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    • 1. 发明授权
    • Donor-substituted oxindigo derivatives and their use as colorants
    • 供体取代的oxindigo衍生物及其作为着色剂的用途
    • US6156914A
    • 2000-12-05
    • US155734
    • 1998-10-05
    • Heinz LanghalsBarbara Wagner
    • Heinz LanghalsBarbara Wagner
    • G03G9/09B41M5/00C07C215/76C07C217/84C09B7/00C07D307/02
    • C09B7/00
    • Oxindigo derivative (1 and 2) in which four to seven of the radicals shown are hydrogen and one to four of these radicals are a radical chosen from the group consisting of a carbocyclic radical, a heterocyclic radical, halogen, C.sub.1 -C.sub.18 alkyl, --OR.sup.12, --CN, --NR.sup.10 R.sup.11, --COR.sup.9, --NR.sup.13 COR.sup.9, --NR.sup.12 COOR.sup.9, --NR.sup.12 CONR.sup.10 R.sup.11, --NHSO.sub.2 R.sup.9, --SO.sub.2 R.sup.9, --SOR.sup.9, --SO.sub.2 OR.sup.9, --CONR.sup.10 R.sup.11, --SO.sub.2 NR.sup.10 R.sup.11, --N.dbd.NR.sup.14, --OCOR.sup.9 and --OCONHR.sup.9, wherein two corresponding adjacent radicals can be combined to build up fused-on aromatic rings, in which R.sup.9 is C.sub.1 -C.sub.18 alkyl, C.sub.6 -C.sub.10 aryl, benzyl or a heterocyclic radical, R.sup.10 and R.sup.11 are hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.3 - to C.sub.24 cycloalkyl, C.sub.6 -C.sub.10 aryl or heteroaryl or in which R.sup.10 and R.sup.11, together with in each case one of the other radicals R.sub.2 to R.sub.4, form a ring, R.sup.12 is hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.3 - to C.sub.24 cycloalkyl, C.sub.6 -C.sub.10 aryl or a heteroaryl, R.sup.13 is hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.3 - to C.sub.24 cycloalkyl, C.sub.1 -C.sub.4 alkylaryl, C.sub.6 -C.sub.10 aryl or a heterocyclic radical and R.sup.14 is the radical of a coupling component or C.sub.6 -C.sub.10 aryl, and a process for their preparation, their use and intermediates.
    • PCT No.PCT / EP97 / 01915 Sec。 371日期:1998年10月5日 102(e)日期1998年10月5日PCT 1996年4月25日PCT公布。 出版物WO97 / 41176 日期:1997年11月6日靛蓝衍生物(1和2),其中4至7个所示的基团是氢,并且这些基团中的一个至四个是选自碳环基团,杂环基团,卤素,C 1 -C18烷基,-OR12,-CN,-NR10R11,-COR9,-NR13COR9,-NR12COOR9,-NR12CONR10R11,-NHSO2R9,-SO2R9,-SOR9,-SO2OR9,-CONR10R11,-SO2NR10R11,-N = NR14,-OCOR9和 -OCONHR9,其中可以组合两个相应的相邻基团以形成稠合的芳环,其中R9是C1-C18烷基,C6-C10芳基,苄基或杂环基,R10和R11是氢,C1-C18烷基,C3- C 12 -C 10芳基或杂芳基,或其中R 10和R 11连同其它基团R 2至R 4一起形成环,R 12为氢,C 1 -C 18烷基,C 3至C 24环烷基,C 6 -C 10芳基或 杂芳基,R 13是氢,C 1 -C 18烷基,C 3至C 24环烷基,C 1 -C 4烷基芳基,C 6 -C 10芳基或杂环基,R 14是偶合基团的基团 或C 6 -C 10芳基,以及它们的制备方法及其用途和中间体。
    • 9. 发明授权
    • Method for producing thermally cleavable, soluble pigment derivatives
    • 用于生产可热切割的可溶性颜料衍生物的方法
    • US06365720B1
    • 2002-04-02
    • US09868679
    • 2001-06-20
    • Hans-Thomas SchachtRamaswami SreenivasanMudaliar Dayal ChandrasekharGilbert MoegleBarbara WagnerCharles Edward Monnier
    • Hans-Thomas SchachtRamaswami SreenivasanMudaliar Dayal ChandrasekharGilbert MoegleBarbara WagnerCharles Edward Monnier
    • C09B6720
    • C09D11/32C09B47/24C09B47/26C09D7/41G03F7/0007G03F7/029
    • The invention relates to a method for preparing a compound of the formula A(D)x(E)y (I) by reaction of a compound of the formula A(H)x(H)y with a pyrocarbonic acid diester of the formula wherein x and y are each independently of the other an integer from 0 to 6, but x and y are not simultaneously the number 0, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, indanthrone, isoindolinone, isoindoline, dioxazine, azo, phthalocyanine or diketopyrrolopyrrole series, which radical is bonded via one or more nitrogen atoms to x groups D and via one or more oxygen atoms to y groups E, the nitrogen atoms and oxygen atoms forming part of the radical A, each group D or E independently of any other(s) is hydrogen or a group of the formula wherein at least one group D or E is not hydrogen, and L is any desired group suitable solubilization, in the presence of a base as catalyst, in which method the reaction takes place in an aromatic or heteroaromatic solvent selected from diphenyl, pyridine, quinoline, pyrrole and benzene unsubstituted or mono- to tri-substituted by C1-C6alkyl, phenyl, benzyl, C1-C6-alkoxy, phenoxy, C1-C24alkylthio, halogen and/or by nitro, and any desired mixtures thereof. By the use of an aromatic solvent, monoazo, bisazo and phthalocyanine pigments in particular are solubilized with surprisingly better results. Both the yield and the purity are markedly higher than in the solvents known hitherto, and more solubilizing groups can be incorporated into the pigment. The method according to the invention is advantageously especially suitable also for the production of latent pigments in relatively large amounts.
    • 本发明涉及通过将式A(H)x(H)y的化合物与式(A)(E)y(I)的化合物与制备方法的热解碳酸二酯反应制备式 和y各自独立地为0至6的整数,但x和y不同时为数字0,A是喹吖啶酮,蒽醌,苝,靛蓝,喹酞酮,阴丹酮,异吲哚啉酮,异吲哚啉的发色团的基团 ,二恶嗪,偶氮,酞菁或二酮吡咯并吡咯系列,该基团通过一个或多个氮原子键合到x基团D上,并且经由一个或多个氧原子结合到基团E,形成基团A的一部分的氮原子和氧原子 独立于任何其它的基团D或E是氢或至少一个D或E基团不是氢的氢或一组基团,L是在作为催化剂的碱存在下适合溶解的任何所需基团,其中 方法是在芳族或杂芳族化合物中发生反应 苯基,苄基,C 1 -C 6烷氧基,苯氧基,C 1 -C 24烷硫基,卤素和/或硝基被单取代或被三取代的苯基,以及任何 通过使用芳族溶剂,特别是单偶氮,双偶氮和酞菁颜料可溶解,效果更好。 产率和纯度均明显高于迄今为止已知的溶剂,并且可以将更多的增溶基团并入颜料中。 根据本发明的方法有利地特别适用于相对大量生产潜在颜料。
    • 10. 发明授权
    • Multi-roller beach chair
    • 多辊沙滩椅
    • US5913572A
    • 1999-06-22
    • US146910
    • 1998-09-04
    • Camille M. GrimaldiJanice MoschettaBarbara Wagner
    • Camille M. GrimaldiJanice MoschettaBarbara Wagner
    • A47C1/14A47C7/02
    • A47C1/143B62B2202/52B62B2301/254
    • A beach chair having multiple rollers is provided which is electrically insulated and that is quiet when rolled upon a hard surface. The frame of the beach chair is curved to fit the curves of the human body so that the weight is evenly distributed over the whole body surface. Thus, edema due to excessive pressure on small body surface areas is eliminated. The open, hollow construction of both the frame and the rollers allows water to enter and exit easily. In this way the chair remains stable and does not float away with wave action. The mulitple, independent rollers allow this lightweight beach chair to turn easily while gripping the sand so that it does not slide sideways. This beach chair rolls easily allowing it to be useful in transporting heavy items over long distances effortlessly over sand, gravel, or pavement without noise.
    • 提供具有多个滚轮的沙滩椅,其电绝缘并且在硬表面上滚动时是安静的。 沙滩椅的框架是弯曲的,以适应人体的曲线,使重量均匀分布在整个身体表面。 因此,消除了由于小体表面积上的过度压力引起的水肿。 框架和滚筒的开放式中空结构允许水容易进出。 以这种方式,椅子保持稳定,并且不会随波浪作用而浮起。 多重独立的滚筒允许这个轻质的沙滩椅轻松转动,同时抓住沙子,使其不会侧滑。 这个沙滩椅很容易滚动,可以很方便地在长时间运输重物,轻松地在沙尘,砾石或路面上无噪音地运送。