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1. 再颁专利

USRE30650E Dispersing and stabilizing agents for dyestuffs 失效
标题翻译：染料分散稳定剂
公开(公告)号：USRE30650E
公开(公告)日：1981-06-16
申请号：US103492
申请日：1979-12-14
申请人： Reinhold Deubel , Helmut Diery , Wolfgang Klinner , Karl-Hermann List , Heinz Uhrig
发明人： Reinhold Deubel , Helmut Diery , Wolfgang Klinner , Karl-Hermann List , Heinz Uhrig
IPC分类号： C08G8/18 , C08G8/28 , C09B67/46 , D06P1/56
CPC分类号： C08G8/28 , C08G8/18 , C09B67/0086 , D06P1/56
摘要： Dispersions of pigments, disperse- or vat-dyestuffs, wherein the dispersing agent is formed either by cocondensation of a phenolic component, formaldehyde and an alkali metal sulfite or of a sulfonated phenolic component and formaldehyde. These dispersions are characterized in that the dispersing agent used shows an improved dispersing effect. Furthermore, they can also be used when being neutralized for the dispersing alkali sensitive dyestuffs and they show no tendency to soil the fabrics so that also clean shades may be dyed.

2. 发明授权

US4214872A Dispersing agents for finely dividing and stabilizing dyestuffs, pigments and optical brighteners as well as the dispersions thereby obtained 失效
标题翻译：用于细分和稳定染料，颜料和荧光增白剂的分散剂以及由此获得的分散体
公开(公告)号：US4214872A
公开(公告)日：1980-07-29
申请号：US777860
申请日：1977-03-15
申请人： Heinz Uhrig , Karl-Hermann List , Reinhold Deubel
发明人： Heinz Uhrig , Karl-Hermann List , Reinhold Deubel
IPC分类号： B01F17/00 , B01F17/02 , B01F17/12 , B01F17/52 , C09B67/46 , D06L3/12 , D06P1/62
CPC分类号： B01F17/0057 , C09B67/0086 , D06L3/1264
摘要： Watersoluble condensation products of mono- or di-alkyl naphthalene sulfonic acids and formaldehyde are dispersants for dyestuffs, pigments and optical brighteners, which do not soil textiles and give highly fluid dispersions. The dispersions are stable to heat and storing.
摘要翻译：单 - 或二 - 烷基萘磺酸和甲醛的水溶性缩合产物是用于染料，颜料和荧光增白剂的分散剂，它们不会污染纺织品并产生高度流体的分散体。分散体对于加热和储存是稳定的。

3. 发明授权

US3993439A Dispersing and stabilizing agents for dyestuffs 失效
标题翻译：染料分散稳定剂
公开(公告)号：US3993439A
公开(公告)日：1976-11-23
申请号：US409781
申请日：1973-10-26
申请人： Reinhold Deubel , Helmut Diery , Wolfgang Klinner , Karl-Hermann List , Heinz Uhrig
发明人： Reinhold Deubel , Helmut Diery , Wolfgang Klinner , Karl-Hermann List , Heinz Uhrig
IPC分类号： C09B67/46 , D06P1/62 , D06P1/16 , D06P1/22 , D06P1/56
CPC分类号： C09B67/0086 , D06P1/621 , D06P1/625
摘要： Dispersions of pigments, disperse- or vat-dyestuffs, wherein the dispersing agent is formed either by co-condensation of a phenolic component, formaldehyde and an alkali metal sulfite or of a sulfonated phenolic component and formaldehyde. These dispersions are characterized in that the dispersing agent used shows an improved dispersing effect. Furthermore, they can also be used when being neutralized for the dispersing alkali sensitive dyestuffs and they show no tendency to soil the fabrics so that also clean shades may be dyed.
摘要翻译：颜料，分散体或染色剂的分散体，其中分散剂通过酚类组分，甲醛和碱金属亚硫酸盐或磺化酚类组分和甲醛的共缩合形成。这些分散体的特征在于所用的分散剂显示出改进的分散效果。此外，它们也可以在分散碱敏感染料被中和时使用，并且它们不显示织物污染的倾向，从而也可以染色干净的色调。

4. 发明授权

US4597906A Surface-active compounds on the basis of arylated fatty substances and their use 失效
标题翻译：基于芳基化脂肪物质的表面活性化合物及其用途
公开(公告)号：US4597906A
公开(公告)日：1986-07-01
申请号：US565906
申请日：1983-12-27
申请人： Heinz Uhrig , Klaus Ehl , Reinhold Deubel
发明人： Heinz Uhrig , Klaus Ehl , Reinhold Deubel
IPC分类号： C07C69/66 , B01F17/00 , B01F17/42 , C07C41/00 , C07C41/02 , C07C43/178 , C07C43/20 , C07C43/205 , C07C51/00 , C07C59/125 , C07C67/00 , C07C219/04 , C07C227/00 , C07C229/12 , C07C301/00 , C07C305/10 , C07C309/03 , C07C309/62 , C08G65/26 , C09D7/45 , C11D1/72 , D06P1/60 , D06P1/613 , C08H3/00
CPC分类号： B01F17/0042 , B01F17/0028 , B01F17/0057 , C08G65/2615 , C09D7/02
摘要： Compounds of the formulaA[(Y--O).sub.x --Y--Z].sub.min which A is the radical of an oxaryl-modified (modified with an aryl group containing a hydroxyl group) fatty alcohol, i.e., the radical of an arylated fatty alcohol, or is the radical of an oxaryl-modified (again, modified with an aryl group containing a hydroxyl group) fatty acid or esterification product thereof, i.e., the radical of an arylated fatty acid or esterification product thereof, Y denotes identical or different groups of the formula--CH.sub.2 --CH.sub.2 -- or --CH.sub.2 --CH(CH.sub.3)--,Z denotes identical or different radicals of the formulae --OH, --O--CO--CH.dbd.CH--COOM and --O--CO--CH.sub.2 --CH(SO.sub.3 M)--COOM, in whichM is a cation,x is an integer of from 1 to 150 andm is a number of from 1 to 7,are suitable as interfacially active agents, in particular as dispersing agents, wetting agents, emulsifiers and dyeing auxiliaries.
摘要翻译：式（A）（YO）xYZ] m的化合物，其中A是被氧杂芳基改性（含有羟基的芳基改性）脂肪醇的基团，即芳基化脂肪醇的基团，或者是氧杂芳基改性（再次用含羟基的芳基改性）脂肪酸或其酯化产物，即芳基化脂肪酸或其酯化产物的基团，Y表示相同或不同的式 - CH 2 -CH 2 - 或-CH 2 -CH（CH 3） - ，Z表示式-OH，-O-CO-CH = CH-COOM和-O-CO-CH 2 -CH（SO 3 M）-COOM的相同或不同的基团，其中M为阳离子，x为1至150的整数，m为1至7的数，适用作界面活性剂，特别是作为分散剂，润湿剂，乳化剂和染色助剂。

5. 发明授权

US5008442A Surface-active compounds on the basis of arylated fatty substances and their use 失效
标题翻译：基于芳基化脂肪物质的表面活性化合物及其用途
公开(公告)号：US5008442A
公开(公告)日：1991-04-16
申请号：US854339
申请日：1986-04-21
申请人： Heinz Uhrig , Klaus Ehl , Reinhold Deubel
发明人： Heinz Uhrig , Klaus Ehl , Reinhold Deubel
IPC分类号： C07C69/66 , B01F17/00 , B01F17/42 , C07C41/00 , C07C41/02 , C07C43/178 , C07C43/20 , C07C43/205 , C07C51/00 , C07C59/125 , C07C67/00 , C07C219/04 , C07C227/00 , C07C229/12 , C07C301/00 , C07C305/10 , C07C309/03 , C07C309/62 , C08G65/26 , C09D7/45 , C11D1/72 , D06P1/60 , D06P1/613
CPC分类号： B01F17/0042 , B01F17/0028 , B01F17/0057 , C08G65/2615 , C09D7/02
摘要： A compound of the formulaA[(Y-O).sub.x - Y - Z].sub.min which A is the radical of an arylated fatty alcohol, Y are identical or different groups of the formulae--CH.sub.2 --CH.sub.2 -- or --CH.sub.2 --CH(CH.sub.3)--,Z are identical or different radicals of the formulae --OH, --O--CO--CH.dbd.CH--COOM and --O--CO--CH.sub.2 --CH(SO.sub.3 M)--COOM,in whichM is a cation,x is an integer from 1 to 150, andm is a number from 1 to 7.

6. 发明授权

US5100989A Resin acid esters based on novolak oxyalkylates, their preparation and their use 失效
标题翻译：基于NOVOLAK氧化亚油酸的树脂酸酯，其制备及其使用
公开(公告)号：US5100989A
公开(公告)日：1992-03-31
申请号：US239509
申请日：1988-09-01
申请人： Heinz Uhrig , Erich Ackermann , Reinhold Deubel
发明人： Heinz Uhrig , Erich Ackermann , Reinhold Deubel
IPC分类号： A01N25/30 , B01F17/00 , B01F17/52 , C08G8/28 , C08G8/34 , C08G8/36 , C08G14/12 , C09B41/00 , D06P1/607
CPC分类号： A01N25/30 , B01F17/0028 , B01F17/0042 , B01F17/0057 , C08G14/12 , C08G8/28
摘要： The invention relates to surface-active compounds of the general formula (I) ##STR1## in which Ar is an aromatic system which is optionally substituted by C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -alkoxy, C.sub.2 -C.sub.5 -alkanoyl, C.sub.6 -C.sub.10 -aryl, (C.sub.6 -C.sub.10 -aryl)-C.sub.1 -C.sub.4 -alkyl, A has the formula --(X--O).sub.n --Y, wherein n denotes 1 to 50, X denotes ethylene or methylethylene and all or some of Y denote an acyl radical of a non-modified or modified natural resin acid and the other radicals Y denote radicals from the group comprising hydrogen, acyl radicals of saturated C.sub.1-24 -carboxylic acids, unsaturated C.sub.3-24 -carboxylic acids, C.sub.2-24 -hydroxy-fatty acids or C.sub.8-18 -alkyl-, -alkenyl- and -alkylidene-succinic acids, maleic acid, fumaric acid, sulfosuccinic acid, sulfuric acid, benzodicarboxylic acids and C.sub.1-16 -n-alkanedicarboxylic acids, W is a group --CHR-- or --CHR--N(R*)--T--N(R*)--CHR--, wherein R*is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -hydroxyalkyl, a radical A or --C.sub.2 -C.sub.4 -alkylene-O--A and R is H or C.sub.1-9 -alkyl, T is C.sub.2 -C.sub.12 -alkylene, which is optionally interrupted by --O-- or --NR'--, R' is H, C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -hydroxyalkyl, A or C.sub.2 -C.sub.4 -alkylene-O--A, W* is H or --CHR--N(R*)--T--N(R*)A and m is 1 to 16.The compounds are prepared on the basis of oxyalkylated novolaks of the formula (I) in which all the radicals Y denote hydrogen. The polyalkylene glycol chains are now terminally esterified or half-esterified in a one- or multi-stage reaction in accordance with the definition of A. The resulting surface-active products are suitable as emulsifiers and dispersing agents for the most diverse fields of applications.
摘要翻译：本发明涉及通式（I）的表面活性化合物（Ⅰ），其中Ar是任选被C 1 -C 18烷基，C 1 -C 18烷氧基，C 2 -C 5 - 烷酰基，C 6 -C 10 - 芳基，（C 6 -C 10 - 芳基）-C 1 -C 4烷基，A具有式 - （XO）n Y，其中n表示1至50，X表示亚乙基或甲基亚乙基，并且全部或部分Y表示未改性或改性的天然树脂酸的酰基，其它基团Y表示包括氢的基团，饱和C1-24羧酸的酰基，不饱和C3-24-羧酸，C2-24-羟基 - 脂肪酸或C 8-18烷基 - ， - 烯基 - 和 - 亚烷基 - 琥珀酸，马来酸，富马酸，磺基琥珀酸，硫酸，苯并二羧酸和C 1-16 - 正烷烃二羧酸，W是基团 - CHR-或-CHR-N（R *）-TN（R *）-CHR-，其中R *是氢，C1-C4-烷基，C2-C4-羟基烷基，基团A或-C2-C4-亚烷基 - OA和R是H或C1-9烷基，T是C2-C12-亚烷基，其是选择性的被-O-或-NR'中断的，R'是H，C 1 -C 4烷基，C 2 -C 4羟基烷基，A或C 2 -C 4亚烷基-OA，W *是H或-CHR-N（R *） - TN（R *）A和m为1至16.该化合物基于其中所有基团Y表示氢的式（I）的烷氧基化线型酚醛清漆制备。聚亚烷基二醇链现在根据A的定义在一步或多步反应中终止酯化或半酯化。得到的表面活性产物适合用作各种应用领域的乳化剂和分散剂。

7. 发明授权

US4333732A Dyestuff preparations containing oxalkylates of modified natural rosin acids 失效
标题翻译：含有改性天然松香酸的烷基化物的染料制剂
公开(公告)号：US4333732A
公开(公告)日：1982-06-08
申请号：US75032
申请日：1979-09-13
申请人： Reinhold Deubel , Konrad Opitz , Hubert Kruse , Manfred Schneider , Heinz Uhrig
发明人： Reinhold Deubel , Konrad Opitz , Hubert Kruse , Manfred Schneider , Heinz Uhrig
IPC分类号： C09B67/20 , C09B67/38 , C09B67/46 , C09D17/00 , C09F1/04 , D06P1/613 , C09B67/00 , D06P1/16
CPC分类号： C09D17/003 , C09B67/006 , C09B67/008 , C09B67/0085 , C09F1/04 , D06P1/613 , Y10S8/922
摘要： Oxalkylates of chemically modified natural rosin acids are useful for dyestuff preparations, especially for dispersions of disperse dyestuffs. The liquid and solid dyestuff preparations containing these oxalkylates are stable to storing even with high dyestuff concentrations, easily redispersible while developing little foam and easily biodegradable.
摘要翻译：化学改性天然松香酸的烷基化物可用于染料制剂，特别是用于分散染料的分散体。含有这些烷基烷基化物的液体和固体染料制剂即使具有高染料浓度也是稳定的，容易再分散，同时开发少量泡沫并易于生物降解。

8. 发明授权

US4297270A Manufacture and use of non-ionogenic interface-active agents based on modified rosins 失效
标题翻译：基于改性松香的非离子型界面活性剂的制造和使用
公开(公告)号：US4297270A
公开(公告)日：1981-10-27
申请号：US75034
申请日：1979-09-13
申请人： Heinz Uhrig , Reinhold Deubel
发明人： Heinz Uhrig , Reinhold Deubel
IPC分类号： B01F17/00 , B01F17/42 , C08G65/26 , C09F1/04 , D06M15/02
CPC分类号： B01F17/005 , B01F17/0028 , B01F17/0057 , C08G65/26 , C09F1/04 , Y10S516/06
摘要： Compounds of the formulaA[(X--O).sub.n --H].sub.mwhereinA is a cycloalkyl-, aralkyl- or aryl-modified rosin acid radical or a radical of an ester of a polyhydric alcohol with such an acid,X stands for the same or different group or groups of the formulae--CH.sub.2 --CH.sub.2 --and--CH.sub.2 --CH(CH.sub.3)--,n is a number of 1 to 100 andm is an integer of 1 to 5are surface- and interface-active agents, especially dispersants, emulsifiers, wetting agents and dyeing adjuvants.
摘要翻译：式A [（XO）nH] m的化合物，其中A是环烷基 - ，芳烷基 - 或芳基 - 改性的松香酸基或多元醇与这种酸的酯基团，X代表相同或不同的式-CH 2 -CH 2 - 和-CH 2 -CH（CH 3） - 的基团或基团，n为1〜100的数，m为1〜5的整数，为表面活性剂和界面活性剂，特别是分散剂，乳化剂，润湿剂和染色助剂。

9. 发明授权

US4939238A Nitrogen-containing condensation products based on unmodified or modified natural resins, process for the preparation thereof and the use thereof 失效
标题翻译：基于未改性或改性天然树脂的含氮缩合产物，其制备方法及其用途
公开(公告)号：US4939238A
公开(公告)日：1990-07-03
申请号：US211214
申请日：1988-06-22
申请人： Heinz Uhrig , Siegfried Schwerin , Reinhold Deubel
发明人： Heinz Uhrig , Siegfried Schwerin , Reinhold Deubel
IPC分类号： C08G65/28 , B01F17/00 , B01F17/52 , C08G65/26 , C08G65/32 , C08G65/333 , C08G65/338 , C08G83/00 , C09D17/00 , C09F1/04
CPC分类号： C09F1/04 , B01F17/0028 , B01F17/0042 , C08G65/26 , C08G65/33306 , C08G65/338 , C09D17/00
摘要： Nitrogen-containing condensation products based on unmodified or modified natural resins, process for the preparation thereof and the use thereof.The invention relates to surface-active agents of the general formulaA--[(X--O).sub.n --Y--Z].sub.min which A is a radical of an unmodified or modified natural resin or esterification product thereof with a polyhydric alcohol, X is 1,2-ethylene or -propylene, Y is as defined for X or is --CH.sub.2 CHOHCH.sub.2 --, Z is OH or (Ia)(--NH--Q).sub.a --NR--(Q--NH--).sub.b H (Ia)in which R is H or C.sub.1 -C.sub.24 --alkyl or (--CH.sub.2 CH.sub.2 O).sub.p --H, with p being 1 to 100, or (--Q--NH).sub.c --H, Q is C.sub.1 -C.sub.24 ---alkylene which can be interrupted by oxygen atoms, a is 0-5 and c is 0-5,at least one Z being other than OH,n is 0 to 150 andm is 1 to 5.The compounds are obtained by alkoxylating resins or esterification products thereof with polyhydric alcohols and, after conversion of hydroxyl groups into suitable leaving groups, reacting the products of with amines of the formula Z-H.The products are suitable above all as coupling auxiliaries, dispersants and formulating agents for colorants.
摘要翻译：基于未改性或改性天然树脂的含氮缩合产物，其制备方法及其用途。本发明涉及通式A - [（XO）nYZ] m的表面活性剂，其中A是未改性或改性天然树脂的基团或其与多元醇的酯化产物，X是1,2-亚乙基或 - 丙烯，Y如对X所定义或是-CH 2 CHOHCH 2 - ，Z是OH或（Ia）（-NH-Q）a -NR - （Q-NH-）b H（Ia），其中R是H或C1 -C 24 - 烷基或（ - CH 2 CH 2 O）pH，p为1至100，或（-Q-NH）cH，Q为可被氧原子间隔的C 1 -C 24 - 亚烷基，a为0-5和c 为0-5，至少一个Z不是OH，n为0至150，m为1至5.通过使树脂或其酯化产物与多元醇烷氧基化，并将羟基转化为合适的离去基团，使式Z的胺与产物反应。该产品首先适用于着色剂的偶联助剂，分散剂和配制剂。

10. 发明授权

US4403077A Anionic compounds based on modified novolak oxyalkylates, their _preparation, and their use as foam-free surface-active agents 失效
标题翻译：基于改性酚醛清漆烷氧基化物的阴离子化合物，它们的制备及其作为无泡沫表面活性剂的用途
公开(公告)号：US4403077A
公开(公告)日：1983-09-06
申请号：US380995
申请日：1982-05-21
申请人： Heinz Uhrig , Joachim Weide , Reinhold Deubel
发明人： Heinz Uhrig , Joachim Weide , Reinhold Deubel
IPC分类号： C11D1/04 , B01F17/00 , B01F17/42 , B01F17/52 , B01J23/00 , B01J23/02 , C07B61/00 , C07C67/00 , C07C69/78 , C07C301/00 , C07C303/20 , C07C303/32 , C07C309/17 , C08G8/00 , C08G8/28 , C08G8/36 , C09B67/46 , D06P1/613 , D06P1/62 , C08G8/30 , C08F283/00
CPC分类号： B01F17/0057 , B01F17/0028 , C08G8/28 , C08G8/36 , C09B67/0086 , D06P1/613 , Y10S516/03
摘要： The invention relates to novolak oxyalkylate mixed esters which, on the one hand, contain benzoyl and/or naphthoyl radicals and, on the other hand, contain maleic acid and/or sulfosuccinic acid half-ester groups. They are obtained by reacting novolak oxyalkylates with benzoic acid and/or naphthoic acid or with its anhydride or chloride on the one hand and maleic anhydride on the other hand and, if appropriate, reacting the maleic acid half-ester groups with sulfites to give sulfosuccinic acid half-ester groups. These compounds are highly suitable for use as dispersing agents for the preparation of low-foam dispersions of pigments, dyestuffs and other agents and as emulsifying, leveling and dyeing auxiliaries.
摘要翻译：本发明涉及酚醛清漆烷氧基化物混合酯，其一方面含有苯甲酰基和/或萘甲酰基，另一方面含有马来酸和/或磺基琥珀酸半酯基。它们通过酚醛清漆和/或萘甲酸或其酸酐或氯化物与马来酸酐反应而得到，另一方面是通过使马来酸半酯基与亚硫酸酯反应得到磺基琥珀酸酸半酯基团。这些化合物非常适合用作制备颜料，染料和其他试剂的低泡沫分散体的分散剂，以及乳化，流平和染色助剂。

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