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    • 4. 发明授权
    • Crosslinked glycerol or oligoglycerol esters, and use thereof as an additive in drilling fluids
    • 交联甘油或寡聚甘油酯,以及其作为钻井液中的添加剂的用途
    • US08193125B2
    • 2012-06-05
    • US12866492
    • 2009-02-06
    • Heinz MullerDiana MakerNadja HerzogAlfred Westfechtel
    • Heinz MullerDiana MakerNadja HerzogAlfred Westfechtel
    • C09K8/04C09K8/035
    • C09K8/36C08G63/48Y10S507/904
    • The present invention relates to a crosslinked glycerol or oligoglycerol ester which can be obtained by crosslinking a non-crosslinked glycerol or oligoglycerol ester which can be obtained by reacting an (A) acid phase comprising (a1) a fatty acid, (a2) a dicarboxylic acid, (a3) a dimeric fatty acid, (a4) an oligomeric fatty acid, (a5) a hydroxy fatty acid or (a6) a mixture of at least two thereof, with a (B) alcohol phase comprising (b1) monoglycerol, (b2) diglycerol, (b3) triglycerol, (b4) oligoglycerol made up of more than three glycerol units, (b5) an alkoxylate of glycerols (b1), (b2), (b3) or (b4), or (b6) a mixture of at least two thereof, forming a full or partial ester and crosslinking the full or partial ester by means of a crosslinking agent, wherein the crosslinking can take place during or after the formation of the full or partial ester.
    • 本发明涉及一种交联甘油或寡甘油酯,其可以通过使(A)酸相(a1)脂肪酸,(a2)二羧酸(A))与(a1)脂肪酸反应获得的非交联甘油或低聚甘油酯 酸,(a3)二聚脂肪酸,(a4)低聚脂肪酸,(a5)羟基脂肪酸或(a6)其至少两种的混合物与(B)醇相包含(b1)单甘油, (b1),(b2),(b3)或(b4)或(b6)的烷氧基​​化物(b2),(b2)双甘油,(b3)三甘油,(b4)低聚甘油, 形成全部或部分酯并通过交联剂交联全部或部分酯的混合物,其中交联可以在形成全部或部分酯期间或之后进行。
    • 5. 发明申请
    • CROSSLINKED GLYCEROL OR OLIGOGLYCEROL ESTERS, AND USE THEREOF AS AN ADDITIVE IN DRILLING FLUIDS
    • 交联的甘油或低聚果糖酯,并将其用作钻井液中的添加剂
    • US20110011645A1
    • 2011-01-20
    • US12866492
    • 2009-02-06
    • Heinz MullerDiana MakerNadja HerzogAlfred Westfechtel
    • Heinz MullerDiana MakerNadja HerzogAlfred Westfechtel
    • E21B7/00C07C67/02C09K8/28
    • C09K8/36C08G63/48Y10S507/904
    • The present invention relates to a crosslinked glycerol or oligoglycerol ester which can be obtained by crosslinking a non-crosslinked glycerol or oligoglycerol ester which can be obtained by reacting an (A) acid phase comprising (a1) a fatty acid, (a2) a dicarboxylic acid, (a3) a dimeric fatty acid, (a4) an oligomeric fatty acid, (a5) a hydroxy fatty acid or (a6) a mixture of at least two thereof, with a (B) alcohol phase comprising (b1) monoglycerol, (b2) diglycerol, (b3) triglycerol, (b4) oligoglycerol made up of more than three glycerol units, (b5) an alkoxylate of glycerols (b1), (b2), (b3) or (b4), or (b6) a mixture of at least two thereof, forming a full or partial ester and crosslinking the full or partial ester by means of a crosslinking agent, wherein the crosslinking can take place during or after the formation of the full or partial ester.
    • 本发明涉及一种交联甘油或寡甘油酯,其可以通过使(A)酸相(a1)脂肪酸,(a2)二羧酸(A))与(a1)脂肪酸反应获得的非交联甘油或低聚甘油酯 酸,(a3)二聚脂肪酸,(a4)低聚脂肪酸,(a5)羟基脂肪酸或(a6)其至少两种的混合物与(B)醇相包含(b1)单甘油, (b1),(b2),(b3)或(b4)或(b6)的烷氧基​​化物(b2),(b2)双甘油,(b3)三甘油,(b4)低聚甘油, 形成全部或部分酯并通过交联剂交联全部或部分酯的混合物,其中交联可以在形成全部或部分酯期间或之后进行。
    • 10. 发明授权
    • Oligoglycerol fatty acid ester lubricant additives for drilling fluids
    • 用于钻井液的低聚甘油脂肪酸酯润滑添加剂
    • US08236735B2
    • 2012-08-07
    • US12677845
    • 2008-09-12
    • Diana MakerHeinz Muller
    • Diana MakerHeinz Muller
    • C08K5/20C09K8/36
    • C09K8/32C09K8/36Y10S507/904
    • The use is described of oligoglycerol fatty acid esters, produced from (a) an acid component, selected from (a1) fatty acids of the general formula (I) R—COOH  (I) in which R stands for a saturated or unsaturated, branched or linear alkyl- or alkenyl radical with 7 to 21C atoms, and/or (a2) dicarboxylic acids and/or (a3) dimer fatty acids and/or (a4) oligomer fatty acids and/or (a5) hydroxy fatty acids with (b) a polyol component, which is selected from oligoglycerols or alkoxylates of oligoglycerols, as additive to oil-based drilling mud compositions to improve the lubricating effect of these mud systems.
    • 使用由(a)选自(a1)通式(I)的脂肪酸R-COOH(I)的酸成分制备的低聚甘油脂肪酸酯,其中R表示饱和或不饱和的支化 或具有7至21C原子的直链烷基或链烯基,和/或(a2)二羧酸和/或(a3)二聚脂肪酸和/或(a4)低聚物脂肪酸和/或(a5)羟基脂肪酸与( b)多元醇组分,其选自低聚甘油的低聚甘油或烷氧基化物,作为油基钻井泥浆组合物的添加剂,以改善这些泥浆体系的润滑效果。