发明授权

US09982147B2 Aqueous dip-coating composition for electroconductive substrates, comprising bismuth and a phosphorus-containing, amine-blocked compound 有权
公开(公告)号：US09982147B2
公开(公告)日：2018-05-29
申请号：US15103118
申请日：2013-12-10
申请人： BASF COATINGS GmbH , HENKEL AG & Co. KGaA
发明人： Sabine Holtschulte , Andreas Niegemeier , Dominik Stoll
IPC分类号： C09D5/44 , C25D9/02 , C25D13/06 , C25D13/12 , C25D13/18 , C25D13/20 , C09D5/08 , C23C18/12
CPC分类号： C09D5/4492 , C09D5/086 , C09D5/443 , C09D5/4488 , C23C18/1254 , C25D9/02 , C25D13/06 , C25D13/12 , C25D13/18 , C25D13/20
摘要： The present invention relates to an aqueous coating composition (A) comprising at least one cathodically depositable binder (A1) and optionally at least one crosslinking agent (A2), for at least partly coating an electrically conductive substrate with an electrocoat material, where (A) comprises a total amount of at least 30 ppm of bismuth, based on the total weight of (A), and additionally at least one phosphorus-containing compound (P) blocked with at least one amine of the general formula (I), to the use of (A) for at least partly coating an electrically conductive substrate with an electrocoat material, to a corresponding coating method, and to an at least partly coated substrate obtainable by this method.

5. 发明授权

US09938417B2 Formulations containing pigment and filler 有权
公开(公告)号：US09938417B2
公开(公告)日：2018-04-10
申请号：US15105250
申请日：2013-12-20
申请人： BASF COATINGS GMBH , HENKEL AG & CO. KGAA
发明人： Konstantinos Markou , Andreas Niegemeier , Sabine Holtschulte , Jerome Moebius
IPC分类号： C09D5/44 , C09D17/00 , C25D13/06 , C25D13/12
CPC分类号： C09D5/4492 , C09D5/4457 , C09D5/4488 , C09D17/001 , C25D13/06 , C25D13/12
摘要： The invention relates to pigment- and/or filler-containing formulations, comprising one or more solids selected from the group of the pigments and fillers, and an emulsifier (EQ), which has the following formula: R1—N⊕(R2)(R3)(R4)X⊖(EQ), where: R1 is a moiety that contains at least one aromatic group and at least one aliphatic group, has 15 to 40 carbon atoms, and contains at least one functional group selected from hydroxy groups, thiol groups, and primary or secondary amino groups and/or comprises at least one carbon-carbon multiple bond; R2, R3, and R4 are, independently of each other, identical or different aliphatic moieties having 1 to 14 carbon atoms; and X⊖ stands for the acid anion of an organic or inorganic acid HX. The invention further relates to coating agents comprising said formulations, the use of said formulations to produce electrocoats, and conductive substrates coated with said coating agent compositions.

6. 发明申请

US20170002215A1 Formulations Containing Pigment And Filler 审中-公开
标题翻译：含颜料和填料的配方
公开(公告)号：US20170002215A1
公开(公告)日：2017-01-05
申请号：US15105250
申请日：2013-12-20
申请人： BASF COATINGS GMBH , HENKEL AG & CO. KGAA
发明人： Konstantinos Markou , Andreas Niegemeier , Sabine Holtschulte , Jerome Moebius
IPC分类号： C09D5/44 , C25D13/06 , C25D13/12 , C09D17/00
CPC分类号： C09D5/4492 , C09D5/4457 , C09D5/4488 , C09D17/001 , C25D13/06 , C25D13/12
摘要： The invention relates to pigment- and/or filler-containing formulations, comprising one or more solids selected from the group of the pigments and fillers, and an emulsifier (EQ), which has the following formula: R1—N⊕(R2)(R3)(R4)XΓ(EQ), where: R1 is a moiety that contains at least one aromatic group and at least one aliphatic group, has 15 to 40 carbon atoms, and contains at least one functional group selected from hydroxy groups, thiol groups, and primary or secondary amino groups and/or comprises at least one carbon-carbon multiple bond; R2, R3, and R4 are, independently of each other, identical or different aliphatic moieties having 1 to 14 carbon atoms; and X⊖ stands for the acid anion of an organic or inorganic acid HX. The invention further relates to coating agents comprising said formulations, the use of said formulations to produce electrocoats, and conductive substrates coated with said coating agent compositions.
摘要翻译：本发明涉及含颜料和/或填料的制剂，其包含一种或多种选自颜料和填料的固体，和乳化剂（EQ），其具有下式：R1-N⊕（R2）（ R3）（R4）XΓ（EQ），其中：R1是含有至少一个芳族基团和至少一个脂族基团的部分，具有15至40个碳原子，并且含有至少一个选自羟基的官能团，硫醇基团和伯或仲氨基和/或包含至少一个碳 - 碳多键; R2，R3和R4彼此独立地为具有1至14个碳原子的相同或不同的脂族部分; X⊖代表有机或无机酸HX的酸性阴离子。本发明还涉及包含所述制剂的涂层剂，所述制剂的用途来制备电涂层，以及用所述涂层剂组合物涂覆的导电基材。

7. 发明申请

US20170002213A1 Process For Preparing Pigment And Filler Containing Formulations 审中-公开
标题翻译：制备含有配方的颜料和填料的方法
公开(公告)号：US20170002213A1
公开(公告)日：2017-01-05
申请号：US15105069
申请日：2013-12-20
申请人： BASF COATINGS GMBH , HENKEL AG & CO. KGAA
发明人： Konstantinos Markou , Andreas Niegemeier , Sabine Holtschulte , Jerome Moebius
IPC分类号： C09D5/44 , C09D5/08 , C25D13/06 , C09D17/00
CPC分类号： C09D5/4457 , C09D5/08 , C09D5/4438 , C09D5/4492 , C09D17/004 , C09D17/005 , C09D17/006 , C09D17/007 , C09D17/008 , C25D13/06
摘要： The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles that have a Z-average particle diameter of 5 to 500 nm and are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A), wherein the emulsion polymerization takes place in the presence of one or more emulsifiers (E) having the following general formula: R1—(R2)(R3), where: R is a moiety that contains at least one aromatic group and at least one aliphatic group, has 15 to 40 carbon atoms, and contains at least one functional group selected from hydroxy groups, thiol groups, and primary or secondary amino groups and/or comprises at least one carbon-carbon multiple bond; and R1, R2, and R3 are, independently of each other, identical or different aliphatic moieties having 1 to 14 carbon atoms. The invention also relates to a method for producing the primary dispersions, coating agents comprising the primary dispersions, use of the primary dispersions to produce electrocoats, and conductive substrates that have been coated with the coating agent compositions.
摘要翻译：本发明涉及水性阳离子稳定的一级分散体，其包含Z平均粒径为5至500nm的分散的聚合物颗粒，并且可通过至少一种烯属不饱和单体（A）的乳液聚合获得，其中乳液聚合发生在一种或多种具有以下通式的乳化剂（E）的存在下，R1-（R2）（R3），其中：R是含有至少一个芳族基团和至少一个脂肪族基团的部分，其具有15至40个并且含有至少一个选自羟基，硫醇基和伯或仲氨基的官能团和/或包含至少一个碳 - 碳多键; 并且R 1，R 2和R 3彼此独立地为具有1至14个碳原子的相同或不同的脂族部分。本发明还涉及用于生产初级分散体的方法，包括初级分散体的涂料，初级分散体的使用以产生电涂层，以及已经用涂料组合物涂覆的导电基材。

8. 发明申请

US20160369114A1 AQUEOUS DIP-COATING COMPOSITION FOR ELECTROCONDUCTIVE SUBSTRATES, COMPRISING BISMUTH AND A PHOSPHORUS-CONTAINING, AMINE-BLOCKED COMPOUND 有权
标题翻译：用于包含双相和含有磷酸盐的胺基封端化合物的电极基材的水性DIP涂层组合物
公开(公告)号：US20160369114A1
公开(公告)日：2016-12-22
申请号：US15103118
申请日：2013-12-10
申请人： BASF COATINGS GmbH , HENKEL AG & Co. KGaA
发明人： Sabine Holtschulte , Andreas Niegemeier , Dominik Stoll
IPC分类号： C09D5/44 , C25D13/20 , C25D13/18 , C09D5/08 , C25D13/12
CPC分类号： C09D5/4492 , C09D5/086 , C09D5/443 , C09D5/4488 , C23C18/1254 , C25D9/02 , C25D13/06 , C25D13/12 , C25D13/18 , C25D13/20
摘要： The present invention relates to an aqueous coating composition (A) comprising at least one cathodically depositable binder (A1) and optionally at least one crosslinking agent (A2), for at least partly coating an electrically conductive substrate with an electrocoat material, where (A) comprises a total amount of at least 30 ppm of bismuth, based on the total weight of (A), and additionally at least one phosphorus-containing compound (P) blocked with at least one amine of the general formula (I), to the use of (A) for at least partly coating an electrically conductive substrate with an electrocoat material, to a corresponding coating method, and to an at least partly coated substrate obtainable by this method.
摘要翻译：本发明涉及包含至少一种阴极可沉积的粘合剂（A1）和任选的至少一种交联剂（A2）的水性涂料组合物（A），用于至少部分地用电泳涂料涂覆导电基材，其中（A ）包含基于（A）的总重量的总量至少30ppm的铋，以及至少一种用至少一种通式（I）的胺封端的含磷化合物（P），至少一种含有通式使用（A）至少部分地用电涂层材料涂覆导电基材，到相应的涂布方法，以及通过该方法可获得的至少部分涂覆的基材。

9. 发明授权

US10174212B2 Method for producing a pigment paste, aqueous electrocoat material, use thereof, method for cataphoretic electrocoating, and coated article 有权
公开(公告)号：US10174212B2
公开(公告)日：2019-01-08
申请号：US15106574
申请日：2013-12-20
申请人： BASF COATINGS GmbH , Henkel AG & Company, KGaA
发明人： Ute Herrmann , Sebastian Sinnwell , Thorsten Gelbrich , Konstantinos Markou , Rolf Schulte , Sabine Holtschulte , Dominik Stoll , Guenther Ott
IPC分类号： C09D5/44 , C09C1/30 , C09C1/36 , C09D5/08 , C09D17/00 , C09D163/00 , C25D13/06 , C25D13/12 , C25D13/18 , C09D5/02 , C25D13/22
摘要： The invention relates to a method for producing a pigment paste and an electrocoat containing the paste, the past being made by mixing solid pigment particles with a grind resin in the presence of water and/or an organic liquid, wherein the grind resin includes a dispersion of core-shell particles in an epoxide prepolymer which is liquid at 20° C. and the core-shell particles have a silicone core and a polymer shell.

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