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1. 发明授权

US5487964A Powder mixtures for metallization of substrate surfaces 失效
标题翻译：用于衬底表面金属化的粉末混合物
公开(公告)号：US5487964A
公开(公告)日：1996-01-30
申请号：US255506
申请日：1994-06-08
申请人： Gunther Reichert , Hans Lietz , Jurgen-Rolf Hassdenteufel , Gunter Sackmann , Frank Kobelka
发明人： Gunther Reichert , Hans Lietz , Jurgen-Rolf Hassdenteufel , Gunter Sackmann , Frank Kobelka
IPC分类号： C09D5/03 , C09D5/46 , C09D7/12 , C09D17/00 , C09D125/14 , C09D167/00 , C23C18/20 , C23C18/30 , G11B7/253 , G11B7/2535 , G11B7/257 , H05K1/09 , H05K9/00
CPC分类号： G11B7/256 , C09D5/033 , C23C18/30 , G11B7/2535
摘要： New spray powder formulations are described which, after application in the form of a thin layer to substrate surfaces with the aid of processes basset on electrostatic attraction and storing of this layer by heat or high-energy radiation, allow the deposition of firmly adhering layers of metal by currentless, wet-chemical metallization. The essential constituents of such a formulation are a pulverulent, non-conductive material and (semi-) noble metal compounds.
摘要翻译：描述了新的喷雾粉末配方，其在以薄膜的形式施加到衬底表面之后，借助于通过热静电吸引并通过热或高能量辐射存储该层的工艺，将沉积在金属通过无电流，湿化学金属化。这种制剂的基本成分是粉状，非导电材料和（半）贵金属化合物。

2. 发明授权

US5356985A Highly-concentrated aqueous polyacrylonitrile emulsions and a method for their preparation 失效
标题翻译：高浓度水性聚丙烯腈乳液及其制备方法
公开(公告)号：US5356985A
公开(公告)日：1994-10-18
申请号：US123256
申请日：1993-09-20
申请人： Gunter Sackmann , Siegfried Korte , Heinrich Alberts , Rolf-Volker Meyer
发明人： Gunter Sackmann , Siegfried Korte , Heinrich Alberts , Rolf-Volker Meyer
IPC分类号： B01F17/52 , C08F2/16 , C08F2/26 , C08F4/30 , C08F4/40 , C08F8/34 , C08F20/42 , C08F20/44 , C08L33/18 , C08L33/20 , D01F6/18 , D01F6/38 , D06P1/52
CPC分类号： D01F6/18 , C08F20/44
摘要： The present invention relates to aqueous emulsions of polymers which contain 80 to 100 weight % of acrylonitrile polymerized within them, to a method for their preparation, and to their use as raw materials for acrylic and modacrylic fibres and as dyeing additives for adjusting the dyestuff affinity of cationic dyestuffs for conventional acrylic and modacrylic polymers and fibre materials produced from them.
摘要翻译：本发明涉及含有80-100重量％的在其内聚合的丙烯腈的聚合物的水性乳液，其制备方法，以及它们作为丙烯酸和改性聚丙烯腈纤维的原料以及用作调节染料亲和力的染色添加剂的用途的用于常规丙烯酸和改性聚丙烯酸聚合物的阳离子染料和由它们生产的纤维材料。

3. 发明授权

US4931510A Polymers from ethylenic monomers 失效
标题翻译：乙烯单体的聚合物
公开(公告)号：US4931510A
公开(公告)日：1990-06-05
申请号：US312089
申请日：1989-02-17
申请人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
发明人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
IPC分类号： C08F210/10 , B01F17/52 , C08F2/24 , C08F8/00 , C08F267/10 , D21H17/34 , D21H19/20 , D21H21/16
CPC分类号： D21H21/16 , C08F267/10 , D21H17/34
摘要： Polymers obtainable by subjecting at least one monomer, polymerizable by free radicals, to a free-radical emulsion polymerization in the presence of a polymer of the formulae I and/or II ##STR1## in which M, n, R, R.sup.1, R.sup.2, x and y have the meanings mentioned in the description, the use of the polymers obtained for surface-sizing of paper or paper-like materials and also novel polymers of the formulae I and/or II.
摘要翻译：聚合物可以通过使至少一种可自由基聚合的单体在式I和/或II的聚合物存在下进行自由基乳液聚合，其中M，n，R R1，R2，x和y具有说明书中提到的含义，用于纸或纸状材料表面施胶的聚合物的用途，以及式I和/或II的新型聚合物。

4. 发明授权

US5635569A Superabsorbent polymers from cross-linked polyacrylonitrile emulsions 失效
标题翻译：来自交联聚丙烯腈乳液的超吸收性聚合物
公开(公告)号：US5635569A
公开(公告)日：1997-06-03
申请号：US512835
申请日：1995-08-09
申请人： Gunter Sackmann , Siegfried Korte , Sergej Schapowalow , Klaus Szablikowski , Wolfgang Koch
发明人： Gunter Sackmann , Siegfried Korte , Sergej Schapowalow , Klaus Szablikowski , Wolfgang Koch
IPC分类号： A61F13/53 , A61F13/49 , A61L15/60 , B01J20/26 , C08F6/06 , C08F6/22 , C08F8/12 , C08F8/44 , D01F6/40 , H01B3/42 , H01B7/282
CPC分类号： A61L15/60 , C08F8/44 , C08F2810/20
摘要： Superabsorbent polymers based on partly hydrolysed homopolymers and/or copolymers of acrylonitrile which are cross-linked through the incorporation of polyfunctional monomers, wherein 30 to 80 mol-% of the nitrile groups are converted into carboxylate groups, 20 to 70 mol-% of the nitrile groups are converted into carbonamide groups and 0 mol-% to 20 mol-% of the nitrile groups are unchanged, and the said cross-linked polymers possess a swelling capacity of 700 g/g in water and of up to 60 g/g in physiological saline and a gel strength of from 20 g to 100 g, their preparation and their use.
摘要翻译：基于部分水解的均聚物和/或丙烯腈共聚物的超吸收聚合物，其通过引入多官能单体而交联，其中30至80mol％的腈基转化为羧酸根，20至70mol％的腈基转化为碳酰胺基，0mol％至20mol％的腈基不变，所述交联聚合物在水中的溶胀能力为700g / g，高达60g / g 在生理盐水中，凝胶强度为20g至100g，其制备及其用途。

5. 发明授权

US4670516A Copolymers based on maleic anhydride and .alpha., .beta.-unsaturated compounds a process for their preparation and their use as paraffin inhibitors 失效
标题翻译：基于马来酸酐和α，β-不饱和化合物的共聚物，其制备方法及其作为石蜡抑制剂的用途
公开(公告)号：US4670516A
公开(公告)日：1987-06-02
申请号：US700411
申请日：1985-02-11
申请人： Gunter Sackmann , Jan Mazanek , Wolfgang Oberkirch , Herbert Bartl
发明人： Gunter Sackmann , Jan Mazanek , Wolfgang Oberkirch , Herbert Bartl
IPC分类号： C08F8/32 , C08F8/44 , C10L1/196 , C10L1/236
CPC分类号： C10L1/1966 , C08F8/32 , C08F8/44 , C10L1/2364
摘要： The new copolymers based on maleic anhydride and .alpha.,.beta.-unsaturated compounds contain, as bivalent structural units,A: 20 to 95 mole % of the structural element ##STR1## B: 0 to 40 mole % of the structural element ##STR2## C: and 0 to 40 mole % of the structural element ##STR3## the sum of the mole percents of (A), (B) and (C) being 100, and wherein R.sup.1 and R.sup.2 are identical or different and denote hydrogen, alkyl, optionally substituted aryl or the ester group ##STR4## in which R.sup.4 represents alkyl with 1 to 20 carbon atoms,R.sup.3 denotes an alkyl, cycloalkyl or optionally substituted aryl radical with 1 to 20 carbon atoms andX and Y are identical or different and represent the group--O--R.sup.5in whichR.sup.5 denotes hydrogen, a cation or alkyl with 1 to 40 carbon atoms, orX and Y represent the group--NHR.sup.3in which R.sup.3 has the abovementioned meaning,at least one of the radicals X and Y representing the group --O--R.sup.5, and at least one of the radicals in the radicals X and Y containing at least 18 carbon atoms.The new copolymers can be prepared by reacting alternating copolymers of maleic anhydride and .alpha.,.beta.-unsaturated compounds with monoalcohols and monoamines. They can be used as paraffin inhibitors.
摘要翻译：基于马来酸酐和α，β-不饱和化合物的新共聚物含有作为二价结构单元的A：20至95摩尔％的结构元素B：0至40摩尔％的结构元素：（A），（B）和（C）的摩尔百分数的总和为100，其中R 1和R 2相同或不同，表示氢，烷基，任选取代的芳基或其中R 4表示具有1至20个碳原子的烷基的酯基“IMAGE”，R 3表示具有1至20个碳原子的烷基，环烷基或任选取代的芳基，X和Y相同或不同，基团-O-R5，其中R5表示氢，阳离子或具有1至40个碳原子的烷基，或X和Y表示其中R3具有上述含义的基团-NHR 3，基团X和Y中的至少一个表示基团-O-R5，并且基团X和Y中的至少一个基团含有至少1个 8个碳原子。新的共聚物可以通过使马来酸酐和α，β-不饱和化合物的交替共聚物与一元醇和单胺反应来制备。它们可以用作石蜡抑制剂。

6. 发明授权

US4596863A N-alkylimide copolymers and their use as sizing agents 失效
标题翻译： N-烷基酰亚胺共聚物及其作为上浆剂的用途
公开(公告)号：US4596863A
公开(公告)日：1986-06-24
申请号：US607103
申请日：1984-05-04
申请人： Gunter Sackmann , Ulrich Beck , Heinz Baumgen
发明人： Gunter Sackmann , Ulrich Beck , Heinz Baumgen
IPC分类号： C08F8/14 , C08F8/32 , D21H17/43 , C08F22/40 , D21D3/00
CPC分类号： C08F8/14 , C08F8/32 , D21H17/43
摘要： The present invention relates to new copolymers based on maleic anhydride/.alpha.,.beta.-unsaturated compounds and characterized in that they consist of(A) 10 to 40 mol percent of the structural element ##STR1## (B) 40 to 80 mol percent of the structural element ##STR2## and (C) 10 to 50 mol percent of the structural element ##STR3## where the total of mol percentages of (A), (B) and (C) is 100 and whereR.sub.1 =hydrogen or alkyl,R.sub.2 =hydrogen, alkyl or optionally substituted aryl,R.sub.3 =a hydrocarbon radical having 10 to 22 C atoms,R.sub.4 =a hydrocarbon radical having 10 to 22 C atoms, andX=an oxygen atom or an NR.sub.5 group where R.sub.5 represents a hydrocarbon radical having 1 to 18 C atoms.The copolymers in question are excellent active ingredients for sizing agents for paper and are suitable not only for pulp-sizing but also for surface-sizing.
摘要翻译：本发明涉及基于马来酸酐/α，β-不饱和化合物的新共聚物，其特征在于它们由（A）10〜40摩尔％的结构单元组成（I）（B）40〜80摩尔（A），（B）和（C）的总摩尔百分数为100的结构单元（II）和（C）的10〜50摩尔％的结构单元的百分比（IMA）并且其中R 1 =氢或烷基，R 2 =氢，烷基或任选取代的芳基，R 3 =具有10-22个碳原子的烃基，R4 =具有10-22个碳原子的烃基，X =氧原子或 NR5基，其中R5表示具有1至18个C原子的烃基。所述共聚物是用于纸张的上浆剂的优异活性成分，并且不仅适用于浆浆施胶，而且适用于表面施胶。

7. 发明授权

US4048422A Production of copolymer powders from maleic anhydride and 1-olefins 失效
标题翻译：从马来酸酐和1-烯烃制备共聚物粉末
公开(公告)号：US4048422A
公开(公告)日：1977-09-13
申请号：US647502
申请日：1976-01-08
申请人： Gunter Sackmann , Gunter Kolb , Friedhelm Muller
发明人： Gunter Sackmann , Gunter Kolb , Friedhelm Muller
IPC分类号： C08F2/00 , C08F2/08 , C08F2/18 , C08F2/24 , C08F8/00 , C08F8/14 , C08F8/32 , C08F210/00 , C08F212/00 , C08F212/08 , C08F220/00 , C08F220/04 , C08F222/06 , C08L21/00 , C08F1/09 , C08F15/02
CPC分类号： C08F222/06 , C08F210/00 , C08F212/08 , C08L21/00
摘要： An improved process for the production of powders of maleic acid anhydride/1-olefin copolymers by suspension polymerization in the presence of special dispersion agents which are obtained by the reaction of a copolymer of maleic acid anhydride and a 1-olefin with an aliphatic monohydric alcohol or an aliphatic monoamine or a mixture thereof, at least 30 mol % of the anhydride groups being esterified to semi-esters or amidated to semi-amides. The copolymer powders obtained have a surprisingly narrowparticle size distribution and can be used without grinding or sifting as reactive fillers for natural and synthetic rubbers. They also can be used for the production of paper coating agents as they dissolve easily and without residue in alkalis, ammonia or amines.
摘要翻译：在马来酸酐与1-烯烃的共聚物与脂族一元醇反应得到的特殊分散剂存在下，通过悬浮聚合制备马来酸酐/ 1-烯烃共聚物粉末的改进方法或脂族单胺或其混合物，至少30mol％的酸酐基团被酯化成半酯或半酰胺化。获得的共聚物粉末具有令人惊讶的窄粒度分布，并且可以在不用作天然和合成橡胶的反应性填料的研磨或筛分下使用。它们也可用于生产纸张涂层剂，因为它们容易溶解，在碱，氨或胺中没有残留物。

8. 发明授权

US4614759A Surface sizing agents for paper 失效
标题翻译：纸表面施胶剂
公开(公告)号：US4614759A
公开(公告)日：1986-09-30
申请号：US762601
申请日：1985-08-05
申请人： Gunter Sackmann , Ulrich Beck , Heinz Baumgen
发明人： Gunter Sackmann , Ulrich Beck , Heinz Baumgen
IPC分类号： D21H17/37 , C08F8/14 , D21H17/43 , C08L35/02
CPC分类号： C08F8/14 , D21H17/43
摘要： Surface sizing agents for paper containing aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers of maleic anhydride and diisobutylene and, if appropriate, a vinyl monomer of the formula ##STR1## in which R designates H, --CH.sub.3, --C.sub.2 H.sub.5, --OR.sub.2, --OCOCH.sub.3, ##STR2## or --CH.sub.2 --O--COCH.sub.3, R.sub.1 designates H or --CH.sub.3 andR.sub.2 designates alkyl, the anhydride groups of the copolymers being bis-esterified to the extent of 25-90 mol % with primary aliphatic monoalcohols with 1 to 12 C atoms.
摘要翻译：含有水性或水性醇碱金属的纸的表面施胶剂，马来酸酐和二异丁烯的共聚物的胺或铵盐溶液，以及如果合适的话，其中R表示H，-CH 3， -C2H5，-OR2，-OCOCH3，...或-CH2-O-COCH3，R1表示H或-CH3，R2表示烷基，共聚物的酸酐基被双酯化至25〜90摩尔％具有1至12个C原子的伯脂族一元醇。

9. 发明授权

US4151336A Process for the production of a substantially equimolecular copolymer of maleic acid anhydride and diisobutylene 失效
标题翻译：用于生产马来酸酐和二异丁烯基本上等摩尔分子共聚物的方法
公开(公告)号：US4151336A
公开(公告)日：1979-04-24
申请号：US869043
申请日：1978-01-13
申请人： Gunter Sackmann , Gunter Kolb , Heinz Fischer , Friedhelm Muller
发明人： Gunter Sackmann , Gunter Kolb , Heinz Fischer , Friedhelm Muller
IPC分类号： C08F2/00 , C08F8/14 , C08F10/00 , C08F10/14 , C08F20/00 , C08F20/02 , C08F210/14 , C08F220/04 , C08F222/06 , D21H17/37 , D21H17/43 , C08F6/06 , C08F6/24
CPC分类号： C08F222/06 , C08F210/14 , D21H17/43
摘要： An improved process for the production of a substantially equimolecular copolymer of maleic acid anhydride and diisobutylene in which from 10 to 100 mole % of the anhydride groups are esterified with linear or branched aliphatic monoalcohols containing from 1 to 20 carbon atoms or with cycloaliphatic monoalcohols containing from 5 to 6 carbon atoms to form the corresponding semiesters, wherein shortly before or after the end of the solution or suspension copolymerization of maleic acid anhydride and diisobutylene a monomer corresponding to the general formula ##STR1## in which R=H, CH.sub.3, C.sub.2 H.sub.5, --OR.sub.2, --O--CO--CH.sub.3, ##STR2## --CH.sub.2 OH, --CH.sub.2 O--C--CH.sub.3, R.sub.1 =H , CH.sub.3 andR.sub.2 =a linear or branched alkyl group containing from 1 to 4 carbon atoms,Or mixtures of these monomers with one another are added to the polymerization mixture in quantities of from 1 to 12 mole %, based on the maleic acid anhydride used. The aqueous or aqueous-alcoholic alkali, amine or ammonium salt solutions of the semiesters of the copolymer are highly effective as anionic sizing agents for paper.
摘要翻译：用于生产马来酸酐和二异丁烯的基本上等分子的共聚物的改进方法，其中10至100摩尔％的酸酐基团被含有1至20个碳原子的直链或支链脂族一元醇或含有1至20个碳原子的脂环族一元醇酯化 5至6个碳原子以形成相应的半分子，其中在马来酸酐和二异丁烯的溶液或悬浮液共聚之前或之后不久，对应于通式为“IMAGE”的单体，其中R = H，CH 3，C 2 H 5， -OR 2，-O-CO-CH 3， -CH 2 OH，-CH 2 O-C-CH 3，R 1 = H，CH 3和R 2 =含有1至4个碳原子的直链或支链烷基，或这些单体的混合物另有一种添加到1至12％MOES％的聚合物混合物中，基于所用的非水性非离子表面活性剂。共聚物的半酯的水性或水性醇碱性，胺或铵盐溶液作为纸张的阴离子施胶剂是非常有效的。

10. 发明授权

US4113506A Emulsions of resinic acid isocyanates as sizing agents for paper 失效
标题翻译：作为纸张尺寸代理的树脂异氰酸酯的乳液
公开(公告)号：US4113506A
公开(公告)日：1978-09-12
申请号：US749455
申请日：1976-12-10
申请人： Gunter Sackmann , Udo-Winfried Hendricks , Hans-Ludwig Honig , Gunter Kolb , Friedhelm Muller
发明人： Gunter Sackmann , Udo-Winfried Hendricks , Hans-Ludwig Honig , Gunter Kolb , Friedhelm Muller
IPC分类号： D21H17/21 , C08G18/71 , C08J3/05 , D21H17/08 , D21H17/62 , C08J3/02
CPC分类号： C08J3/05 , C08G18/71 , D21H17/08 , D21H17/62 , C08J2393/00
摘要： Stable aqueous emulsions comprising a resinic acid isocyanate, a non-ionic and/or anionic emulsifier and an optionally chlorinated hydrocarbon are used as sizing agents for paper or paper-like materials.

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