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1. 发明授权

US5298554A Polymers of olefinically unsaturated monomers and solutions of these polymers 失效
标题翻译：烯属不饱和单体的聚合物和这些聚合物的溶液
公开(公告)号：US5298554A
公开(公告)日：1994-03-29
申请号：US721836
申请日：1991-06-26
申请人： Gerd Rehmer , Juergen Barwich , Gerhard Auchter
发明人： Gerd Rehmer , Juergen Barwich , Gerhard Auchter
IPC分类号： C08F2/00 , C08F2/04 , C08F2/06 , C08F220/10 , C08F220/18 , C08L33/04 , C08L33/08 , C09J133/04 , C09J133/08 , C08F20/02 , C08F20/56 , C08F20/68
CPC分类号： C08F2/06
摘要： Abstract of the Disclosure: Polymers of olefinically unsaturated monomers and solutions of these polymers are obtainable by a process in which the olefinically unsaturated monomers are polymerized in the presence of a free radical initiator in solution under polymerization conditions which are otherwise predetermined, in such a way that the solvent and/or a liquid part of one or more reactants of the polymerization batch are initially taken and heated to the polymerization temperature, and some or the total amount of the monomers to be polymerized is fed continuously to the agitated initially taken part of the polymerization batch via one or more feeds, with maintenance or initiation of the polymerization, in such a way that the outlet orifice of the one or more feeds is located below the surface of the initially taken liquid part of the polymerization batch.
摘要翻译：摘要：烯属不饱和单体的聚合物和这些聚合物的溶液可通过其中烯属不饱和单体在自由基引发剂存在下在溶液中在聚合条件下进行聚合的方法获得，这些聚合条件以其它方式预先确定首先将聚合批料的一种或多种反应物的溶剂和/或液体部分取出并加热至聚合温度，并将待聚合的单体的一些或总量连续供给到搅拌的初始取出的部分通过一个或多个进料的聚合批料，维持或开始聚合，使得一种或多种进料的出口孔位于聚合批料的初始取出的液体部分的表面下方。

2. 发明授权

US5223645A Unsaturated phenone derivatives and their use as contact adhesives 失效
标题翻译：不饱和的苯醌衍生物及其作为联系人粘合剂的用途
公开(公告)号：US5223645A
公开(公告)日：1993-06-29
申请号：US764205
申请日：1991-09-23
申请人： Juergen Barwich , Gerd Rehmer , Kaspar Bott
发明人： Juergen Barwich , Gerd Rehmer , Kaspar Bott
IPC分类号： C07C231/06 , C07C235/20 , C07C235/78 , C07C235/84 , C08F20/60 , C08F220/60 , C08F246/00 , C09J7/02 , C09J133/24
CPC分类号： C08F220/60 , C07C235/20 , C07C235/78 , C07C235/84 , C08F246/00 , C09J133/24 , C09J7/0217
摘要： Unsaturated phenone derivatives of the general formula I ##STR1##whereR.sup.1 is C.sub.1 -C.sub.4 -alkyl, cyclopropyl, cyclopentyl, cyclohexyl, indanonyl, tetralonyl, phenyl or phenyl in which some or all of the hydrogen atoms have been replaced by a C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -thioalkyl group, or together with R.sup.2 or R.sup.6 forms an ethylene or propylene bridge,R.sup.2 to R.sup.6 are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -thioalkyl, and R.sup.3, R.sup.4 and R.sup.5 may each additionally be hydroxyl, R.sup.2 or R.sup.6 may additionally together with R.sup.1 form an ethylene or propylene bridge and one or more, but not more than three, of the radicals R.sup.2 to R.sup.6 are a group of the general formula II ##STR2## whereK is C.sub.1 -C.sub.10 -alkylene which may contain 1 or 2 oxygen or sulfur atoms,Y is straight-chain or branched C.sub.1 -C.sub.10 -alkylene or is C.sub.1 -C.sub.10 -alkylene which is substituted by carboxyl, a carboxylate anion, an alkyl C.sub.1 -C.sub.4 -carboxylate group or hydroxyl, X is --NH-- or --(N-Alkyl)-- of 1 to 4 carbon atoms andZ is hydrogen or C.sub.1 -C.sub.4 -alkyl.
摘要翻译：其中R 1是C 1 -C 4 - 烷基，环丙基，环戊基，环己基，茚满基，四氢萘基，苯基或苯基，其中一些或全部氢原子被C1- 或者与R 2或R 6一起形成乙烯或丙烯桥，R 2至R 6各自为氢，C 1 -C 4烷基，C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷氧基或C 1 -C 4 - -C 4 - 硫代烷基和R 3，R 4和R 5可各自另外为羟基，R 2或R 6可以另外与R 1一起形成乙烯或丙烯桥，并且一个或多个但不多于三个基团R 2至R 6为其中K是可以含有1或2个氧或硫原子的C 1 -C 10 - 亚烷基，Y是直链或支链C 1 -C 10 - 亚烷基或是C 1 -C 10亚烷基被羧基，羧酸根阴离子，C1-C4羧酸烷基酯基或羟基取代的-C10-亚烷基，X是1〜4个碳原子的-NH-或 - （N-烷基），Z是氢或C 1 -C 4 - 烷基。

3. 发明授权

US5294688A UV-crosslinkable copolymers 失效
标题翻译：紫外线交联共聚物
公开(公告)号：US5294688A
公开(公告)日：1994-03-15
申请号：US974818
申请日：1992-11-16
申请人： Gerd Rehmer , Gerhard Auchter , Andreas Boettcher , Lothar Franz , Helmut Jaeger
发明人： Gerd Rehmer , Gerhard Auchter , Andreas Boettcher , Lothar Franz , Helmut Jaeger
IPC分类号： C08F2/04 , C08F224/00 , C08F226/06 , C08F228/06 , C08F246/00 , C08J3/28
CPC分类号： C08F226/06 , C08F224/00 , C08F228/06 , C08F246/00 , Y10S522/904 , Y10S522/905
摘要： The invention relates to UV-crosslinkable copolymers built up fromA) from 99.5 to 75% by weight of olefinically unsaturated monomers,B) from 0.5 to 25% by weight of unsaturated compounds of the formula I ##STR1## and C) from 0.01 to 10% by weight of copolymerizable, olefinically unsaturated acetophenone and/or benzophenone derivatives containing no phenyl group having a free hydroxyl group in the ortho-position to the carbonyl group, whereX is O, S or NR.sup.1 andR is unsubstituted or substituted C.sub.2 - to C.sub.6 -alkylene, andR.sup.1 is C.sub.1 - to C.sub.8 -alkyl or phenyl.The copolymers according to the invention are suitable, after crosslinking, as coating agents, impregnants or adhesives and in particular as contact adhesives.
摘要翻译：本发明涉及由A）为99.5-75重量％的烯属不饱和单体组成的UV-可交联共聚物，B）0.5-25重量％的式I的不饱和化合物（*化学结构*）和C） 0.01〜10重量％的可与羰基邻位不含苯基的可共聚的烯属不饱和苯乙酮和/或二苯甲酮衍生物，其中X为O，S或NR1，R为未取代的或未取代的取代的C 2 -C 6亚烷基，R 1是C 1 -C 8烷基或苯基。根据本发明的共聚物在交联后适合作为包衣剂，浸渍剂或粘合剂，特别是作为接触粘合剂。

4. 发明授权

US5128386A UV-crosslinkable materials based on (meth)acrylate polymers 失效
标题翻译：基于（甲基）丙烯酸酯聚合物的紫外线交联材料
公开(公告)号：US5128386A
公开(公告)日：1992-07-07
申请号：US451085
申请日：1989-12-15
申请人： Gerd Rehmer , Andreas Boettchher , Gerhard Auchter
发明人： Gerd Rehmer , Andreas Boettchher , Gerhard Auchter
IPC分类号： C08F212/08 , C08F2/46 , C08F20/10 , C08F20/26 , C08F20/52 , C08F212/00 , C08F220/18 , C08F220/30 , C08F220/58 , C08F290/00 , C08F290/06 , C08F299/00 , C09D4/00 , C09D133/04 , C09J4/00 , C09J133/04
CPC分类号： C08F220/30 , C08F220/58 , Y10S522/904 , Y10S522/905
摘要： UV-crosslinkable materials based on (meth)acrylate copolymers contain copolymerized monomers of the general formula I ##STR1## where R is a certain alkyl radical, an aryl radical or a radical R.sup.1 and R.sup.1 is a radical ##STR2## where R.sup.2 to R.sup.6 are each H, alkyl, a non-ortho OH group, OCH.sub.3, OC.sub.2 H.sub.3, SH, SCH.sub.3, Cl, F, CN, COOH, COO(C.sub.1 -C.sub.3 -alkyl), CF.sub.3, N(CH.sub.3).sub.2, N(C.sub.2 H.sub.5).sub.2, N(CH.sub.3)C.sub.6 H.sub.5, .sup.+ N(CH.sub.3).sub.3 X.sup.- or .sup.+N(CH.sub.3).sub.X X.sup.-, where X.sup.- is an acid anion, and one or more of the radicals R.sup.2 to R.sup.6 are each a radical ##STR3## where Sp is one of the spacer groups of the following type ##STR4## and R', R" and R'" are each H or a certain hydrocarbon, and where the radicals X may be identical or different and are each a divalent, alkylene radical, a cycloalkylene radical or phenylene radical, which are bonded directly to one another and/or are bonded to one another by identical or different groups Y, and Y is a divalent radical from the group consisting of ##STR5## and k and m are each from 1 to 10 and 1 and n are each from 0 to 25.
摘要翻译：基于（甲基）丙烯酸酯共聚物的紫外线交联材料含有通式I（I）的共聚单体，其中R是某一烷基，芳基或基团R 1，R 1是基团，其中R 2 （C 1 -C 3 - 烷基），CF 3，N（CH 3）2，N（CH 3）2， C2H5）2，N（CH3）C6H5，+ N（CH3）3X-或+ N（CH3）XX-，其中X-是酸阴离子，并且一个或多个基团R 2至R 6各自为基团或或其中Sp是以下类型的间隔基之一，R'，R“和R”'各自为H或某些烃，并且其中基团X可以相同或不同，并且各自是直接相互键合和/或通过相同或不同基团Y彼此键合的二价，亚烷基，亚环烷基或亚苯基，Y是二价各自由和k和m组成的组中的根基 1〜10和1，n分别为0〜25。

5. 发明授权

US5276069A Contact adhesives for self-adhesive articles 失效
标题翻译：接触粘合剂用于自粘物品
公开(公告)号：US5276069A
公开(公告)日：1994-01-04
申请号：US695413
申请日：1991-05-03
申请人： Gerd Rehmer , Gerhard Auchter , Helmut Jaeger
发明人： Gerd Rehmer , Gerhard Auchter , Helmut Jaeger
IPC分类号： C08F20/12 , C08F2/50 , C08F8/00 , C08F8/30 , C08F8/32 , C08F20/34 , C08F20/36 , C08F20/52 , C08F20/58 , C08F220/10 , C08F220/12 , C09J4/00 , C09J4/02 , C08F2/54 , C08F216/36 , C08F220/00
CPC分类号： C08F8/32 , C08F8/14 , C08F2800/20 , C08F2810/30 , Y10S522/904 , Y10S522/905
摘要： Synthetic resins are obtainable by chemically bonding one or more compounds of the general formula I ##STR1## where R.sup.1 is --OH, --NH.sub.2, ##STR2## --NHR.sup.3 or ##STR3## R.sup.2 is --H, --CH.sub.3 or --C.sub.2 H.sub.5, R.sup.3 is --C.sub.m H.sub.2m+1, where m is from 1 to 6, R.sup.4 is --H or --CH.sub.3 and n is from 1 to 12, via the oxygen or nitrogen atom of R.sup.1 to one or more polymers A which consist ofa) from 50 to 100% by weight of one or more esters of acrylic or methacrylic acid with monohydric alcohols of 1 to 18 carbon atoms or a mixture of these esters (monomers a) andb) from 0 to 50% by weight of other copolymerizable monomers (monomers b) in polymerized form,in amounts such that the synthetic resin contains from 0.01 to 1 mole of double bonds per kg of polymer A.After exposure to ultraviolet light or to electrons, these synthetic resins are suitable as contact adhesives.
摘要翻译：合成树脂可以通过化学键合一种或多种通式I（*化学结构*）（I）的化合物，其中R1是-OH，-NH2，（*化学结构*）-NHR 3或（*化学结构*）R2 是-H，-CH 3或-C 2 H 5，R 3是-C m H 2m + 1，其中m是1至6，R 4是-H或-CH 3，n是1至12，经由R 1的氧或氮原子至一个或更多的聚合物A，其由a至50重量％至100重量％的一种或多种丙烯酸或甲基丙烯酸酯与1至18个碳原子的一元醇或这些酯（单体a）和b）的混合物从0 至50重量％的聚合形式的其它可共聚单体（单体b），其量使得合成树脂每kg聚合物A含有0.01至1摩尔双键。在暴露于紫外光或电子之后，这些合成的树脂适合作为接触粘合剂。

6. 发明授权

US06225401B1 Production of highly concentrated adhesive dispersions and their use 有权
标题翻译：生产高度浓缩的胶粘剂分散体及其用途
公开(公告)号：US06225401B1
公开(公告)日：2001-05-01
申请号：US09147707
申请日：1999-02-22
申请人： Gerd Rehmer , Bernd Stanger , Gerhard Auchter , Johannes Türk , Oral Aydin , Rüdiger Füssl
发明人： Gerd Rehmer , Bernd Stanger , Gerhard Auchter , Johannes Türk , Oral Aydin , Rüdiger Füssl
IPC分类号： C08F216
CPC分类号： C08F220/18
摘要： Readily filterable and deodorizable aqueous dispersions of pressure-sensitive adhesive, especially for self-adhesive labels, having solids contents of more than 65%, can be prepared with readily reproducible properties by copolymerizing esters of acrylic and/or methacrylic acid in the presence of less than 50 ppm of inhibitor and, preferably, in the presence of from 0.01 to 5% by weight of reducing agent by a special emulsion technique. The highly concentrated pressure-sensitive adhesive dispersion, subsequently deodorized with steam, is free from coagulum and seediness.
摘要翻译：通过在较少的丙烯酸和/或甲基丙烯酸的存在下共聚合丙烯酸和/或甲基丙烯酸的酯，可以制备易于过滤和可除臭的粘合剂水分散体，特别是具有固体含量大于65％的自粘标签，超过50ppm的抑制剂，优选在0.01至5重量％的还原剂存在下，通过特殊的乳液技术。随后用蒸汽除臭的高度浓缩的压敏粘合剂分散体没有凝结物和籽粒。

7. 发明授权

US5971036A Filling and emptying of storage tanks containing aqueous dispersions 失效
标题翻译：填充和排空含有水分散体的储罐
公开(公告)号：US5971036A
公开(公告)日：1999-10-26
申请号：US60104
申请日：1998-04-15
申请人： Gerd Rehmer , Walter Holtrup
发明人： Gerd Rehmer , Walter Holtrup
IPC分类号： B67D3/00 , B67D7/06 , B65B1/04
CPC分类号： B67D7/062 , Y10T137/86236 , Y10T137/86252 , Y10T137/86372
摘要： A method of filling and emptying storage tanks containing aqueous dispersions, where the storage tank is emptied via a line whose opening is located in the lower section of the storage tank entails filling the storage tank with a line whose outlet follows the changes in the level of the liquid surface in the course of filling and removal procedures, the level of the outlet being adjusted such that the opening is located approximately at the height of the level of the liquid.
摘要翻译：一种填充和排空含有水分散体的储罐的方法，其中储罐通过其开口位于储罐的下部的管线排空，使得管线的出口遵循水平的变化，液体表面在装卸过程中，调节出口的高度，使得开口大致位于液面高度处。

8. 发明授权

US5284734A Radiation-sensitive mixture and use thereof 失效
标题翻译：辐射敏感混合物及其用途
公开(公告)号：US5284734A
公开(公告)日：1994-02-08
申请号：US412467
申请日：1989-09-26
申请人： Rainer Blum , Gerd Rehmer , Hans Schupp
发明人： Rainer Blum , Gerd Rehmer , Hans Schupp
IPC分类号： C08G73/06 , C08G73/10 , C08J3/28 , C08L79/04 , C08L79/08 , C09D179/00 , C09D179/04 , C09D179/08 , G03F7/038 , H01L31/09 , H05K3/28 , G03C1/492
CPC分类号： G03F7/0387 , C08G73/06 , C08G73/0694 , C08G73/1025 , C08L79/04 , C08L79/08
摘要： Radiation-reactive mixtures suitable for producing insulating layers and printed circuits are composed of certain precursors for preparing polyimides polyisoindoloquinazolinediones, polyoxazinediones, polyquinazolinediones or polyquinazolones and aryl-containing carbonyl compounds which when excited by UV radiation are capable of hydrogen abstraction, these mixtures undergoing solubility differentiation on irradiation with actinic light.
摘要翻译：适用于制备绝缘层和印刷电路的辐射反应混合物由某些用于制备聚酰亚胺多异吲哚喹唑啉二聚物，聚氧杂环己二烯，聚喹唑啉酮或聚喹唑啉酮和含芳基羰基化合物的前体组成，当被紫外线辐射激发能够吸氢时，这些混合物经历溶解度分化用光化射线照射。

9. 发明授权

US5208282A Aqueous synthetic resin formulations 失效
标题翻译：水性合成树脂配方
公开(公告)号：US5208282A
公开(公告)日：1993-05-04
申请号：US698858
申请日：1991-05-13
申请人： Gerd Rehmer , Maria G. Rau , Eckehardt Wistuba , Reinhard Baecher , Helmut Teichmann , Wilhelm F. Beckerle
发明人： Gerd Rehmer , Maria G. Rau , Eckehardt Wistuba , Reinhard Baecher , Helmut Teichmann , Wilhelm F. Beckerle
IPC分类号： C08L31/02 , C08F2/22 , C08K5/07 , C08K5/25 , C08L31/04 , C08L33/00 , C08L33/04 , C09D5/02 , C09D131/02 , C09D131/04 , C09D133/06 , C09J131/02 , C09J131/04
CPC分类号： C09D133/064 , C08K5/07 , C08K5/25
摘要： Aqueous synthetic resin formulations containingA) from 3 to 75% by weight of one or more synthetic resins,B) one or more organic compounds having two or more hydrazide groups,C) from 0 to 10% by weight, based on the synthetic resin A, of benzophenone or acetophenone or of one or more acetophenone or benzophenone derivatives which are not monoethylenically unsaturated or of a mixture of these active ingredients,D) effective amounts of emulsifiers or protective colloids or of a mixture of these active ingredients,E) not less than 5% by weight of water andF) from 0 to 85% by weight of finely divided fillers, with the proviso that the total amount of the monomers d polymerized in the one or more synthetic resins A and of component C is from 0.05 to 10% by weight, based on the one or more synthetic resins A, and the ratio of the number of moles of hydrazide groups of component B and the number of moles of the aldehyde and keto groups of the monomers c polymerized in the one or more synthetic resins A is from 0.01 to 2.These synthetic resin formulations are suitable for coating, adhesive bonding, sealing or impregnating.
摘要翻译：含有A）3〜75重量％的一种或多种合成树脂的水性合成树脂制剂B）一种或多种具有两个或更多个酰肼基团的有机化合物，C）基于合成树脂的0至10重量％ A，二苯甲酮或苯乙酮或一种或多种不是单烯属不饱和的苯乙酮或二苯甲酮衍生物或这些活性成分的混合物，D）有效量的乳化剂或保护胶体或这些活性成分的混合物，E）不小于5重量％的水和F）0至85重量％的细碎填料，条件是在一种或多种合成树脂A和组分C中聚合的单体d的总量为0.05 至10重量％，基于一种或多种合成树脂A，以及组分B的酰肼基团的摩尔数与在该聚合的单体c中聚合的单体c的醛和酮基的摩尔数之比更多sy 合成树脂A为0.01至2.这些合成树脂配方适用于涂料，粘合剂，密封或浸渍。

10. 发明授权

US4879361A Preparation of bead polymers from water-soluble, ethylenically unsaturated monomers 失效
标题翻译：从水溶性烯属不饱和单体制备珠聚合物
公开(公告)号：US4879361A
公开(公告)日：1989-11-07
申请号：US168825
申请日：1988-03-16
申请人： Gerd Rehmer , Manfred Niessner , Wilfried Heide , Heinrich Hartmann , Karl-Clemens Peters
发明人： Gerd Rehmer , Manfred Niessner , Wilfried Heide , Heinrich Hartmann , Karl-Clemens Peters
IPC分类号： C08F2/00 , C08F2/32 , C08F257/00
CPC分类号： C08F2/32
摘要： Polymers in bead form are prepared from water-soluble ethylenically unsaturated monomers by a reverse suspension polymerization of a liquid in the presence of polymerization initiators and protective colloids obtainable by grafting polymers (A) containing (a) aromatic monovinyl monome from 40 to 100% by weight (b) C.sub.3-6 monoethylenically unsaturated carboxylic acid and/or maleic anhydride from 0 to 60% by weight (c) other monoethylenically unsaturated monomers from 0-20% by weight, as copolymerized units with the proviso that the sum of the weight (a) to (c) is always 100 and the polymer (A) has a molecular weight (number average) from 500 to 20,000 and a hydrogenation iodine number from 1.3 to 51 with a fixed monomer mixture at given concentration levels.
摘要翻译：珠粒形式的聚合物通过在聚合引发剂存在下通过液体的反向悬浮聚合和保护性胶体由水溶性烯键式不饱和单体制备，所述保护胶体可通过将含有（a）芳族单乙烯基单体的聚合物（A）从40至100％重量（b）0-6％重量的（c）C 3-6单烯属不饱和羧酸和/或马来酸酐，（c）0-20％重量的其它单烯属不饱和单体作为共聚单元，条件是重量之和（a）〜（c）总是为100，聚合物（A）的分子量（数均）为500〜20,000，加氢碘值为1.3〜51。

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