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    • 2. 发明授权
    • Azaneophyl sulfides, and their use as pesticides
    • 硫唑烷酮和它们作为农药的用途
    • US5002957A
    • 1991-03-26
    • US327971
    • 1989-03-23
    • Hans H. SchubertGerhard SalbeckHans-Peter KrauseWerner KnaufAnna WaltersdorferManfred Kern
    • Hans H. SchubertGerhard SalbeckHans-Peter KrauseWerner KnaufAnna WaltersdorferManfred Kern
    • C07D253/06A01N43/40A01N55/00A01N55/10C07D213/32C07D213/61C07D213/64C07D213/643C07D213/70C07D237/12C07D237/14C07D237/18C07D239/26C07D239/32C07D239/34C07D241/16C07D241/18C07D257/08C07D401/12C07D409/12C07D491/056C07F7/10
    • C07D213/64A01N43/40A01N55/00C07D213/643C07D213/70C07D409/12
    • Azaneophyl and silazaneophyl sulfides, processes for their preparation, agents containing them, and their use as pesticides.Compounds of the formula I, their optical isomers and mixtures thereof ##STR1## where M denotes C or Si,R.sup.1 denotes unsubstituted or substituted pyridyl, unsubstituted or substituted pyrimidyl, andwhen M=C- denotes unsubstituted or substituted pyridazinyl, unsubstituted or substituted pyrazinyl, unsubstituted or substituted 1,2,4-triazinyl, unsubstituted or substituted 1,2,4,5-tetrazinyl, R.sup.2, R.sup.3 independently or one another denote alkyl, alkenyl, haloalkyl, phenyl, or R.sup.2 and R.sup.3 denote an alkylene chain which - together with the quaternary central atom (M) - form an unsubstituted or fluorine-substituted ring having four to six ring members (when M=Si) or having three to six ring members (when M=C),R.sup.4 denotes H, F, --CN, --CCl.sub.3, --C.dbd.CH, (C.sub.1 -C.sub.4)alkyl, ##STR2## R.sup.5 denotes pyridyl, furyl, thienyl, all of which can be substituted, phthalimidyl, dialkylmaleinimidyl, thiophthalimidyl, dihydrophthalimidyl, tetrahydrophthalimidyl, substituted phenylor R.sup.4 and R.sup.5 - together with the carbon atom bridging them denote an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical,and to their salts and quaternization products for advantageous insecticidal, acaricidal or nematocidal properties.
    • Azaneophyl和silazaneophyl硫化物,它们的制备方法,含有它们的试剂,以及它们作为农药的用途。 式I化合物,其旋光异构体及其混合物,其中M表示C或Si,R1表示未取代或取代的吡啶基,未取代或取代的嘧啶基,当M = C-表示未取代或取代的哒嗪基时,未取代的 或取代的吡嗪基,未取代或取代的1,2,4-三嗪基,未取代或取代的1,2,4,5-四嗪基,R2,R3独立地或者彼此表示烷基,烯基,卤代烷基,苯基或R2和R3表示 亚烷基链与四元中心原子(M)一起形成具有四至六个环成员(当M = Si)或具有三至六个环成员(当M = C时)的未取代或氟取代的环,R4表示 H,F,-CN,-CCl 3,-C = CH,(C 1 -C 4)烷基,R 5表示吡啶基,呋喃基,噻吩基,它们都可被取代,苯二酰亚氨基,二烷基马来酰亚胺基,硫代邻苯二甲酰亚胺基,二氢邻苯二甲酰亚氨基,四氢邻苯二甲酰亚胺基, 取代的苯基或R 4和R 5 - 与碳原子一起 桥接它们表示任选取代的茚满基,环戊烯基或环戊烯基,以及它们的盐和季铵化产物,用于有利的杀虫,杀螨或杀线虫性质。