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    • 7. 发明授权
    • Compositions comprising a fiber material and a thermoplastic binder
    • US10526460B2
    • 2020-01-07
    • US15465966
    • 2017-03-22
    • Henkel AG & Co. KGaA
    • Andreas FerenczOlaf LammerschopTamara SchmidtAndrew SlarkDirk Kasper
    • C08G18/00C08J5/04C08G18/76C08J5/24C08G18/42C08G18/66
    • The invention relates to compositions comprising a fiber material and a specific thermoplastic binder. The thermoplastic binder comprises at least one thermoplastic polyurethane polymer (A), wherein said thermoplastic polyurethane polymer (A) comprises a reaction product of (i) at least one polyester polyol and (ii) at least one polyisocyanate, optionally at least one diol (iii) which is different from the polyester polyol (i) is contained. The molar ratio of the NCO groups of said polyisocyanate (ii) to the sum of OH groups of said polyester polyol (i) and said optionally containing diol (iii) is less than 1.00:1. Said polyester polyol (i) comprises (a) at least one semi-crystalline polyester polyol having a melting point (Tm) of from 40 to 180° C., and (b) at least one non-crystalline polyester polyol. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermosetting polyurethane polymer matrix reinforced by the composition according to the present invention. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.
    • 10. 发明申请
    • HYBRID MATRIX FOR FIBER COMPOSITE MATERIALS
    • 用于纤维复合材料的混合基质
    • US20140039118A1
    • 2014-02-06
    • US14050940
    • 2013-10-10
    • HENKEL AG & CO. KGAA
    • Martin RENKELEmilie BarriauMartin HornungAndreas FerenczKonrad Becker
    • C08K7/14C08J5/04
    • C09J163/00B29C43/12B29C43/203B29C45/1671B29C70/443B29C70/46B29C70/48B29K2105/06B29L2031/3041C08G18/4045C08G59/4021C08J5/043C08J5/24C08K7/14C08L75/04C09J5/06C09J175/04C09J2463/00C09J2475/00Y10T428/31511
    • A fiber composite material obtainable by (a) mixing the components of a multi-component agent immediately before use, wherein component A of the multi-component agent contains at least one compound having two or more isocyanate groups, component B of the multi-component agent contains at least one compound which has at least two reactive groups selected from hydroxyl groups, thiol groups, primary amino groups and secondary amino groups and is simultaneously free from epoxy groups, and at least one of the components of the multi-component agent contains at least one epoxide prepolymer, (b) introducing the resulting application preparation into a mold in which fibers and optionally further additives are present, the resulting mixture containing at least one latent hardener for epoxide prepolymers, (c) pre-curing the resulting mixture at a temperature from 5° C. to 90° C., and (d) then finally curing the pre-cured fiber composite material at temperatures from 100° C. to 240° C., wherein the fiber composite material being removed from the mold after step (c) or step (d).
    • 一种纤维复合材料,其可以通过以下方法获得:(a)在即将使用之前混合多组分试剂的组分,其中多组分试剂的组分A含有至少一种具有两个或更多个异氰酸酯基团的化合物,多组分的组分B 试剂含有至少一种具有至少两个选自羟基,硫醇基,伯氨基和仲氨基的反应性基团并且同时不含环氧基的化合物,并且多组分试剂的至少一种组分含有 至少一种环氧化物预聚物,(b)将所得应用制剂引入其中存在纤维和任选的其它添加剂的模具中,所得混合物含有至少一种用于环氧化物预聚物的潜在硬化剂,(c)将所得混合物预固化 温度为5℃至90℃,(d)然后在100℃至240℃的温度下最终固化预固化的纤维复合材料,其中 在步骤(c)或步骤(d)之后,将纤维复合材料从模具中除去。