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1. 发明授权

US4931510A Polymers from ethylenic monomers 失效
标题翻译：乙烯单体的聚合物
公开(公告)号：US4931510A
公开(公告)日：1990-06-05
申请号：US312089
申请日：1989-02-17
申请人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
发明人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
IPC分类号： C08F210/10 , B01F17/52 , C08F2/24 , C08F8/00 , C08F267/10 , D21H17/34 , D21H19/20 , D21H21/16
CPC分类号： D21H21/16 , C08F267/10 , D21H17/34
摘要： Polymers obtainable by subjecting at least one monomer, polymerizable by free radicals, to a free-radical emulsion polymerization in the presence of a polymer of the formulae I and/or II ##STR1## in which M, n, R, R.sup.1, R.sup.2, x and y have the meanings mentioned in the description, the use of the polymers obtained for surface-sizing of paper or paper-like materials and also novel polymers of the formulae I and/or II.
摘要翻译：聚合物可以通过使至少一种可自由基聚合的单体在式I和/或II的聚合物存在下进行自由基乳液聚合，其中M，n，R R1，R2，x和y具有说明书中提到的含义，用于纸或纸状材料表面施胶的聚合物的用途，以及式I和/或II的新型聚合物。

2. 发明授权

US5288787A Emulsion polymers 失效
标题翻译：乳液聚合物
公开(公告)号：US5288787A
公开(公告)日：1994-02-22
申请号：US714317
申请日：1991-06-10
申请人： Gunter Sackmann , Wolfgang Henning , Joachim Probst , Joachim Konig , Heinz Baumgen
发明人： Gunter Sackmann , Wolfgang Henning , Joachim Probst , Joachim Konig , Heinz Baumgen
IPC分类号： C08F2/26 , C08F220/12 , D21H17/34 , C08K3/20
CPC分类号： D21H17/34 , C08F2/26 , C08F220/12
摘要： Emulsion polymers obtainable by emulsifying a mixture consisting ofA) 5 to 95 % by weight of at least one monomer from the series consisting of acrylonitrile, methacrylonitrile, optionally substituted styrene, vinyl carboxylate andB) 5 to 95 % by weight of acrylic and/or methacrylic esters,the sum of components A)+B) being 100% by weight, in the presence of an aqueous solution or dispersion of an anionically modified polyurethane, preferably containing --SO.sub.3.sup.-Me.sup.+ and/or -COO.sup.- Me.sup.+ groups (Me.sup.+ =cation, preferably H.sup.+, Na.sup.+, K.sup.+, Li.sup.+, NH.sub.4.sup.+ or a substituted ammonium ion), and subjecting the resulting emulsion to a polymerization initiated by free radicals.The emulsion polymers produced are preferably used as surface sizing agents for paper.
摘要翻译：通过乳化由A）5-95重量％的至少一种由丙烯腈，甲基丙烯腈，任选取代的苯乙烯，乙烯基羧酸酯组成的系列中的至少一种单体的混合物得到的乳液聚合物和B）5-95重量％的丙烯酸和/ 或甲基丙烯酸酯，组分A）+ B的总和）为100重量％，在阴离子改性聚氨酯的水溶液或分散体存在下，优选含有-SO 3 Me +和/或-COO-Me +基团（Me + =阳离子，优选H +，Na +，K +，Li +，NH 4 +或取代的铵离子），并将所得乳液进行由自由基引发的聚合。所生产的乳液聚合物优选用作纸的表面施胶剂。

3. 发明授权

US4771097A Tub sizes for paper 失效
标题翻译：纸的尺寸
公开(公告)号：US4771097A
公开(公告)日：1988-09-13
申请号：US26340
申请日：1987-03-16
申请人： Gunter Sackmann , Ulrich Beck , Joachim Konig , Heinz Baumgen , Klaus-Dieter Albrecht
发明人： Gunter Sackmann , Ulrich Beck , Joachim Konig , Heinz Baumgen , Klaus-Dieter Albrecht
IPC分类号： C08F8/44 , C08F8/14 , C08L35/00 , D21H17/43 , D21H19/20 , D21H21/16 , C08L35/02
CPC分类号： C08F8/14 , D21H17/43 , D21H21/16
摘要： Tub sizes for paper, containing aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers of maleic anhydride and diisobutylene and, if appropriate, a vinyl monomer of the formula ##STR1## in which R designates H, --CH.sub.3, --C.sub.2 H.sub.5, --OR.sub.2, --OCOCH.sub.3, ##STR2## --CH.sub.2 OH or --CH.sub.2 --O--COCH.sub.3, R.sub.1 designates H or --CH.sub.3 andR.sub.2 designates alkyl,the anhydride groups of the copolymers being bis-esterified to the extent of about 3 to about 20 mol %, relative to the anhydride groups, with aliphatic monoalcohols having 1 to 12 C atoms.
摘要翻译：用于含有水性或含水醇碱金属的纸的桶尺寸，马来酸酐和二异丁烯的共聚物的胺或铵盐溶液，以及如果合适的话，其中R表示H，-CH 3， C 2 H 5，-OR 2，-OCOCH 3，-CH 2 OH或-CH 2 -O-COCH 3，R 1表示H或-CH 3，R 2表示烷基，所述共聚物的酸酐基团被双酯化至约3至约相对于酸酐基团为20摩尔％，具有1至12个碳原子的脂肪族一元醇。

4. 发明授权

US5258466A Paper size 失效
标题翻译：纸张尺寸
公开(公告)号：US5258466A
公开(公告)日：1993-11-02
申请号：US713923
申请日：1991-06-12
申请人： Gunter Sackmann , Joachim Konig , Fritz Puchner , Heinz Baumgen
发明人： Gunter Sackmann , Joachim Konig , Fritz Puchner , Heinz Baumgen
IPC分类号： C08F2/24 , C08F2/26 , C08F267/10 , D21H17/42 , C08F20/10 , C08F22/06
CPC分类号： D21H17/42 , C08F267/10
摘要： Emulsion polymers which are prepared by free-radical polymerisation of monomers in the presence ofa) polymers of the formulae ##STR1## wherein the radicals have the meanings given in the description, and b) low-molecular anionic emulsifiers,are outstandingly suitable as surface sizes for paper. They are distinguished by a low tendency to foaming and by a wide application spectrum.
摘要翻译：通过在a）式（I）的聚合物（II）的存在下，通过单体的自由基聚合制备的乳液聚合物，其中基团具有在说明书中给出的含义，和b）分子阴离子乳化剂，非常适合作为纸张的表面尺寸。它们的特征在于低发泡趋势和广泛的应用范围。

5. 发明授权

US5013794A Polymers of diisobutylene-sulfonate alkane maleic acid derivatives 失效
标题翻译：二异丁烯磺酸烷烃马来酸衍生物的聚合物
公开(公告)号：US5013794A
公开(公告)日：1991-05-07
申请号：US475623
申请日：1990-02-06
申请人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
发明人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
IPC分类号： C08F267/10 , D21H17/34 , D21H21/16
CPC分类号： C08F267/10 , D21H17/34 , D21H21/16
摘要： Polymers obtainable by subjecting at least one monomer, polymerizable by free radicals, to a free-radical emulsion polymerization in the presence of a polymer of the formulae I and/or II ##STR1## in which M, n, R, R.sup.1, R.sup.2, x and y have the meanings mentioned in the description, the use of the polymers obtained for surface-sizing of paper or paper-like materials and also novel polymers of the formulae I and/or II.
摘要翻译：聚合物可以通过使至少一种可自由基聚合的单体在式I和/或II的聚合物存在下进行自由基乳液聚合，其中M，n，R R1，R2，x和y具有说明书中提到的含义，用于纸或纸状材料表面施胶的聚合物的用途，以及式I和/或II的新型聚合物。

6. 发明授权

US4614759A Surface sizing agents for paper 失效
标题翻译：纸表面施胶剂
公开(公告)号：US4614759A
公开(公告)日：1986-09-30
申请号：US762601
申请日：1985-08-05
申请人： Gunter Sackmann , Ulrich Beck , Heinz Baumgen
发明人： Gunter Sackmann , Ulrich Beck , Heinz Baumgen
IPC分类号： D21H17/37 , C08F8/14 , D21H17/43 , C08L35/02
CPC分类号： C08F8/14 , D21H17/43
摘要： Surface sizing agents for paper containing aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers of maleic anhydride and diisobutylene and, if appropriate, a vinyl monomer of the formula ##STR1## in which R designates H, --CH.sub.3, --C.sub.2 H.sub.5, --OR.sub.2, --OCOCH.sub.3, ##STR2## or --CH.sub.2 --O--COCH.sub.3, R.sub.1 designates H or --CH.sub.3 andR.sub.2 designates alkyl, the anhydride groups of the copolymers being bis-esterified to the extent of 25-90 mol % with primary aliphatic monoalcohols with 1 to 12 C atoms.
摘要翻译：含有水性或水性醇碱金属的纸的表面施胶剂，马来酸酐和二异丁烯的共聚物的胺或铵盐溶液，以及如果合适的话，其中R表示H，-CH 3， -C2H5，-OR2，-OCOCH3，...或-CH2-O-COCH3，R1表示H或-CH3，R2表示烷基，共聚物的酸酐基被双酯化至25〜90摩尔％具有1至12个C原子的伯脂族一元醇。

7. 发明授权

US4596863A N-alkylimide copolymers and their use as sizing agents 失效
标题翻译： N-烷基酰亚胺共聚物及其作为上浆剂的用途
公开(公告)号：US4596863A
公开(公告)日：1986-06-24
申请号：US607103
申请日：1984-05-04
申请人： Gunter Sackmann , Ulrich Beck , Heinz Baumgen
发明人： Gunter Sackmann , Ulrich Beck , Heinz Baumgen
IPC分类号： C08F8/14 , C08F8/32 , D21H17/43 , C08F22/40 , D21D3/00
CPC分类号： C08F8/14 , C08F8/32 , D21H17/43
摘要： The present invention relates to new copolymers based on maleic anhydride/.alpha.,.beta.-unsaturated compounds and characterized in that they consist of(A) 10 to 40 mol percent of the structural element ##STR1## (B) 40 to 80 mol percent of the structural element ##STR2## and (C) 10 to 50 mol percent of the structural element ##STR3## where the total of mol percentages of (A), (B) and (C) is 100 and whereR.sub.1 =hydrogen or alkyl,R.sub.2 =hydrogen, alkyl or optionally substituted aryl,R.sub.3 =a hydrocarbon radical having 10 to 22 C atoms,R.sub.4 =a hydrocarbon radical having 10 to 22 C atoms, andX=an oxygen atom or an NR.sub.5 group where R.sub.5 represents a hydrocarbon radical having 1 to 18 C atoms.The copolymers in question are excellent active ingredients for sizing agents for paper and are suitable not only for pulp-sizing but also for surface-sizing.
摘要翻译：本发明涉及基于马来酸酐/α，β-不饱和化合物的新共聚物，其特征在于它们由（A）10〜40摩尔％的结构单元组成（I）（B）40〜80摩尔（A），（B）和（C）的总摩尔百分数为100的结构单元（II）和（C）的10〜50摩尔％的结构单元的百分比（IMA）并且其中R 1 =氢或烷基，R 2 =氢，烷基或任选取代的芳基，R 3 =具有10-22个碳原子的烃基，R4 =具有10-22个碳原子的烃基，X =氧原子或 NR5基，其中R5表示具有1至18个C原子的烃基。所述共聚物是用于纸张的上浆剂的优异活性成分，并且不仅适用于浆浆施胶，而且适用于表面施胶。

8. 发明授权

US4568421A Monofluorotriazinyl compounds, processes for their preparation and their use as sizing agents 失效
标题翻译：单氟三嗪化合物，其制备方法及其作为施胶剂的用途
公开(公告)号：US4568421A
公开(公告)日：1986-02-04
申请号：US537476
申请日：1983-09-30
申请人： Gunter Sackmann , Horst Jager , Ulrich Beck , Heinz Baumgen
发明人： Gunter Sackmann , Horst Jager , Ulrich Beck , Heinz Baumgen
IPC分类号： C07D251/38 , C07D251/50 , D21H17/03 , D21H17/09 , D21H17/11 , D21H19/10 , D21H3/12
CPC分类号： C07D251/50 , D21H17/09 , D21H17/11
摘要： New monofluorotriazinyl compounds of the formula ##STR1## wherein R.sup.1 and R.sup.2 can be identical or different and represent a hydrocarbon radical with 12 to 24 C atoms andX represents an oxygen atom, a sulphur atom or the group NR.sup.3,whereinR.sup.3 denotes hydrogen or a hydrocarbon radical with 1 to 24 C atoms.In formula (1), the hydrocarbon radicals R.sup.1 and R.sup.2 preferably represent linear or branched alkyl (C.sub.12 -C.sub.24), cycloalkyl (C.sub.12 -C.sub.24) or aromatic radicals with fused-on hydroaromatic systems with 12 to 24 C atoms. The hydrocarbon radical R.sup.3 is preferably one of the abovementioned substituents or methyl.The compounds of the formula (1) are suitable as effective components in reactive sizing agents for paper.
摘要翻译：新颖的式（IMAGE）的单氟三嗪化合物，其中R 1和R 2可相同或不同，表示具有12至24个C原子的烃基，X表示氧原子，硫原子或基团NR 3，其中R 3表示氢或具有1至24个C原子的烃基。在式（1）中，烃基R 1和R 2优选表示具有12至24个C原子的具有稠合的氢芳族体系的直链或支链烷基（C 12 -C 24），环烷基（C 12 -C 24）或芳族基团。烃基R 3优选为上述取代基之一或甲基。式（1）的化合物适用于纸张的反应性施胶剂中的有效成分。

9. 发明授权

US4481319A Low-foam surface sizing agents for paper which contain copolymeric _maleic anhydride semi-amides 失效
标题翻译：用于含有共聚马来酸酐半酰胺的纸的低泡表面施胶剂
公开(公告)号：US4481319A
公开(公告)日：1984-11-06
申请号：US410906
申请日：1982-08-24
申请人： Gunter Sackmann , Gunter Kolb , Joachim Probst , Friedhelm Muller , Heinz Baumgen
发明人： Gunter Sackmann , Gunter Kolb , Joachim Probst , Friedhelm Muller , Heinz Baumgen
IPC分类号： C08F8/32 , D21H17/35 , D21H17/43 , D21H17/45 , C08K5/21 , C08K5/05
CPC分类号： D21H17/45 , C08F8/32 , D21H17/35 , D21H17/43
摘要： Low-foam surface sizing agents for paper in the form of aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers containing carboxylic acid semi-amide groups obtainable by reacting copolymers of maleic acid anhydride and diisobutylene and/or terpolymers of maleic acid anhydride, diisobutylene and a vinyl monomer copolymerizing with maleic acid anhydride, with from 5 to 50 mole percent, based on maleic acid anhydride groups, of a primary aliphatic or aromatic monoamine. The solutions may optionally contain urea or derivatives of urea.
摘要翻译：水性或水性醇碱金属形式的纸的低泡表面施胶剂，含有羧酸半酰胺基团的共聚物的胺或铵盐溶液，可通过马来酸酐和二异丁烯的共聚物和/或马来酸三元共聚物与马来酸酐共聚的酸酐，二异丁烯和乙烯基单体，基于马来酸酐基团的5-50摩尔％的伯脂肪族或芳族单胺。溶液可以任选地含有脲或尿素衍生物。

10. 发明授权

US5356985A Highly-concentrated aqueous polyacrylonitrile emulsions and a method for their preparation 失效
标题翻译：高浓度水性聚丙烯腈乳液及其制备方法
公开(公告)号：US5356985A
公开(公告)日：1994-10-18
申请号：US123256
申请日：1993-09-20
申请人： Gunter Sackmann , Siegfried Korte , Heinrich Alberts , Rolf-Volker Meyer
发明人： Gunter Sackmann , Siegfried Korte , Heinrich Alberts , Rolf-Volker Meyer
IPC分类号： B01F17/52 , C08F2/16 , C08F2/26 , C08F4/30 , C08F4/40 , C08F8/34 , C08F20/42 , C08F20/44 , C08L33/18 , C08L33/20 , D01F6/18 , D01F6/38 , D06P1/52
CPC分类号： D01F6/18 , C08F20/44
摘要： The present invention relates to aqueous emulsions of polymers which contain 80 to 100 weight % of acrylonitrile polymerized within them, to a method for their preparation, and to their use as raw materials for acrylic and modacrylic fibres and as dyeing additives for adjusting the dyestuff affinity of cationic dyestuffs for conventional acrylic and modacrylic polymers and fibre materials produced from them.
摘要翻译：本发明涉及含有80-100重量％的在其内聚合的丙烯腈的聚合物的水性乳液，其制备方法，以及它们作为丙烯酸和改性聚丙烯腈纤维的原料以及用作调节染料亲和力的染色添加剂的用途的用于常规丙烯酸和改性聚丙烯酸聚合物的阳离子染料和由它们生产的纤维材料。

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