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    • 7. 发明授权
    • Fine-particulate alkali metal aluminosilicates in the process of washing
and cleaning rawhides and fur skins
    • 细粒状碱金属铝硅酸盐在洗涤和清洁生皮和毛皮的过程中
    • US4210416A
    • 1980-07-01
    • US903597
    • 1978-05-08
    • Juergen PlapperMilan J. SchwugerHeinz G. SmolkaKlaus SchumannEmanuel ArndtEmil Ruscheinsky
    • Juergen PlapperMilan J. SchwugerHeinz G. SmolkaKlaus SchumannEmanuel ArndtEmil Ruscheinsky
    • C11D3/00C11D3/12C14C1/00C14C1/02D06L1/12D01C3/00
    • D06L1/12C11D3/0031C11D3/1246C11D3/128C14C1/00C14C1/02
    • In the process of washing and cleaning rawhides and fur skins before tanning comprising subjecting rawhides and fur skins to the action of an aqueous solution containing (1) surface-active compounds selected from the group consisting of anionic surface-active compounds, nonionic surface-active compounds and mixtures thereof, (2) emulsifiable solvents for fats and (3) electrolytes, removing said aqueous solution, rinsing, and recovering washed and cleaned rawhides and fur skins, the improvement consisting essentially of employing a fine-particulate, water-insoluble alkali metal aluminosilicate, containing bound water, of the formula(M.sub.2 O).sub.x.Al.sub.2 O.sub.3.(SiO.sub.2).sub.ywherein M represents an alkali metal, x is an integer from 0.7 to 1.5 and y is an integer from 0.8 to 6, said aluminosilicates having an average particle size in the range of from 0.1 to 25.mu. and a calcium binding power of from 20 to 200 mg CaO/gm of anhydrous active substance measured at 22.degree. C. according to the Calcium Binding Power Test Method set out in the specification, as partial or total replacement of said electrolyte and optionally partial replacement of said surface-active compounds, whereby the pH of said aqueous solution is maintained between 6.5 and 8.5.
    • 在鞣制前洗涤和清洁生皮和毛皮的过程包括使生皮和毛皮受到含有(1)选自阴离子表面活性化合物,非离子表面活性化合物的表面活性化合物的水溶液的作用 化合物及其混合物,(2)脂肪的乳化溶剂和(3)电解质,去除所述水溶液,漂洗和回收洗涤和清洁的生皮和皮毛皮,改进主要包括使用细颗粒的水不溶性碱 含有结合水的金属硅铝酸盐,其具有式(M 2 O)x.Al 2 O 3(SiO 2)y,其中M表示碱金属,x是0.7至1.5的整数,y是0.8至6的整数,所述铝硅酸盐具有 根据钙结合力,平均粒度在0.1至25μm的范围内,钙结合力为20至200mg CaO / gm的无水活性物质在22℃下测量 在本说明书中列出的测试方法,作为部分或全部替代所述电解质和任选地部分替代所述表面活性化合物,由此所述水溶液的pH保持在6.5至8.5之间。
    • 9. 发明授权
    • Water-insoluble aluminosilicates in the manufacture of leather
    • 水不溶性铝硅酸盐在制造皮革
    • US4264319A
    • 1981-04-28
    • US56355
    • 1979-07-10
    • Juergen PlapperKlaus SchumannEmanuel ArndtEmil Ruscheinsky
    • Juergen PlapperKlaus SchumannEmanuel ArndtEmil Ruscheinsky
    • C14C3/02C14C3/06C14C3/04C14C3/08C14C3/22
    • C14C3/06C14C3/02
    • In an improved process of tanning for the production of leather comprising subjecting pickled uncured hides to the action of an aqueous liquor containing (1) chemical tanning or pretanning agents and (2) auxiliary chemicals to tanning and recovering leather, the improvement consisting essentially of employing (i) a water-insoluble aluminosilicate, containing bound water, of the formula(Cat.sub.2/n O).sub.x.Al.sub.2 O.sub.3.(SiO.sub.2).sub.ywherein Cat represents a cation selected from the group consisting of alkali metals, bivalent metal ions, trivalent metal ions, and mixtures thereof; n represents an integer of from 1 to 3; x is a number of from 0.5 to 1.8; and y is a number of from 0.8 to 50, said aluminosilicates having an average particle size in the range of from about 0.1.mu. to 5 mm and a calcium binding power of from about 0 to 200 mg CaO/gm of anhydrous active substance measured at 22.degree. C. according to the Calcium Binding Power Test Method, and (ii) carboxylic acids having at least two carboxyl groups and containing ester groups and/or urethane groups and/or amide groups, said carboxylic acids having a molecular weight of from about 200 to 30,000 and being water-soluble or water-dispersible, as partial replacement of said chemical tanning or pretanning agents and said auxiliary chemicals to tanning.
    • 在改进的鞣革制造方法中,包括将酸洗的未固化的皮革用于含有(1)化学鞣制或预鞣剂的水性液体和(2)辅助化学品对鞣制和回收皮革的作用,其改进主要包括采用 (i)含有结合水的式(Cat2 / nO)x.Al2O3。(SiO2)y的水不溶性硅铝酸盐,其中Cat代表选自碱金属,二价金属离子,三价金属离子 ,及其混合物; n表示1〜3的整数, x是从0.5到1.8的数; y为0.8〜50的数,所述铝硅酸盐的平均粒径为约0.1〜5mm,钙结合力为约0〜200mg CaO / gm的无水活性物质, 22℃,根据钙结合力测试方法,和(ii)具有至少两个羧基并含有酯基和/或氨基甲酸酯基和/或酰胺基的羧酸,所述羧酸的分子量为约 200至30,000,并且是水溶性或水分散性的,作为所述化学鞣制或预处理剂和所述辅助化学品的部分替代物进行鞣制。