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    • 3. 发明授权
    • High-K dielectric gate material uniquely formed
    • 高K介电栅极材料独特地形成
    • US06919263B2
    • 2005-07-19
    • US10643687
    • 2003-08-19
    • Sheldon AronowitzVladimir ZubkovGrace Sun
    • Sheldon AronowitzVladimir ZubkovGrace Sun
    • C23C16/40C23C16/44H01L21/28H01L21/316H01L29/51H01L21/3205
    • H01L29/517C23C16/40H01L21/28194H01L21/31604H01L21/31683
    • A new relatively high-k gate dielectric gate material comprising calcium oxide will reduce leakage from the silicon substrate to the polysilicon gate, prevent boron penetration in p-channel devices, and reduce electron trapping in the dielectric. The surface of a silicon wafer is saturated with hydroxyl groups. A calcium halide, preferably calcium bromide, is heated to a temperature sufficient to achieve atomic layer deposition, and is transported to the silicon wafer. The calcium halide reacts with the hydroxyl groups. Water is added to carry away the resultant hydrogen halide. Gaseous calcium and water are then added to form a calcium oxide gate dielectric, until the desired thickness has been achieved. In an alternative embodiment of the method, the calcium halide is transported to the silicon wafer to react with the hydroxyl groups, followed by transport of gaseous water to the silicon wafer. These two steps are repeated until the desired thickness has been achieved.
    • 包含氧化钙的新的相对高k的栅介质栅极材料将减少从硅衬底到多晶硅栅极的泄漏,防止在p沟道器件中的硼渗透,并减少电介质中的电子俘获。 硅晶片的表面被羟基饱和。 将卤化钙,优选溴化钙加热到足以实现原子层沉积的温度,并被输送到硅晶片。 卤化钙与羟基反应。 加入水以携带所得的卤化氢。 然后加入气态钙和水以形成氧化钙栅极电介质,直至达到所需的厚度。 在该方法的替代实施方案中,将卤化钙输送到硅晶片以与羟基反应,然后将气态水输送到硅晶片。 重复这两个步骤,直到达到所需的厚度。