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1. 发明授权

US4912157A Ink compositions and preparation 失效
标题翻译：油墨组成和制备
公开(公告)号：US4912157A
公开(公告)日：1990-03-27
申请号：US187712
申请日：1988-04-29
申请人： Gary T. Clark , John N. Rasar , Rebecca R. Stockl
发明人： Gary T. Clark , John N. Rasar , Rebecca R. Stockl
IPC分类号： C09D11/10 , C09D167/00
CPC分类号： C09D167/00 , C09D11/104
摘要： A composition useful in printing inks exemplified as comprising:(1) from about 4 to about 80% by weight of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from about 1.0 to about 60% by weight of pigment material;(3) from about 0.05 to about 30% by weight of a nonionic, polyether type property modifier; and(4) from substantially none to about 90% by weight of water.
摘要翻译：用于印刷油墨的组合物，其例证包括：（1）约4至约80重量％的一种或多种聚酯材料，其酸组分为约75至约84摩尔％间苯二甲酸，相反地约25至约 16摩尔％的5-磺基间苯二甲酸，并且具有约45至约60摩尔％二甘醇的二元醇组分，相反地，约55至约40摩尔％的1,4-环己烷二甲醇或乙二醇或其混合物; （2）约1.0至约60重量％的颜料; （3）约0.05至约30重量％的非离子型聚醚型性质改性剂; 和（4）基本上不超过约90重量％的水。

2. 发明授权

US5554675A Ink compositions and preparation 失效
公开(公告)号：US5554675A
公开(公告)日：1996-09-10
申请号：US240288
申请日：1994-05-09
申请人： Gary T. Clark , John N. Rasar , Rebecca R. Stockl
发明人： Gary T. Clark , John N. Rasar , Rebecca R. Stockl
IPC分类号： C09D11/10 , C09D167/00 , C08K5/06
CPC分类号： C09D167/00 , C09D11/104
摘要： A composition useful in printing inks exemplified as comprising:(1) from about 4 to about 80% by weight of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from about 1.0 to about 60% by weight of pigment material;(3) from about 0.05 to about 30% by weight of a nonionic, polyether type property modifier; and(4) from substantially none to about 90% by weight of water.

3. 发明授权

US5274025A Ink and coating compositions containing a blend of water-dispersible polyester and hydantoin-formaldehyde resins 失效
标题翻译：含有水分散性聚酯和乙内酰脲 - 甲醛树脂的混合物的油墨和涂料组合物
公开(公告)号：US5274025A
公开(公告)日：1993-12-28
申请号：US19711
申请日：1993-02-19
申请人： Rebecca R. Stockl , Hieu D. Phan , Gary T. Clark
发明人： Rebecca R. Stockl , Hieu D. Phan , Gary T. Clark
IPC分类号： C08L67/00 , C09D11/10 , C08L77/00
CPC分类号： C08L67/00 , C09D11/102
摘要： This invention relates to a polymer blend comprising water-dissipatable, sulfonate containing, a hydantoin-formaldehyde resin.
摘要翻译：本发明涉及一种包含可水分散的磺酸盐，含有乙内酰脲 - 甲醛树脂的聚合物共混物。

4. 发明授权

US4847316A Aqueous dispersion blends of polyesters and polyurethane materials and printing inks therefrom 失效
标题翻译：聚酯和聚氨酯材料的水分散体共混物和印刷油墨
公开(公告)号：US4847316A
公开(公告)日：1989-07-11
申请号：US151685
申请日：1988-02-02
申请人： Martin F. Schick , William C. Hickman , Gary T. Clark , Rebecca R. Stockl
发明人： Martin F. Schick , William C. Hickman , Gary T. Clark , Rebecca R. Stockl
IPC分类号： C08L67/00 , C08L75/00 , C08L75/04 , C09D11/10 , C09D167/00 , C09D175/00 , C09D175/04 , C09D175/06
CPC分类号： C08L75/04 , C08L67/00 , C09D11/102
摘要： Compositions useful as printing inks or as dry or wet concentrates for the preparation of inks, comprising substantially homogenous blends of from about 0.1 to about 50.0 wt. % water dispersible polyurethane, and conversely from about 99.9 to about 50.0 wt. % water dispersible polyester, and preferably containing from about 1.0 to about 95.0 wt. % of a solvent system comprising water or water admixed with cosolvent, the cosolvent comprising up to about 30.0 wt. % of the solvent system. These blends show exceptionally marked improvements in certain physical properties such as: stability of viscosity to ambient and process conditions; linearity of viscosity change with water dilution; consistency of viscosity for a great variety of pigments; and greatly improved shelf-life (no significant polymer segregation of layering). Such properties greatly enhance the utility of these blends for use in pigmented or dyed printing inks and in other substrate coating formulations which may or may not contain colorants. Also disclosed is a process useful for the preparation of such compositions.

5. 发明授权

US4181653A Disperse dyes from 2-halo-4,6-dinitroaniline and 2(2'-alkoxy-5'-alkanoylaminoanilino)alkanes 失效
标题翻译：来自2-卤代-4,6-二硝基苯胺和2（2'-烷氧基-5'-烷酰基氨基苯胺基）烷烃的分散染料
公开(公告)号：US4181653A
公开(公告)日：1980-01-01
申请号：US839530
申请日：1977-10-05
申请人： Gary T. Clark
发明人： Gary T. Clark
IPC分类号： C09B29/08 , D06P1/18 , C09B29/26
CPC分类号： C09B29/081 , C09B29/08 , D06P1/18
摘要： Disclosed are disperse dyes comprising a chloro- or bromodinitroaniline azo moiety and a particular group of 2(2'-alkoxy-5'-alkanoylaminoanilino)alkane couplers. These dyes give exceptional color depth and brightness, shade permanency on heat setting, build, leveling, barre coverage, dye exhaustion and dyeing rate on fibers of polyester, cellulose acetate, cellulose triacetate, and polyamide (nylon) over widely varying dyeing conditions of, for example, temperature and pressure. The dyes exhibit blue shades with excellent colorfastness properties on polyester fibers and have excellent dyeability by heat fixation (Thermosol) or exhaust (boil and pressure) methods of application on this substrate. Uniform dyeability under a wide variety of conditions is an exceptional feature of the present dyes.
摘要翻译：公开了包含氯或溴二硝基苯胺偶氮部分和特定的2（2'-烷氧基-5'-烷酰基氨基苯胺基）烷烃成色剂的分散染料。这些染料在广泛变化的染色条件下，赋予聚酯，乙酸纤维素，乙酸纤维素，三乙酸纤维素，和聚酰胺（尼龙）的纤维上特殊的颜色深度和亮度，遮光性，热定型，平整度，覆盖率，染色剂耗尽和染色速率，例如温度和压力。染料在聚酯纤维上具有优异的耐色牢度性质的蓝色色调，并且通过在该基材上的热定型（热溶胶）或排气（沸腾和压力）方法具有优异的可染性。在各种条件下的均匀染色性是本发明染料的特征。

6. 发明授权

US4397781A Azo dyes from 2-amino-3-nitro-5-acylthiophene 失效
标题翻译：来自2-氨基-3-硝基-5-酰基噻吩的偶氮染料
公开(公告)号：US4397781A
公开(公告)日：1983-08-09
申请号：US276543
申请日：1981-06-22
申请人： Gary T. Clark , Max A. Weaver
发明人： Gary T. Clark , Max A. Weaver
IPC分类号： C09B29/00 , C09B29/08
CPC分类号： C09B29/0059 , C09B29/081
摘要： Disclosed are novel azo dyes containing a substituted thiophene diazo moiety which produces bright blue shades on polyester and also have good affinity, dyeability and other properties on cellulose esters. The dyes have the formula ##STR1## wherein R is selected from alkyl, phenyl and phenyl substituted with 1-3 of alkyl, alkoxy, halogen or nitro; R.sub.1 and R.sub.2 are each alkyl or one of which is also selected from hydrogen; R.sub.3 is selected from hydrogen, cycloalkyl, alkyl, alkoxy, alkylamino, phenyl, phenyl substituted as for R above, and alkyl substituted with 1-3 of hydroxy, alkoxy, acyloxy, halogen, phenyl, phenoxy or cyclohexyl; X is hydrogen, alkyl, or alkoxy; and wherein each alkyl and alkoxy moiety is straight or branched and contains from 1-8 carbons.
摘要翻译：公开了含有取代的噻吩重氮部分的新型偶氮染料，其在聚酯上产生明亮的蓝色色调，并且对纤维素酯具有良好的亲和性，染色性和其它性能。所述染料具有式“IMAGE”，其中R选自烷基，苯基和被1-3个烷基，烷氧基，卤素或硝基取代的苯基; R1和R2各自为烷基或其中一个还选自氢; R3选自氢，环烷基，烷基，烷氧基，烷基氨基，苯基，如上述取代的苯基，和被1-3个羟基，烷氧基，酰氧基，卤素，苯基，苯氧基或环己基取代的烷基; X是氢，烷基或烷氧基; 并且其中每个烷基和烷氧基部分是直链或支链的并含有1-8个碳原子。

7. 发明授权

US4374768A Disperse dyes from 5-amino-4-halo-3-methylisothiazoles 失效
标题翻译：从5-氨基-4-卤代-3-甲基异噻唑的分散染料
公开(公告)号：US4374768A
公开(公告)日：1983-02-22
申请号：US254705
申请日：1981-04-16
申请人： Jean C. Fleischer , Gary T. Clark , Ronald J. Maner
发明人： Jean C. Fleischer , Gary T. Clark , Ronald J. Maner
IPC分类号： C09B29/00 , C09B29/22
CPC分类号： C09B29/0081
摘要： Disclosed are monoazo dyes derived from diazotized 5-amino-4-halo-3-methylisothiazoles and m-acylaminoaniline couplers. These dyes impart scarlet and red shades on nylon and polyester fibers and exhibit good fastness properties. The dyes are represented by the general formula: ##STR1## wherein R.sub.1 and R.sub.2 are each selected from lower alkyl, cycloalkyl, substituted cycloalkyl, or lower alkyl substituted with phenyl, cyano, sulfonamido, carboxamido, alkoxy, hydroxy, or an imide radical; R.sub.3 is lower alkyl, lower alkyl substituted as above, phenyl, or trifluoromethyl; and X is chlorine or bromine.
摘要翻译：公开了衍生自重氮化的5-氨基-4-卤代-3-甲基异噻唑和间 - 酰基氨基苯胺偶联剂的单偶氮染料。这些染料赋予尼龙和聚酯纤维上的猩红色和红色色调，并表现出良好的牢度性能。染料由以下通式表示：其中R 1和R 2各自选自低级烷基，环烷基，取代的环烷基或被苯基，氰基，亚磺酰氨基，甲酰胺基，烷氧基，羟基或酰亚胺基取代的低级烷基; R3是低级烷基，如上所述取代的低级烷基，苯基或三氟甲基; X为氯或溴。

8. 发明授权

US4278599A Mono azo dyes from (2-alkoxy-5-alkanoylaminoanilino)alkoxy or aryloxy alkanes 失效
标题翻译：（2-烷氧基-5-烷酰基氨基苯胺基）烷氧基或芳氧基烷烃的单偶氮染料
公开(公告)号：US4278599A
公开(公告)日：1981-07-14
申请号：US86115
申请日：1979-10-18
申请人： Gary T. Clark
发明人： Gary T. Clark
IPC分类号： C09B29/08 , C07C107/06 , C09B29/14
CPC分类号： C09B29/0813
摘要： Disperse dyes from cyano, chloro, or bromodinitroaniline and (2'-methoxy-5'-alkanoylaminoanilino)alkoxy or aryloxy alkanes impart blue shades with excellent colorfastness properties and shade reproducibility on polyester fibers. The dyes of this invention have excellent dyeing properties by either heat fixation on polyester fibers or exhaust (boil and pressure) methods of application on acetate, triacetate, polyester, or polyamide fibers.These dyes are represented by the following general structure. ##STR1## wherein X is halogen or cyano;R.sub.1 and R.sub.3 are straight or branched alkyl of 1-10 carbons;R.sub.2 is 1-4C alkyl optionally substituted with lower alkoxy or aryloxy, aryl or optionally substituted aryl; andn is an integer 1-4.
摘要翻译：来自氰基，氯或溴二硝基苯胺和（2'-甲氧基-5'-烷酰基氨基苯胺基）烷氧基或芳氧基烷烃的分散染料赋予蓝色色调，在聚酯纤维上具有优异的耐色牢度和色调再现性。本发明的染料通过在聚酯纤维上的热固化或在乙酸酯，三乙酸酯，聚酯或聚酰胺纤维上的排气（煮沸和压力）方法具有优异的染色性能。这些染料由以下一般结构表示。其中X为卤素或氰基; R1和R3是1-10个碳原子的直链或支链烷基; R 2是任选被低级烷氧基或芳氧基，芳基或任选取代的芳基取代的1-4C烷基; n为整数1-4。

9. 发明授权

US5075364A Ink composition containing a blend of a polyester, an acrylic polymer and a vinyl polymer 失效
标题翻译：含有聚酯，丙烯酸聚合物和乙烯基聚合物共混物的油墨组合物
公开(公告)号：US5075364A
公开(公告)日：1991-12-24
申请号：US481544
申请日：1990-02-20
申请人： Hieu D. Phan , Gary T. Clark
发明人： Hieu D. Phan , Gary T. Clark
IPC分类号： C09D11/10
CPC分类号： C09D11/10
摘要： Disclosed is a novel blend of a water-dissipatable polyester material, an acrylic polymer and a water-dissipatable vinyl polymer. The acrylic polymer and the vinyl polymer must be compatible with the polyester. The polyester is exemplified in having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 44 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof.The polymer blends are useful for preparing ink compositions having improved block resistance, water resistance, and alcohol resistance.
摘要翻译：公开了一种新型的可水分散的聚酯材料，丙烯酸聚合物和可水分散的乙烯基聚合物的共混物。丙烯酸聚合物和乙烯基聚合物必须与聚酯相容。聚酯的实例是具有约75至约84摩尔％间苯二甲酸的酸组分，相反地具有约25至约16摩尔％的5-磺基间苯二甲酸，并且具有约45至约60摩尔％二甘醇的二醇组分二醇，相反地，约55-约44摩尔％1,4-环己烷二甲醇或乙二醇或其混合物。聚合物共混物可用于制备具有改善的耐粘连性，耐水性和耐醇性的油墨组合物。

10. 发明授权

US4921899A Ink composition containing a blend of a polyester, an acrylic polymer and a vinyl polymer 失效
标题翻译：含有聚酯，丙烯酸聚合物和乙烯基聚合物共混物的油墨组合物
公开(公告)号：US4921899A
公开(公告)日：1990-05-01
申请号：US256344
申请日：1988-10-11
申请人： Hieu D. Phan , Gary T. Clark
发明人： Hieu D. Phan , Gary T. Clark
IPC分类号： C08L33/06 , C08L27/06 , C08L33/04 , C08L67/00 , C09D11/10 , C09D125/00 , C09D127/00 , C09D167/00 , C09D167/02
CPC分类号： C09D11/10 , C08L27/06 , C08L67/00
摘要： Disclosed is a novel blend of a water-dissipatable polyester material, an acrylic polymer and a water-dissipatable vinyl polymer. The acrylic polymer and the vinyl polymer must be compatible with the polyester. The polyester is exemplified in having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 44 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof.The polymer blends are useful for preparing ink compositions having improved block resistance, water resistance, and alcohol resistance.

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