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1. 发明授权

US06781021B2 Method for isomerizing halogenated aromatics 有权
标题翻译：异构化卤代芳烃的方法
公开(公告)号：US06781021B2
公开(公告)日：2004-08-24
申请号：US10010561
申请日：2001-11-08
申请人： Hajime Kato , Kazuyoshi Iwayama , Masashi Kato , Shinobu Yamakawa , Hirohito Okino
发明人： Hajime Kato , Kazuyoshi Iwayama , Masashi Kato , Shinobu Yamakawa , Hirohito Okino
IPC分类号： C07C1700
CPC分类号： C07C17/358 , B01J29/18 , B01J29/40 , B01J35/023 , B01J2229/42 , Y02P20/584 , C07C25/10 , C07C25/02
摘要： A catalyst composition with a high halogenated aromatics isomerization activity, a halogenated aromatic isomerization method using said catalyst composition, and a halogenated aromatics isomerization method capable of prolonging the life or regeneration period of the catalyst. The invention also includes a catalyst composition characterized in that the maximum diameter of secondary particles of the zeolite in the formed catalyst is 5 microns or less is used to improve the halogenated aromatics isomerization activity. Furthermore, if dissolved oxygen is decreased, the life or regeneration period of the catalyst can be prolonged.
摘要翻译：具有高卤化芳烃异构化活性的催化剂组合物，使用所述催化剂组合物的卤代芳族异构化方法和能够延长催化剂寿命或再生期的卤代芳烃异构化方法。本发明还包括一种催化剂组合物，其特征在于所形成的催化剂中沸石的二次颗粒的最大直径为5微米或更小，用于改善卤代芳烃异构化活性。此外，如果溶解氧降低，则可延长催化剂的寿命或再生时间。

2. 发明授权

US06320087B2 Adsorbent for separating halogenated aromatic compounds and separation method 有权
标题翻译：用于分离卤代芳族化合物的吸附剂和分离方法
公开(公告)号：US06320087B2
公开(公告)日：2001-11-20
申请号：US09287044
申请日：1999-04-06
申请人： Kazuyoshi Iwayama , Shinobu Yamakawa , Masashi Kato , Hirohito Okino
发明人： Kazuyoshi Iwayama , Shinobu Yamakawa , Masashi Kato , Hirohito Okino
IPC分类号： C07C1738
CPC分类号： B01J20/28014 , B01D53/02 , B01J20/183 , B01J20/28004 , B01J20/28011 , B01J20/28069 , C07C17/389 , C07C22/04 , C07C25/08 , C07C25/125
摘要： An adsorbing and separating agent for halogenated aromatic compounds and an adsorbing and separating method for the compounds, using an adsorbent which has a porosity of from 0.20 cc/cc to 0.37 cc/cc, a packing density of from 0.50 g/ml to 0.70 g/ml, and a grain size of from 0.1 mm to 1.0 mm.
摘要翻译：用于卤化芳族化合物的吸附和分离剂以及该化合物的吸附和分离方法，使用孔隙率为0.20cc / cc至0.37cc / cc的吸附剂，填充密度为0.50g / ml至0.70g / ml，粒径为0.1mm〜1.0mm。

3. 发明授权

US6040490A Process for producing aromatic compounds by dealkylation, transalkylation, or disproportionation 有权
标题翻译：通过脱烷基化，烷基转移反应或歧化反应生产芳族化合物的方法
公开(公告)号：US6040490A
公开(公告)日：2000-03-21
申请号：US132654
申请日：1998-08-12
申请人： Ryoji Ichioka , Shinobu Yamakawa , Hirohito Okino , Hajime Kato , Kazuyoshi Iwayama , Hiroshi Konta , Akira Kitamura
发明人： Ryoji Ichioka , Shinobu Yamakawa , Hirohito Okino , Hajime Kato , Kazuyoshi Iwayama , Hiroshi Konta , Akira Kitamura
IPC分类号： C07C6/12 , C07C5/22 , C07C2/66 , C07C4/12
CPC分类号： C07C6/126 , C07C2523/36 , C07C2529/26
摘要： Aromatic hydrocarbons are efficiently converted by bringing feedstock containing from 5 to 50% by weight of an aromatic hydrocarbon having an ethyl group and a C.sub.9 alkyl aromatic hydrocarbon into contact with a catalyst capable of disproportionation, trans-alkylation and dealkylation, a secondary particle diameter of a zeolite in the catalyst being 10 .mu.m or less.
摘要翻译：通过将含有5至50重量％的具有乙基和C 9烷基芳族烃的芳族烃的原料与能够歧化，反式烷基化和脱烷基化的催化剂接触来进行芳族烃的有效转化，催化剂中的沸石为10μm以下。

4. 发明授权

US5847256A Process for producing xylene 失效
标题翻译：二甲苯生产工艺
公开(公告)号：US5847256A
公开(公告)日：1998-12-08
申请号：US955870
申请日：1997-10-22
申请人： Ryoji Ichioka , Shinobu Yamakawa , Hirohito Okino
发明人： Ryoji Ichioka , Shinobu Yamakawa , Hirohito Okino
IPC分类号： C07C6/12 , C07C15/08
CPC分类号： C07C6/126 , C07C2529/20 , C07C2529/26
摘要： An improved process for producing xylene from feedstock containing C.sub.9 alkyl aromatic hydrocarbons with the aid of a catalyst capable of disproportionation, rearrangement, and dealkylation, wherein said improvement comprises performing the reaction in the presence of an aromatic hydrocarbon having one or more ethyl groups in an amount of 5 to 50 wt %.
摘要翻译：一种用于能够歧化，重排和脱烷基化的催化剂，由含有C 9烷基芳烃的原料生产二甲苯的改进方法，其中所述改进包括在具有一个或多个乙基的芳族烃存在下进行反应用量为5〜50重量％。

5. 发明授权

US06972347B1 Method for converting aromatic hydrocarbons 有权
标题翻译：芳烃转化方法
公开(公告)号：US06972347B1
公开(公告)日：2005-12-06
申请号：US09589588
申请日：2000-06-08
申请人： Akira Kitamura , Ryoji Ichioka , Shinobu Yamakawa
发明人： Akira Kitamura , Ryoji Ichioka , Shinobu Yamakawa
IPC分类号： C10G35/04 , C07C6/12 , C07C5/00
CPC分类号： C10G35/04 , C07C6/126 , C07C2523/36 , C07C2529/18
摘要： A method for converting aromatic hydrocarbons by contacting an aromatic hydrocarbon starting material including benzene and having a non-aromatic compound content of 1% by weight or less, with a catalystto generate useful C7 and C8 aromatic hydrocarbons while reducing the catalyst deactivation.
摘要翻译：通过使包含苯并且具有1重量％以下的非芳香族化合物含量的芳香族烃原料与催化剂接触来生成有用的C7和C8芳香烃，同时减少催化剂失活的方法来转化芳烃。

6. 发明授权

US06379552B1 Method for resolving optical isomers 失效
标题翻译：拆分光学异构体的方法
公开(公告)号：US06379552B1
公开(公告)日：2002-04-30
申请号：US09347062
申请日：1999-07-02
申请人： Tetsuji Kitagawa , Atsushi Okamoto , Takashi Kanai , Katsuhiro Shibayama , Tomoyuki Aoki , Shinobu Yamakawa
发明人： Tetsuji Kitagawa , Atsushi Okamoto , Takashi Kanai , Katsuhiro Shibayama , Tomoyuki Aoki , Shinobu Yamakawa
IPC分类号： B01D1500
CPC分类号： C07B57/00
摘要： A method for efficiently resolving optical isomers, in which a discriminating liquid consisting of a discriminating agent capable of discriminating optical isomers and a diluent are brought into contact with a mixture containing said optical isomers in countercurrent flow, to resolve the optical isomers by adsorption separation, distillation separation, absorption separation or membrane separation, and recovered at an optical isomer content of 5 wt % or less for recycled use, under one or more of the following conditions: (a) the dielectric constant of the diluent is 30 or less and the viscosity of the discriminating liquid is 0.2 Pa·s or less at the temperature of the resolving operation; (b) the discriminating agent contained has the effect of splitting the 1H or 13C-NMR spectrum peak of the optical isomers when added and the diluent contained has a dielectric constant equal to or lower than the dielectric constant of the measuring solvent at the time of measuring the 1H or 13C-NMR spectrum; (c) the boiling point of at least one compound of the discriminating agent at the pressure of the resolving operation is higher than the boiling point of at least one compound of the diluent at the pressure of the resolving operation; (d) the boiling point of at least one compound of the diluent at the pressure of the resolving operation is higher than the boiling point of the optical isomers to be resolved, at the pressure of the resolving operation, by 10° C. or more; and (e) the concentration of the discriminating agent in the discriminating liquid is 10 wt % or more.
摘要翻译：光学异构体的有效解决方法是将由能够鉴别光学异构体的识别剂组成的识别液与稀释剂逆流流动地与包含所述光学异构体的混合物接触，从而通过吸附分离来分解光学异构体，蒸馏分离，吸收分离或膜分离，并在一种或多种以下条件下以5重量％以下的光学异构体含量回收再循环使用：（a）稀释剂的介电常数为30以下，鉴定液的粘度在分解操作的温度下为0.2Pa.s以下;（b）所含的鉴别剂具有在添加时分解光学异构体的1H或13C-NMR谱峰的作用，并且稀释剂含有介电常数等于或低于在测量1H或13C-NMR谱时测量溶剂的介电常数（c）解析操作压力下鉴别剂的至少一种化合物的沸点高于分解操作压力下至少一种稀释剂化合物的沸点;（d）在拆分操作压力下，至少一种稀释剂化合物的沸点高于分解操作压力下要拆分的光学异构体的沸点10℃或更高; 和（e）鉴别液中鉴别剂的浓度为10重量％以上。

7. 发明申请

US20100179360A1 METHOD FOR CONVERSION OF ETHYLBENZENE AND PROCESS FOR PRODUCTION OF PARA-XYLENE 审中-公开
标题翻译：苯乙烯转化方法及其制备方法
公开(公告)号：US20100179360A1
公开(公告)日：2010-07-15
申请号：US12295006
申请日：2007-03-28
申请人： Ryoji Ichioka , Eiichi Minomiya , Shinobu Yamakawa
发明人： Ryoji Ichioka , Eiichi Minomiya , Shinobu Yamakawa
IPC分类号： C07C5/22 , C07C4/12
CPC分类号： C07C5/2724 , B01J29/48 , B01J2229/186 , C07C4/18 , C07C5/2708 , C07C7/148 , C07C15/08 , C07C2529/48 , C07C2529/78 , Y02P20/52 , C07C15/04
摘要： A process for converting ethylbenzene, by which ethylbenzene in a feedstock containing C8 aromatic hydrocarbon is converted to benzene at a high degree of conversion is disclosed. The process for converting ethylbenzene includes bringing a C8 aromatic hydrocarbon mixed feedstocks containing ethylbenzene into contact with an acid type catalyst containing at least one metal selected from the group consisting of the metals belonging to Group VII and Group VIII in the presence of H2 to convert ethylbenzene to benzene. The feedstock contains C9-C10 aromatic hydrocarbons including ethyltoluene, and the ethyltoluene is converted to toluene together with the conversion of ethylbenzene.
摘要翻译：公开了将含有C8芳香族烃的原料中的乙苯以高转化率转化为苯的乙苯的转化方法。转化乙苯的方法包括使含有乙苯的C8芳族烃混合原料与含有至少一种选自属于第VII和VIII族的金属的酸式催化剂在H 2存在下接触，以转化乙苯到苯。原料含有C 9 -C 10芳族烃，包括乙基甲苯，乙基甲苯与乙苯的转化一起转化为甲苯。

8. 发明授权

US07151354B2 Magnetic noise reduction method for AC rotary electric machine, and motor control apparatus and AC rotary electric machine apparatus using the same 有权
标题翻译：交流旋转电机的磁噪声降低方法以及使用其的电动机控制装置和交流旋转电机装置
公开(公告)号：US07151354B2
公开(公告)日：2006-12-19
申请号：US10868095
申请日：2004-06-16
申请人： Soichi Yoshinaga , Kenichi Wakabayashi , Takatoshi Takai , Tatsuru Morioka , Hiroya Tsuji , Makoto Okamura , Shinobu Yamakawa
发明人： Soichi Yoshinaga , Kenichi Wakabayashi , Takatoshi Takai , Tatsuru Morioka , Hiroya Tsuji , Makoto Okamura , Shinobu Yamakawa
IPC分类号： G05B5/01
CPC分类号： H02P21/00 , H02J3/01 , H02K19/36 , H02M1/44 , H02P29/50 , Y02E40/40
摘要： The invention provides techniques for reducing or altering the magnetic noise of an AC rotary electric machine. A magnetic noise reducing harmonic current of order n, whose frequency is n times the frequency of the fundamental frequency component of a polyphase AC current fed to an armature of a polyphase AC rotary electric machine, is superimposed on the polyphase AC current, thereby reducing or altering a harmonic component having a frequency (n−1) times the frequency of the fundamental frequency component and occurring due to a radial magnetic excitation force acting radially on an iron core of the AC rotary electric machine. Magnetic noise is caused by a vibration whose energy is the sum of the circumferential and radial vibrations of the iron core occurring due to the magnetomotive force of the rotor, and altering the radial vibration is particularly effective in altering the magnetic noise; as the harmonic component of the radially acting magnetic excitation force, occurring due to harmonic components having frequencies 3, 5, 7, and 13 times the fundamental frequency, has a frequency 6 or 12 times the fundamental frequency, the magnetomotive force of the rotor can be effectively reduced or altered when a current having a frequency 7 or 13 times the fundamental frequency is superimposed on the stator current.
摘要翻译：本发明提供减少或改变交流旋转电机的磁噪声的技术。频率为进给多相AC旋转电机的电枢的多相AC电流的基频分量的频率的n倍的磁噪声降低谐波电流叠加在多相AC电流上，由此减少或改变具有基频频率的频率（n-1）倍的谐波分量，并且由于径向地作用在交流旋转电机的铁芯上的径向磁激励力而发生。磁噪声是由振动引起的，其能量是由于转子的磁动势而产生的铁芯的周向振动和径向振动的总和，并且改变径向振动在改变磁噪声方面特别有效; 由于由于具有基频的频率3,5,7和13的谐波分量而产生的径向作用的磁激励力的谐波分量具有基频的6或12倍的频率，转子的磁动势可以当具有基频的频率7或13倍的电流叠加在定子电流上时，可以有效地减小或改变。

9. 发明申请

US20050073280A1 Magnetic noise reduction method for AC rotary electric machine, and motor control apparatus and AC rotary electric machine apparatus using the same 有权
标题翻译：交流旋转电机的磁噪声降低方法以及使用其的电动机控制装置和交流旋转电机装置
公开(公告)号：US20050073280A1
公开(公告)日：2005-04-07
申请号：US10868095
申请日：2004-06-16
申请人： Soichi Yoshinaga , Kenichi Wakabayashi , Takatoshi Takai , Tatsuru Morioka , Hiroya Tsuji , Makoto Okamura , Shinobu Yamakawa
发明人： Soichi Yoshinaga , Kenichi Wakabayashi , Takatoshi Takai , Tatsuru Morioka , Hiroya Tsuji , Makoto Okamura , Shinobu Yamakawa
IPC分类号： H02J3/01 , H02K19/36 , H02P21/00 , H02P21/05 , H02P29/00 , H02P1/24
CPC分类号： H02P21/00 , H02J3/01 , H02K19/36 , H02M1/44 , H02P29/50 , Y02E40/40
摘要： The invention provides techniques for reducing or altering the magnetic noise of an AC rotary electric machine. A magnetic noise reducing harmonic current of order n, whose frequency is n times the frequency of the fundamental frequency component of a polyphase AC current fed to an armature of a polyphase AC rotary electric machine, is superimposed on the polyphase AC current, thereby reducing or altering a harmonic component having a frequency (n−1) times the frequency of the fundamental frequency component and occurring due to a radial magnetic excitation force acting radially on an iron core of the AC rotary electric machine. Magnetic noise is caused by a vibration whose energy is the sum of the circumferential and radial vibrations of the iron core occurring due to the magnetomotive force of the rotor, and altering the radial vibration is particularly effective in altering the magnetic noise; as the harmonic component of the radially acting magnetic excitation force, occurring due to harmonic components having frequencies 3, 5, 7, and 13 times the fundamental frequency, has a frequency 6 or 12 times the fundamental frequency, the magnetomotive force of the rotor can be effectively reduced or altered when a current having a frequency 7 or 13 times the fundamental frequency is superimposed on the stator current.
摘要翻译：本发明提供减少或改变交流旋转电机的磁噪声的技术。频率为进给多相AC旋转电机的电枢的多相AC电流的基频分量的频率的n倍的磁噪声降低谐波电流叠加在多相AC电流上，由此减少或改变具有基频频率的频率（n-1）倍的谐波分量，并且由于径向地作用在交流旋转电机的铁芯上的径向磁激励力而发生。磁噪声是由振动引起的，其能量是由于转子的磁动势而产生的铁芯的周向振动和径向振动的总和，并且改变径向振动在改变磁噪声方面特别有效; 由于由于具有基频的频率3,5,7和13的谐波分量而产生的径向作用的磁激励力的谐波分量具有基频的6或12倍的频率，转子的磁动势可以当具有基频的频率7或13倍的电流叠加在定子电流上时，可以有效地减小或改变。

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