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1. 发明申请

US20080032197A1 Inorganic Separator-Electrode-Unit for Lithium-Ion Batteries, Method for the Production Thereof and Use Thereof in Lithium Batteries 有权
标题翻译：锂离子电池无机分离器 - 电极单元及其生产方法及其在锂电池中的应用
公开(公告)号：US20080032197A1
公开(公告)日：2008-02-07
申请号：US11577542
申请日：2004-10-21
申请人： Gerhard Horpel , Volker Hennige , Christian Hying , Sven Augustin
发明人： Gerhard Horpel , Volker Hennige , Christian Hying , Sven Augustin
IPC分类号： H01M4/48 , H01M4/08 , H01M4/36
CPC分类号： H01M10/052 , H01M2/1646 , H01M2/166 , H01M4/0404 , H01M4/131 , H01M4/1391 , H01M4/621 , H01M2004/027 , H01M2004/028 , Y10T29/49114
摘要： The present invention concerns separator-electrode assemblies for lithium batteries and also a process for their production. The separator-electrode assemblies (SEAs) comprise a porous electrode useful as an electrode, ie. Positive (cathode) or negative (anode) electrode, in a lithium battery and a separator layer applied to this electrode. The separator electrode assembly (SEA) is characterized in that it has an inorganic separator layer comprising at least two fractions of metal oxide particles different from each other in their average particle size and/or in the metal, and an electrode whose active mass particles are bonded together and to the current collector by inorganic adhesive. The separator-electrode assembly of the invention has the advantage that it is simple to manufacture as one component and that distinctly higher temperatures can be employed in production than in the production of conventional separator-electrode assemblies, since the electrode does not contain heat-sensitive organic materials.
摘要翻译：本发明涉及用于锂电池的分离器 - 电极组件，以及它们的生产方法。分离器电极组件（SEA）包括可用作电极的多孔电极，即，在正极（阴极）或负极（阳极）电极中的锂电池和分隔层施加到该电极上。分离器电极组件（SEA）的特征在于其具有包含在平均粒径和/或金属中彼此不同的金属氧化物颗粒的至少两个部分的无机隔离层和活性质量颗粒为通过无机粘合剂结合在一起并与集电体接合。本发明的分离器 - 电极组件的优点在于，作为一个部件制造简单，并且在生产中可以使用明显更高的温度，而不是生产常规的隔离器 - 电极组件，因为电极不含有热敏感有机材料。

2. 发明申请

US20080138700A1 Use Of A Ceramic Separator In Lithium Ion Batteries, Comprising An Electrolyte Containing Ionic Fluids 有权
标题翻译：在锂离子电池中使用陶瓷分离器，包括含有离子液体的电解质
公开(公告)号：US20080138700A1
公开(公告)日：2008-06-12
申请号：US11578664
申请日：2005-02-24
申请人： Gerhard Horpel , Volker Hennige , Christian Hying , Sven Augustin , Carsten Jost
发明人： Gerhard Horpel , Volker Hennige , Christian Hying , Sven Augustin , Carsten Jost
IPC分类号： H01M2/16 , B05D3/00
CPC分类号： H01M2/162 , H01M2/14 , H01M2/145 , H01M2/1626 , H01M2/1646 , H01M2/1666 , H01M8/0293 , H01M10/052 , H01M10/0525 , H01M10/0566 , H01M2300/0025 , H01M2300/0094 , Y02E60/122 , Y02E60/50 , Y02P70/54
摘要： The invention relates to a separator filled with an electrolyte composition. The separator has a ceramic surface and the electrolyte composition comprises an ionic fluid. Filling with the electrolyte composition can take place, for example, by inserting the separator into a battery, e.g. into a lithium ion battery, which is filled with a corresponding electrolyte composition.
摘要翻译：本发明涉及填充有电解质组合物的隔膜。隔膜具有陶瓷表面，电解质组合物包含离子流体。填充电解质组合物可以例如通过将分离器插入电池中进行，例如，进入锂离子电池，其中填充有相应的电解质组合物。

3. 发明申请

US20050221192A1 Separator-electrode unit for lithium-ion batteries, method for the production and use thereof in lithium batteries 有权
标题翻译：锂离子电池用隔膜电极单元，锂电池的制造方法及其制造方法
公开(公告)号：US20050221192A1
公开(公告)日：2005-10-06
申请号：US10524665
申请日：2003-07-04
申请人： Volker Hennige , Christian Hying , Gerhard Horpel , Sven Augustin
发明人： Volker Hennige , Christian Hying , Gerhard Horpel , Sven Augustin
IPC分类号： B05D5/12 , H01M2/14 , H01M2/16 , H01M4/13 , H01M10/0525 , H01M10/36 , H01M10/42 , H01M10/50
CPC分类号： H01M10/0525 , H01M2/1646 , H01M2/1673 , H01M2/1686 , H01M4/0402 , H01M4/0471 , H01M4/13 , H01M10/052 , H01M10/0562 , H01M10/4235
摘要： The present invention relates to separator-electrode units for lithium batteries and also to a process for their production. The separator-electrode units comprise a porous electrode which is useful as a positive electrode (cathode) or negative electrode (anode) in a lithium battery and a separator layer applied to this electrode and are characterized in that the separator-electrode units comprise a purely inorganic separator layer which comprises at least two fractions of metal oxide particles which differ from each other in their average particle size and/or in the metal. More particularly, the separator layer comprises metal oxide particles having an average particle size (Dg) which is greater than the average pore size (d) of the pores of the porous positive electrode that are bonded together by metal oxide particles having a particle size (Dk) which is smaller than the pores of the porous electrode. The separator-electrode unit of the invention has the advantage that it is simple to manufacture as one component and, since the step of laminating the separator onto the electrode can be omitted, that it can comprise a large variation of materials. In addition, a separator-electrode unit according to the invention possesses excellent mechanical stability and a very low separator thickness, which is why it can even be used in lithium high energy batteries.
摘要翻译：本发明涉及锂电池用隔膜电极单元及其制造方法。分离电极单元包括可用作锂电池中的正电极（阴极）或负电极（阳极）的多孔电极和施加到该电极上的隔板层，其特征在于，隔板电极单元包括纯无机分离器层，其包含在其平均粒度和/或金属中彼此不同的金属氧化物颗粒的至少两个级分。更具体地说，隔板层包含平均粒径（D≤G）的金属氧化物颗粒，该平均粒径大于多孔正极的孔的平均孔径（d）具有比多孔电极的孔更小的粒径（D >k）的金属氧化物颗粒。本发明的隔膜 - 电极单元的优点在于，作为一个部件制造简单，并且由于可以省略将隔膜层压到电极上的步骤，所以可以包括大的材料变化。此外，根据本发明的隔膜 - 电极单元具有优异的机械稳定性和非常低的隔板厚度，这就是为什么甚至可以用于锂高能电池中的原因。

4. 发明申请

US20060166085A1 Ion conducting battery separator for lithium batteries, method for the production and use thereof 有权
标题翻译：用于锂电池的离子导电电池隔板，其制造和使用方法
公开(公告)号：US20060166085A1
公开(公告)日：2006-07-27
申请号：US10519097
申请日：2003-07-21
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： H01M4/00 , H01M2/14 , B05D5/12 , B05D3/12 , B05D1/02 , B05D1/18
CPC分类号： H01M2/162 , H01B1/122 , H01M2/145 , H01M2/1646 , H01M2/1666 , H01M10/0525 , H01M10/4235
摘要： The invention relates to separators for lithium batteries and to a process for producing them, and also to their use. The separators of the invention for lithium batteries, based on a sheetlike flexible substrate provided with a plurality of openings and having a porous inorganic electrically insulating coating on and in said substrate, said coating closing the openings in the substrate, the material of the substrate being selected from woven or non-woven electrically nonconductive polymeric fibers and the inorganic electrically conductive coating comprising metal oxide particles, are notable for the fact that the separators have lithium ion conducting properties without the presence of an electrolyte. After filling them with an additional lithium ion conducting electrolyte, the resulting ion conduction is much higher than in the case of conventional combinations of non-lithium ion conducting separators and electrolyte. The separators of the invention are especially suitable for use in high power lithium batteries.
摘要翻译：本发明涉及锂电池用隔膜及其制造方法，也涉及其用途。本发明的用于锂电池的隔板基于设置有多个开口的片状柔性基板，并且在所述基板上和之上具有多孔无机电绝缘涂层，所述涂层封闭基板中的开口，基板的材料为选自织造或非织造非导电聚合物纤维和包含金属氧化物颗粒的无机导电涂层是显着的，因为隔板具有锂离子传导性能而不存在电解质。在用额外的锂离子传导电解质填充它们之后，所得到的离子传导比非传统的非锂离子传导隔离物和电解质的组合的情况高得多。本发明的分离器特别适用于大功率锂电池。

5. 发明申请

US20060024569A1 Separator for use in high-energy batteries and method for the production thereof 有权
标题翻译：用于高能电池的分离器及其制造方法
公开(公告)号：US20060024569A1
公开(公告)日：2006-02-02
申请号：US10524669
申请日：2003-07-04
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： H01M2/16 , B05D7/02
CPC分类号： H01M2/162 , H01M2/1646 , H01M2/1666 , H01M2/1686 , H01M10/0525 , Y10T428/249955 , Y10T428/249957
摘要： The present invention relates to electrical separators, especially for use in lithium high energy batteries, and to a process for making them. Separators for use in lithium high energy batteries have to have a very low weight and a very low thickness. It has been found that, surprisingly, such separators having a weight of less than 50 g/m2 and a thickness of less than 35 μm are preparable by applying a ceramic coating to a polymeric web less than 30 μm in thickness, these separators being very useful in lithium high energy batteries when pyrogenic oxides of the elements Al, Si and/or Zr are used as a particulate pore-forming component.
摘要翻译：本发明涉及特别用于锂高能电池的电隔离器及其制造方法。用于锂高能电池的分离器必须具有非常低的重量和非常低的厚度。已经发现，令人惊讶的是，通过将陶瓷涂层施加到小于30μm的聚合物网上，可以制备重量小于50g / m 2和厚度小于35μm的这种隔板这些隔板在锂高能电池中非常有用，当元素Al，Si和/或Zr的热解氧化物用作颗粒成孔组分时。

6. 发明申请

US20080248381A1 Ceramic Separator for Electrochemcial Cells With Improved Conductivity 审中-公开
标题翻译：陶瓷分离器电化学电池改善电导率
公开(公告)号：US20080248381A1
公开(公告)日：2008-10-09
申请号：US10575274
申请日：2004-08-19
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： H01M2/16 , H01M2/00
CPC分类号： H01M2/145 , H01M2/1646 , H01M2/1686 , H01M10/0525
摘要： Separator for an electrochemical cell comprising a flexible perforate carrier having a ceramic coating on and in the carrier, the ceramic coating comprising from 75 to 99 parts by mass of oxidic particles selected from particles of ZrO2, SiO2 and Al2O3 and comprising from 1 to 25 parts by mass of zeolite particles. These separators exhibit distinctly improved ion conductivity after filling with an electrolyte and are useful as separators in lithium ion batteries in particular.
摘要翻译：用于电化学电池的分离器包括在载体上和载体上具有陶瓷涂层的柔性穿孔载体，所述陶瓷涂层包含75至99质量份的选自ZrO 2颗粒，SiO 2，含有1〜25质量份的沸石颗粒的2'和2“O 3 O 3。这些分离器在填充电解质后显示出明显改善的离子传导性，并且特别用作锂离子电池中的分离器。

7. 发明申请

US20050084761A1 Electric separator, method for the production and use thereof 有权
标题翻译：电分离器，其生产和使用方法
公开(公告)号：US20050084761A1
公开(公告)日：2005-04-21
申请号：US10504144
申请日：2003-01-15
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： H01M2/14 , H01M2/16
CPC分类号： H01M2/162 , H01M2/1646 , H01M2/1666
摘要： The present invention relates to electrical separators and to a process for making them. An electrical separator is a separator used in batteries and other arrangements in which electrodes have to be separated from each other while maintaining ion conductivity for example. The separator is preferably a thin porous insulating material possessing high ion permeability, good mechanical strength and long-term stability to the chemicals and solvents used in the system, for example in the electrolyte of the battery. In batteries, the separator should fully electrically insulate the cathode from the anode. Moreover, the separator has to be permanently elastic and to follow movements in the system, for example in the electrode pack in the course of charging and discharging. This object is achieved by an electrical separator according to the invention, comprising a sheetlike flexible substrate having a multiplicity of openings and having a coating on and in said substrate, said substrate being a polymeric nonwoven and said coating being a porous electrically insulating ceramic coating, said separator being characterized by a thickness of less than 80 μm.
摘要翻译：本发明涉及电动分离器及其制造方法。电分离器是用于电池和其它布置的隔板，其中电极必须彼此分离，同时保持例如离子传导性。隔膜优选是具有高离子渗透性，良好的机械强度和对系统中使用的化学品和溶剂的长期稳定性的薄多孔绝缘材料，例如在电池的电解质中。在电池中，分离器应使阴极与阳极完全电绝缘。此外，分离器必须是永久的弹性的并且可以跟随系统中的运动，例如在充电和放电过程中的电极组中。该目的通过根据本发明的电气分离器实现，其包括具有多个开口的片状柔性基底，并且在所述基底上和所述基底中具有涂层，所述基底是聚合物非织造材料，所述涂层是多孔电绝缘陶瓷涂层，所述分离器的特征在于小于80μm的厚度。

8. 发明申请

US20060172641A1 Textile substrates having self-cleaning properties 失效
标题翻译：具有自清洁性能的纺织基材
公开(公告)号：US20060172641A1
公开(公告)日：2006-08-03
申请号：US11312340
申请日：2005-12-21
申请人： Volker Hennige , Christian Hying , Gerhard Horpel , Markus Oles , Edwin Nun , Bernhard Schleich
发明人： Volker Hennige , Christian Hying , Gerhard Horpel , Markus Oles , Edwin Nun , Bernhard Schleich
IPC分类号： B32B5/02 , B32B27/04 , B32B27/12 , D04H3/04
CPC分类号： D06M13/50 , D06M11/79 , D06M11/83 , D06M23/08 , D06M2200/05 , Y10T442/20 , Y10T442/2041 , Y10T442/2131 , Y10T442/2164 , Y10T442/2221
摘要： The present invention relates to a vapor-pervious water-impervious substrate, preferably a fibrous nonwoven web, which can be used in particular as a textile continuous sheet material, for example as an awning or as an inlet in apparel. The substrate according to the present invention may have self-cleaning properties. The substrate according to the present invention is simple to produce in an at least two-step process wherein a coating on the fibers of the substrate is produced in the first step and then hydrophobic particles are applied to the coated fibers by means of an adhesion promoter.
摘要翻译：本发明涉及可透气的不透水基材，优选纤维非织造纤维网，其可特别用作织物连续片材，例如作为遮阳篷或作为服装的入口。根据本发明的基底可以具有自清洁性质。根据本发明的基材易于以至少两步法生产，其中在第一步中制备基材纤维上的涂层，然后通过粘合促进剂将疏水性颗粒施加到涂覆的纤维上。

9. 发明申请

US20060003230A1 Pyrogenic oxidic powder, production thereof and use thereof in a separatior for an electrochemical cell 有权
标题翻译：热分解氧化粉末，其制备方法及其在电化学电池分离中的用途
公开(公告)号：US20060003230A1
公开(公告)日：2006-01-05
申请号：US10534952
申请日：2003-11-05
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： H01M2/16
CPC分类号： H01M10/052 , B82Y30/00 , C01B33/18 , C01F7/021 , C01F7/043 , C01G1/02 , C01G25/00 , C01P2004/64 , C01P2006/12 , C01P2006/40 , H01M2/166 , H01M10/0525 , H01M10/0565 , Y10T428/2982
摘要： A pyrogenic oxidic powder composed of particles, comprising (i) atoms of an element of groups 3A, 4A, 3B or 4B of the periodic table of the elements, and (ii) oxygen atoms, said particles being characterized by lithium atoms attached to said atoms via an oxygen bridge.
摘要翻译：由颗粒组成的热解氧化粉末，其包含（i）元素周期表的3A，4A，3B或4B族元素的原子，和（ii）氧原子，所述颗粒的特征在于与所述原子通过氧桥。

10. 发明申请

US20050221165A1 Electrical separator comprising a shut-down mechanism, method for the production thereof and its use in kithium batteries 失效
标题翻译：电分离器包括关闭机构，其制造方法及其在锂电池中的应用
公开(公告)号：US20050221165A1
公开(公告)日：2005-10-06
申请号：US10524145
申请日：2003-07-08
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： B05D1/12 , C08J7/06 , D06M11/45 , D06M11/48 , D06M11/79 , D06M13/513 , D06M15/227 , D06M23/08 , H01M2/00 , H01M2/14 , H01M2/16 , H01M10/0525 , H01M10/36 , H01M10/50
CPC分类号： D06M15/227 , C08J7/06 , D06M11/45 , D06M11/48 , D06M11/79 , D06M13/513 , D06M23/08 , H01M2/145 , H01M2/1613 , H01M2/162 , H01M2/164 , H01M2/1646 , H01M2/1653 , H01M2/166 , H01M2/1666 , H01M10/0525
摘要： The present invention relates to electrical separators for batteries, especially lithium batteries, having a shutdown mechanism and also a process for their production. An electrical separator is a separator which is used in batteries and other systems in which electrodes have to be separated from each other while maintaining ion conductivity for example. Safety is very important in lithium batteries, since in contrast to other types of battery (Pb, NiCd, NiMeH) the solvent for the electrolyte is not water but a combustible solvent, for example organic carbonates. This is why it is absolutely necessary for a separator for lithium cells to possess a suitable shutdown mechanism and at the same time for it not to be able to melt down. This object is achieved by an electrical separator according to the invention that comprises a shutdown layer which consists of particles which melt at a desired temperature, close the pores of the separator and so stop ion flow. Since the separator also comprises a porous inorganic (ceramic) layer on a carrier, the cells cannot melt down as a result of a completely melted separator.
摘要翻译：本发明涉及一种具有关机机构的电池隔离器，特别是锂电池，以及其制造方法。电分离器是用于电池和其它系统的隔板，其中电极必须彼此分离，同时保持例如离子传导性。安全性在锂电池中是非常重要的，因为与其他类型的电池（Pb，NiCd，NiMeH）相反，电解质的溶剂不是水而是可燃溶剂，例如有机碳酸盐。这就是为什么锂离子电池隔板绝对需要具有合适的关断机制，同时又不能熔化的原因。该目的通过根据本发明的电分离器实现，其包括由在所需温度下熔化的颗粒组成的关闭层，闭合分离器的孔并停止离子流。由于分离器还包含载体上的多孔无机（陶瓷）层，所以由于完全熔化的分离器，电池不能熔化。

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