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    • 2. 发明申请
    • PROCESS FOR PREPARING ALLYL ALCOHOL ALKOXYLATES
    • 制备全部醇金酸盐的方法
    • US20120035381A1
    • 2012-02-09
    • US13197336
    • 2011-08-03
    • Markus KLUMPEThomas OstrowskiMatthias Zipplies
    • Markus KLUMPEThomas OstrowskiMatthias Zipplies
    • C07C41/03
    • C07C41/03C08G65/2696C07C43/1785
    • A process for preparing polyether alcohols by reacting one or more unsaturated starters having at least one active hydrogen atom per molecule with one or more alkylene oxides in the liquid phase in the presence of a basic catalyst in a reactor, wherein the one or more alkylene oxides are introduced into the reactor in such a way that the concentration of unreacted alkylene oxide in the liquid reaction mixture in the reactor is increased as far as possible with increasing degree of addition of the alkylene oxide onto the starter, with the proviso that the temperature at the end of a runaway reaction is at any point in time at least 100 K below the onset temperature of the decomposition reaction of the liquid reaction mixture, is proposed.
    • 一种制备聚醚醇的方法,其通过使反应器中碱性催化剂存在下,使每一分子中具有至少一个活性氢原子的一种或多种不饱和起始物与液相中的一种或多种烯化氧反应,其中所述一种或多种烯化氧 以使得反应器中的液体反应混合物中未反应的烯化氧的浓度尽可能地增加到起始物上的环氧烷加成程度增加的方式引入反应器,条件是温度在 失控反应的结束是在液体反应混合物的分解反应开始温度以下至少100K的任何时间点。
    • 7. 发明授权
    • Process for preparing reactive polyether polyols having an ethylene oxide end block
    • 制备具有环氧乙烷端嵌段的活性聚醚多元醇的方法
    • US07186867B2
    • 2007-03-06
    • US10828967
    • 2004-04-21
    • Thomas OstrowskiRaimund RuppelGerd HöppnerSascha BergmannKoenraad VandewalleEva Baum
    • Thomas OstrowskiRaimund RuppelGerd HöppnerSascha BergmannKoenraad VandewalleEva Baum
    • C07C41/02
    • C08G65/2696C08G18/4841C08G18/4866C08G65/2663
    • Process for preparing polyether polyols having an end block of ethylene oxide by addition of alkylene oxides onto H-functional starter substances, in which A) a polyether polyol precursor is prepared by means of double metal cyanide (DMC) catalysis in a semicontinuous mode of operation in which previously prepared polyether polyol together with the DMC catalyst are placed in a reactor and H-functional starter substance and propylene oxide are added continuously, B) the polyether polyol precursor from stage A) is reacted with propylene oxide or an ethylene oxide/propylene oxide mixture in the presence of the DMC catalyst in a continuously operating reactor to give a polyether polyol intermediate, C) the intermediate from stage B) is mixed with an alkali metal hydroxide as catalyst and D) reacted with ethylene oxide in a continuously operating reactor to give the final product, E) the catalyst is separated off from the final product obtained in stage D).
    • 制备具有环氧乙烷端嵌段的聚醚多元醇的方法,其通过在H-功能起始物质上加入环氧烷烃,其中A)聚醚多元醇前体是通过半连续运行模式中的双金属氰化物(DMC)催化制备的 其中将预先制备的聚醚多元醇与DMC催化剂一起放入反应器中,并连续加入H官能引发剂物质和环氧丙烷,B)将来自阶段A)的聚醚多元醇前体与环氧丙烷或环氧乙烷/丙烯 氧化物混合物在DMC催化剂存在下在连续操作的反应器中得到聚醚多元醇中间体,C)将来自阶段B)的中间体与作为催化剂的碱金属氢氧化物混合,并且D)在连续操作的反应器中与环氧乙烷反应 得到最终产物,E)将催化剂从阶段D)中得到的最终产物中分离出来。