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1. 发明授权

US4871484A Process for the preparation of 2,2-bis-chloro-methylalkanecarboxylic acid chlorides 失效
标题翻译：制备2,2-双氯 - 甲基链烷羧酸氯化物的方法
公开(公告)号：US4871484A
公开(公告)日：1989-10-03
申请号：US50993
申请日：1987-05-15
申请人： Helmut Fiege , Manfred Jautelat , Dieter Arlt
发明人： Helmut Fiege , Manfred Jautelat , Dieter Arlt
IPC分类号： C07C53/50 , C07C51/00 , C07C51/58 , C07C51/60 , C07C51/62 , C07C67/00
CPC分类号： C07C51/58
摘要： A process for the preparation of a 2,2-bis-chloro-methyl-alkanecarboxylic acid of the formula ##STR1## in which R is hydrogen, alkyl, cycloalkyl or optionally substituted phenyl,which comprises reacting an oxetane-3-carboxylic acid of the formula ##STR2## or a salt thereof, with an inorganic acid chloride at a temperature between 20.degree. C. and the boiling point of the reaction mixture. The products are known intermediates for fungicides and herbicides.
摘要翻译：一种制备式“IMAGE”的2,2-双氯 - 甲基 - 链烷羧酸的方法，其中R是氢，烷基，环烷基或任选取代的苯基，其中包括使氧杂环丁烷-3-羧酸式中的“IMAGE”或其盐与无机酰氯在20℃和反应混合物的沸点之间。该产品是用于杀真菌剂和除草剂的已知中间体。

2. 发明授权

US4824975A Process for the preparation of oxetane-3-carboxylic acids 失效
标题翻译：氧杂环丁烷-3-羧酸的制备方法
公开(公告)号：US4824975A
公开(公告)日：1989-04-25
申请号：US49749
申请日：1987-05-13
申请人： Helmut Fiege , Manfred Jautelat , Dieter Arlt
发明人： Helmut Fiege , Manfred Jautelat , Dieter Arlt
IPC分类号： C07B61/00 , B01J23/00 , B01J23/42 , B01J23/44 , C07C53/50 , C07D305/08
CPC分类号： C07C53/50 , C07D305/08
摘要： A process for the preparation of an oxetane-3-carboxylic acid of the formula ##STR1## in which R represents hydrogen, alkyl, cycloalkyl or optionally substitute phenyl, comprising reacting a 3-hydroxymethyl-oxetane of the formula ##STR2## with oxygen in an aqueous alkaline medium at a temperature between about 0.degree. C. and the boiling point of the reaction mixture on a palladium and/or platinum catalyst. The product is an intermediate for known fungicides and herbicides.
摘要翻译：制备式“IMAGE”的氧杂环丁烷-3-羧酸的方法，其中R表示氢，烷基，环烷基或任选取代的苯基，包括使式“IMAGE”的3-羟甲基 - 氧杂环丁烷与氧反应在约0℃的温度和钯和/或铂催化剂上的反应混合物的沸点之间的碱性水溶液。该产品是已知杀真菌剂和除草剂的中间体。

3. 发明授权

US4681952A Intermediates in the preparation of 2,2-dimethyl-3-aryl-cyclopropanecarboxylic acids and esters 失效
标题翻译：中间体制备2,2-二甲基-3-芳基 - 环丙烷羧酸和酯
公开(公告)号：US4681952A
公开(公告)日：1987-07-21
申请号：US669182
申请日：1984-11-07
申请人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
发明人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
IPC分类号： C07C69/753 , C07C45/00 , C07C45/63 , C07C45/65 , C07C45/68 , C07C49/223 , C07C49/587 , C07C49/657 , C07C49/683 , C07C49/697 , C07C49/753 , C07C51/00 , C07C61/39 , C07C61/40 , C07C67/00 , C07C201/00 , C07C205/55 , C07C227/00 , C07C227/02 , C07C229/46 , C07C253/00 , C07C255/56 , C07C255/57 , C07C313/00 , C07C315/04 , C07C317/24 , C07C317/44 , C07C319/20 , C07C323/62 , C07D307/46 , C07D307/54 , C07D307/56 , C07D307/68 , C07D307/70 , C07D333/24 , C07D333/28 , C07D333/38 , C07D333/42 , C07F7/08 , C07D307/02 , C07D333/16
CPC分类号： C07D307/56 , C07C45/63 , C07C45/65 , C07C45/68 , C07C49/223 , C07C49/657 , C07C49/683 , C07C49/697 , C07C49/753 , C07C51/00 , C07D307/68 , C07D307/70 , C07D333/28 , C07D333/38 , C07D333/42
摘要： A process for the preparation of 2,2-dimethyl-3-arylcyclopropanecarboxylic acid or ester of the formula ##STR1## in which Ar is naphthyl or the radical ##STR2## R.sup.1 is H or C.sub.1 -C.sub.4 -alkyl, Z is oxygen, sulphur, or 1,2-ethenediyl, andR.sup.2 represents hydrogen, halogen, cyano, nitro or trialkylsilyl or a radical, which is optionally substituted by halogen, from the series comprising alkyl, cycloalkyl, alkenyl, alkoxy, alkylenedioxy, alkylthio, alkylsulphinyl, alkylsulphonyl, dialkylamino, phenyl and phenoxy,comprising reacting a 1-aryl-1-halogeno-2,2-dimethyl-3-butanone of the formula ##STR3## in which X.sup.1 is chlorine or bromine, with a base in the presence of a diluent at a temperature between about -20.degree. and +150.degree. C., thereby to form a 2,2-dimethyl-3-arylcyclobutanone of the formula ##STR4## and reacting such 2,2-dimethyl-3-arylcyclobutanone with chlorine or bromine in the presence of an inert diluent at a temperature between about -30.degree. and +50.degree. C., reacting such 2,2-dimethyl-3-arylcyclobutanone with chlorine or bromine in the presence of an inert diluent at a temperature between about -30.degree. and +150.degree. C., thereby to form a 2,2-dimethyl-3-aryl-4-halogenocyclobutanone of the formula ##STR5## and reacting such 2,2-dimethyl-3-aryl-4-halogenocyclobutanone with an alkali metal alcoholate in the presence of an organic solvent or with an alkali metal or alkaline earth metal hydroxide or carbonate in the presence of water and an organic solvent, at a temperature between about -20.degree. and +100.degree. C. The various intermediates are new and the end product is a known intermediate for known insecticides.
摘要翻译：制备2,2-二甲基-3-芳基环丙烷羧酸或其中Ar为萘基或R 1为R 1的式“IMAGE”的酯的方法为H或C 1 -C 4 - 烷基，Z为氧，硫或1,2-乙烯二基，R 2代表氢，卤素，氰基，硝基或三烷基甲硅烷基或任选被卤素取代的基团，包括烷基，环烷基，烯基，烷氧基，亚烷基二氧基，烷硫基，烷基亚磺酰基，烷基磺酰基，二烷基氨基，苯基和苯氧基，包括使X1为氯或溴的式“IMAGE”的1-芳基-1-卤代-2,2-二甲基-3-丁酮与碱在稀释剂存在下反应在约-20℃至+ 150℃之间的温度下，由此形成下式的2,2-二甲基-3-芳基环丁酮，并使这种2,2-二甲基-3-芳基环丁酮与氯或溴反应在惰性稀释剂存在下，在-30℃〜+ 50℃的温度下，使这样的2,2-二甲基-3-芳基氯丁酮与氯或溴在惰性稀释剂存在下，在约-30℃至+ 150℃之间的温度下反应，由此形成下式的“2,2-二甲基-3-芳基-4-卤代环丁酮” 并在有机溶剂或碱金属或碱土金属氢氧化物或碳酸盐存在下，在水和有机溶剂的存在下，使这种2,2-二甲基-3-芳基-4-卤代环丁酮与碱金属醇盐反应，在约-20℃至+ 100℃之间的温度下。各种中间体是新的，最终产物是已知杀虫剂的已知中间体。

4. 发明授权

US4663465A Preparation of 2,2-dimethyl-3-aryl-cyclopropanecarboxylic acid and esters and new intermediates therefor 失效
标题翻译：制备2,2-二甲基-3-芳基 - 环丙烷羧酸和酯及其新的中间体
公开(公告)号：US4663465A
公开(公告)日：1987-05-05
申请号：US805502
申请日：1985-12-04
申请人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
发明人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
IPC分类号： C07C69/743 , C07C45/00 , C07C45/63 , C07C45/68 , C07C49/20 , C07C49/223 , C07C49/233 , C07C49/235 , C07C49/237 , C07C49/255 , C07C51/00 , C07C61/39 , C07C61/40 , C07C62/30 , C07C67/00 , C07C69/753 , C07C201/00 , C07C205/55 , C07C225/22 , C07C227/00 , C07C227/02 , C07C229/46 , C07C253/00 , C07C255/56 , C07C255/57 , C07C313/00 , C07C315/04 , C07C317/44 , C07C319/20 , C07C323/62 , C07D307/54 , C07D333/24 , C07D327/00 , C07D307/02 , C07D307/48 , C07D409/00
CPC分类号： C07D333/24 , C07C45/63 , C07C45/68 , C07C49/223 , C07C49/235 , C07C49/237 , C07C49/255 , C07C51/00 , C07D307/54
摘要： 2,2-Dimethyl-3-arylcyclopropanecarboxylic acids and esters, suitable as insecticide intermediates, of the formula ##STR1## in which Ar is naphthyl or substituted furyl, thienyl or phenyl, andR.sup.1 is hydrogen or alkyl, are produced by subjecting ##STR2## to radical polymerization to produce ##STR3## reacting that with chlorine or bromine to produce ##STR4## and reacting that with an alkali metal or alkaline earth metal hydroxide or carbonate. Various intermediates II and III are new.
摘要翻译：其中Ar为萘基或取代的呋喃基，噻吩基或苯基，R1为氢或烷基的式（Ⅰ）中适合作为杀虫剂中间体的2,2-二甲基-3-芳基环丙烷羧酸和酯由（IV）进行自由基聚合以产生与氯或溴反应产生（II）并与碱金属或碱土金属氢氧化物或碳酸酯反应的反应（III）。各种中间体II和III是新的。

5. 发明授权

US4426529A Preparation of 2-(2-2-dimethyl-3-buten-1-yl)-2-oxaxolines 失效
标题翻译： 2-（2-2-二甲基-3-丁烯-1-基）-2-恶唑啉的制备
公开(公告)号：US4426529A
公开(公告)日：1984-01-17
申请号：US342276
申请日：1982-01-25
申请人： Manfred Jautelat , Dieter Arlt
发明人： Manfred Jautelat , Dieter Arlt
IPC分类号： C07D263/04 , C07D263/12 , C07D263/10
CPC分类号： C07D263/04 , C07D263/12
摘要： A process comprising reacting a 2-methyloxazoline with a 3-methyl-2-buten-1-yl derivative of the formula ##STR1## in which X is halide, sulphonate or phosphate thereby to produce a 2-methyl-3-(3-methyl-2-butenyl)-2-oxazolinium salt of the formula ##STR2## reacting the oxazolinium salt with an alcoholate of the formulaR.sup.5 --O--M (V)in which M is one equivalent of an alkali metal or alkaline earth metal cation, to produce an oxazolidine of the formula ##STR3## pyrolyzing the oxazolidine to produce a 2-methyl-3-(3-methyl-2-butenyl)-oxazolindine of the formula ##STR4## and heating the 2-methylene-3-(3-methyl-2-butenyl)-oxazolidine to produce a 2-(2,2-dimethyl-3-buten-1-yl)-2-oxazoline.
摘要翻译：一种方法，包括使2-甲基恶唑啉与式（VII）的3-甲基-2-丁烯-1-基衍生物反应，其中X为卤化物，磺酸盐或磷酸盐，从而产生2-甲基-3- （Ⅳ）的（3-甲基-2-丁烯基）-2-恶唑啉盐（Ⅳ）使恶唑啉盐与式为R5-OM（Ⅴ）的醇化物反应，其中M为1当量的碱金属或碱土金属阳离子，以产生式（III）的恶唑烷，式（III）热解恶唑烷以产生式“IMAGE”的2-甲基-3-（3-甲基-2-丁烯基） - 恶唑啉并加热 2-亚甲基-3-（3-甲基-2-丁烯基） - 恶唑烷，得到2-（2,2-二甲基-3-丁烯-1-基）-2-恶唑啉。

6. 发明授权

US4191712A Process for the preparation of 1,1-dihalo-4-methyl-1,3-pentadiene compounds 失效
标题翻译：制备1,1-二卤代-4-甲基-1,3-戊二烯化合物的方法
公开(公告)号：US4191712A
公开(公告)日：1980-03-04
申请号：US964216
申请日：1978-11-27
申请人： Dieter Arlt , Manfred Jautelat
发明人： Dieter Arlt , Manfred Jautelat
IPC分类号： C07C17/00 , C07C17/25 , C07C17/361 , C07C21/06 , C07C21/19 , C07C67/00 , C07C17/24
CPC分类号： C07C17/361
摘要： Process for making 1,1-dihalo-4-methyl-1,3-pentadiene compounds which process comprises reacting a 2-2-dimethyl-3,5,5,5-tetrahelogenopent-1-yl derivative of the formula ##STR1## in which Hal.sup.1 is defined as above,Hal.sup.2 is halogen, andR is hydrogen or alkanoyl of up to 5 carbon atoms with a substance having a basic reaction in a temperature range from 20.degree. to 160.degree. C. Certain intermediates produced in such process can also be used as the initial starting material.
摘要翻译：制备1,1-二卤代-4-甲基-1,3-戊二烯化合物的方法包括使下式的图像形式的2-二甲基-3,5,5,5-四脱木酸-1-基衍生物：（I），其中Hal1如上所定义，Hal2是卤素，R是氢或具有至多5个碳原子的烷酰基，物质在20至160℃的温度范围内具有碱性反应。产生某些中间产物在这种过程中也可以用作初始起始材料。

7. 发明授权

US5082527A Nitrogen-containing polymeric compounds 失效
标题翻译：含氮的聚合物
公开(公告)号：US5082527A
公开(公告)日：1992-01-21
申请号：US323457
申请日：1989-03-14
申请人： Henning Bachem , Georg Schroder , Carlhans Suling , Jurgen Reiners , Janos Muszik , Dieter Arlt , Manfred Jautelat , Wolf-Dieter Schroer
发明人： Henning Bachem , Georg Schroder , Carlhans Suling , Jurgen Reiners , Janos Muszik , Dieter Arlt , Manfred Jautelat , Wolf-Dieter Schroer
IPC分类号： C08G73/00 , C08G59/10 , C08G69/48 , C08G73/02 , D21H17/54 , D21H17/55
CPC分类号： C08G73/0253 , C08G69/48 , C08G73/022 , D21H17/54
摘要： Crosslinkable compounds obtainable by reaction of water-soluble mono- or polyamines with 2,3-epoxypropyl sulphonates or 2-hydroxypropyl 1,3-bis-sulphonates or their mixtures with up to 15 mol % of an epihalogenohydrin or dihalogenohydrin are used for imparting wet strength to paper.
摘要翻译：可通过水溶性单胺或多胺与2,3-环氧丙基磺酸盐或2-羟丙基1,3-双磺酸盐或其与至多15mol％表卤代醇或二卤代醇的混合物的反应获得的可交联化合物用于赋予湿力量到纸。

8. 发明授权

US4992577A Preparation of 3-vinyl-substituted 2,2-dimethylcyclopropane-1-carboxylic acids and esters and intermediates therefor 失效
标题翻译：制备3-乙烯基取代的2,2-二甲基环丙烷-1-羧酸及其酯及其中间体
公开(公告)号：US4992577A
公开(公告)日：1991-02-12
申请号：US355578
申请日：1989-05-22
申请人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
发明人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
IPC分类号： C07C45/63 , C07C45/72 , C07C49/227 , C07C49/235 , C07C51/00
CPC分类号： C07C45/72 , C07C45/63 , C07C49/227 , C07C49/235 , C07C51/00
摘要： A process for preparing a compound of the formula ##STR1## in which Y is halogen, alkyl or cycloalkyl optionally substituted by halogen or C.sub.1-4 -alkoxy, alkenyl optionally substituted by halogen, aryl, heteroaryl or alkoxycarbonyl,X is hydrogen, halogen or optionally halogen-substituted alkyl, orX and Y, together with the adjacent C atom, form a saturated cycloalkphatic ring having up to 6 C atoms, andR is hydrogen or C.sub.1 -C.sub.4 -alkyl, comprising reacting an aldehyde of the formula ##STR2## with 2-methylbutan-3-one of the formula ##STR3## in the presence of a hydrohalic acid thereby to form a 4,4-dimethyl-3-halogeno-1-hexen-5-one of the formula ##STR4## in which Hal is halogen, halogenating said compound to produce a compound of the formula ##STR5## and reacting said compound with a base of the formulaR--OM (VI)in whichM is one equivalent of an alkali or alkaline earth metal ion.Compounds IV and V are new. By suitable conditions the trans isomer is selectively produced.
摘要翻译：制备式（I）化合物的方法，其中Y为卤素，任选被卤素或C 1-4 - 烷氧基取代的烷基或环烷基，任选被卤素，芳基，杂芳基或烷氧基羰基取代的链烯基，X为氢，卤素或任选的卤素取代的烷基，或X和Y与相邻的C原子一起形成具有至多6个C原子的饱和环烷基环，R是氢或C 1 -C 4烷基，包括使式（II）化合物与式（III）的2-甲基丁-3-酮在氢卤酸存在下反应，从而形成4,4-二甲基-3-卤代-1-己烯-5 其中Hal是卤素的式（Ⅳ）化合物，卤化所述化合物以制备下式化合物（Ⅴ），并使所述化合物与式R-OM（Ⅵ）的碱反应在其中M为1当量碱金属或碱土金属离子。化合物IV和V是新的。通过合适的条件选择性地制备反式异构体。

9. 发明授权

US4826865A Novel azolyl-aroxymethyl-dimethylpentinol fungicides 失效
标题翻译：新型唑基 - 羟基甲基 - 二甲基辛醇杀菌剂
公开(公告)号：US4826865A
公开(公告)日：1989-05-02
申请号：US175467
申请日：1988-03-30
申请人： Gerhard Jager , Manfred Jautelat , Dieter Arlt , Paul Reinecke , Wilhelm Brandes , Gerd Hanssler
发明人： Gerhard Jager , Manfred Jautelat , Dieter Arlt , Paul Reinecke , Wilhelm Brandes , Gerd Hanssler
IPC分类号： A01N43/50 , A01N43/64 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , C07D233/54
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Novel fungicidally active compounds of the formula ##STR1## in which X is nitrogen or the CH group,Y is hydrogen, bromine or iodine,Z is oxygen, sulphur, the --SO-- group or the --SO.sub.2 -- group, andAr is optionally substituted aryl,or physiologically tolerated addition products thereof with acids or metal salts.
摘要翻译：新型杀真菌活性化合物，其中X是氮或CH基，Y是氢，溴或碘，Z是氧，硫，-SO-基或-SO 2 - 基，Ar是任选的取代的芳基或其与酸或金属盐的生理上耐受的加成产物。

10. 发明授权

US4460793A Preparation of monochloromethyl ketones 失效
标题翻译：单氯甲基酮的制备
公开(公告)号：US4460793A
公开(公告)日：1984-07-17
申请号：US329959
申请日：1981-12-11
申请人： Manfred Jautelat , Dieter Arlt , Gerhard Jager
发明人： Manfred Jautelat , Dieter Arlt , Gerhard Jager
IPC分类号： C07C17/25 , C07C17/26 , C07C41/00 , C07C43/225 , C07C45/00 , C07C45/51 , C07C49/16 , C07C49/175 , C07C49/223 , C07C49/227 , C07C49/255 , C07C49/327 , C07C67/00 , C07C69/757 , C07C45/42
CPC分类号： C07C49/327 , C07C17/25 , C07C17/269 , C07C43/225 , C07C45/513 , C07C49/16 , C07C49/223 , C07C49/227 , C07C49/255
摘要： A process for the production of a monochloromethyl ketone of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 each independently is a hydrogen atom or an optionally substituted alkyl, alkenyl, alkinyl or aryl radical, orR.sup.1 and R.sup.2 together with the carbon atom to which they are attached form an optionally substituted carbocyclic ring,comprising reacting a 1,1-dichloroalkene of the formula ##STR2## with a phenolate of the formula ##STR3## in which R.sup.4 each independently is a halogen atom, a nitro group, or an optionally substituted alkyl, alkoxy or aryl radical,n is 0, 1, 2 or 3, andM is one equivalent of an alkali metal ion or alkaline earth metal ion,thereby to obtain a phenyl ether intermediate, and then subjecting the phenyl ether intermediate to an acid hydrolysis. The products are useful as intermediates in the synthesis of fungicides.
摘要翻译：制备式“IMAGE”的单氯甲基酮的方法，其中R 1，R 2和R 3各自独立地为氢原子或任选取代的烷基，烯基，炔基或芳基，或R 1和R 2与碳原子一起它们所连接的化合物形成任选取代的碳环，包括使式IMAMA的1,1-二氯链烯与式（Ⅰa）的酚盐反应，其中R 4各自独立地为卤原子，硝基或任选取代的烷基，烷氧基或芳基，n为0,1,2或3，M为1当量碱金属离子或碱土金属离子，从而得到苯基醚中间体，然后使苯基醚中间体进行酸水解。该产品可用作合成杀真菌剂的中间体。

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