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    • 4. 发明授权
    • Crosslinked glycerol or oligoglycerol esters, and use thereof as an additive in drilling fluids
    • 交联甘油或寡聚甘油酯,以及其作为钻井液中的添加剂的用途
    • US08193125B2
    • 2012-06-05
    • US12866492
    • 2009-02-06
    • Heinz MullerDiana MakerNadja HerzogAlfred Westfechtel
    • Heinz MullerDiana MakerNadja HerzogAlfred Westfechtel
    • C09K8/04C09K8/035
    • C09K8/36C08G63/48Y10S507/904
    • The present invention relates to a crosslinked glycerol or oligoglycerol ester which can be obtained by crosslinking a non-crosslinked glycerol or oligoglycerol ester which can be obtained by reacting an (A) acid phase comprising (a1) a fatty acid, (a2) a dicarboxylic acid, (a3) a dimeric fatty acid, (a4) an oligomeric fatty acid, (a5) a hydroxy fatty acid or (a6) a mixture of at least two thereof, with a (B) alcohol phase comprising (b1) monoglycerol, (b2) diglycerol, (b3) triglycerol, (b4) oligoglycerol made up of more than three glycerol units, (b5) an alkoxylate of glycerols (b1), (b2), (b3) or (b4), or (b6) a mixture of at least two thereof, forming a full or partial ester and crosslinking the full or partial ester by means of a crosslinking agent, wherein the crosslinking can take place during or after the formation of the full or partial ester.
    • 本发明涉及一种交联甘油或寡甘油酯,其可以通过使(A)酸相(a1)脂肪酸,(a2)二羧酸(A))与(a1)脂肪酸反应获得的非交联甘油或低聚甘油酯 酸,(a3)二聚脂肪酸,(a4)低聚脂肪酸,(a5)羟基脂肪酸或(a6)其至少两种的混合物与(B)醇相包含(b1)单甘油, (b1),(b2),(b3)或(b4)或(b6)的烷氧基​​化物(b2),(b2)双甘油,(b3)三甘油,(b4)低聚甘油, 形成全部或部分酯并通过交联剂交联全部或部分酯的混合物,其中交联可以在形成全部或部分酯期间或之后进行。
    • 5. 发明申请
    • CROSSLINKED GLYCEROL OR OLIGOGLYCEROL ESTERS, AND USE THEREOF AS AN ADDITIVE IN DRILLING FLUIDS
    • 交联的甘油或低聚果糖酯,并将其用作钻井液中的添加剂
    • US20110011645A1
    • 2011-01-20
    • US12866492
    • 2009-02-06
    • Heinz MullerDiana MakerNadja HerzogAlfred Westfechtel
    • Heinz MullerDiana MakerNadja HerzogAlfred Westfechtel
    • E21B7/00C07C67/02C09K8/28
    • C09K8/36C08G63/48Y10S507/904
    • The present invention relates to a crosslinked glycerol or oligoglycerol ester which can be obtained by crosslinking a non-crosslinked glycerol or oligoglycerol ester which can be obtained by reacting an (A) acid phase comprising (a1) a fatty acid, (a2) a dicarboxylic acid, (a3) a dimeric fatty acid, (a4) an oligomeric fatty acid, (a5) a hydroxy fatty acid or (a6) a mixture of at least two thereof, with a (B) alcohol phase comprising (b1) monoglycerol, (b2) diglycerol, (b3) triglycerol, (b4) oligoglycerol made up of more than three glycerol units, (b5) an alkoxylate of glycerols (b1), (b2), (b3) or (b4), or (b6) a mixture of at least two thereof, forming a full or partial ester and crosslinking the full or partial ester by means of a crosslinking agent, wherein the crosslinking can take place during or after the formation of the full or partial ester.
    • 本发明涉及一种交联甘油或寡甘油酯,其可以通过使(A)酸相(a1)脂肪酸,(a2)二羧酸(A))与(a1)脂肪酸反应获得的非交联甘油或低聚甘油酯 酸,(a3)二聚脂肪酸,(a4)低聚脂肪酸,(a5)羟基脂肪酸或(a6)其至少两种的混合物与(B)醇相包含(b1)单甘油, (b1),(b2),(b3)或(b4)或(b6)的烷氧基​​化物(b2),(b2)双甘油,(b3)三甘油,(b4)低聚甘油, 形成全部或部分酯并通过交联剂交联全部或部分酯的混合物,其中交联可以在形成全部或部分酯期间或之后进行。
    • 8. 发明授权
    • Borehole treatment agent containing low-toxic oil phase
    • 钻孔处理剂含有低毒油相
    • US07666820B2
    • 2010-02-23
    • US10527212
    • 2003-09-09
    • Heinz MuellerNadja HerzogStephan Von Tapavicza
    • Heinz MuellerNadja HerzogStephan Von Tapavicza
    • C09K8/36E21B21/00
    • C09K8/34C09K8/36Y10S507/905
    • The invention relates to a borehole treatment composition containing an aqueous phase and a non-aqueous oil phase, emulsifiers and, where appropriate, further customary additives, the non-aqueous oil phase containing at least one of a) paraffins having from 5 to 22 carbon atoms; and b) internal olefins having from 12 to 30 carbon atoms in the molecule; in the form of a blend with c) carboxylic esters of the formula R—COO—R′, where R stands for a linear or branched, saturated or unsaturated alkyl radical having from 15 to 25 carbon atoms and R′ denotes a saturated, linear or branched alkyl radical having from 3 to 22 carbon atoms. The ratio of the toxicity of internal olefins of chain length C16/C18 (standard IO) to the toxicity of the constituents of the non-aqueous oil phase, in each case measured by the Leptocheirus plumulosus acute, static 96 hour/10 day sediment toxicity test (in accordance with ASTM E 1367-92 & EPA/600/R-94/025, Section 11), is less than 1.
    • 本发明涉及一种含有水相和非水性油相的乳
      液处理组合物,乳化剂以及适当的进一步的常规添加剂,所述非水性油相含有a)至少一种具有5-22个碳原子的链烷烃 原子 和b)分子中具有12至30个碳原子的内烯烃; 与c)式R-COO-R'的羧酸酯的形式,其中R代表具有15至25个碳原子的直链或支链,饱和或不饱和的烷基,R'表示饱和的,直链的 或具有3至22个碳原子的支链烷基。 链长C16 / C18(标准IO)的内烯烃的毒性与非水性油相的成分的毒性的比例,在每种情况下由Leptocheirus plumulosus急性,静态96小时/ 10天的沉淀物毒性测定 测试(根据ASTM E 1367-92和EPA / 600 / R-94/025,第11节)小于1。