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1. 发明授权

US5227477A Dyes having one or two 2,4- or 4,6-dichloro-5-cyanopyrimidyl groups linked through bridging radicals containing at least two nitrogen atoms to chloro-1,3,5-triazinyl groups 失效
标题翻译：具有一个或两个通过含有至少两个氮原子的桥连基团连接的2,4-或4,6-二氯-5-氰基嘧啶基的染料与氯-1,3,5-三嗪基
公开(公告)号：US5227477A
公开(公告)日：1993-07-13
申请号：US736196
申请日：1991-07-26
申请人： Gunther Auerbach , Kurt Brenneisen , Markus Doerr , Paul Doswald , Markus Gisler , Werner Koch , Helmut A. Moser , Roland Wald
发明人： Gunther Auerbach , Kurt Brenneisen , Markus Doerr , Paul Doswald , Markus Gisler , Werner Koch , Helmut A. Moser , Roland Wald
IPC分类号： C09B62/02
CPC分类号： C09B62/02
摘要： Metal-free compounds of the formula ##STR1## a 1:1 or 1:2 metal complex of a metallizable compound of said formula or a salt of a metal-free compound of said formula or of a 1:1 or 1:2 metal complex thereof each cation of which is independently a non-chromophoric cation, or a mixture, thereof, whereinF.sub.c is the radical of a water-soluble azo, formazan, phthalocyanine, azomethine, oxazine, thiazine, phenazine or triphenylmethane dye,each W is independently --NR.sub.1 --B.sub.1 --NR.sub.1 --, ##STR2## wherein B.sub.1 is linear or branched C.sub.2-6 alkylene; linear or branched C.sub.2-6 alkylene interrupted by --O-- or --NR.sub.1 --; linear or branched C.sub.3-6 alkylene monosubstituted by hydroxy or carboxy or disubstituted by hydroxy, ##STR3## wherein R.sub.2 is hydrogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, carboxy or sulfo, andn is 0, 1, 2, 3 or 4, andm is 0 or 1,each X is independently a direct bond, --CO-- or --SO.sub.2 --,each a is independently 0 or 1, and b is 1 or 2,whereineach Alk is independently linear or branched C.sub.2-4 alkylene, andeach R.sub.1 is independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by hydroxy, halo, sulfo, sulfato or carboxy,with the proviso that the hydroxy groups of each alkylene radical substituted by two hydroxy groups are attached to different carbon atoms, useful for dyeing and printing hydroxy group- and nitrogen-containing organic substrates, for example, leather and fibrous materials comprising, natural, or synthetic polyamides or natural or regenerated cellulose, especially textile materials comprising cotton.
摘要翻译：所述式的金属化化合物或所述式的金属化合物或1：1或1：2金属的盐的1：1或1：2金属配合物的金属化合物其复合物各自独立地是非发色阳离子或其混合物，其中Fc是水溶性偶氮，甲an，酞菁，偶氮甲碱，恶嗪，噻嗪，吩嗪或三苯甲烷染料的基团，每个W是独立地是-NR1-B1-NR1-，其中B1是直链或支链的C 2-6亚烷基; 由-O-或-NR1-中断的直链或支链C 2-6亚烷基; 被羟基或羧基单取代或被羟基二取代的直链或支链C 3-6亚烷基，其中R 2是氢，C 1-4烷基，C 1-4烷氧基，羧基或磺基，n是0,1,2,3或4，和 m为0或1，每个X独立地为直接键，-CO-或-SO 2 - ，各a独立地为0或1，b为1或2，其中每个Alk独立地为直链或支链C 2-4亚烷基，和每个R 1独立地是氢，C 1-4烷基或被羟基，卤素，磺基，硫酸根或羧基单取代的C 1-4烷基，条件是被两个羟基取代的每个亚烷基的羟基连接到不同的碳原子上，可用于染色和印刷羟基和含氮有机基材，例如包含天然或合成聚酰胺或天然或再生纤维素，特别是包含棉花的纺织材料的皮革和纤维材料。

2. 发明授权

US5527886A Dyes containing 5-cyano-2,4 or 4,6-dichloropyrimidyl fiber-reactive groups 失效
标题翻译：染料含有5-氰基-2,4或4,6-二氯嘧啶基纤维反应性基团
公开(公告)号：US5527886A
公开(公告)日：1996-06-18
申请号：US899570
申请日：1992-06-16
申请人： Gunther Auerbach , Markus Dorr , Paul Doswald , Markus Gisler , Werner Koch , Helmut A. Moser , Roland Wald
发明人： Gunther Auerbach , Markus Dorr , Paul Doswald , Markus Gisler , Werner Koch , Helmut A. Moser , Roland Wald
IPC分类号： C09B62/44 , C09B62/08 , C07F3/10 , C07F9/02
CPC分类号： C09B62/4422
摘要： Fiber-reactive compounds of the formulaX-O.sub.2 S-W.sub.1 [F.sub.c ]W.sub.2 -NR-Z,and water-soluble salts thereof each cation of which is independently a non-chromophoric cation, and mixtures of such compounds or water-soluble salts,whereinFc is a chromophore-containing radical of a monoazo, disazo, polyazo, formazan, anthraquinone, dioxazine, phenazine or azomethine dye, which is in metal-free or metal complex form,each of W.sub.1 and W.sub.2 is independently a direct bond or a bridging group which is attached to a carbon atom of an aromatic carbocyclic ring or to a carbon or nitrogen atom of an aromatic heterocyclic ring present in F.sub.c,X is --CH.dbd.CH.sub.2 or --C.sub.2-4 alkylene--Y, wherein Y is hydroxy or a group which can be split off under alkaline conditions,R is hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by hydroxy, halo, cyano, --SO.sub.3 H, --OSO.sub.3 H or --COOH, andZ is ##STR1## with the provisos as set forth herein.
摘要翻译：式X-O 2 S-W1 [Fc] W2-NR-Z的纤维反应性化合物及其各自阳离子独立地是非发色阳离子的水溶性盐，以及这些化合物或水溶性盐的混合物，其中Fc是含有金属或金属络合物形式的单偶氮，二偶氮，多偶氮，甲an，蒽醌，二恶嗪，吩嗪或偶氮甲碱染料的含发色团的基团，W1和W2各自独立地为直接键或连接于芳香族碳环的碳原子或存在于Fc中的芳香族杂环的碳原子或氮原子上的桥连基团，X为-CH = CH 2或-C 2-4亚烷基-Y，其中Y为羟基或基团可以在碱性条件下分离，R是氢，C 1-4烷基或被羟基，卤素，氰基，-SO 3 H，-OSO 3 H或-COOH单取代的C 1-4烷基，Z是，条件是如上所述这里。

3. 发明授权

US5084068A Dyes containing two phthalocyanine groups linked by a radical containing two quaternized nitrogen atoms 失效
标题翻译：含有两个季铵盐化合物的两个PHTHOCOCANANINE组合的染料
公开(公告)号：US5084068A
公开(公告)日：1992-01-28
申请号：US484583
申请日：1990-02-23
申请人： Helmut A. Moser , Roland Wald
发明人： Helmut A. Moser , Roland Wald
IPC分类号： C09B47/26 , C09B47/32 , C09B62/537 , C09B67/32 , D06P3/02 , D06P3/30 , D06P3/60 , D21H21/28
CPC分类号： C09B47/32 , Y10S8/919
摘要： Compounds of the formula ##STR1## and mixtures thereof, whereineach Mt is independently copper, nickel or cobalt,each Pc is the phthalocyanine radical,each R.sub.4 is independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by hydroxy,each R.sub.5 and R.sub.6 is independently C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by halo, cyano, hydroxy or phenyl; or C.sub.5-6 cycloalkyl,each W.sub.1 is independently --A--.sup..sym. NR.sub.1 R.sub.2 R.sub.3 An.sup..crclbar. or --A--NR.sub.2 R.sub.3, wherein R.sub.1 is hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by halo, cyano, hydroxy or phenyl; or C.sub.5-6 cycloalkyl, andeach of R.sub.2 and R.sub.3 is independently C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by halo, cyano, hydroxy or phenyl; or C.sub.5-6 cycloalkyl,Y is a divalant radical linked to each of the two quarternized nitrogen atoms by an aliphatic carbon atom,each M is independently hydrogen or a non-chromophoric cation,each of m and m' is independently 0 or 1,each of n and n' is independently 1, 2 or 3, and p is 1 or 2, with the provisos that m+n+p.ltoreq.4, and m'+n'+p.ltoreq.4,whereineach A is independently linear or branched C.sub.2-6 alkylene or linear or branched C.sub.3-6 alkylene monosubstituted by hydroxy, andeach An.sup..crclbar. is independently a non-chromophoric anion, liquid and solid dye compositions comprising them and their use for dyeing and printing hydroxy group- and nitrogen-containing organic substrates, particularly textile materials comprising cellulose, especially cotton, bast fibres, leather and paper.
摘要翻译：式中的化合物及其混合物，其中每个Mt独立地为铜，镍或钴，每个Pc为酞菁基，每个R 4独立地为氢，C 1-4烷基或被羟基单取代的C 1-4烷基，每个R 5和R 6 独立地是C 1-4烷基; 被卤素，氰基，羟基或苯基单取代的C 1-4烷基; 每个W 1独立地为-A - （+）NR 1 R 2 R 3 An（ - ）或-A-NR 2 R 3，其中R 1为氢; C 1-4烷基; 被卤素，氰基，羟基或苯基单取代的C 1-4烷基; 或C 5-6环烷基，R 2和R 3各自独立地为C 1-4烷基; 被卤素，氰基，羟基或苯基单取代的C 1-4烷基; 或C 5-6环烷基，Y是通过脂族碳原子与两个季铵化氮原子中的每一个连接的二价基团，每个M独立地为氢或非发色阳离子，m和m'各自独立地为0或1，每个 n和n'独立地为1,2或3，p为1或2，条件是m + n + p = 4，m'+ n'+ p = 4，其中每个A 独立地是直链或支链C 2-6亚烷基或被羟基单取代的直链或支链C 3-6亚烷基，并且每个An（ - ）独立地是非发色阴离子，包含它们的液体和固体染料组合物及其用于染色和印刷羟基 - 和含氮有机基材，特别是包含纤维素，特别是棉，韧皮纤维，皮革和纸的纺织材料。

4. 发明授权

US5059683A Dyes containing 6-hydroxypyrid-2-one groups the 1-positions of which contain substituted 1,3,5-triazinyl or pyrimidyl-piperazino or -piperazinium groups linked through bridging radicals and intermediates therefor 失效
标题翻译：包含6-羟基-2-基的组合物包含通过桥联物和其中间体连接的1,3,5-三嗪或吡嗪基哌嗪或邻苯二胺的组合的1位。
公开(公告)号：US5059683A
公开(公告)日：1991-10-22
申请号：US348340
申请日：1989-05-05
申请人： Helmut A. Moser , Roland Wald
发明人： Helmut A. Moser , Roland Wald
IPC分类号： C09B44/08 , C07D401/12 , C07D401/14 , C09B29/42 , C09B35/031 , C09B35/039 , C09B43/16 , C09B45/14
CPC分类号： C07D401/12 , C07D401/14 , C09B29/3626 , C09B35/031 , C09B35/039 , C09B43/16 , C09B45/14
摘要： Compounds of the formula ##STR1## and acid addition salts thereof whereinA.sub.1 is C.sub.1-8 alkylene; C.sub.2-8 alkylene substituted by 1 or 2 substituents selected from hydroxy, halo and cyano; C.sub.2-8 alkenylene; cyclohexylene; cyclohexylene substituted by 1 to 3 C.sub.1-4 alkyl groups; phenylene or phenylene substituted by 1 or 2 substituents selected from halo, C.sub.1-4 alkyl and C.sub.1-4 alkoxy,B.sub.1 is ##STR2## wherein the quaternized nitrogen atom is bound to a carbon atom of A.sub.1,R is hydrogen, C.sub.1-4 alkyl, C.sub.5-6 cycloalkyl, phenyl, benzyl or phenylethyl,T is hydrogen, cyano, --COOR.sub.1, --CON(R.sub.2).sub.2, --SO.sub.2 N(R.sub.2).sub.2, ##STR3## wherein R.sub.1 is C.sub.1-6 alkyl or phenyl(C.sub.1-3 alkyl),each R.sub.3 is independently hydrogen, C.sub.1-4 alkyl, --CON(R.sub.2).sub.2 or --N(R.sub.5).sub.2, andX.sub.1 is --S--, --O-- or --N(R.sub.5)--,Y is hydrogen or a chromophoric group, andZ is ##STR4## wherein R.sub.11 is ##STR5## wherein W is --NR.sub.6 R.sub.7 or --.sup..sym. NR.sub.8 R.sub.9 R.sub.10 A.sup..crclbar.,R.sub.12 is ##STR6## --O--R.sub.14, --O--A.sub.2 --O--R.sub.14 or --NR.sub.6 R.sub.7, whereinW is as defined above,R.sub.13 is hydrogen, halo, C.sub.1-4 alkyl, --O--R.sub.14, --O--A.sub.2 --O--R.sub.14 or --NR.sub.6 R.sub.7, andR.sub.15 is hydrogen or halo,with the proviso that the compounds are free of sulfo groups. The compounds wherein Y is other than hydrogen are useful for dyeing and printing substrates such as natural and regenerated cellulose, acid-modified polyamide, leather and paper.

5. 发明授权

US5037964A Metal-free sulfo group-free basis disazo and trisazo compounds containing two different 6-hydroxypyrid-2-one coupling component radicals 失效
标题翻译：含有两个不同的6-羟基吡啶-2-酮偶联组分基团的无金属的无磺基双偶氮和三偶氮化合物
公开(公告)号：US5037964A
公开(公告)日：1991-08-06
申请号：US920820
申请日：1986-10-17
申请人： Helmut A. Moser , Roland Wald
发明人： Helmut A. Moser , Roland Wald
IPC分类号： C07D213/74 , C07D213/76 , C07D401/14 , C09B35/03 , C09B35/031 , C09B35/037 , C09B35/039 , C09B43/16 , C09B44/02 , C09B44/08 , C09B62/09
CPC分类号： C09B62/09 , C09B35/031 , C09B43/16 , C09B44/08
摘要： (i) Metal-free compounds of the formula ##STR1## These compounds are useful as dyes for paper and textiles.
摘要翻译：（i）下式的金属化合物：这些化合物可用作纸和纺织品的染料。

6. 发明授权

US4900812A Sulfo group-containing metal phlhalocyanine azo compound having a 6-hydroxypyrid-2-one coupling component radicals having a fiber-reactive group 失效
公开(公告)号：US4900812A
公开(公告)日：1990-02-13
申请号：US149813
申请日：1988-01-29
申请人： Helmut A. Moser , Roland Wald
发明人： Helmut A. Moser , Roland Wald
IPC分类号： C09B62/016 , C09B62/006 , C09B62/10 , C09B62/26 , C09B62/44 , C09B62/483 , C09B62/517
CPC分类号： C09B62/4403 , C09B62/0068 , Y10S534/01
摘要： Compounds of the formula ##STR1## and water-soluble salts thereof each cation of which is independently a non-chromophoric cation, whereinMe is cobalt, copper or nickel,Pc is the phthalocyanine radical,each R.sub.1 and R.sub.2 is independently hydrogen or C.sub.1-6 alkyl,each R.sub.4 is independently hydrogen, halo, hydroxy, C.sub.1-4 alkoxy, C.sub.1-4 alkyl, carboxy or sulfo,each R.sub.6 is hydrogen, cyano, carbamoyl or ##STR2## wherein An .crclbar. is a non-chromophoric anion,each R.sub.7 is hydrogen, C.sub.1-4 alkyl, C.sub.5-6 cycloalkyl, phenyl, benzyl, phenylethyl or carboxy,each W is linear or branched C.sub.2-6 alkylene; linear or branched C.sub.3-6 alkylene monosubstituted by hydroxy; linear or branched C.sub.2-6 alkylene interrupted by ##STR3## wherein R.sub.11 is linear or branched C.sub.1-4 alkylene,m is 0 or 1, andthe ** indicates the bond attached to the nitrogen atom of the pyridone ring, or ##STR4## wherein the ** is as set forth above, each Y is a fiber-reactive group,a is 1, 2 or 3,b is 0, 1 or 2,c is 1 or 2, with the provisos that a+b+c does not exceed 4 and that each of the four units of the phthalocyanine nucleus contains a maximum of one substituent selected from those to which a, b and c relate, andn is 0 or 1,whereineach R.sub.3 is independently hydrogen, C.sub.1-4 alkyl or C.sub.2-4 hydroxyalkyl,each R.sub.5 is independently halo, amino or an aliphatic, cycloaliphatic, aromatic or heterocyclic amino group, andeach R.sub.12 is independently linear or branched C.sub.2-4 -alkylene,and mixtures of such compounds and salts, useful for dyeing and printing hydroxy group- or nitrogen- containing organic substrates, for example leather and fiber materials containing or consisting of natural or synthetic polyamides or of natural or regenerated cellulose, preferably textile material containing or consisting of cotton.

7. 发明授权

US07091328B2 Fiber-reactive mono-azo dyes 有权
标题翻译：纤维反应性单偶氮染料
公开(公告)号：US07091328B2
公开(公告)日：2006-08-15
申请号：US10475624
申请日：2002-04-15
申请人： Roland Wald , Markus Gisler
发明人： Roland Wald , Markus Gisler
IPC分类号： C09B62/51 , C09B67/22 , C09D11/02 , D06P1/384
CPC分类号： C09B67/0051 , C09B62/4413
摘要： According to the invention there are provided fiber-reactive dyestuffs which are compounds of the formula (I) wherein the substituents are defined as in claim 1, a process making the same and their use in dyeing or printing hydroxy-group-containing organic substrates.
摘要翻译：根据本发明，提供了作为式（I）化合物的纤维反应性染料，其中取代基如权利要求1中所定义，其制备方法及其在染色或印刷含羟基的有机底物中的用途。

8. 发明授权

US5491221A Fibre-reactive copper-complex formazan compounds which contain a difluoropyrimidinyl group 失效
标题翻译：含有二氟嘧啶基的纤维反应性铜络合物甲an化合物
公开(公告)号：US5491221A
公开(公告)日：1996-02-13
申请号：US247154
申请日：1994-05-20
申请人： Markus Gisler , Roland Wald
发明人： Markus Gisler , Roland Wald
IPC分类号： C09B62/20 , C09B62/44 , C09B62/465 , D06P1/38
CPC分类号： C09B62/205 , C09B62/4422
摘要： Fibre-reactive formazan compounds, salts thereof or free acid forms thereof according to formula (I) ##STR1## in which R.sub.1 is hydrogen or --COOH, each of R.sub.2 and R.sub.4 is independently hydrogen, --COOH, --SO.sub.3 H, --NHCOCH.sub.3, --NHCOCHY.sub.2 --CH.sub.2 Y.sub.1, --NHCOCY.sub.2 .dbd.CH.sub.2 or --NHCOCH.sub.2 Y.sub.1,R.sub.3 is hydrogen, halogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, --COOH or --SO.sub.3 H,Y.sub.1 is chlorine, bromine, --OSO.sub.3 H or --SSO.sub.3 H,Y.sub.2 is hydrogen, chlorine or bromine, andZ is ##STR2## The compounds are particularly useful in dyeing or printing hydroxy-group containing or nitrogen-containing organic substrates, including leather, fiber materials, and textiles.
摘要翻译：根据式（I）的纤维反应性甲an化合物，其盐或游离酸形式，R 2和R 4各自独立地是氢，-COOH，-SO 3 H，-NHCOCH 3，-NHCOCHY 2 -CH 2 Y 1，-NHCOCY 2 = CH 2或-NHCOCH 2 Y 1 ，R3为氢，卤素，C1-4烷基，C1-4烷氧基，-COOH或-SO3H，Y1为氯，溴，-OSO3H或-SSO3H，Y2为氢，氯或溴，Z为化合物特别适用于染色或印刷包含皮革，纤维材料和纺织品的含羟基或含氮有机基材。

9. 发明授权

US5126443A Phthalocyanine azo dyes containing 5-cyano-dichloropyrimidyl group 失效
标题翻译：含有5-氰基 - 二氯嘧啶基的酞菁偶氮染料
公开(公告)号：US5126443A
公开(公告)日：1992-06-30
申请号：US585531
申请日：1990-09-19
申请人： Helmut A. Moser , Roland Wald
发明人： Helmut A. Moser , Roland Wald
IPC分类号： C09B62/24 , C09B62/26 , C09B67/22 , D06P3/66
CPC分类号： C09B62/242 , C09B62/26 , C09B67/0035 , D06P3/666
摘要： Compounds of the formulae ##STR1## salts thereof, and mixtures of such compounds or salts,wherein Me, Pc, Q.sub.1, R.sub.1, R.sub.2, R.sub.3, Y, a, b, c and d as defined,useful as fiber-reactive dyes for dyeing or printing hydroxy group- and nitrogen-containing organic substrates, for example, textile material comprising cotton, the obtained dyeings and prints having good all-round fastnesses, such as good light fastness.
摘要翻译：其中的化合物及其盐，其中Me，Pc，Q 1，R 1，R 2，R 3，Y，a，b，c和d如上所定义，可用作纤维用于染色或印刷羟基和含氮有机基材的反应性染料，例如包含棉的纺织材料，所得染色和印刷品具有良好的全面牢度，例如良好的耐光性。

10. 发明授权

US5001226A Metal-free disazo and polyazo compounds having at least one 6-hydroxypyrid-2-one coupling component radical linked to a 1-amino- or hydroxy-3-amino- or hydroxybenzene coupling component radical and metal complexes thereof 失效
标题翻译：具有与1-氨基 - 或羟基-3-氨基 - 或羟基苯偶联组分基团及其金属络合物连接的至少一个6-羟基吡啶-2-酮偶联组分的无金属双偶氮和多偶氮化合物
公开(公告)号：US5001226A
公开(公告)日：1991-03-19
申请号：US452878
申请日：1989-12-19
申请人： Helmut A. Moser , Roland Wald
发明人： Helmut A. Moser , Roland Wald
IPC分类号： C09B44/02 , C09B35/60 , C09B44/08 , C09B45/24 , D06P1/41
CPC分类号： C09B44/08 , C09B35/60 , C09B45/24 , Y10S534/01
摘要： Compounds of the formula ##STR1## 1:1 and 1:2 metal complexes thereof, salts of such compounds and metal complexes and mixture thereof, whereineach of B.sub.1 and B.sub.2 is independently hydroxy or amino,each D is independently ##STR2## wherein R is hydrogen, C.sub.1-4 alkyl, C.sub.5-6 cycloalkyl, phenyl, benzyl or phenylethyl,R.sub.1 is hydrogen, cyano, --COOR.sub.4, --CONR.sub.5 R.sub.6, --SO.sub.2 NR.sub.5 R.sub.6, ##STR3## wherein each R.sub.3 is independently hydrogen, C.sub.1-4 alkyl, --NR.sub.5 R.sub.6 or --CONR.sub.5 R.sub.6,R.sub.4 is C.sub.1-6 alkyl or phenyl(C.sub.1-3 alkyl),R.sub.7 is C.sub.1-4 alkyl,R.sub.8 is hydrogen or C.sub.1-4 alkyl, andR.sub.9 is --S--, --O-- or --NR.sub.5 --,R.sub.2 is hydrogen, hydroxy or C.sub.1-4 alkoxy,R.sub.2a is hydrogen, C.sub.1-4 alkyl or halo,M is hydrogen; C.sub.1-8 alkyl; (C.sub.1-4 alkoxy)C.sub.1-4 alkyl; C.sub.2-4 hydroxyalkyl; C.sub.5-6 cycloalkyl; C.sub.5-6 cycloalkyl substituted by 1 to 3 C.sub.1-4 alkyls; phenyl(C.sub.1-3 alkyl); phenyl (C.sub.1-3 alkyl) the phenyl group of which is substituted by 1 to 3 C.sub.1-4 alkyls; --NR.sub.11 R.sub.12 ; --A.sub.1 --NR.sub.13 R.sub.14 ;--A.sub.2 --N.sup..sym. R.sub.13 R.sub.14 R.sub.15 A.sup..crclbar. or ##STR4## wherein A.sub.1 is C.sub.1-6 alkylene or C.sub.2-6 alkenylene,A.sub.2 is C.sub.2-6 alkylene or C.sub.2-6 alkenylene,R.sub.10 is C.sub.1-10 alkylene; C.sub.2-10 alkenylene; alkylene or alkenylene having a maximum of 10 carbon atoms and interrupted by 1 or 2 atoms selected from oxygen and nitrogen; phenylene; or cyclohexylene,R.sub.16 is hydrogen, halo, nitro, C.sub.1-4 alkyl or C.sub.1-4 alkoxy,R.sub.20 is hydrogen, --CO--(CH.sub.2).sub.m --NR.sub.11 R.sub.12, --CO--(CH.sub.2).sub.m --N.sup..sym. R.sub.13 R.sub.14 R.sub.15 A.sup..crclbar. or ##STR5## wherein m is 1 to 6, with the proviso that R.sub.20 is other than hydrogen when g is 0, andq is 0 or 1,v is 0, 1 or 2, andeach n is independently 0 or 1,are basic dyes useful for dyeing and printing paper, leather and textile substrates.
摘要翻译：下式化合物1：1和1：2的金属络合物，这些化合物的盐和金属络合物及其混合物，其中B1和B2各自独立地是羟基或氨基，每个D独立地是其中R C 1-4烷基，C 5-6环烷基，苯基，苄基或苯基乙基，R 1是氢，氰基，-COOR 4，-CONR 5 R 6，-SO 2 NR 5 R 6，其中每个R 3独立地是氢，C 1-4烷基，-NR5R6或-CONR5R6，R4是C1-6烷基或苯基（C1-3烷基），R7是C1-4烷基，R8是氢或C1-4烷基，R9是-S-，-O-或-NR5-，R2 是氢，羟基或C 1-4烷氧基，R 2a是氢，C 1-4烷基或卤素，M是氢; C 1-8烷基; （C 1-4烷氧基）C 1-4烷基; C2-4羟烷基; C5-6环烷基; 被1至3个C 1-4烷基取代的C 5-6环烷基; 苯基（C 1-3烷基）; 苯基（C 1-3烷基），其苯基被1至3个C 1-4烷基取代; -NR11R12; -A1-NR13R14; -A2-N（+）R13R14R15A（ - ）或其中A1是C1-6亚烷基或C2-6亚烯基，A2是C2-6亚烷基或C2-6亚烯基，R10是C1-10亚烷基; C2-10亚烯具有最多10个碳原子并被1或2个选自氧和氮的原子中断的亚烷基或亚烯基; 亚苯基; 或 - 环己基，R 16是氢，卤素，硝基，C 1-4烷基或C 1-4烷氧基，R 20是氢，-CO-（CH 2）m -NR 11 R 12，-CO-（CH 2）m N（+）R 13 R 14 R 15 A（ - 其中m为1至6，条件是当g为0时，R20不为氢，q为0或1，v为0,1或2，并且每个n独立为0或1，为碱性染料用于染色和印刷纸张，皮革和纺织品基材。

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