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1. 发明授权

US5002957A Azaneophyl sulfides, and their use as pesticides 失效
标题翻译：硫唑烷酮和它们作为农药的用途
公开(公告)号：US5002957A
公开(公告)日：1991-03-26
申请号：US327971
申请日：1989-03-23
申请人： Hans H. Schubert , Gerhard Salbeck , Hans-Peter Krause , Werner Knauf , Anna Waltersdorfer , Manfred Kern
发明人： Hans H. Schubert , Gerhard Salbeck , Hans-Peter Krause , Werner Knauf , Anna Waltersdorfer , Manfred Kern
IPC分类号： C07D253/06 , A01N43/40 , A01N55/00 , A01N55/10 , C07D213/32 , C07D213/61 , C07D213/64 , C07D213/643 , C07D213/70 , C07D237/12 , C07D237/14 , C07D237/18 , C07D239/26 , C07D239/32 , C07D239/34 , C07D241/16 , C07D241/18 , C07D257/08 , C07D401/12 , C07D409/12 , C07D491/056 , C07F7/10
CPC分类号： C07D213/64 , A01N43/40 , A01N55/00 , C07D213/643 , C07D213/70 , C07D409/12
摘要： Azaneophyl and silazaneophyl sulfides, processes for their preparation, agents containing them, and their use as pesticides.Compounds of the formula I, their optical isomers and mixtures thereof ##STR1## where M denotes C or Si,R.sup.1 denotes unsubstituted or substituted pyridyl, unsubstituted or substituted pyrimidyl, andwhen M=C- denotes unsubstituted or substituted pyridazinyl, unsubstituted or substituted pyrazinyl, unsubstituted or substituted 1,2,4-triazinyl, unsubstituted or substituted 1,2,4,5-tetrazinyl, R.sup.2, R.sup.3 independently or one another denote alkyl, alkenyl, haloalkyl, phenyl, or R.sup.2 and R.sup.3 denote an alkylene chain which - together with the quaternary central atom (M) - form an unsubstituted or fluorine-substituted ring having four to six ring members (when M=Si) or having three to six ring members (when M=C),R.sup.4 denotes H, F, --CN, --CCl.sub.3, --C.dbd.CH, (C.sub.1 -C.sub.4)alkyl, ##STR2## R.sup.5 denotes pyridyl, furyl, thienyl, all of which can be substituted, phthalimidyl, dialkylmaleinimidyl, thiophthalimidyl, dihydrophthalimidyl, tetrahydrophthalimidyl, substituted phenylor R.sup.4 and R.sup.5 - together with the carbon atom bridging them denote an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical,and to their salts and quaternization products for advantageous insecticidal, acaricidal or nematocidal properties.
摘要翻译： Azaneophyl和silazaneophyl硫化物，它们的制备方法，含有它们的试剂，以及它们作为农药的用途。式I化合物，其旋光异构体及其混合物，其中M表示C或Si，R1表示未取代或取代的吡啶基，未取代或取代的嘧啶基，当M = C-表示未取代或取代的哒嗪基时，未取代的或取代的吡嗪基，未取代或取代的1,2,4-三嗪基，未取代或取代的1,2,4,5-四嗪基，R2，R3独立地或者彼此表示烷基，烯基，卤代烷基，苯基或R2和R3表示亚烷基链与四元中心原子（M）一起形成具有四至六个环成员（当M = Si）或具有三至六个环成员（当M = C时）的未取代或氟取代的环，R4表示 H，F，-CN，-CCl 3，-C = CH，（C 1 -C 4）烷基，R 5表示吡啶基，呋喃基，噻吩基，它们都可被取代，苯二酰亚氨基，二烷基马来酰亚胺基，硫代邻苯二甲酰亚胺基，二氢邻苯二甲酰亚氨基，四氢邻苯二甲酰亚胺基，取代的苯基或R 4和R 5 - 与碳原子一起桥接它们表示任选取代的茚满基，环戊烯基或环戊烯基，以及它们的盐和季铵化产物，用于有利的杀虫，杀螨或杀线虫性质。

2. 发明授权

US4966902A Heterocyclic neophane analogs, processes for their preparation and their use as pest-combating agents 失效
公开(公告)号：US4966902A
公开(公告)日：1990-10-30
申请号：US181705
申请日：1988-04-13
申请人： Hans H. Schubert , Gerhard Salbeck , Hans-Peter Krause , Walter Luders , Werner Knauf , Anna Waltersdorfer , Manfred Kern
发明人： Hans H. Schubert , Gerhard Salbeck , Hans-Peter Krause , Walter Luders , Werner Knauf , Anna Waltersdorfer , Manfred Kern
IPC分类号： C07D253/06 , A01N43/40 , A01N43/54 , A01N43/58 , A01N43/60 , A01N55/10 , A01P7/02 , A01P7/04 , C07D213/61 , C07D213/63 , C07D213/64 , C07D213/643 , C07D213/65 , C07D213/70 , C07D237/12 , C07D237/14 , C07D237/18 , C07D239/26 , C07D239/30 , C07D239/34 , C07D239/38 , C07D241/16 , C07D241/18 , C07D253/07 , C07D253/08 , C07D257/08 , C07D401/06 , C07D401/08 , C07D401/12 , C07D409/06 , C07D409/08 , C07D491/04 , C07D491/056
CPC分类号： C07D213/64 , A01N43/40 , A01N43/54 , A01N43/58 , A01N43/60 , C07D213/61 , C07D213/643 , C07D213/65 , C07D213/70 , C07D237/12 , C07D237/14 , C07D237/18 , C07D239/26 , C07D239/34 , C07D239/38 , C07D241/16 , C07D241/18 , C07D253/07 , C07D257/08 , C07D401/06 , C07D401/08 , C07D401/12 , C07D409/06 , C07D409/08 , C07D491/04
摘要： Compounds of the formula (I) and their stereoisomers ##STR1## wherein A, B, C' and D independently of one another denote CH or N, in which at least one of the symbols A, B, C' or D must correspond to a nitrogen atom,X denotes CH.sub.2 or oxygen,R.sup.1 denotes a radical bonded to a carbon atom from the series comprising H, trialkylsilyl, halogen, nitro, cyano, alkenyl, alkynyl, amino, cycloalkyl, phenyl, phenxy, alkoxy, alkenyloxy, alkynyloxy, hydroxycarbonyl, alkylthio, cycloalkyloxy, alkylcarbonyl, alkoxycarbonyl, alkenyloxycarbonyl, alkynyloxycarbonyl, halogenoalkyl, alkoxyalkyl, halogenoalkoxy, halogenoalkylthio, halogenoalkoxyalkyl, alkylthioalkyl, alkoxyalkoxy, halogenoalkoxyalkoxy, alkenyloxyalkoxy, halogenoalkenyloxy, alkoxyalkylthio, alkylthioalkoxy, alkylthioalkylthio, halogenoalkoxycarbonyl, halogenoalkenyloxycarbonyl or dialkylamino or two radicals R.sup.1 when they are positioned ortho to one another together denote a methylenedioxy, ethylenedioxy or alkylene radical,R.sup.2 and R.sup.3 independently of one another denote alkyl, alkenyl or phenyl, or R.sup.2 and R.sup.3 denote an alkylene chain which--together with the quaternary carbon atom-forms an unsubstituted or fluorinesubstituted ring having three to six ring members,R.sup.4 denotes --H, F, --CN, --CCl.sub.3, --C.tbd.CH, (C.sub.1 -C.sub.4)alkyl, --C--NH.sub.2, SR.sup.5 denotes pyridyl, furyl or thienyl which can all be substituted, phthalimidyl, dialkylmaleimidyl, thiophthalimidyl, dihydrophthalimidyl, tetrahydrophthalimidyl or substituted phenyl, orR.sup.4 and R.sup.5 --together with the carbon atom bridging them--denote an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical and n denotes 0, 1 or 2, possess advantageous properties for combating pests, in particular insects and acarids. Furthermore, processes for the preparation of compounds of the formula I are described.

3. 发明授权

US5116826A Silazaneophyl sulfides, and their use as pesticides 失效
标题翻译：硅藻土硫化物及其作为杀虫剂使用
公开(公告)号：US5116826A
公开(公告)日：1992-05-26
申请号：US637304
申请日：1991-01-03
申请人： Hans H. Schubert , Gerhard Salbeck , Hans-Peter Krause , Werner Knauf , Anna Waltersdorfer , Manfred Kern
发明人： Hans H. Schubert , Gerhard Salbeck , Hans-Peter Krause , Werner Knauf , Anna Waltersdorfer , Manfred Kern
IPC分类号： C07D253/06 , A01N43/40 , A01N55/00 , A01N55/10 , C07D213/32 , C07D213/61 , C07D213/64 , C07D213/643 , C07D213/70 , C07D237/12 , C07D237/14 , C07D237/18 , C07D239/26 , C07D239/32 , C07D239/34 , C07D241/16 , C07D241/18 , C07D257/08 , C07D401/12 , C07D409/12 , C07D491/056 , C07F7/10
CPC分类号： C07D213/64 , A01N43/40 , A01N55/00 , C07D213/643 , C07D213/70 , C07D409/12
摘要： Azaneophyl and silazaneophyl sulfides, processes for their preparation, agents containing them, and their use as pesticidesCompounds of the formula I, their optical isomers and mixtures thereof ##STR1## where M denotes C or Si,R.sup.1 denotes unsubstituted or substituted pyridyl, unsubstituted or substituted pyrimidyl, andwhen M=C-- denotes unsubstituted or substituted pyridazinyl, unsubstituted or substituted pyrazinyl, unsubstituted or substituted 1,2,4-triazinyl, unsubstituted or substituted 1,2,4,5-tetrazinyl,R.sup.2, R.sup.3 independently of one another denote alkyl, alkenyl, haloalkyl, phenyl, or R.sup.2 and R.sup.3 denote an alkylene chain which--together with the quaternary central atom (M)--form an unsubstituted or fluorine-substituted ring having four to six ring members (when M=Si) or having three to six ring members (when M=C),R.sup.4 denotes H, F, --CN, --CCl.sub.3, --C.dbd.CH, (C.sub.1 -C.sub.4)alkyl, ##STR2## R.sup.5 denotes pyridyl, furyl, thienyl, all of which can be substituted, phthalimidyl, dialkylmaleinimidyl, thiophthalimidyl, dihydrophthalimidyl, tetrahydrophthalimidyl, substituted phenylor R.sup.4 and R.sup.5 --together with the carbon atom bridging them--denote an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical,and to their salts and quaternization products for advantageous insecticidal, acaricidal or nematocidal properties.

4. 发明授权

US4775664A Silane derivatives, agents containing them, and their use as pesticides 失效
标题翻译：硅烷衍生物，含有它们的试剂，以及它们作为杀虫剂的用途
公开(公告)号：US4775664A
公开(公告)日：1988-10-04
申请号：US36575
申请日：1987-04-10
申请人： Hans H. Schubert , Gerhard Salbeck , Walter Luders , Werner Knauf , Anna Waltersdorfer
发明人： Hans H. Schubert , Gerhard Salbeck , Walter Luders , Werner Knauf , Anna Waltersdorfer
IPC分类号： C07F7/10 , A01N55/00 , A01N55/10 , A01P7/04 , C07F7/08 , C07F7/12 , C07F7/18 , C07F9/58
CPC分类号： A01N55/00 , C07F7/0812 , C07F7/0818
摘要： The compounds of the formula (I) ##STR1## in which X denotes CH.sub.2 or O,R.sup.1 denotes (subst.) pyridyl or (subst.) pyrimidyl,R.sup.2 and R.sup.3 denote alkyl or alkenyl or R.sup.2 and R.sup.3 denote an alkylene chain,R.sup.4 denotes --H, --CN, --CCl.sub.3, --C.tbd.CH, alkyl, F, or --C(S)--NH.sub.2,R.sup.5 denotes pyridyl, furyl, thienyl, phthalimidyl, di(C.sub.1 -C.sub.4)alkylmaleimidyl, thiophthalimidyl, dihydrophthalimidyl or tetrahydrophthalimidyl, which may all be substituted, or substituted phenyl, orR.sup.4 and R.sup.5 --together with the carbon atom bridging them--denote an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical,have advantageous insecticidal, acaricidal and nematocidal properties.
摘要翻译：式（I）化合物其中X表示CH2或O，R1表示（取代）吡啶基或（取代）嘧啶基，R2和R3表示烷基或烯基或R2和R3表示亚烷基链，R4表示-H，-CN，-CCl3，-C3BCH，烷基，F或-C（S）-NH2，R5表示吡啶基，呋喃基，噻吩基，苯二酰亚氨基，二（C1-C4）烷基马来酰亚胺基，，可以全部被取代的二氢邻苯二甲酰亚胺基或四氢邻苯二甲酰亚胺基，或者取代的苯基，或者R4和R5-与它们连接的碳原子一起表示任选取代的茚满基，环戊烯基或环戊烯基，具有有利的杀虫，杀螨和杀线虫性质。

5. 发明授权

US4990621A Certain propene derivatives as intermediates for the preparation of pesticidal silane derivatives 失效
标题翻译：某些丙烯衍生物作为制备杀虫剂硅烷衍生物的中间体
公开(公告)号：US4990621A
公开(公告)日：1991-02-05
申请号：US359098
申请日：1989-05-30
申请人： Hans H. Schubert , Gerhard Salbeck , Walter Luders , Werner Knauf , Anna Waltersdorfer
发明人： Hans H. Schubert , Gerhard Salbeck , Walter Luders , Werner Knauf , Anna Waltersdorfer
IPC分类号： A01N20060101 , A01N43/40 , A01N55/00 , A01N55/02 , A01N55/10 , A01P7/04 , A23K20060101 , A61K20060101 , C07C20060101 , C07C7/08 , C07C25/13 , C07C43/215 , C07C43/225 , C07D213/64 , C07F20060101 , C07F7/08 , C07F7/10
CPC分类号： C07F7/0818 , A01N55/00 , C07F7/0812
摘要： New propene derivatives as intermediates for the preparation of pesticidal silane derivatives. Compounds of the formula ##STR1## wherein R.sup.4 is H, R.sup.5 is a radical of the formula ##STR2## and R.sup.17 is H or halogen are useful intermediates for the preparation of pesticidal silane derivatives.

6. 发明授权

US5139785A Pesticides 失效
标题翻译：农药
公开(公告)号：US5139785A
公开(公告)日：1992-08-18
申请号：US657285
申请日：1991-02-19
申请人： Anna Waltersdorfer , Manfred Kern , Werner Knauf , Hans H. Schubert
发明人： Anna Waltersdorfer , Manfred Kern , Werner Knauf , Hans H. Schubert
IPC分类号： A01N55/00
CPC分类号： A01N55/00
摘要： Pesticides containing at least one compound of the formula I ##STR1## where M denotes carbon or silicon,X denotes CH.sub.2, O, S, NR.sup.6,R.sup.1 denotes (C.sub.2 -C.sub.18)alkyl, (C.sub.5 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, phenyl, naphthyl, pyridyl, pyrimidyl, pyridazinyl, pyrazinyl, 1,2,4-triazinyl or 1,2,4,5-tetrazinyl, it being possible for all these substituents to be monosubstituted or polysubstituted,R.sup.2, R.sup.3 independently of one another denote (C.sub.1 -C.sub.3)alkyl, (C.sub.2 -C.sub.8)alkenyl or phenyl, or R.sup.2 and R.sup.3 denote an alkylene chain which--together with the quaternary central atom (M)--form an unsubstituted or fluorine-substituted ring having four to six ring members (where M=Si) or having three to six ring members (where M=C),R.sup.4 denotes --H, --CN, --CCl.sub.3, --C.tbd.CH, (C.sub.1 -C.sub.4)alkyl, F, ##STR2## R.sup.5 denotes pyridyl, furyl or thienyl, each of which can be substituted, phthalimidyl, di(C.sub.1 -C.sub.4)alkylmaleimidyl, thiophthalimidyl, dihydrophthalimidyl, tetrahydrophthalimidyl or substituted phenyl, or R.sup.4 and R.sup.5 --together with the carbon atom linking them--form an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical, andR.sup.6 denotes H, (C.sub.1 -C.sub.3)alkyl or phenyl,in combination with a compound from the group comprising endosulfan (IX), buprofezin (X), cyromazine (XI), flubenzimine (XIII), flufenoxuron (XIII), deltamethrin (XIIIa), triazophos (XIIIb) and heptenophos (XIIIc), or a compound of the formula XIV ##STR3## where R.sub.15, R.sub.16, R.sub.17 and R.sub.18 independently of one another denote hydrogen or halogen,R.sub.19 denotes CH.sub.3, CF.sub.3 or halogen andR.sub.20 denotes (C.sub.1 -C.sub.3)haloalkyl, or a compound of the formula XV ##STR4## where R.sub.21 and R.sub.22 independently of one another denote H or halogen, show advantageous synergistic effects.
摘要翻译：含有至少一种式I化合物的农药，其中M表示碳或硅，X表示CH 2，O，S，NR 6，R 1表示（C 2 -C 18）烷基，（C 5 -C 7）环烷基，（C 2 -C 8 ）链烯基，苯基，萘基，吡啶基，嘧啶基，哒嗪基，吡嗪基，1,2,4-三嗪基或1,2,4,5-四嗪基，所有这些取代基可能是单取代或多取代的，R2，R3独立地彼此表示（C 1 -C 3）烷基，（C 2 -C 8）烯基或苯基，或者R 2和R 3表示亚烷基链，其与四元中心原子（M）一起形成未取代或氟取代的环，其具有四个至六个环成员（其中M = Si）或具有三至六个环成员（其中M = C），R4表示-H，-CN，-CCl3，-C3BCH，（C1-C4）烷基，图示R5表示吡啶基，呋喃基或噻吩基，其各自可以被取代，苯二酰亚氨基，二（C1-C4）烷基马来酰亚胺基，硫代邻苯二甲酰亚胺基，二氢邻苯二甲酰亚胺基，四氢邻苯二甲酰亚胺基或取代的苯基，或R4和R5与碳一起连接它们 - 形成任选取代的茚满基，环戊烯酰基或环戊烯基，R 6表示H，（C 1 -C 3）烷基或苯基，与来自包含硫丹（IX），布吡嗪（X），环丙嗪 XI），氟西坦（XIII），氟草酮（XIII），溴氰菊酯（XIIIa），三唑磷（XIIIb）和庚烯磷（XIIIc））或式XIV的化合物，其中R15，R16，R17和R18彼此独立地表示氢或卤素，R 19表示CH 3，CF 3或卤素，R 20表示（C 1 -C 3）卤代烷基，或其中R 21和R 22彼此独立地表示H或卤素的式XV化合物（XV）协同效应。

7. 发明授权

US5530153A Process for preparation of aryldimethyl (3-aryl-propyl)silanes 失效
标题翻译：制备芳基二甲基（3-芳基 - 丙基）硅烷的方法
公开(公告)号：US5530153A
公开(公告)日：1996-06-25
申请号：US379037
申请日：1995-01-27
申请人： Hans H. Schubert
发明人： Hans H. Schubert
IPC分类号： A01N55/00 , A01N55/10 , C07F7/08 , C07F7/12
CPC分类号： A01N55/00 , C07F7/0827 , C07F7/122
摘要： Process for the preparation of aryldimethyl(3-arylpropyl)silanes by a route comprising hydrosilylation followed by a modified Grignard reaction.
摘要翻译：通过包括氢化硅烷化然后进行改性格氏反应的途径制备芳基二甲基（3-芳基丙基）硅烷的方法。

8. 发明授权

US5028706A Process for the preparation of halosilanes 失效
标题翻译：卤代硅烷的制备方法
公开(公告)号：US5028706A
公开(公告)日：1991-07-02
申请号：US379094
申请日：1989-07-13
申请人： Hans H. Schubert
发明人： Hans H. Schubert
IPC分类号： C07F7/12
CPC分类号： C07F7/123
摘要： The present invention relates to a process for the preparation of compounds of the formula I ##STR1## in which Hal denotes F, Cl, Br or I; X denoted O, S or CH.sub.2 ; Y denotes CH or N; R.sup.1 denotes H or (C.sub.1 -C.sub.4 -alkyl; R.sup.2 denotes H, F, Cl or Br and R.sup.3 denotes H, F, Cl, Br, (C.sub.1 -C.sub.4)alkyl or (C.sub.1 -C.sub.4)alkoxy, which comprises reacting a compound of the formula II ##STR2## in which aryl stands for an unsubstituted or substituted phenyl, naphthyl or thienyl radical of the formulae (A), (B) or (C) ##STR3## in which R.sup.4, R.sup.5 and R.sup.6 independently of each other denote H, alkyl, alkoxy, alkylthio, dialkylamino, phenoxy, phenylthio or phenyl and m, n and o independently of each denote the values 0, 1 or 2, and X, Y, R.sup.1, R.sup.2 and R.sup.3 are as defined in formula I,with a halogen or a halogen compound of the formula IIIHal.sub.p --Z.sub.q (III)in which Z denotes F, Cl, Br, I, H, PHal.sub.4 or SO.sub.2 Hal and p and q independently of each other denote the values 1 to 5 and Hal is as defined in formula I.
摘要翻译：本发明涉及制备式I化合物（I）的方法，其中Hal表示F，Cl，Br或I; X表示为O，S或CH2; Y表示CH或N; R 1表示H或（C 1 -C 4 - 烷基; R 2表示H，F，Cl或Br，R 3表示H，F，Cl，Br，（C 1 -C 4）烷基或（C 1 -C 4）烷氧基，式（II）其中芳基代表式（A），（B）或（C）的未取代或取代的苯基，萘基或噻吩基。）其中R 4，R 5和R 6彼此独立地表示H，烷基，烷氧基，烷硫基，二烷基氨基，苯氧基，苯硫基或苯基，m，n和o各自独立地表示0,1或 2，X，Y，R 1，R 2和R 3如式I所定义，与卤素或式III Halp-Zq（III）的卤素化合物，其中Z表示F，Cl，Br，I，H， PHal4或SO2Hal，p和q彼此独立地表示值1至5，Hal如式I中所定义。

9. 发明授权

US5286862A Process for the preparation of aryldimethyl(3-aryl-propyl)silanes 失效
标题翻译：芳基二甲基（3-芳基 - 丙基）硅烷的制备方法
公开(公告)号：US5286862A
公开(公告)日：1994-02-15
申请号：US398058
申请日：1989-08-24
申请人： Hans H. Schubert
发明人： Hans H. Schubert
IPC分类号： A01N55/00 , A01N55/10 , C07F7/08 , C07F7/12 , C07F7/02
CPC分类号： A01N55/00 , C07F7/0827 , C07F7/122
摘要： The present invention relates to a process for the preparation of compounds of the formula I ##STR1## where X is CH.dbd.CH, N.dbd.CH, CH.dbd.N or S,R.sup.1 and R.sup.2 independently of one another are H, halogen, alkyl, alkoxy, alkylthio, haloalkyl, haloalkoxy, haloalkylthio or the bivalent methylenedioxy group,R.sup.3 is a radical of the formulae (A), (B) or (C) ##STR2## where R.sup.4 and R.sup.5 independently of one another are H, halogen, alkyl, alkoxy or a radical of the formula (D) ##STR3## in which R.sup.6 is H or halogen andY is CH.sub.2, O or S, andm, n, o, p and q are 0, 1, or 2, which comprises reacting a compound of the formula IIH.sub.2 C.dbd.CH--CH.sub.2 --R.sup.3 (II) where R.sup.3 is as defined in formula I, with dichloromethylsilane in the presence of a catalyst suitable for hydrosilylation reactions, and reacting the resulting intermediate of the formula III ##STR4## where R.sup.3 is as defined in formula I, in succession and without isolation of the resulting intermediate, with a methylmagnesium halide and an arylmagnesium halide of the general formula IV ##STR5## where R.sup.1, R.sup.2, m, n and X are as defined in formula I and Hal is halogen.The invention furthermore relates to the compounds of the formula III.
摘要翻译：本发明涉及制备式Ⅰ“化合物”的方法，其中X表示CH = CH，N = CH，CH = N或S，R 1和R 2彼此独立地表示H，卤素，烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基，卤代烷硫基或二价基亚甲二氧基，R 3表示式（A），（B），（C） R 4和R 5彼此独立地表示H，卤素，烷基，烷氧基或式（D）的基团，其中R 6表示H或卤素，Y表示CH 2，O或S，以及 m，n，o，p和q表示0,1或2，其特征在于式II化合物H 2 C = CH-CH 2 -R 3（II）其中R 3具有如式 I在与适用于氢化硅烷化反应的催化剂存在下与二氯甲基硅烷反应，得到的式III化合物（其中R 3具有式I的含义）的中间体连续反应，而不分离得到的中间体，与其中R 1，R 2，m，n和X具有式I中的含义，Hal表示卤素，通式为“IMAGE”的甲基卤化镁和芳基镁卤化物。本发明还涉及式III的化合物。

10. 发明授权

US4920212A Process for the preparation of (aryl)-(dimethyl)-(3-(4-fluoro-3-aryloxyphenyl)propyl)silanes 失效
标题翻译：制备（芳基） - （二甲基） - （3-（4-氟-3-芳氧基苯基）丙基）硅烷的方法
公开(公告)号：US4920212A
公开(公告)日：1990-04-24
申请号：US245404
申请日：1988-09-16
申请人： Hans H. Schubert
发明人： Hans H. Schubert
IPC分类号： C07F7/12 , B01J23/72 , B01J27/122 , C07B61/00 , C07F7/08
CPC分类号： C07F7/083
摘要： The present invention relates to a process for the preparation of compounds of the formula I ##STR1## in which R.sup.1 denotes H, halogen, (C.sub.1 -C.sub.4)-alkyl or (C.sub.1 -C.sub.4)-alkoxy andR.sup.2 denotes H, halogen, (C.sub.1 -C.sub.4)-alkyl, (C.sub.1 -C.sub.4)-alkyl-thio, (C.sub.1 -C.sub.4)-alkoxy or the bivalent group 3,4-0-CH.sub.2 -O, comprising reacting a compound of the formula II ##STR2## in which X denotes halogen and R.sup.2 has the meaning as in formula I, in the presence of a copper catalyst with an alkali metal phenolate or alkaline earth metal phenolate of the formula III ##STR3## in which M denotes an alkali metal or an alkaline earth metal and R.sup.1 has the meaning as in formula I.
摘要翻译：本发明涉及制备式I化合物（I）的方法，其中R 1表示H，卤素，（C 1 -C 4） - 烷基或（C 1 -C 4） - 烷氧基，R 2表示H，卤素，（C 1 -C 4） - 烷基，（C 1 -C 4） - 烷基 - 硫基，（C 1 -C 4） - 烷氧基或二价基团3,4-0-CH 2 -O，（II）其中X表示卤素，R 2具有式I的含义，在铜催化剂存在下，其具有式III的碱金属酚盐或碱土金属酚盐（III），其中M 表示碱金属或碱土金属，R 1具有式I中的含义。

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