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1. 发明申请

US20110092356A1 CATALYTIC STRUCTURES INCLUDING CATALYST MATERIALS IN POROUS ZEOLITE MATERIALS, AND METHODS OF FORMING SAME 审中-公开
标题翻译：包含多孔沸石材料中催化材料的催化结构及其形成方法
公开(公告)号：US20110092356A1
公开(公告)日：2011-04-21
申请号：US12970643
申请日：2010-12-16
申请人： Harry W. Rollins , Lucia Petkovic , Daniel M. Ginosar
发明人： Harry W. Rollins , Lucia Petkovic , Daniel M. Ginosar
IPC分类号： B01J29/04 , B01J29/08 , B01J29/18 , B01J29/70 , B01J29/83 , B01J29/85 , B01J29/40 , B01J37/02 , B82Y30/00
CPC分类号： B01J29/061 , B01J29/005 , B01J29/035 , B01J29/041 , B01J29/072 , B01J29/40 , B01J29/46 , B01J29/80 , B01J37/0018 , C07C1/20 , C07C2529/46 , C07C2529/84 , C07C2529/85 , C10G3/45 , C10G3/47 , C10G3/49 , C10G3/50 , C10G2400/20 , C10G2400/22 , Y02P30/40 , C07C11/02
摘要： Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.
摘要翻译：催化结构包括设置在沸石材料内的催化材料。催化材料可能能够催化从一氧化碳和/或二氧化碳形成甲醇，并且沸石材料可以能够催化甲醇形成烃分子。催化材料可以包括铜和氧化锌。沸石材料可以包括基本上由沸石材料的晶体结构限定的第一多个孔和分散在整个沸石材料中的第二多个孔。合成烃分子的系统还包括催化结构。合成烃分子的方法包括使氢和一氧化碳和二氧化碳中的至少一种与这种催化结构接触。催化结构通过至少部分地围绕模板结构形成沸石材料，去除模板结构以及将催化材料引入到沸石材料中来制造。

2. 发明授权

US07592282B2 Enhancement of alkylation catalysts for improved supercritical fluid regeneration 有权
标题翻译：用于改进超临界流体再生的烷基化催化剂的增强
公开(公告)号：US07592282B2
公开(公告)日：2009-09-22
申请号：US10986742
申请日：2004-11-11
申请人： Daniel M. Ginosar , Lucia Petkovic
发明人： Daniel M. Ginosar , Lucia Petkovic
IPC分类号： B01J38/48 , B01J38/64 , B01J38/66 , B01J38/02 , B01J21/20 , B01J23/90 , B01J25/04
CPC分类号： C07C2/66 , B01J29/084 , B01J29/18 , B01J29/60 , B01J29/7007 , B01J35/023 , B01J37/009 , B01J2229/10 , B01J2229/38 , Y02P20/544
摘要： A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.
摘要翻译：一种改性烷基化催化剂以减少其上的稠合烃物质形成的方法。该方法包括提供包含多个活性位点的烷基化催化剂。烷基化催化剂上的多个活性位点可以包括多个弱酸性活性位点，中间酸性活性位点和强酸性活性位点。碱被吸附到多个活性位点的一部分，例如强酸性活性位点，选择性地中毒强酸性活性位点。还公开了通过提供烷基化催化剂来改性烷基化催化剂的方法，所述烷基化催化剂包含空间上约束烷基化催化剂上的稠合烃物质的形成的孔径分布，或通过合成烷基化催化剂以包含减少数量的强酸性活性位点，以及提高烷基化催化剂的再生效率的方法也是如此。

3. 发明授权

US07592291B2 Method of fabricating a catalytic structure 有权
标题翻译：制造催化结构的方法
公开(公告)号：US07592291B2
公开(公告)日：2009-09-22
申请号：US11688930
申请日：2007-03-21
申请人： Harry W. Rollins , Lucia M. Petkovic , Daniel M. Ginosar
发明人： Harry W. Rollins , Lucia M. Petkovic , Daniel M. Ginosar
IPC分类号： B01J23/06 , B01J23/72 , B01J35/08
CPC分类号： B01J29/005 , B01J29/035 , B01J29/041 , B01J29/061 , B01J29/072 , B01J29/40 , B01J29/46 , B01J29/80 , B01J37/0018 , C07C1/20 , C07C2529/46 , C07C2529/84 , C07C2529/85 , C10G2/33 , C07C11/02
摘要： A precursor to a catalytic structure comprising zinc oxide and copper oxide. The zinc oxide has a sheet-like morphology or a spherical morphology and the copper oxide comprises particles of copper oxide. The copper oxide is reduced to copper, producing the catalytic structure. The catalytic structure is fabricated by a hydrothermal process. A reaction mixture comprising a zinc salt, a copper salt, a hydroxyl ion source, and a structure-directing agent is formed. The reaction mixture is heated under confined volume conditions to produce the precursor. The copper oxide in the precursor is reduced to copper. A method of hydrogenating a carbon oxide using the catalytic structure is also disclosed, as is a system that includes the catalytic structure.
摘要翻译：包含氧化锌和氧化铜的催化结构的前体。氧化锌具有片状形态或球形形态，氧化铜包含氧化铜颗粒。氧化铜被还原成铜，产生催化结构。催化结构通过水热法制备。形成包含锌盐，铜盐，羟基离子源和结构导向剂的反应混合物。将反应混合物在有限体积条件下加热以产生前体。前体中的氧化铜还原成铜。还公开了使用催化结构使碳氧化物氢化的方法，以及包括催化结构的体系。

4. 发明申请

US20080045403A1 STRUCTURES INCLUDING CATALYTIC MATERIALS DISPOSED WITHIN POROUS ZEOLITE MATERIALS, SYSTEMS AND METHODS FOR USING THE SAME, AND METHODS OF FABRICATING CATALYTIC STRUCTURES 有权
标题翻译：包括在多孔沸石材料，系统和使用它们的方法中处理的催化材料的结构以及制备催化结构的方法
公开(公告)号：US20080045403A1
公开(公告)日：2008-02-21
申请号：US11464566
申请日：2006-08-15
申请人： Harry W. Rollins , Lucia M. Petkovic , Daniel M. Ginosar
发明人： Harry W. Rollins , Lucia M. Petkovic , Daniel M. Ginosar
IPC分类号： B01J29/04 , C01B39/00
CPC分类号： B01J29/061 , B01J29/005 , B01J29/035 , B01J29/041 , B01J29/072 , B01J29/40 , B01J29/46 , B01J29/80 , B01J37/0018 , C07C1/20 , C07C2529/46 , C07C2529/84 , C07C2529/85 , C10G3/45 , C10G3/47 , C10G3/49 , C10G3/50 , C10G2400/20 , C10G2400/22 , Y02P30/40 , C07C11/02
摘要： Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing the formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing the formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by the crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.
摘要翻译：催化结构包括设置在沸石材料内的催化材料。催化材料可能能够催化从一氧化碳和/或二氧化碳形成甲醇，并且沸石材料可以能够催化甲醇形成烃分子。催化材料可以包括铜和氧化锌。沸石材料可以包括基本上由沸石材料的晶体结构限定的第一多个孔和分散在整个沸石材料中的第二多个孔。合成烃分子的系统还包括催化结构。合成烃分子的方法包括使氢和一氧化碳和二氧化碳中的至少一种与这种催化结构接触。催化结构通过至少部分地围绕模板结构形成沸石材料，去除模板结构以及将催化材料引入到沸石材料中来制造。

5. 发明申请

US20080045400A1 PRECURSOR OF A CATALYTIC STRUCTURE, A CATALYTIC STRUCTURE, A METHOD OF FABRICATING THE SAME, AND A SYSTEM AND A METHOD FOR USING THE SAME 有权
标题翻译：催化结构的前体，催化结构，其制造方法和系统及其使用方法
公开(公告)号：US20080045400A1
公开(公告)日：2008-02-21
申请号：US11688930
申请日：2007-03-21
申请人： Harry W. Rollins , Lucia M. Petkovic , Daniel M. Ginosar
发明人： Harry W. Rollins , Lucia M. Petkovic , Daniel M. Ginosar
IPC分类号： B01J35/08 , B01J23/06 , B01J23/72
CPC分类号： B01J29/005 , B01J29/035 , B01J29/041 , B01J29/061 , B01J29/072 , B01J29/40 , B01J29/46 , B01J29/80 , B01J37/0018 , C07C1/20 , C07C2529/46 , C07C2529/84 , C07C2529/85 , C10G2/33 , C07C11/02
摘要： A precursor to a catalytic structure comprising zinc oxide and copper oxide. The zinc oxide has a sheet-like morphology or a spherical morphology and the copper oxide comprises particles of copper oxide. The copper oxide is reduced to copper, producing the catalytic structure. The catalytic structure is fabricated by a hydrothermal process. A reaction mixture comprising a zinc salt, a copper salt, a hydroxyl ion source, and a structure-directing agent is formed. The reaction mixture is heated under confined volume conditions to produce the precursor. The copper oxide in the precursor is reduced to copper. A method of hydrogenating a carbon oxide using the catalytic structure is also disclosed, as is a system that includes the catalytic structure.
摘要翻译：包含氧化锌和氧化铜的催化结构的前体。氧化锌具有片状形态或球形形态，氧化铜包含氧化铜颗粒。氧化铜被还原成铜，产生催化结构。催化结构通过水热法制备。形成包含锌盐，铜盐，羟基离子源和结构导向剂的反应混合物。将反应混合物在有限体积条件下加热以产生前体。前体中的氧化铜还原成铜。还公开了使用催化结构使碳氧化物氢化的方法，以及包括催化结构的体系。

6. 发明授权

US07879749B2 Methods of using structures including catalytic materials disposed within porous zeolite materials to synthesize hydrocarbons 有权
标题翻译：使用包括设置在多孔沸石材料内的催化材料的结构来合成烃的方法
公开(公告)号：US07879749B2
公开(公告)日：2011-02-01
申请号：US11464566
申请日：2006-08-15
申请人： Harry W. Rollins , Lucia M. Petkovic , Daniel M. Ginosar
发明人： Harry W. Rollins , Lucia M. Petkovic , Daniel M. Ginosar
IPC分类号： B01J29/04 , C01B39/00
CPC分类号： B01J29/061 , B01J29/005 , B01J29/035 , B01J29/041 , B01J29/072 , B01J29/40 , B01J29/46 , B01J29/80 , B01J37/0018 , C07C1/20 , C07C2529/46 , C07C2529/84 , C07C2529/85 , C10G3/45 , C10G3/47 , C10G3/49 , C10G3/50 , C10G2400/20 , C10G2400/22 , Y02P30/40 , C07C11/02
摘要： Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.
摘要翻译：催化结构包括设置在沸石材料内的催化材料。催化材料可能能够催化从一氧化碳和/或二氧化碳形成甲醇，并且沸石材料可以能够催化甲醇形成烃分子。催化材料可以包括铜和氧化锌。沸石材料可以包括基本上由沸石材料的晶体结构限定的第一多个孔和分散在整个沸石材料中的第二多个孔。合成烃分子的系统还包括催化结构。合成烃分子的方法包括使氢和一氧化碳和二氧化碳中的至少一种与这种催化结构接触。催化结构通过至少部分地围绕模板结构形成沸石材料，去除模板结构以及将催化材料引入到沸石材料中来制造。

7. 发明授权

US07718051B2 Conversion of crop seed oils to jet fuel and associated methods 失效
标题翻译：将作物种子油转化为喷气燃料和相关方法
公开(公告)号：US07718051B2
公开(公告)日：2010-05-18
申请号：US11856607
申请日：2007-09-17
申请人： Daniel M. Ginosar , Lucia M. Petkovic , David N. Thompson
发明人： Daniel M. Ginosar , Lucia M. Petkovic , David N. Thompson
IPC分类号： C10G47/00
CPC分类号： C10G3/46 , C10G3/49 , C10G3/52 , C10G2300/1014 , C10G2300/1018 , C10G2300/42 , C10G2400/08 , Y02P30/20
摘要： Aspects of the invention include methods to produce jet fuel from biological oil sources. The method may be comprised of two steps: hydrocracking and reforming. The process may be self-sufficient in heat and hydrogen.
摘要翻译：本发明的方面包括从生物油源产生喷气燃料的方法。该方法可以包括两个步骤：加氢裂化和重整。该方法在热和氢中可能是自给自足的。

8. 发明申请

US20080267835A1 SYSTEM FOR REACTIVATING CATALYSTS 有权
标题翻译：反应催化剂体系
公开(公告)号：US20080267835A1
公开(公告)日：2008-10-30
申请号：US12165301
申请日：2008-06-30
申请人： Daniel M. Ginosar , David N. Thompson , Raymond P. Anderson
发明人： Daniel M. Ginosar , David N. Thompson , Raymond P. Anderson
IPC分类号： B01J8/18
CPC分类号： B01J38/56 , B01J2038/005
摘要： A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst is provided. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.
摘要翻译：提供了重新催化剂如固体催化剂或液体催化剂的方法。该方法包括提供至少部分由结垢剂去活化的催化剂。催化剂与处于流体还原剂的临界点以上的流体还原剂接触并且具有足够的密度以溶解杂质。流体再活化剂与至少一种结垢剂反应，从催化剂中释放至少一种结垢剂。至少一种结垢剂溶解在流体再活化剂中，随后从流体再活化剂中分离或除去，使得流体再生剂可以重复使用。还公开了还原催化剂的系统。

9. 发明授权

US07241340B2 System configured for applying a modifying agent to a non-equidimensional substrate 失效
标题翻译：被配置用于将改性剂施加到非等尺寸底物上的系统
公开(公告)号：US07241340B2
公开(公告)日：2007-07-10
申请号：US10627530
申请日：2003-07-24
申请人： Stuart K. Janikowski , Mark D. Argyle , Robert V. Fox , W. Alan Propp , William J. Toth , Daniel M. Ginosar , Charles A. Allen , David L. Miller
发明人： Stuart K. Janikowski , Mark D. Argyle , Robert V. Fox , W. Alan Propp , William J. Toth , Daniel M. Ginosar , Charles A. Allen , David L. Miller
IPC分类号： B05C11/00
CPC分类号： D06M23/105 , B05D1/18 , B05D7/20 , B05D2252/02 , B05D2252/10 , B05D2401/90 , C03C25/12 , C03C25/22
摘要： The present invention is related to systems and methods for modifying various non-equidimensional substrates with modifying agents. The system comprises a processing chamber configured for passing the non-equidimensional substrate therethrough, wherein the processing chamber is further configured to accept a treatment mixture into the chamber during movement of the non-equidimensional substrate through the processing chamber. The treatment mixture can comprise of the modifying agent in a carrier medium, wherein the carrier medium is selected from the group consisting of a supercritical fluid, a near-critical fluid, a superheated fluid, a superheated liquid, and a liquefied gas. Thus, the modifying agent can be applied to the non-equidimensional substrate upon contact between the treatment mixture and the non-equidimensional substrate.
摘要翻译：本发明涉及用修饰剂修饰各种非等维底物的系统和方法。该系统包括被配置用于使非等量基底通过其中的处理室，其中处理室还被配置成在非等量基底通过处理室运动期间接受处理混合物进入腔室。处理混合物可以在载体介质中包含改性剂，其中载体介质选自超临界流体，近临界流体，过热流体，过热液体和液化气体。因此，在处理混合物和非等尺寸底物之间接触时，改性剂可以施加到非等维基底上。

10. 发明授权

US08308954B2 Methods for recovering a polar solvent from a fluid stream contaminated with at least one polar impurity 有权
标题翻译：从被至少一种极性杂质污染的流体流中回收极性溶剂的方法
公开(公告)号：US08308954B2
公开(公告)日：2012-11-13
申请号：US12238225
申请日：2008-09-25
申请人： Daniel M. Ginosar , Daniel S. Wendt
发明人： Daniel M. Ginosar , Daniel S. Wendt
IPC分类号： B01D11/00
CPC分类号： C11B7/0025 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , Y02P30/20
摘要： A method of removing a polar solvent from a fluid volume contaminated with at least one polar impurity, such as a free fatty acid, is provided. The method comprises providing a fluid volume that includes at least one polar impurity dissolved in at least one solvent. The fluid volume is contacted with an expanding gas to remove the at least one solvent. The expanding gas may be dissolved into the at least one solvent in the fluid volume to form a gas-expanded solvent. The immiscibility of the polar impurities in the gas-expanded solvent enables separation of the polar impurities from the gas-expanded solvent. After separation of the polar impurities, at least one of the temperature and pressure may be reduced to separate the solvent from the expanding gas such that the clean solvent may be reused.
摘要翻译：提供了从由至少一种极性杂质污染的流体体积如游离脂肪酸中除去极性溶剂的方法。该方法包括提供包含溶解在至少一种溶剂中的至少一种极性杂质的流体体积。流体体积与膨胀气体接触以除去至少一种溶剂。膨胀气体可以溶解在流体体积中的至少一种溶剂中以形成气体膨胀溶剂。气体膨胀溶剂中的极性杂质的不混溶性使得能够从气体膨胀溶剂中分离极性杂质。在分离极性杂质之后，可以降低温度和压力中的至少一个以使溶剂与膨胀气体分离，使得清洁溶剂可以重复使用。

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