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    • 2. 发明授权
    • Multicomponent mixtures for use in geological exploration
    • 用于地质勘探的多组分混合物
    • US6022833A
    • 2000-02-08
    • US933188
    • 1997-09-18
    • Heinz MuellerClaus-Peter HeroldThomas FoersterStephan von TapaviczaJohann-Friedrich FuesMarcus Claas
    • Heinz MuellerClaus-Peter HeroldThomas FoersterStephan von TapaviczaJohann-Friedrich FuesMarcus Claas
    • C09K3/00C09K8/28C09K8/36C09K7/00
    • C09K8/28C09K3/00C09K8/36
    • The invention relates to flowable and pumpable multicomponent mixtures based on a multiphase mixture of water and oil containing emulsifiers and, if desired, other soluble, emulsifiable and/or dispersible auxiliaries for their use in exploration by drilling and/or for the further treatment of the wells thus drilled. The invention is characterized by the use of emulsifiers or emulsifier systems which, in the particular multicomponent mixture in question, lead to temperature-controlled phase inversion at a phase inversion temperature (PIT) in a temperature range of which the upper limit is so far below the working temperature of the multicomponent mixture in geological exploration that the water-based part of the multicomponent mixture is present as a disperse (invert) phase in the continuous oil phase (w/o invert emulsion) while the lower limit of this temperature range enables the multicomponent mixture to be converted into an o/w emulsion with a continuous aqueous phase. At least partly nonionic emulsifiers or emulsifier systems with a PIT of 0 to 100.degree. C. are particularly suitable. The invention enables the requirements in regard to technical performance, ecological compatibility and cost/effectiveness ratio to be optimally satisfied.
    • 本发明涉及可流动和可泵送的多组分混合物,其基于水和油的多相混合物,其包含乳化剂,并且如果需要,其它可溶性,可乳化和/或可分散的助剂用于通过钻井和/或进一步处理 所钻的井。 本发明的特征在于使用乳化剂或乳化剂体系,其在所述特定的多组分混合物中在相转变温度(PIT)下导致温度控制的相转化,其温度范围远远低于 多组分混合物在地质勘探中的工作温度,多组分混合物的水基部分作为连续油相(w / o反相乳液)中的分散(反相)相存在,而该温度范围的下限允许 将多组分混合物转化成具有连续水相的o / w乳液。 PIT为0至100℃的至少部分非离子乳化剂或乳化剂体系是特别合适的。 本发明使技术性能,生态兼容性和成本效益比方面的要求得到最佳的满足。
    • 5. 发明授权
    • Process for the facilitated waste disposal of working substances based
on water-in-oil invert emulsions
    • 基于油包水反相乳液促进废物处理工作物质的方法
    • US6165946A
    • 2000-12-26
    • US297481
    • 1999-04-30
    • Heinz MuellerClaus-Peter HeroldThomas FoersterStephan von TapaviczaJohann-Friedrich Fues
    • Heinz MuellerClaus-Peter HeroldThomas FoersterStephan von TapaviczaJohann-Friedrich Fues
    • E21B21/06B09C1/08C09K3/00C09K8/28C09K8/32C09K8/36E21B21/00
    • E21B21/068C09K8/28C09K8/36Y10S507/927
    • The invention relates to a process for facilitating the disposal of flowable and pumpable working fluids based on emulsifiers containing W/O invert emulsions--more particularly corresponding auxiliaries of the type used in geological exploration, such as oil-based w/o invert drilling muds--and for the simplified cleaning of solid surfaces soiled therewith, if desired using flowable spraying aids, the process being characterized in that, by selecting and adapting the emulsifiers/emulsifier systems to the oil phase of the invert emulsion, temperature-controlled phase inversion is achieved at temperatures below the in-use temperatures of the w/o invert emulsions, but above the freezing point of the aqueous phase and in that disposal and cleaning are carried out at temperatures in and/or below the phase inversion temperature range. The invention also relates to the use of this process for the cleaning and disposal of roc cuttings covered with residual drilling mud from geological exploration during and/or preferably before their on-shore or off-shore dumping
    • PCT No.PCT / EP97 / 05798 Sec。 371日期1999年4月30日 102(e)1999年4月30日PCT PCT 1997年10月21日PCT公布。 第WO98 / 18882号公报 日期1998年5月7日本发明涉及一种促进基于含有W / O反相乳液的乳化剂处理可流动和可泵送的工作流体的方法,更具体地说涉及在地质勘探中使用的类型的相应助剂,例如油基w / o 反转钻井泥浆 - 并且为了简化清洁其中污染的固体表面,如果需要,使用可流动的喷洒助剂,该方法的特征在于通过选择和适应乳化剂/乳化剂体系到反相乳液的油相,温度控制 在低于w / o反相乳液的使用温度但高于水相的凝固点的温度下实现相转化,并且处理和清洗在相转变温度范围内和/或低于相转变温度范围的温度下进行 。 本发明还涉及这种方法用于清洁和处理在其在岸或离岸倾倒期间和/或优选在其岸上倾倒之前的地质勘探中覆盖有残留钻井泥浆的罗切切割