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1. 发明授权

US4256684A High-shrinkage acrylic fibers and the process for their production 失效
标题翻译：高收缩丙烯酸纤维及其生产工艺
公开(公告)号：US4256684A
公开(公告)日：1981-03-17
申请号：US44690
申请日：1979-06-01
申请人： Georges Achard , Gilbert Anouilh , Pierre Chion , Roger Vincent
发明人： Georges Achard , Gilbert Anouilh , Pierre Chion , Roger Vincent
IPC分类号： D01F6/18 , D01D5/22
CPC分类号： D01F6/18
摘要： Acrylic yarns and fibers having a high shrinkage power, ranging up to 50%, obtained by wet spinning, a stretching of 1.3 to 3 .times. in air, washing, a stretching of 1 to 2.5 .times. into boiling water, drying, steaming at 105.degree.-150.degree. C., over-stretching of 1.2 to 2 .times. at 90.degree.-100.degree. C.
摘要翻译：通过湿法纺丝获得的收缩率高达50％的高收缩力的丙烯酸纤维和纤维，在空气中拉伸1.3至3倍，洗涤，在沸水中拉伸1至2.5倍，干燥，在105℃蒸 -150℃，90〜-100℃过度拉伸1.2〜2倍。

2. 发明授权

US4297412A Two-component mixed acrylic fibres wherein acrylic components have different amounts of non-ionizable plasticizing comonomer 失效
标题翻译：双组分混合丙烯酸纤维，其中丙烯酸组分具有不同量的不可离子化的增塑共聚单体
公开(公告)号：US4297412A
公开(公告)日：1981-10-27
申请号：US97954
申请日：1979-11-28
申请人： Georges Achard , Pierre Chion , Jacques Menault
发明人： Georges Achard , Pierre Chion , Jacques Menault
IPC分类号： D01F8/08 , B32B27/02 , D02G1/18 , D02G3/00
CPC分类号： D01F8/08 , Y10T428/2924 , Y10T428/2929 , Y10T428/2931
摘要： The present invention relates to two-component acrylic fibres and yarns and their process of preparation.They consist of two copolymers based on acrylonitrile, in which the proportion of plasticizing comonomer differs by between 4 and 15% and which contain a total number of milliequivalents of acid of at least 50 per kg of polymer; they comprise a mixture of monolaminar, bilaminar and multilaminar strands; they possess a crimp, the direction of which depends on the heat and/or mechanical treatments to which they have been subjected, component B, which contains the smaller proportion of plasticizing comonomer, being located on the inside of the helix formed by the filaments, after treatment, without tension, at a temperature which is below about 110.degree. C. and at least equal to ambient temperature, and being located on the outside of the helix after treatment under tension or after heat treatment at a temperature above 110.degree. C., and the contraction and the crimp spacing varying from one strand to the next and along one and the same strand.The yarns and fibres according to the invention can be used in all the known textile-converting techniques, namely stretch-breaking, converting, carding and the like.
摘要翻译：本发明涉及双组分丙烯酸纤维和纱线及其制备方法。它们由两种基于丙烯腈的共聚物组成，其中增塑共聚单体的比例差异在4至15％之间，并且其含有每千克聚合物至少为50的丙酸的总数; 它们包括单层，双层和多层链的混合物; 它们具有卷曲，其方向取决于它们经受的热和/或机械处理，组分B包含较小比例的增塑共聚单体，位于由长丝形成的螺旋的内部，在低于约110℃并且至少等于环境温度的温度下处理后没有张力，并且在张力下或在高于110℃的温度下热处理后位于螺旋的外部。，并且收缩和卷曲间距从一条链到下一条并沿着同一条链变化。根据本发明的纱线和纤维可以用于所有已知的纺织品转化技术，即拉伸断裂，转换，梳理等。

3. 发明授权

US4780368A Yarns and fibers with good properties, based on a mixture of polyvinyl chloride and postchlorinated polyvinyl chloride 失效
标题翻译：基于聚氯乙烯和氯化聚氯乙烯的混合物，具有良好性能的纱线和纤维
公开(公告)号：US4780368A
公开(公告)日：1988-10-25
申请号：US825946
申请日：1986-02-03
申请人： Georges Achard , Pierre Chion , Jacques Menault
发明人： Georges Achard , Pierre Chion , Jacques Menault
IPC分类号： D01F6/48 , D01F6/10
CPC分类号： D01F6/10 , Y10T428/2913 , Y10T428/2929
摘要： The present invention relates to filaments based on a mixture of atactic polyvinyl chloride and postchlorinated polyvinyl chloride, and also to the process for their production.The filaments according to the present invention possess a residual shrinkage in boiling water of less than 2%, a modulus of elasticity of more than 3 kN/mm.sup.2 and a shrinkage stress, after shrinkage in an aqueous fluid medium at a temperature between 98.degree. and 130.degree. C., which is greater than or equal to 1.6.multidot.10.sup.-2 g/dtex.The filaments are obtained by spinning and stretching in a manner which is in itself known, then continuous stabilization under tension, at a temperature between 105.degree. and 125.degree. C., in the presence of steam under pressure, for 1 to 3 seconds, and then shrinkage in an aqueous fluid medium at a temperature between 98.degree. and 130.degree. C.The filaments according to the invention can be used, by themselves or blended with other filaments, for the production of woven fabrics, knitted fabrics and non-woven articles.
摘要翻译：本发明涉及基于无规立构聚氯乙烯和后氯化聚氯乙烯的混合物的长丝，以及其生产方法。根据本发明的长丝在水溶液介质中在98℃和98℃的温度下收缩后，沸水中的残余收缩率小于2％，弹性模量大于3kN / mm 2，收缩应力 130℃，其大于或等于1.6×10 -2 g / dtex。长丝通过以本身已知的方式通过旋转和拉伸获得，然后在105℃至125℃的温度下，在压力下的蒸汽存在下持续1至3秒，然后在张力下连续稳定，并且然后在98〜130℃的温度下在含水流体介质中收缩。根据本发明的长丝本身或与其它长丝混合可用于生产机织织物，针织物和无纺织物。

4. 发明授权

US4681595A Process for disperse dyeing dry-spun atactic polyvinyl chloride-based filaments and fibres after drawing the wet tow 失效
标题翻译：拉伸湿丝后分散染色干纺无规聚乙烯基长丝和纤维的方法
公开(公告)号：US4681595A
公开(公告)日：1987-07-21
申请号：US843603
申请日：1986-03-25
申请人： Pierre Chion , Jacques Menault
发明人： Pierre Chion , Jacques Menault
IPC分类号： D06P1/16 , D01F6/10 , D06P3/00 , D06P3/72 , D06P7/00 , D06B3/04
CPC分类号： D01F6/10 , D06P3/004 , D06P7/005 , Y10S8/928
摘要： The present invention relates to a process for continuous dyeing of filaments based on atactic polyvinyl chloride in the course of production.It comprises, in succession, the phases of drawing, impregnation of the filaments by padding while, at the time of the impregnation, the filaments have a density of between 1.3 and 1.4 g/cm.sup.3 (the filament roving having a water content of 10 to 30% by weight), of stabilization under tension in the presence of steam under pressure at a temperature between 100.degree. and 130.degree. C. for 2 to 20 seconds, and then oiling and shrinking in a known manner.Dyeing carried out in this manner is quick and makes it possible to produce colors having good fastness.
摘要翻译：本发明涉及一种在生产过程中基于无规立构聚氯乙烯连续染色长丝的方法。它连续地包括拉伸的阶段，通过浸渍浸渍长丝，而在浸渍时，长丝具有1.3-1.4g / cm 3的密度（纤维粗纱的水含量为10至 30％（重量）），在压力存在下，在100-130℃的温度下，在张力下稳定2至20秒，然后以已知的方式进行加脂和收缩。以这种方式进行的染色是快速的并且可以产生具有良好牢度的颜色。

5. 发明授权

US4308004A Device for the production of bi-component yarns 失效
标题翻译：用于生产双组分纱线的装置
公开(公告)号：US4308004A
公开(公告)日：1981-12-29
申请号：US43121
申请日：1979-05-29
申请人： Pierre Chion , Robert Cuidard , Jean Pommier , Marc Tricot
发明人： Pierre Chion , Robert Cuidard , Jean Pommier , Marc Tricot
IPC分类号： D01D5/32 , B01F5/06 , D01D5/28 , D01D5/30 , D01D5/36 , D01D3/00
CPC分类号： B01F5/0615 , B01F5/0613 , B01F5/0644 , D01D5/28 , B01F2005/0639 , Y10T428/2929
摘要： The present invention relates to a process and a device for the production of bi-component yarns containing bilaminar and multilaminar filaments.Two polymer compositions are spun after feeding through a dichotomic mixer possessing tubes of identical internal diameter (5 to 25 mm), inside which 4 to 9 helical elements are placed in series, the leading edge of each of the elements being placed at 90.degree. relative to the trailing edge of the previous element. The process and device according to the invention can be used for all types of spinning, namely solution spinning, melt spinning, semi-melt spinning and the like. The yarns obtained contain only a minor proportion of monolaminar filaments.
摘要翻译：本发明涉及用于生产含有双层和多层细丝的双组分纱线的方法和装置。两种聚合物组合物在通过具有相同内径（5至25mm）的管的二分相混合器进料之后进行纺丝，其中4至9个螺旋元件串联放置，每个元件的前缘相对于90° 到前一个元素的后端。根据本发明的方法和装置可用于所有类型的纺丝，即溶液纺丝，熔融纺丝，半熔纺等。所获得的纱线仅含有少量的单层细丝。

6. 发明授权

US4454091A Solutions, which can be shaped, from mixtures of cellulose and polyvinyl chloride, and shaped articles resulting therefrom and the process for their manufacture 失效
标题翻译：可以从纤维素和聚氯乙烯的混合物形成的可以成型的溶液，以及由此产生的成型制品及其制造方法
公开(公告)号：US4454091A
公开(公告)日：1984-06-12
申请号：US272251
申请日：1981-06-10
申请人： Pierre Chion , Jacques Menault , Henry Rodier , Jean-Paul Sacre
发明人： Pierre Chion , Jacques Menault , Henry Rodier , Jean-Paul Sacre
IPC分类号： C08L27/00 , C08J3/11 , C08K5/41 , C08L1/00 , C08L1/02 , C08L27/06 , C08L33/00 , C08L33/02 , D01F2/00 , D01F6/48 , D02G3/02 , D02J1/22 , D01F8/04
CPC分类号： D01F6/48 , C08L1/02 , C08L27/06 , Y10T428/2929 , Y10T428/2931
摘要： The present invention relates to new polymer solutions which make it possible to obtain shaped articles such as yarns and fibres, films, sheets and the like.These solutions consist of cellulose having a degree of polymerization of at least 200, polyvinyl chloride, dimethyl sulphoxide and formaldehyde, the weight ratio cellulose/polyvinyl chloride being 0.05 to 0.5, preferably 0.1 to 0.5, the ratio formaldehyde/cellulose being 0.2 to 2 and the total polymer concentration being 6 to 20%, preferably 10 to 18%.Such solutions are particularly suitable for the manufacture of filaments consisting of fibrils substantially orientated along the axis of the fibre and closely interlaced, the cellulose macromolecules being partially involved in a crystal lattice characteristic of cellulose II. The filaments possess valuable properties for textile use.
摘要翻译：本发明涉及可以获得成形制品如纱线和纤维，薄膜，片材等的新的聚合物溶液。这些溶液由聚合度至少为200的纤维素，聚氯乙烯，二甲基亚砜和甲醛组成，纤维素/聚氯乙烯的重量比为0.05至0.5，优选为0.1至0.5，甲醛/纤维素的比例为0.2至2，总聚合物浓度为6〜20％，优选为10〜18％。这种溶液特别适用于制造由纤维基本上沿着纤维轴线定向且紧密交错的纤维组成的纤维，纤维素大分子部分参与纤维素II的晶格特征。长丝具有用于织物使用的有价值的性质。

7. 发明授权

US4681594A Process for disperse dyeing dry-spun atactic polyvinyl chloride-based filaments and fibres before drawing 失效
标题翻译：拉伸前分散染色干纺无规聚乙烯基长丝和纤维的方法
公开(公告)号：US4681594A
公开(公告)日：1987-07-21
申请号：US838352
申请日：1986-03-11
申请人： Pierre Chion , Jacques Menault
发明人： Pierre Chion , Jacques Menault
IPC分类号： D06P1/16 , D01F6/10 , D06P3/00 , D06P3/79 , D06P7/00 , D06B3/04
CPC分类号： D06P7/005 , D01F6/10 , D06P3/004 , Y10S8/928
摘要： The invention relates to a process for continuous dyeing of filaments based on atactic polyvinyl chloride in the course of their production.The undrawn filaments are impregnated with a composition containing at least one plastosoluble dye while they have a density of between 1.3 and 1.4 g/cm.sup.3, are fixed continuously in the presence of steam under pressure at a temperature of between 100.degree. and 120.degree. C. for 2 to 20 seconds, are drawn in a known manner, are then fixed under tension in the presence of steam under pressure at a temperature of between 100.degree. and 130.degree. C. for 1 to 20 seconds, and are then oiled and shrunk in a known manner.Such a process permits quick dyeing, on an industrial scale, with good color fastness.
摘要翻译：本发明涉及一种在其生产过程中基于无规立构聚氯乙烯连续染色长丝的方法。未拉伸长丝用含有至少一种塑性染料的组合物浸渍，同时密度为1.3-1.4g / cm3，在蒸汽存在下，在压力为100-120℃的温度下连续地固定。 2至20秒，以已知方式抽出，然后在压力为100-130℃的蒸汽存在下，在张力下固定1至20秒，然后将其加油并收缩一种已知的方式。这种方法允许在工业规模上快速染色，具有良好的色牢度。

8. 发明授权

US4363895A Solutions, which can be shaped, from mixtures of cellulose and polyamide-imide, and shaped articles obtained 失效
标题翻译：可以从纤维素和聚酰胺 - 酰亚胺的混合物形成的可以成型的溶液和获得的成型制品
公开(公告)号：US4363895A
公开(公告)日：1982-12-14
申请号：US244135
申请日：1981-03-16
申请人： Pierre Chion , Jacques Menault , Henry Rodier
发明人： Pierre Chion , Jacques Menault , Henry Rodier
IPC分类号： C08L79/08 , C08L1/00 , C08L1/02 , D01F2/00 , D01F6/74 , D01F6/90 , D01F6/94 , C08G73/14 , D01F8/02
CPC分类号： D01F6/90 , C08L1/02 , Y10T428/2907 , Y10T428/2933
摘要： The present invention relates to new polymer solutions which make it possible to produce shaped articles, such as yarns and fibres, films, sheets and the like.These solutions consist of cellulose having a degree of polymerisation of at least 200, polyamide-imide, dimethyl sulphoxide and formaldehyde, with a weight ratio cellulose/polyamide-imide of 0.05 to 1, preferably 0.1 to 1, a ratio formaldehyde/cellulose of 0.2 to 2 and a total concentration of 6 to 25%, preferably 15 to 20%.These solutions are particularly suitable for the production of filaments which consist of fibrils substantially orientated along the axis of the fibre and closely intersecting, the cellulose macromolecules being partially involved in a crystal lattice characteristic of cellulose II. The filaments possess valuable properties for use in textiles.
摘要翻译：本发明涉及可以生产成形制品如纱线和纤维，薄膜，片材等的新的聚合物溶液。这些溶液由聚合度至少为200的纤维素，聚酰胺 - 酰亚胺，二甲基亚砜和甲醛组成，纤维素/聚酰胺 - 酰亚胺的重量比为0.05-1，优选0.1-1，甲醛/纤维素的比例为0.2 至2，总浓度为6〜25％，优选为15〜20％。这些溶液特别适用于生产由纤维基本上沿着纤维的轴线取向并且紧密相交的细丝，纤维素大分子部分参与纤维素II的晶格特征。长丝具有用于纺织品的有价值的性质。

9. 发明授权

US4052550A Poly(vinylidene fluoride) yarns and fibers 失效
标题翻译： POLY（VINYLIDENE FLUORIDE）YARNS AND FIBERS
公开(公告)号：US4052550A
公开(公告)日：1977-10-04
申请号：US653654
申请日：1976-01-29
申请人： Pierre Chion , Robert Cuidard
发明人： Pierre Chion , Robert Cuidard
IPC分类号： D01F6/12 , C08F14/22 , C08F114/22
CPC分类号： D01F6/12
摘要： A process of making polyvinylidene fluoride yarns and fibers of homogeneous structure and good dry strength includes the steps of spinning the solution of the polymer into a coagulating bath containing 45 to 60% by weight aprotic polar organic solvent and 40 to 55% by weight water, stretching the filaments in air to a ratio of 1.5 to 5x and then in boiling water to a ratio of 1.5 to 4x (overall stretching ratio of 3x to 6.5x) and then washing in water at room temperature.

10. 发明授权

US4307054A Process for the production of bi-component yarns 失效
标题翻译：生产双组分纱线的方法
公开(公告)号：US4307054A
公开(公告)日：1981-12-22
申请号：US971323
申请日：1978-12-20
申请人： Pierre Chion , Robert Cuidard , Jean Pommier , Marc Tricot
发明人： Pierre Chion , Robert Cuidard , Jean Pommier , Marc Tricot
IPC分类号： D01D5/32 , B01F5/06 , D01D5/28 , D01D5/30 , D01D5/36 , B29F3/10
CPC分类号： B01F5/0615 , B01F5/0613 , B01F5/0644 , D01D5/28 , B01F2005/0639 , Y10T428/2929
摘要： The present invention relates to a process and a device for the production of bi-component yarns containing bilaminar and multilaminar filaments.Two polymer compositions are spun after feeding through a dichotomic mixer possessing tubes of identical internal diameter (5 to 25 mm), inside which 4 to 9 helical elements are placed in series, the leading edge of each of the elements being placed at 90.degree. relative to the trailing edge of the previous element. The process and device according to the invention can be used for all types of spinning, namely solution spinning, melt spinning, semi-melt spinning and the like. The yarns obtained contain only a minor proportion of monolaminar filaments.
摘要翻译：本发明涉及用于生产含有双层和多层细丝的双组分纱线的方法和装置。两种聚合物组合物在通过具有相同内径（5至25mm）的管的二分相混合器进料之后进行纺丝，其中4至9个螺旋元件串联放置，每个元件的前缘相对于90° 到前一个元素的后端。根据本发明的方法和装置可用于所有类型的纺丝，即溶液纺丝，熔融纺丝，半熔纺等。所获得的纱线仅含有少量的单层细丝。

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