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1. 发明授权

US5869434A Free-flowing borehole servicing preparations containing linear .alpha.-olefins, more patricularly corresponding drilling fluids 失效
标题翻译：自由流动的钻孔维护准备，包含线性α-烯烃，更多的是相应的钻井液
公开(公告)号：US5869434A
公开(公告)日：1999-02-09
申请号：US750829
申请日：1996-12-13
申请人： Heinz Mueller , Claus-Peter Herold , Matthias Fies , Stephan Von Tapavicza
发明人： Heinz Mueller , Claus-Peter Herold , Matthias Fies , Stephan Von Tapavicza
IPC分类号： C09K8/26 , C09K8/34 , C09K7/00 , C09K7/02
CPC分类号： C09K8/34 , C09K8/26 , Y10S507/905
摘要： The invention relates to the use of at least predominantly linear hydrocarbon compounds olefinically unsaturated in the alpha-position with flashpoints of at least about 80.degree. as the oil phase or as part of the oil phase of oil- or water-based free-flowing borehole servicing preparations. Particular significance is attributed to corresponding drilling fluids which, together with the alpha-olefins, contain other oil phases from the field of borehole servicing preparations and are distinguished by ecological compatibility, being degradable under both aerobic and anaerobic conditions. Suitable mixture components for the oil phase are, in particular, oleophilic alcohols, ethers and corresponding esters selected from carboxylic acid esters and/or carbonic acid esters.
摘要翻译： PCT No.PCT / EP95 / 02143 Sec。 371日期1996年12月13日第 102（e）日期1996年12月13日PCT归档1995年6月6日PCT公布。公开号WO95 / 34610 日期1995年12月21日本发明涉及至少主要是在α-位上烯属不饱和的烃类化合物的使用，其中至少约80℃的闪点为油相或作为油相或水 - 油的油相的一部分，基于自由流动的钻孔维修准备。特别的意义归因于相应的钻井液，其与α-烯烃一起含有来自钻孔维修制剂领域的其他油相，并且通过生态相容性来区分，在有氧和无氧条件下都是可降解的。用于油相的合适的混合物组分特别是亲油醇，醚和选自羧酸酯和/或碳酸酯的相应的酯。

2. 发明授权

US06350788B1 Low-foam surfactant concentrates for use in the domain of plant growth stimulation 失效
标题翻译：低泡表面活性剂浓缩物用于植物生长刺激的领域
公开(公告)号：US06350788B1
公开(公告)日：2002-02-26
申请号：US09341731
申请日：1999-10-22
申请人： Claus-Peter Herold , Stephan Von Tapavicza , Heinz Mueller , Heinz Boettcher
发明人： Claus-Peter Herold , Stephan Von Tapavicza , Heinz Mueller , Heinz Boettcher
IPC分类号： B01F1756
CPC分类号： A01N25/30 , Y10S71/903 , Y10S516/06
摘要： A low-foam wetting composition which, when mixed with water, enhances the penetration and spread of water on a plant, the composition containing: (a) an alkyl polyglycoside corresponding to formula I R—O—(G)x (I) wherein R is a primary hydrocarbon radical having from 8 to 18 carbon atoms, G is a glycose unit having 5 or 6 carbon atoms, and x is a number from 1 to 10; (b) an olefinically unsaturated alcohol; and (c) a lower water-soluble alcohol.
摘要翻译：一种低泡沫润湿组合物，当与水混合时，其增强水对植物的渗透和扩散，该组合物包含：（a）对应于式I的烷基多糖苷，其中R是具有8至18个碳原子的伯烃基原子，G是具有5或6个碳原子的糖苷单元，x是1至10的数; （b）烯属不饱和醇; 和（c）较低水溶性醇。

3. 发明授权

US5028342A Drilling mud additives based on a polymer mixture, their use, and a process for their production 失效
标题翻译：基于聚合物混合物的钻井泥浆添加剂，其用途及其生产方法
公开(公告)号：US5028342A
公开(公告)日：1991-07-02
申请号：US414978
申请日：1989-09-29
申请人： Willy Opitz , Heinz Mueller , Claus-Peter Herold , Stephan Von Tapavicza
发明人： Willy Opitz , Heinz Mueller , Claus-Peter Herold , Stephan Von Tapavicza
IPC分类号： C09K8/10 , C09K8/20
CPC分类号： C09K8/10 , C09K8/206 , Y10S507/925
摘要： Drilling mud additives based on a polymer mixture of 20 to 80% by weight carboxymethyl cellulose and 80 to 20% by weight of a polycarboxylic acid selected from polyacrylate, polymethacrylate and/or copolymers thereof and/or salts thereof, in which the carboxymethyl cellulose, which has been obtained from raw linters and/or wood cellulose by the slurry process, is mixed in wet, alcohol-moist form with the polycarboxylic acid and dried, to their use in drilling muds or workover and packer liquids, and to a process for their production.
摘要翻译：基于20-80重量％羧甲基纤维素和80-20重量％选自聚丙烯酸酯，聚甲基丙烯酸酯和/或其共聚物和/或其盐的多元羧酸的聚合物混合物的钻井泥浆添加剂，其中羧甲基纤维素，其通过浆料方法从原料短纤维和/或木纤维素获得，以湿，醇 - 湿形式与多元羧酸混合并干燥，用于钻井泥浆或修井和封隔器液体，以及用于他们的生产。

4. 发明授权

US06716799B1 Use of selected fatty alcohols and their mixtures with carboxylic acid esters as lubricant components in water-based drilling fluid systems for soil exploration 失效
标题翻译：选择的脂肪醇及其与羧酸酯的混合物作为用于土壤勘探的水基钻井液体系中的润滑剂组分
公开(公告)号：US06716799B1
公开(公告)日：2004-04-06
申请号：US09308400
申请日：1999-06-01
申请人： Heinz Mueller , Claus-Peter Herold , Stephan Von Tapavicza
发明人： Heinz Mueller , Claus-Peter Herold , Stephan Von Tapavicza
IPC分类号： C09K702
CPC分类号： C09K8/265 , C09K8/12 , C09K8/22
摘要： The invention relates to the use of linear and/or branched fatty alcohols containing at least 12 carbon atoms in the molecule and/or to the use of mixtures of such fatty alcohols with carboxylic acid esters as a lubricating additive in water-based drilling fluids for their use in geological exploration by drilling. The fatty-alcohol-based lubricants or lubricant systems are particularly suitable for use in water-based alkali metal silicate drilling muds which are known to be distinguished by comparatively high pH values. The additives according to the invention combine their lubricating effect with a foam-suppressing effect, i.e. prevent unwanted foaming.
摘要翻译：本发明涉及在分子中含有至少12个碳原子的直链和/或支链脂肪醇的用途和/或在水基钻井液中使用这种脂肪醇与羧酸酯作为润滑添加剂的混合物它们在钻探地质勘探中的应用。基于脂肪醇的润滑剂或润滑剂系统特别适用于已知通过较高pH值区分的水基碱金属硅酸盐钻井泥浆。根据本发明的添加剂将其润滑效果与泡沫抑制效果相结合，即防止不希望的起泡。

5. 发明授权

US06211119B1 Multiphase lubricant concentrates for use in water based systems in the field of exploratory soil drilling 失效
标题翻译：多相润滑剂浓缩物用于探索性土壤钻井领域的水基系统
公开(公告)号：US06211119B1
公开(公告)日：2001-04-03
申请号：US09308399
申请日：1999-06-01
申请人： Claus-Peter Herold , Heinz Mueller , Thomas Foerster , Stephan Von Tapavicza , Marcus Claas
发明人： Claus-Peter Herold , Heinz Mueller , Thomas Foerster , Stephan Von Tapavicza , Marcus Claas
IPC分类号： C09K702
CPC分类号： C10M173/00 , C09K8/26 , C09K8/36 , C10M2201/02 , C10M2203/00 , C10M2203/02 , C10M2203/022 , C10M2203/024 , C10M2203/04 , C10M2207/021 , C10M2207/022 , C10M2207/04 , C10M2207/046 , C10M2207/08 , C10M2207/126 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/287 , C10M2207/288 , C10M2207/289 , C10M2207/32 , C10M2209/102 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/107 , C10M2209/108 , C10M2209/109 , C10M2209/12 , C10M2211/00 , C10M2211/06 , C10M2215/00 , C10M2215/042 , C10M2215/062 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/10 , C10M2215/12 , C10M2215/122 , C10M2215/202 , C10M2215/28 , C10M2217/00 , C10M2217/02 , C10M2217/04 , C10M2217/044 , C10M2219/02 , C10M2219/022 , C10M2219/024 , C10M2223/02 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/049 , C10M2223/06 , C10M2223/061 , C10M2223/065 , C10M2223/10 , C10M2229/02 , C10M2229/04 , C10M2229/041 , C10M2229/042 , C10M2229/043 , C10M2229/044 , C10M2229/045 , C10M2229/046 , C10M2229/047 , C10M2229/048 , C10M2229/05 , C10M2229/051 , C10M2229/052 , C10M2229/053 , C10M2229/054 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2250/02 , C10N2270/02
摘要： The invention relates to multiphase lubricant concentrates with improved properties for use in aqueous fluids for geological exploration by drilling which contain organic lubricating components which are solid and/or liquid at room temperature (O phase) together with emulsifiers finely dispersed in a continuous aqueous phase (W phase). These concentrates are characterized in that the system of O phase/W phase and emulsifiers has a phase inversion temperature (PIT) above room temperature and has been produced by heating the multiphase system to temperatures equal to or above the PIT and subsequent cooling to temperatures below the PIT. The present invention also relates to the use of the multiphase lubricant concentrates as an additive in water-based fluids for use in geological exploration by drilling and for the subsequent treatment of the resulting boreholes.
摘要翻译：本发明涉及具有改进性能的多相润滑剂浓缩物，其用于通过钻井进行地质勘探的含水流体，其包含在室温（O相）下固体和/或液体的有机润滑组分以及细分散在连续水相中的乳化剂（ W相）。这些浓缩物的特征在于，O相/ W相和乳化剂的体系具有高于室温的相转化温度（PIT），并且通过将多相体系加热至等于或高于PIT的温度并随后冷却至低于 PIT。本发明还涉及多相润滑剂浓缩物作为添加剂在水基流体中的用途，用于通过钻孔进行地质勘探和随后处理所得到的钻孔。

6. 发明授权

US06946524B2 Methods for producing polyester amides based on polyisobutylenes, polyester amides produced thereby, and uses therefor in stabilizing crude oil 失效
标题翻译：基于聚异丁烯生产聚酯酰胺的方法，由此生产的聚酯酰胺，以及用于稳定原油的方法
公开(公告)号：US06946524B2
公开(公告)日：2005-09-20
申请号：US10363451
申请日：2001-08-29
申请人： Wolfgang Breuer , Paul Birnbrich , Claus-Peter Herold , Stephan Von Tapavicza , Didier Groffe , Matthias Hof
发明人： Wolfgang Breuer , Paul Birnbrich , Claus-Peter Herold , Stephan Von Tapavicza , Didier Groffe , Matthias Hof
IPC分类号： C08F8/32 , C08F255/00
CPC分类号： C08F8/32 , C08F8/46 , C08F110/10
摘要： Processes for producing polyester amides, by reacting a polyisobutylene with a first reagent selected from the group consisting of at least monounsaturated acids having from 3 to 21 carbon atoms and derivatives thereof; and a second reagent selected from the group consisting of monoethanolamine and alkylamines of the general formula R—NH2, wherein R represents an alkyl group having from 1 to 4 carbon atoms; are described. The polyester amides thus produced and their uses in stabilizing asphaltenes in crude oil and crude oil derivatives are also described.
摘要翻译：通过使聚异丁烯与选自至少具有3至21个碳原子的单不饱和酸及其衍生物的第一试剂反应制备聚酯酰胺的方法; 和选自单乙醇胺和通式为R-NH 2的烷基胺的第二试剂，其中R表示具有1至4个碳原子的烷基; 被描述。这样生产的聚酯酰胺及其在稳定原油和原油衍生物中沥青质的用途也被描述。

7. 发明申请

US20080171671A1 Use of Ethoxylated Amidoamines as Emulsifiers in Drilling Fluids 审中-公开
标题翻译：乙氧基化氨基胺在钻井液中的应用
公开(公告)号：US20080171671A1
公开(公告)日：2008-07-17
申请号：US10595083
申请日：2005-10-14
申请人： Heinz Mueller , Jens Hartmann , Stephan Von Tapavicza , Diana Maeker
发明人： Heinz Mueller , Jens Hartmann , Stephan Von Tapavicza , Diana Maeker
IPC分类号： C09K8/04 , C07C229/02
CPC分类号： C09K8/36
摘要： The invention relates to the use of ethoxylated derivatives of amidoamines corresponding to general formula (I): R1—OC—NR2—[(CH2)n—NR3]m—CO—R4 (I) In which R1, R2, R3 and R4 independently of one another represent a hydrogen atom, a branched or unbranched alkyl or alkenyl group containing 5 to 23 carbon atoms or a CO—CH=CH—COOH group and n is a number of 1 to 6 and m is a number of 1 to 8,as an emulsifier in drilling fluids which contain at least one continuous oil phase, an aqueous phase and typical additives.
摘要翻译：本发明涉及对应于通式（I）的氨基胺的乙氧基化衍生物的用途：<？在线公式描述=“在线公式”end =“lead”→R＆lt; 1＆ -OC-NR 2 - [（CH 2）n - ） - - - - - （CH 2）n - SUB-CO-R 4（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 1〜 R 2，R 3和R 4彼此独立地表示氢原子，支链或非支链烷基或烯基，其含有5〜 23个碳原子或CO-CH = CH-COOH基，n为1〜6的数，m为1〜8的数，作为含有至少一个连续油相的水相中的乳化剂，水相和典型的添加剂。

8. 发明申请

US20070142234A1 Borehole treatment agent containing low-toxic oil phase 有权
标题翻译：钻孔处理剂含有低毒油相
公开(公告)号：US20070142234A1
公开(公告)日：2007-06-21
申请号：US10527212
申请日：2003-09-09
申请人： Heinz Mueller , Nadja Herzog , Stephan Von Tapavicza
发明人： Heinz Mueller , Nadja Herzog , Stephan Von Tapavicza
IPC分类号： C09K8/58
CPC分类号： C09K8/34 , C09K8/36 , Y10S507/905
摘要： The invention relates to a borehole treatment composition containing an aqueous phase and a non-aqueous oil phase, emulsifiers and, where appropriate, further customary additives, the non-aqueous oil phase containing at least one of a) paraffins having from 5 to 22 carbon atoms; and b) internal olefins having from 12 to 30 carbon atoms in the molecule; in the form of a blend with c) carboxylic esters of the formula R—COO—R′, where R stands for a linear or branched, saturated or unsaturated alkyl radical having from 15 to 25 carbon atoms and R′ denotes a saturated, linear or branched alkyl radical having from 3 to 22 carbon atoms. The ratio of the toxicity of internal olefins of chain length C16/C18 (standard IO) to the toxicity of the constituents of the non-aqueous oil phase, in each case measured by the Leptocheirus plumulosus acute, static 96 hour/10 day sediment toxicity test (in accordance with ASTM E 1367-92 & EPA/600/R-94/025, Section 11), is less than 1.
摘要翻译：本发明涉及一种含有水相和非水性油相的乳
液处理组合物，乳化剂和适当的进一步常规添加剂，所述非水性油相含有a）至少一种具有5-22个碳原子的链烷烃原子和b）分子中具有12至30个碳原子的内烯烃; 与c）式R-COO-R'的羧酸酯的形式，其中R代表具有15至25个碳原子的直链或支链，饱和或不饱和的烷基，R'表示饱和的，直链的或具有3至22个碳原子的支链烷基。链长C16 / C18（标准IO）的内烯烃的毒性与非水性油相的成分的毒性的比例，在每种情况下由Leptocheirus plumulosus急性，静态96小时/ 10天的沉淀物毒性测定测试（根据ASTM E 1367-92和EPA / 600 / R-94/025，第11节）小于1。

9. 发明授权

US07666820B2 Borehole treatment agent containing low-toxic oil phase 有权
标题翻译：钻孔处理剂含有低毒油相
公开(公告)号：US07666820B2
公开(公告)日：2010-02-23
申请号：US10527212
申请日：2003-09-09
申请人： Heinz Mueller , Nadja Herzog , Stephan Von Tapavicza
发明人： Heinz Mueller , Nadja Herzog , Stephan Von Tapavicza
IPC分类号： C09K8/36 , E21B21/00
CPC分类号： C09K8/34 , C09K8/36 , Y10S507/905
摘要： The invention relates to a borehole treatment composition containing an aqueous phase and a non-aqueous oil phase, emulsifiers and, where appropriate, further customary additives, the non-aqueous oil phase containing at least one of a) paraffins having from 5 to 22 carbon atoms; and b) internal olefins having from 12 to 30 carbon atoms in the molecule; in the form of a blend with c) carboxylic esters of the formula R—COO—R′, where R stands for a linear or branched, saturated or unsaturated alkyl radical having from 15 to 25 carbon atoms and R′ denotes a saturated, linear or branched alkyl radical having from 3 to 22 carbon atoms. The ratio of the toxicity of internal olefins of chain length C16/C18 (standard IO) to the toxicity of the constituents of the non-aqueous oil phase, in each case measured by the Leptocheirus plumulosus acute, static 96 hour/10 day sediment toxicity test (in accordance with ASTM E 1367-92 & EPA/600/R-94/025, Section 11), is less than 1.
摘要翻译：本发明涉及一种含有水相和非水性油相的乳
液处理组合物，乳化剂以及适当的进一步的常规添加剂，所述非水性油相含有a）至少一种具有5-22个碳原子的链烷烃原子和b）分子中具有12至30个碳原子的内烯烃; 与c）式R-COO-R'的羧酸酯的形式，其中R代表具有15至25个碳原子的直链或支链，饱和或不饱和的烷基，R'表示饱和的，直链的或具有3至22个碳原子的支链烷基。链长C16 / C18（标准IO）的内烯烃的毒性与非水性油相的成分的毒性的比例，在每种情况下由Leptocheirus plumulosus急性，静态96小时/ 10天的沉淀物毒性测定测试（根据ASTM E 1367-92和EPA / 600 / R-94/025，第11节）小于1。

10. 发明授权

US06566304B1 Biogenic control and limitation of the reproduction of parasitic earth nematodes in stock culture 失效
标题翻译：生物控制和限制寄生的地球线虫在库存培养中的繁殖
公开(公告)号：US06566304B1
公开(公告)日：2003-05-20
申请号：US09701599
申请日：2001-02-06
申请人： Doris Bell , Bettina Kopp-Holtwiesche , Stephan Von Tapavicza
发明人： Doris Bell , Bettina Kopp-Holtwiesche , Stephan Von Tapavicza
IPC分类号： A01N4728
CPC分类号： C05G3/06 , A47B2200/0023 , C05B15/00 , Y10S71/903 , C05C9/00
摘要： The invention relates to use of (a) compounds of phosphorus containing at least partly lipophilic organic radicals together with (b) urea and/or urea derivatives in selected quantity ratios of (a) to (b) as a soil additive for biologically controlling plant-parasitic soil nematodes by strengthening the correspondingly antagonistic soil potential, more particularly by strengthening the growth of antagonistic and/or nematicidal rhizosphere bacteria and/or corresponding mycorrhiza strains—and at the same time strengthening the growth of cultivated plants in soil. The multicomponent mixtures which strengthen bacterial growth are preferably introduced into the region of the plant roots in the form of an aqueous preparation using plant-compatible emulsifiers before and/or during plant growth. Components (a) and (b) are used in such quantity ratios that the ratio by weight of C to N is no higher than 6:1 and preferably no higher than 5:1.
摘要翻译：本发明涉及（a）含有至少部分亲脂性有机基团的磷化合物与（b）选择量比例的（a）至（b）的脲和/或脲衍生物的化合物作为生物控制植物的土壤添加剂通过加强对应的土壤潜力，特别是通过加强拮抗和/或杀线虫根际细菌和/或相应的菌根菌株的生长，同时加强土壤中栽培植物的生长，从而增强土壤线虫。加强细菌生长的多组分混合物优选在植物生长之前和/或植物生长期间以植物相容的乳化剂以水性制剂的形式引入植物根的区域。组分（a）和（b）以这样的数量比例使用，即C与N的重量比不高于6:1，优选不高于5:1。

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