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    • 2. 发明授权
    • Use of selected ethers of monofunctional alcohols in drilling fluids
    • 在钻井液中使用选择的单官能醇醚
    • US5318955A
    • 1994-06-07
    • US37499
    • 1993-03-24
    • Heinz MuellerGerhard StollClaus-Peter HeroldStephan von Tapavicza
    • Heinz MuellerGerhard StollClaus-Peter HeroldStephan von Tapavicza
    • C09K8/34C09K7/06
    • C09K8/34
    • The invention describes the use of water-insoluble esters with flash points above 80.degree. C., from monohydric alcohols of natural and/or synthetic origin with at least 4 carbon atoms, preferably at least 6 carbon atoms in the alcohol radicals, as the oil phase, or a constituent of the oil phase of invert drilling fluids which exist as W/O-emulsions, have a dispersed aqueous phase and ideally also have further usual additives in the continuous oil phase, which is fluid and pumpable in the temperature range of 0.degree. to 5.degree. C., and which are suitable for the environment-friendly development of, e.g., petroleum and natural gas deposits. Drilling fluids of the above type are also described which are characterized in that they contain as the continuous oil phase, or dissolved in ecologically-acceptable water-insoluble oils, an additive of at least largely water-insoluble ethers from monohydric alcohols, the oil phase in each case being fluid and pumpable in the temperature range of 0.degree. to 5.degree. C. and having flash points above 80.degree. C.
    • 本发明描述了闪点高于80℃的水不溶性酯,其具有天然和/或合成来源的至少4个碳原子,优选至少6个碳原子的醇基中的一元醇作为油 相或作为W / O乳液存在的倒置钻井液的油相的成分具有分散的水相,并且理想地在连续油相中还具有进一步通常的添加剂,其在流体和可泵送的温度范围内是可流动的 0℃〜5℃,适用于石油天然气矿床的环境友好型开发。 还描述了上述类型的钻井液,其特征在于它们作为连续油相包含或溶解在生态上可接受的水不溶性油中,至少主要是来自一元醇的水不溶性醚的添加剂,油相 在每种情况下都是在0℃至5℃的温度范围内流动并可泵送,闪点高于80℃。
    • 3. 发明授权
    • Process for the facilitated waste disposal of working substances based
on water-in-oil invert emulsions
    • 基于油包水反相乳液促进废物处理工作物质的方法
    • US6165946A
    • 2000-12-26
    • US297481
    • 1999-04-30
    • Heinz MuellerClaus-Peter HeroldThomas FoersterStephan von TapaviczaJohann-Friedrich Fues
    • Heinz MuellerClaus-Peter HeroldThomas FoersterStephan von TapaviczaJohann-Friedrich Fues
    • E21B21/06B09C1/08C09K3/00C09K8/28C09K8/32C09K8/36E21B21/00
    • E21B21/068C09K8/28C09K8/36Y10S507/927
    • The invention relates to a process for facilitating the disposal of flowable and pumpable working fluids based on emulsifiers containing W/O invert emulsions--more particularly corresponding auxiliaries of the type used in geological exploration, such as oil-based w/o invert drilling muds--and for the simplified cleaning of solid surfaces soiled therewith, if desired using flowable spraying aids, the process being characterized in that, by selecting and adapting the emulsifiers/emulsifier systems to the oil phase of the invert emulsion, temperature-controlled phase inversion is achieved at temperatures below the in-use temperatures of the w/o invert emulsions, but above the freezing point of the aqueous phase and in that disposal and cleaning are carried out at temperatures in and/or below the phase inversion temperature range. The invention also relates to the use of this process for the cleaning and disposal of roc cuttings covered with residual drilling mud from geological exploration during and/or preferably before their on-shore or off-shore dumping
    • PCT No.PCT / EP97 / 05798 Sec。 371日期1999年4月30日 102(e)1999年4月30日PCT PCT 1997年10月21日PCT公布。 第WO98 / 18882号公报 日期1998年5月7日本发明涉及一种促进基于含有W / O反相乳液的乳化剂处理可流动和可泵送的工作流体的方法,更具体地说涉及在地质勘探中使用的类型的相应助剂,例如油基w / o 反转钻井泥浆 - 并且为了简化清洁其中污染的固体表面,如果需要,使用可流动的喷洒助剂,该方法的特征在于通过选择和适应乳化剂/乳化剂体系到反相乳液的油相,温度控制 在低于w / o反相乳液的使用温度但高于水相的凝固点的温度下实现相转化,并且处理和清洗在相转变温度范围内和/或低于相转变温度范围的温度下进行 。 本发明还涉及这种方法用于清洁和处理在其在岸或离岸倾倒期间和/或优选在其岸上倾倒之前的地质勘探中覆盖有残留钻井泥浆的罗切切割
    • 7. 发明授权
    • Fluid drill-hole treatment agents based on polycarboxylic acid diesters
    • 基于多元羧酸二酯的流体钻孔处理剂
    • US5441927A
    • 1995-08-15
    • US336726
    • 1994-11-09
    • Heinz MuellerClaus-Peter HeroldStephan von TapaviczaJohann F. Fues
    • Heinz MuellerClaus-Peter HeroldStephan von TapaviczaJohann F. Fues
    • C09K8/26C09K8/34C09K7/06C09K7/02
    • C09K8/26C09K8/34
    • Described is the use of oleophilic esters of ecologically compatible polycarboxylic acids with oil-soluble and ecologically compatible monofunctional alcohols and/or polyfunctional alcohols which may also be watersoluble as the oil phase or as a component of the oil phase of oil-based or water-based drilling fluids and other fluid drill-hole treatment agents. The oleophilic polycarboxylic acid esters are especially suitable as component of the continuous oil phase of inverted fluids of the W/O type. Here--if rheologically suitable compounds will be employed--they may comprise the at least predominant portion of the continuous oil phase; but also possible is the concomitant use of complex oleophilic polycarboxylic acid esters, which are not or just to a restricted degree fluid in a temperature range of from 0.degree. C. to 20.degree. C., as an additive in fluid oils of the class of the non-polluting oils. Here, suitable oil mixing phases especially are oleophilic alcohols, ethers, respective esters of monocarboxylic acids and fluid oils based on oleophilic carbonic acid diesters.
    • 描述了生态相容的多元羧酸的亲油酯与油溶性和生态相容的单官能醇和/或多官能醇的使用,它们也可以作为油相或作为油相或水溶性油相的油相的组分, 基础钻井液和其他流体钻孔处理剂。 亲油性多羧酸酯特别适合作为W / O型倒置流体的连续油相的组分。 在这里 - 如果使用流变学合适的化合物 - 它们可以包括连续油相的至少主要部分; 但是也可能伴随使用复杂的亲油性多元羧酸酯,它们在0℃至20℃的温度范围内不是或仅限于限制流体,作为该类流体油中的添加剂 无污染的油。 这里,合适的油混合阶段尤其是亲油醇,醚,单羧酸的各自的酯和基于亲油碳酸二酯的流体油。
    • 9. 发明授权
    • Compositions for freeing jammed drill pipes
    • 释放堵塞钻杆的组成
    • US4964615A
    • 1990-10-23
    • US198428
    • 1988-05-25
    • Heinz MuellerClaus-Peter HeroldStephan von Tapavicza
    • Heinz MuellerClaus-Peter HeroldStephan von Tapavicza
    • C09K8/02
    • C09K8/02Y10S507/94
    • Compositions free from mineral oil and used for freeing jammed drill pipes in drilling operations, and processes for using such compositions are disclosed. The compositions comprise a mixture of:(a) one or more fatty acid alkyl esters corresponding to the following general formula ##STR1## in which R.sup.1 is a linear C.sub.7 -C.sub.23 alkyl, alkenyl or alkadienyl radical andR.sup.2 is a linear or branched C.sub.1 -C.sub.8 alkyl or hydroxyalkylene radical,(b) one or more thickeners such as organophilic bentonites, and(c) one or more emulsifiers.Preferred emulsifiers include a mixture of an aminoamide or a polyamine and a fatty acid or calcium salt thereof. The composition may contain other conventional additives and is adapted to be formulated in the field by blending with water and/or weighting agents to achieve the proper thickness and density for use as a well spotting fluid.
    • 公开了不含矿物油并用于在钻井作业中释放堵塞的钻杆的组合物,以及使用这种组合物的方法。 所述组合物包含以下混合物:(a)一种或多种对应于以下通式“IMAGE”的脂肪酸烷基酯,其中R 1是直链C 7 -C 23烷基,烯基或链二烯基,R 2是直链或支链C1- C8烷基或羟基亚烷基,(b)一种或多种增稠剂,例如亲有机膨润土,和(c)一种或多种乳化剂。 优选的乳化剂包括氨基酰胺或多胺及其脂肪酸或钙盐的混合物。 该组合物可以含有其它常规添加剂,并且适于通过与水和/或加重剂混合来配制在现场,以获得适当的厚度和密度,以用作良好的点样流体。