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    • 3. 发明授权
    • Flat electrochemical sensor, and method of its manufacture
    • 平面电化学传感器及其制造方法
    • US4294679A
    • 1981-10-13
    • US145738
    • 1980-05-01
    • Helmut MaurerKlaus MullerErnst LinderFranz RiegerGunther Stecher
    • Helmut MaurerKlaus MullerErnst LinderFranz RiegerGunther Stecher
    • G01N27/41B01L3/00G01N27/406G01N27/407G01N27/409G01N27/413G01N27/416G01N27/48G01N27/58
    • G01N27/4071G01N27/4067G01N27/48Y10T29/49002
    • To apply a measured quantity of air to the electrodes applied to a plate-like solid electrolyte body, which may be a chip on a carrier or may, itself, form the carrier, grooves, flutes, ducts, or depressions are formed in the carrier and/or a cover plate, the grooves terminating at an edge portion with access to the gas to be supplied, and having a size such that their clear height is preferably in the lower micron region, and a width, preferably under 1 mm, and particularly between 0.2 and 0.4 mm. The higher limits are applicable to apply, for example, air to a reference electrode, to apply ambient oxygen thereto; the lower limits are appropriate when operating the sensor as a polarographic sensor, in which the diffusion limited current, upon application of a bias voltage, is an analog measure of the oxygen concentration in the gas, and the gas supply to the electrode must be suitably controlled to prevent saturation conditions. The grooves may be formed, for example, by sandblasting or by applying insulating material in the form of posts, ridges, and the like, on the respective element, filling the space therebetween with a filler substance which, upon subsequent sintering, escapes, thus leaving the voids forming the grooves, depressions, and the like.
    • 为了将应用于板状固体电解质体的电极施加测量量的空气,该固体电解质体可以是载体上的芯片,或者可以自身形成载体,在载体中形成凹槽,凹槽,管道或凹陷 和/或盖板,所述槽终止于边缘部分,具有进入待供应气体的通道,并且具有这样的尺寸,使得它们的透明高度优选地在较低的微米区域中,宽度优选地在1mm以下,以及 特别是在0.2和0.4毫米之间。 上限适用于将例如空气施加到参比电极,以向其施加环境氧; 当将传感器作为极谱传感器操作时,下限是适当的,其中在施加偏压时扩散受限电流是气体中氧浓度的模拟测量,并且对电极的气体供应必须适当 控制以防止饱和条件。 凹槽可以例如通过喷砂或通过在各个元件上施加柱状物,脊等的形式的绝缘材料形成,用填充物填充其间的空间,该填充物在随后的烧结时逸出,因此 留下形成凹槽,凹陷等的空隙。
    • 4. 发明授权
    • Temperature compensated polarographic oxygen gas sensor and sensing
system, particularly for automotive application
    • 温度补偿极谱氧气传感器和传感系统,特别适用于汽车应用
    • US4391691A
    • 1983-07-05
    • US242579
    • 1981-03-11
    • Ernst LinderHelmut MaurerKlaus MullerFranz Rieger
    • Ernst LinderHelmut MaurerKlaus MullerFranz Rieger
    • G01N27/41F02D41/14G01N27/406G01N27/407G01N27/416G01N27/48G01N27/56G01N27/58
    • G01N27/4071F02D41/1476G01N27/4065G01N27/48
    • To render output of a polarographic sensor essentially independent of aging of electrodes and temperature effects of the solid electrolyte body, within the operating ranges of the sensor to measure the oxygen composition of exhaust gases, the solid electrolyte plate of, for example, 50 mm length, 8 mm width and 1 mm thickness has a sensing electrode system including a cathode (2), and an anode (3) applied thereto, connected to a voltage source (7) of controllable output voltage. An oxygen molecule diffusion barrier (6) is applied to the cathode electrode. Additionally, a further electrode pair (5,4) is applied to the solid electrolyte body (1), serially connected in the current limiting circuit including the control voltage source. The voltage across one (2,3) of the electrode pairs is measured and compared with the voltage across the other electrode pair (4,5) voltage source, since the resistance of the zirconium solid electrolyte body drops with increasing temperature at roughly the same rate as the increase in limit current flow with increasing temperature. Both electrode pairs (2,3; 4,5) on the solid electrolyte body (1) are exposed to the gases, the oxygen content of which is to be analyzed.
    • 为了使极谱传感器的输出基本上独立于电极的老化和固体电解质体的温度效应,在用于测量废气的氧气组成的传感器的操作范围内,固体电解质板例如为50mm长度 宽8mm,厚1mm的感测电极系统具有与可控输出电压的电压源(7)连接的阴极(2)和阳极(3)的检测电极系统。 向阴极施加氧分子扩散阻挡层(6)。 另外,在包括控制电压源的限流电路中串联连接到固体电解质体(1)上的另一电极对(5,4)。 测量一个(2,3)电极对上的电压,并与另一个电极对(4,5)电压源上的电压进行比较,因为锆固体电解质体的电阻随温度升高大致相同而下降 随着温度的升高,限流电流的增加。 将固体电解质体(1)上的两个电极对(2,3; 4,5)暴露于要分析其含氧量的气体。
    • 5. 发明授权
    • Optical engine knock sensing system
    • 光学发动机爆震传感系统
    • US4369748A
    • 1983-01-25
    • US268856
    • 1981-06-01
    • Leo SteinkeErnst LinderHelmut MaurerKlaus MullerFranz Rieger
    • Leo SteinkeErnst LinderHelmut MaurerKlaus MullerFranz Rieger
    • G01M15/00F02P5/152F02P5/153G01H9/00G01H17/00G01L23/22F02P5/04F02B3/00
    • G01L23/22F02P5/1525Y02T10/46
    • A sensor (10) optically coupled to the combustion chamber (10') of an internal combustion (IC) engine is kept free from contaminating or dirt deposits, or the like, by subjecting the sensor to mechanical shocks or vibration. The mechanical shocks or vibration are obtained by the engine itself by controlling the engine to operate for a predetermined time period as set by a monostable flip-flop (FF) (18) under controlled knocking conditions, the shock waves within the combustion chamber causing flaking off or dropping off of contaminating deposits. Controlled knocking can be obtained by advancing ignition timing by additional control of an ignition system (19) in a direction of excessive spark advance, or overriding a knocking inhibiting system already present on the engine. The degree of contamination of the sensor can be determined, for example, by integrating the light received over a predetermined angle of rotation of the engine crankshaft and comparing this rotation with the amount of fuel supplied to the engine for combustion, for example by comparison with timing of a fuel injection pulse, or the like.
    • 光学耦合到内燃机(IC)发动机的燃烧室(10')的传感器(10)通过使传感器受到机械冲击或振动而保持没有污染或污垢沉积物等。 发动机本身通过控制发动机在受控的爆震条件下由单稳态触发器(FF)(18)设定的预定时间段来实现机械冲击或振动,燃烧室内的冲击波引起剥落 脱落或掉落污染沉积物。 可以通过在点火系统(19)的过度火花提前的方向上进一步控制点火正时或者超越已经存在于发动机上的爆震抑制系统来获得控制爆震。 传感器的污染程度可以例如通过将在发动机曲轴的预定旋转角度上接收到的光积分并将该旋转与供给到发动机用于燃烧的燃料量进行比较来确定,例如通过与 燃料喷射脉冲的定时等。
    • 9. 发明授权
    • Electro-chemical sensor construction
    • 电化学传感器构造
    • US4155827A
    • 1979-05-22
    • US918145
    • 1978-06-22
    • Helmut MaurerFranz RiegerErnst Linder
    • Helmut MaurerFranz RiegerErnst Linder
    • G01N27/409G01N27/403G01N27/406G01N27/407G01N27/413G01N27/58
    • G01N27/407G01N27/4067G01N27/4078
    • An electro-chemical sensor to determine the oxygen content of exhaust gases, particularly from internal combustion engines. The sensor contains a tubular solid electrolyte closed at one end having a catalytically active layer on the outside to be exposed to the exhaust gas. The inside of said solid electrolyte tube is exposed to the ambient air and is provided with a contact portion arranged at the bottom of said solid electrolyte tube. The sensor contains an elongated axial center electrode which is pressured against the bottom (closed end) of the inside of the tubular solid electrolyte, preferably by means of a compression spring which may be mounted internal of said center electrode or external thereof. The central electrode comprises an insulating body having a heating element in the area which will be adjacent the portion of the solid electrolyte in contact with the exhaust gases. Additionally the central electrode also carries an electric lead to said contact portion. The contact portion may be attached to the central electrode.
    • 一种电化学传感器,用于确定排气的氧含量,特别是内燃机的氧气含量。 该传感器包含在一端封闭的管状固体电解质,其在外部具有暴露于废气的催化活性层。 所述固体电解质管的内部暴露于环境空气中,并且设置有布置在所述固体电解质管的底部的接触部分。 传感器包含细长的轴向中心电极,其优选地通过可安装在所述中心电极内部或其外部的压缩弹簧抵靠管状固体电解质内部的底部(封闭端)。 中心电极包括绝缘体,该绝缘体在与废气接触的部分固体电解质附近的区域中具有加热元件。 此外,中心电极还带有电引线到所述接触部分。 接触部分可以附接到中心电极。