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1. 发明授权

US06689710B2 Method for producing multimetal cyanide compounds 失效
标题翻译：多金属氰化物的制备方法
公开(公告)号：US06689710B2
公开(公告)日：2004-02-10
申请号：US10204367
申请日：2002-08-20
申请人： Georg Heinrich Grosch , Dirk Franke , Manfred Munzinger , Kathrin Harre , Eva Baum , Michael Stösser
发明人： Georg Heinrich Grosch , Dirk Franke , Manfred Munzinger , Kathrin Harre , Eva Baum , Michael Stösser
IPC分类号： B01J2726
CPC分类号： C08G65/2663 , B01J27/26
摘要： A process for preparing multimetal cyanide compounds by reacting a metal salt with a cyanometalate compound comprises the steps a) precipitation of the multimetal cyanide compound by reaction of a metal salt with a cyanometalate compound and b) recrystallization of the multimetal cyanide compound precipitated in step a).
摘要翻译：通过使金属盐与氰基金属化合物反应制备多金属氰化合物的方法包括以下步骤：通过金属盐与氰基金属化合物的反应沉淀多金属氰化合物，和b）在步骤a）中沉淀的多金属氰化物化合物的重结晶。

2. 发明授权

US07015364B2 Process for preparing polyether polyols 失效
标题翻译：制备聚醚多元醇的方法
公开(公告)号：US07015364B2
公开(公告)日：2006-03-21
申请号：US10745136
申请日：2003-12-22
申请人： Georg Heinrich Grosch , Dirk Franke , Manfred Munzinger , Kathrin Harre , Eva Baum , Michael Stösser
发明人： Georg Heinrich Grosch , Dirk Franke , Manfred Munzinger , Kathrin Harre , Eva Baum , Michael Stösser
IPC分类号： C07C41/03
CPC分类号： C08G65/2663 , B01J27/26
摘要： A process for preparing polyether polyols includes a precipitation step, a recrystallization step, and a reaction step. In the precipitation step, a multimetal cyanide compound is precipitated by reaction of a metal salt with a cyanometalate compound. In the recrystallization step, the multimetal cyanide compound precipitated above is recrystallized by adding further metal salt and/or further cyanometalate compound. The recrystallization forms a multimetal cyanide catalyst compound. In the reaction step, an initiator and one or more alkylene oxide are reacted in the presence of the multimetal cyanide catalyst compound.
摘要翻译：制备聚醚多元醇的方法包括沉淀步骤，重结晶步骤和反应步骤。在沉淀步骤中，通过金属盐与氰基金属化合物的反应使多金属氰化物化合物沉淀。在重结晶步骤中，通过添加另外的金属盐和/或其他氰基金属化合物，使上述析出的多金属氰化物化合物重结晶。重结晶形成多金属氰化物催化剂化合物。在反应步骤中，引发剂和一种或多种烯化氧在多金属氰化物催化剂化合物的存在下反应。

3. 发明授权

US06764978B2 Multimetal cyanide compounds 失效
标题翻译：多金属氰化物
公开(公告)号：US06764978B2
公开(公告)日：2004-07-20
申请号：US10229979
申请日：2002-08-28
申请人： Georg Heinrich Grosch , Edward Bohres , Raimund Ruppel , Kathrin Harre , Eva Baum , Michael Stösser , Jeffery T. Miller , Richard B. Prager
发明人： Georg Heinrich Grosch , Edward Bohres , Raimund Ruppel , Kathrin Harre , Eva Baum , Michael Stösser , Jeffery T. Miller , Richard B. Prager
IPC分类号： B01J2726
CPC分类号： B01J35/002 , B01J27/26 , C08G65/2663
摘要： The invention relates to DMC catalysts which comprise at least 10% by weight, based on the weight of the DMC catalysts, of a crystalline multimetal cyanide compound whose X-ray diffractogram shows sharp reflections at least at the d values of 11.4 Å±0.5 Å 8.9 Å±0.5 Å 6.3 Å±0.5 Å 5.8 Å±0.5 Å 5.5 Å±0.5 Å 4.5 Å±0.5 Å 4.4 Å±0.5 Å 3.9 Å±0.4 Å 3.7 Å±0.4 Å 3.4 Å±0.4 Å.
摘要翻译：本发明涉及DMC催化剂，其基于DMC催化剂的重量计至少10重量％的结晶多金属氰化物化合物，其X射线衍射图至少在d值为±0.4±0.5时显示出尖锐的反射 Å8.9Å±0.5Å6.3Å±0.5Å5.8Å±0.5Å5.5Å±0.5Å4.5Å±0.5Å4.4Å±0.5Å3.9Å±0.4Å3.7Å±0.4Å3。 4Å±0.4Å。

4. 发明授权

US06800583B2 Suspension of multimetal cyanide compounds, their preparation and their use 失效
标题翻译：多金属氰化物的悬浮液，其制备及其用途
公开(公告)号：US06800583B2
公开(公告)日：2004-10-05
申请号：US09324271
申请日：1999-06-02
申请人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge , Edward Michael Dexheimer
发明人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge , Edward Michael Dexheimer
IPC分类号： B01J2726
CPC分类号： B01J27/26 , C08G65/2663
摘要： Catalyst suspensions for the ring-opening polymerization of alkylene oxides comprise a) at least one multimetal cyanide compound having a crystalline structure and a content of platelet-shaped particles of at least 30% by weight, based on the multimetal cyanide compound, and b) at least one organic complexing agent c) water and/or d) at least one polyether and/or e) at least one surface-active substance, with the proviso that at least component a) and at least two of the components b) to e) have to be present.
摘要翻译：用于烯化氧的开环聚合的催化剂悬浮液包括：a）至少一种具有至少30重量％以上的多金属氰化合物的结晶结构和片状颗粒的含量的多金属氰化物化合物，和b）至少一种有机络合剂c）水和/或）至少一种聚醚和/矿）至少一种表面活性物质，条件是至少组分a）和至少两种组分b）至e）必须是当下。

5. 发明授权

US06753402B1 Polyester-polyether block copolymers 失效
标题翻译：聚酯 - 聚醚嵌段共聚物
公开(公告)号：US06753402B1
公开(公告)日：2004-06-22
申请号：US10110297
申请日：2002-04-10
申请人： Stephan Bauer , Georg Heinrich Grosch , Gerlinde Tischer , Kathrin Harre , Eva Baum , Thomas Ostrowski , Reinhard Lorenz , Regina Pretzsch , Michael Pcolinski , Stefan Dinsch , Inge Rotermund
发明人： Stephan Bauer , Georg Heinrich Grosch , Gerlinde Tischer , Kathrin Harre , Eva Baum , Thomas Ostrowski , Reinhard Lorenz , Regina Pretzsch , Michael Pcolinski , Stefan Dinsch , Inge Rotermund
IPC分类号： C08G1842
CPC分类号： C08G81/00 , C08G18/4018 , C08G18/42 , C08G18/4261 , C08G65/2609 , C08G65/2663 , C08G2101/0008 , C08G2101/0083 , C08G2130/00 , C08L71/02 , C08L2666/18
摘要： Polyester-polyether block copolymers can be prepared by catalytic addition of alkylene oxides onto H-functional initiator substances, using polyester alcohols as H-functional initiator substances and multimetal cyanide compounds as catalysts.
摘要翻译：聚酯 - 聚醚嵌段共聚物可以通过使用聚酯醇作为H官能引发剂物质和多金属氰化物作为催化剂将环氧烷催化加成到H官能引发剂物质上来制备。

6. 发明授权

US06906110B1 Method for the production of polyurethanes 有权
标题翻译：生产聚氨酯的方法
公开(公告)号：US06906110B1
公开(公告)日：2005-06-14
申请号：US10019998
申请日：2000-11-04
申请人： Reinhard Lorenz , Stephan Bauer , Dieter Junge , Eva Baum , Kathrin Harre , Jörg Erbes , Thomas Ostrowski , Georg Heinrich Grosch
发明人： Reinhard Lorenz , Stephan Bauer , Dieter Junge , Eva Baum , Kathrin Harre , Jörg Erbes , Thomas Ostrowski , Georg Heinrich Grosch
IPC分类号： C08G18/22 , C08G18/48 , C08G65/26 , C08K3/10 , C08K3/16 , C08K3/24 , C08K3/26 , C08K5/09
CPC分类号： C08G18/4866 , C08G18/225 , C08G65/2663 , C08G2101/0008 , C08G2101/0083
摘要： In a process for producing polyurethanes by reacting at least one polyisocyanate with at least one compound containing at least two hydrogen atoms which are reactive toward isocyanate groups, the compound having at least two active hydrogen atoms which is used is at least one polyether alcohol prepared by addition of alkylene oxides onto H-functional initiator substances by means of multimetal cyanide catalysis and the reaction is carried out in the presence of at least one metal salt.
摘要翻译：在通过使至少一种多异氰酸酯与至少一种含有至少两个对异氰酸酯基团具有反应性的氢原子的化合物反应来生产聚氨酯的方法中，使用至少两个活性氢原子的化合物是至少一种由通过多金属氰化物催化将氧化烯加成到H-官能引发剂物质上，并且反应在至少一种金属盐的存在下进行。

7. 发明授权

US06613714B2 Multimetal cyanide compounds, their preparation and their use 失效
标题翻译：多金属氰化合物，其制备及其用途
公开(公告)号：US06613714B2
公开(公告)日：2003-09-02
申请号：US09324145
申请日：1999-06-02
申请人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
发明人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
IPC分类号： B01J2726
CPC分类号： C08G65/2663 , B01J27/26 , B01J35/023
摘要： In multimetal cyanide complexes, more than 30% by weight of the primary particles have a platelet-like habit, i.e. the length and width of the primary particles is at least three times the thickness of the particles.
摘要翻译：在多金属氰化物络合物中，超过30重量％的初级颗粒具有血小板样习惯，即一次颗粒的长度和宽度至少为颗粒厚度的三倍。

8. 发明授权

US06806393B2 Multimetal cyanide compounds, their preparation and their use 失效
标题翻译：多金属氰化合物，其制备及其用途
公开(公告)号：US06806393B2
公开(公告)日：2004-10-19
申请号：US10447521
申请日：2003-05-29
申请人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
发明人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
IPC分类号： C07C4311
CPC分类号： C08G65/2663 , B01J27/26 , B01J35/023
摘要： In multimetal cyanide complexes, more than 30% by weight of the primary particles have a platelet-like habit, i.e. the length and width of the primary particles is at least three times the thickness of the particles.
摘要翻译：在多金属氰化物络合物中，超过30重量％的初级颗粒具有血小板样习惯，即一次颗粒的长度和宽度至少为颗粒厚度的三倍。

9. 发明申请

US20050203274A1 Dmc catalysts, polyether alcohols, and method for the production thereof 审中-公开
标题翻译： Dmc催化剂，聚醚醇及其制备方法
公开(公告)号：US20050203274A1
公开(公告)日：2005-09-15
申请号：US10514714
申请日：2003-06-18
申请人： Edward Bohres , Dirk Franke , Michael Stosser , Raimund Ruppel , Eva Baum , Kathrin Harre
发明人： Edward Bohres , Dirk Franke , Michael Stosser , Raimund Ruppel , Eva Baum , Kathrin Harre
IPC分类号： C08G65/12 , B01J27/26 , B01J37/03 , C08G18/48 , C08G65/26 , C08G65/04
CPC分类号： B01J27/26 , B01J37/03 , C08G18/4866 , C08G65/2663
摘要： The invention relates to a process for preparing polyether alcohols by addition of alkylene oxides onto H-functional starter substances using multimetal cyanide compounds as catalysts, wherein the multimetal cyanide compound is prepared by a process comprising the steps: a) adding a metal salt solution to a cyanometalate solution at a specific stirring power ε in the range from 0.05 to 10 W/l, preferably from 0.4 to 4 W/l, a temperature in the range from 0° C. to 100° C., preferably from 20° C. to 60° C., and an addition time of from 5 to 120 minutes, b) reducing the specific stirring power ε to a value in the range from 0.03 to 0.8 W/l and at the same time adding a surface-active agent, c) heating the solution while stirring at a specific stirring power ε of from 0.03 to 0.8 W/l, to a temperature of not more than 100° C., preferably in the range from 55° C. to 75° C., d) adding further metal salt solution while stirring at a specific stirring power ε of from 0.03 to 0.8 W/l, e) when the conductivity begins to drop, dispersing the solid, for example by stirring while increasing the specific stirring power ε to >0.7 W/l or by installation of a pumped circuit with an appropriate pump or by means of a high-speed stirrer, f) stirring at the specific stirring power ε of step e) until the conductivity or the pH remains constant, g) separating off the multimetal cyanide compound and washing it with water and, if desired, h) drying the catalyst.
摘要翻译：本发明涉及通过使用多金属氰化物作为催化剂将烯化氧加成到H官能起始物质上制备聚醚醇的方法，其中所述多金属氰化合物通过包括以下步骤的方法制备：a）将金属盐溶液加入到在特定搅拌功率ε为0.05至10W / l，优选0.4至4W / l的范围内的氰酸金属盐溶液，温度范围为0℃至100℃，优选为20℃ 至60℃，加入时间为5至120分钟，b）将比重搅拌功率ε3降低至0.03-0.8W / l的范围内，同时加入表面活性剂，c）在0.03-0.8W / l的特定搅拌功率ε的搅拌下将溶液加热至不超过100℃，优选在55℃至75℃的温度， d）在搅拌下以特定搅拌功率ε加入另外的金属盐溶液从0.03至0.8W / l，e）当电导率开始下降时，例如通过搅拌分散固体，同时将特定搅拌功率ε提高至> 0.7W / l或通过用合适的泵安装泵浦回路或通过高速搅拌器，f）在步骤e）的特定搅拌功率ε下搅拌，直到导电率或pH保持恒定，g）分离多金属氰化合物并用水洗涤，如果需要，h ）干燥催化剂。

10. 发明授权

US07022884B2 Preparation of polyetherpolyols in the presence of a multimetal cyanide complex catalyst 失效
标题翻译：在多金属氰化物配合物催化剂存在下制备聚醚多元醇
公开(公告)号：US07022884B2
公开(公告)日：2006-04-04
申请号：US10203836
申请日：2001-02-16
申请人： Thomas Ostrowski , Kathrin Harre , Georg Heinrich Grosch , Jürgen Winkler
发明人： Thomas Ostrowski , Kathrin Harre , Georg Heinrich Grosch , Jürgen Winkler
IPC分类号： C07C41/03
CPC分类号： B01J27/26 , B01J19/18 , B01J2219/00085 , B01J2219/00092 , B01J2219/00094 , C08G65/2663 , C08G65/2696
摘要： Polyetherpolyols are prepared by reacting diols or polyols with ethylene oxide, propylene oxide, butylene oxide or a mixture thereof in the presence of a multimetal cyanide complex catalyst by a process which is carried out in a vertical, highly cylindrical reactor having a central stirrer and having heat exchanger plates through which a heat-exchange medium flows and which are arranged essentially in the longitudinal direction of the reactor, at an angle α of from 0 to 70° in the direction of rotation of the stirrer relative to the reactor radius.
摘要翻译：聚醚多元醇通过二醇或多元醇与环氧乙烷，环氧丁烷，环氧丁烷或其混合物在多金属氰化物配合物催化剂存在下反应来制备，所述方法是在具有中心搅拌器的垂直，高度圆柱形的反应器中进行，并且具有热交换介质流过热交换介质，其基本上沿反应器的纵向布置，在搅拌器相对于反应器半径的旋转方向上以0至70°的角度α。

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