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1. 发明授权

US06514621B1 Patterned coated articles and methods for producing the same 失效
标题翻译：图案涂层制品及其制造方法
公开(公告)号：US06514621B1
公开(公告)日：2003-02-04
申请号：US09199976
申请日：1998-11-25
申请人： Gary J. Marietti , Mehran Arbab , James J. Finley
发明人： Gary J. Marietti , Mehran Arbab , James J. Finley
IPC分类号： C03C1727
CPC分类号： B44C1/04 , B32B17/10174 , B32B17/10247 , B32B17/10339 , B44F1/08 , Y10T428/12597 , Y10T428/24802
摘要： The present invention is directed to an article with a patterned appearance provided by a visually observable contrast between one or more generally transparent thin film coatings deposited over a substrate. At least one of the deposited coatings exhibits a reflected color and/or contrast and visible differing transmitted color and/or contrast or a plurality of coatings together exhibit different reflected colors and/or contrasts. The coatings are selected from the group of: metals depositable by magnetron sputtering vacuum deposition, chemical vapor deposition, pyrolytic coating, or sol-gel techniques, metal oxide coatings, metal nitride coatings, semi-conductor containing coatings, metal oxynitrides and mixtures thereof. The present invention is also directed to a method of making the articles having a visually observable patterned appearance involving masking and applying the coating or applying the coating and removing a portion of the coating to form the pattern.
摘要翻译：本发明涉及具有图案外观的制品，其通过在基底上沉积的一个或多个通常透明的薄膜涂层之间的视觉上可观察到的对比度来提供。沉积的涂层中的至少一个表现出反射的颜色和/或对比度，并且可见的不同的透射颜色和/或对比度或多个涂层一起显示不同的反射颜色和/或对比度。涂层选自：通过磁控溅射真空沉积，化学气相沉积，热解涂层或溶胶 - 凝胶技术沉积的金属，金属氧化物涂层，金属氮化物涂层，含半导体的涂层，金属氮氧化物及其混合物。本发明还涉及一种制造具有视觉上可观察到的图案外观的制品的方法，其包括掩蔽和施加涂层或施加涂层并除去涂层的一部分以形成图案。

2. 发明授权

US06666983B2 Patterned coated articles and methods for producing the same 失效
标题翻译：图案涂层制品及其制造方法
公开(公告)号：US06666983B2
公开(公告)日：2003-12-23
申请号：US10263499
申请日：2002-10-03
申请人： Gary J. Marietti , Mehran Arbab , James J. Finley
发明人： Gary J. Marietti , Mehran Arbab , James J. Finley
IPC分类号： C03C1500
CPC分类号： B44C1/04 , B32B17/10174 , B32B17/10247 , B32B17/10339 , B44F1/08 , Y10T428/12597 , Y10T428/24802
摘要： The present invention is directed to an article with a patterned appearance provided by a visually observable contrast between one or more genereally transparent thin film coatings deposited over a substrate. At least one of the deposited coatings exhibits a reflected color and/or contrast and visible differing transmitted color and/or contrast or a plurality of coatings together exhibit different reflected colors and/or contrasts. The coatings are selected from the group of: metals depositable by magnetron sputtering vacuum deposition, chemical vapor deposition, pyrolytic coating, or sol-gel techniques, metal oxide coatings, metal nitride coatings, semi-conductor containing coatings, metal oxynitrides and mixtures thereof. The present invention is also directed to a method of making the articles having a visually observable patterned appearance involving masking and applying the coating or applying the coating and removing a portion of the coating to form the pattern.
摘要翻译：本发明涉及具有图案外观的制品，其通过在基底上沉积的一个或多个基本上透明的薄膜涂层之间的视觉上可观察到的对比度来提供。沉积的涂层中的至少一个表现出反射的颜色和/或对比度，并且可见的不同的透射颜色和/或对比度或多个涂层一起显示不同的反射颜色和/或对比度。涂层选自：通过磁控溅射真空沉积，化学气相沉积，热解涂层或溶胶 - 凝胶技术沉积的金属，金属氧化物涂层，金属氮化物涂层，含半导体的涂层，金属氮氧化物及其混合物。本发明还涉及一种制造具有视觉上可观察到的图案外观的制品的方法，其包括掩蔽和施加涂层或施加涂层并除去涂层的一部分以形成图案。

3. 发明授权

US06495251B1 Silicon oxynitride protective coatings 失效
标题翻译：氮氧化硅保护涂层
公开(公告)号：US06495251B1
公开(公告)日：2002-12-17
申请号：US09058440
申请日：1998-04-09
申请人： Mehran Arbab , Gary J. Marietti , Paul A. Medwick , Larry A. Miller
发明人： Mehran Arbab , Gary J. Marietti , Paul A. Medwick , Larry A. Miller
IPC分类号： B32B1706
CPC分类号： C03C17/3605 , C03C17/3435 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3639 , C03C17/3642 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C2217/78 , C23C14/0676 , C23C28/322 , C23C28/34 , C23C28/345 , C23C28/347 , C23C28/36 , Y10T428/24942 , Y10T428/265
摘要： A layer for protecting an underlying functional coating stack for example a single silver layer or double silver layer Low-E coating stack includes silicon oxynitride or silicon aluminum oxynitride layer. The protective film may have a uniform composition throughout its thickness i.e. homogeneous protective layer, a constantly increasing or decreasing index of infraction throughout its thickness i.e. a graded protective layer, or a combination of all or some of the foregoing i.e. a non-homogeneous protective layer. The graded and non-homogeneous layers may have an outer surface of silicon nitride, silicon aluminum nitride, silicon dioxide, silicon oxynitride or silicon aluminum oxynitride. The protective layer of the invention may be the last layer deposited on the functional coating stack or may have a film deposited thereon.
摘要翻译：用于保护底层功能性涂层叠层的层，例如单个银层或双层银层Low-E涂层堆叠包括氮氧化硅或硅铝氧氮化物层。保护膜可以在其整个厚度上具有均匀的组成，即均匀的保护层，其整个厚度的不断增加或减少的破坏指数，即渐变保护层，或全部或部分前述的组合，即非均匀保护层。分级和非均匀层可以具有氮化硅，氮化硅铝，二氧化硅，氮氧化硅或氮氧化硅铝的外表面。本发明的保护层可以是沉积在功能涂层叠层上的最后层，或者可以在其上沉积薄膜。

4. 发明授权

US5942338A Coated articles 失效
标题翻译：涂层文章
公开(公告)号：US5942338A
公开(公告)日：1999-08-24
申请号：US23746
申请日：1998-02-13
申请人： Mehran Arbab , Russell C. Criss , Gary J. Marietti , Paul A. Medwick
发明人： Mehran Arbab , Russell C. Criss , Gary J. Marietti , Paul A. Medwick
IPC分类号： B32B7/02 , B32B9/00 , B32B15/08 , B32B17/06 , B32B18/00 , C03C17/36 , C23C14/00 , G02B1/11 , G02B5/20 , G02B5/28 , B21D39/00
CPC分类号： C03C17/36 , C03C17/3618 , C03C17/3639 , C03C17/3642 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , G02B1/116 , G02B5/208 , G02B5/282 , C03C2217/78 , Y10T428/12549 , Y10T428/12597 , Y10T428/12611 , Y10T428/12618 , Y10T428/12875
摘要： Multilayer high transmittance, low emissivity coatings deposited over transparent substrates have improved mechanical durability, e.g. scratch resistance by the inclusion of at least one mechanical durability enhancing layer (hereinafter "MDE layer"). The MDE layer includes one or more pairs of a zinc oxide sublayer having deposited thereover a sublayer of an oxide of zinc and tin. In one embodiment of the present invention, the MDE layer is composed of two sublayers which includes a first sublayer of an oxide of zinc having deposited thereover a second sublayer of an oxide of zinc and tin. In another embodiment of the invention, the MDE layer is composed of four sublayers which includes a first sublayer of an oxide of zinc, having deposited thereover a second sublayer of an oxide of zinc and tin, having deposited thereover a third sublayer of an oxide of zinc, having deposited thereover a fourth sublayer of an oxide of zinc and tin. Coated articles having the MDE layer of the invention can be thermally processed for tempering, heat strengthening, annealing or bending without haze formation and can be manipulated prior to such thermal processing with little or no surface scratching appearing after such thermal processing.
摘要翻译：沉积在透明基底上的多层高透光率，低辐射率涂层具有改善的机械耐久性，例如通过包含至少一个机械耐久性增强层（以下称为“MDE层”）的耐擦伤性。 MDE层包括一对或多对氧化锌层，其上沉积有锌和锡的氧化物的子层。在本发明的一个实施方案中，MDE层由两个子层组成，这两个子层包括锌的氧化物的第一子层，其上沉积有锌和锡的氧化物的第二子层。在本发明的另一个实施方案中，MDE层由四个子层组成，其包括锌的氧化物的第一子层，其上沉积有锌和锡的氧化物的第二子层，其上沉积有第三子层的氧化物锌，其上沉积有锌和锡的氧化物的第四子层。具有本发明的MDE层的涂层制品可以进行热处理以进行回火，热强化，退火或弯曲而不产生雾度，并且可以在这种热加工之前进行操作，在这种热处理之后几乎没有或没有出现表面划痕。

5. 发明授权

US06682773B2 Light-transmitting and/or coated article with removable protective coating and methods of making the same 有权
标题翻译：具有可移除保护涂层的透光和/或涂层制品及其制造方法
公开(公告)号：US06682773B2
公开(公告)日：2004-01-27
申请号：US10080824
申请日：2002-02-22
申请人： Paul A. Medwick , Erin Goodreau , Ernest L. Lawton , James J. Finley , George M. Martin , James P. Thiel , Gary J. Marietti , Roger L. Scriven
发明人： Paul A. Medwick , Erin Goodreau , Ernest L. Lawton , James J. Finley , George M. Martin , James P. Thiel , Gary J. Marietti , Roger L. Scriven
IPC分类号： B05D100
CPC分类号： C09D5/008 , B65B33/04 , B65G49/069 , C03C17/32 , C03C17/38 , C03C17/42 , C03C2217/475 , C03C2217/485 , C03C2218/328 , C03C2218/355 , Y10T428/273 , Y10T428/30 , Y10T428/31507 , Y10T428/31649 , Y10T428/31681 , Y10T428/31692 , Y10T428/31699 , Y10T428/31703 , Y10T428/31786 , Y10T428/31931 , Y10T428/31935
摘要： A method and coating are provided for temporarily protecting a substrate or article during shipping, handling or storage by applying a removable protective coating over at least a portion of the substrate. The substrate may be flat or curved and may have zero, one or more functional coatings. A plurality of substrates with the protective coating of the invention may be arranged in a shipping container so that the protective coating reduces the possibility of damage to the substrate or optional functional coating. In one embodiment, the protective coating is the evaporation or reaction product of an aqueous coating composition containing a polyvinyl alcohol polymer which may be subsequently removed by aqueous washing, thermal decomposition or combustion. In another embodiment, the protective coating is formed by sputtering a substantially carbon coating onto the substrate. The carbon coating is subsequently removed by combustion. The protective coating may have identification materials, such as colorants or fragrance materials, such that different types of substrates and/or functional coatings can be distinguished from each other. Additionally, the temporary protective coating can improve the heating of a functionally coated glass substrate.
摘要翻译：提供了一种方法和涂层，用于在运输，处理或存储期间通过在基底的至少一部分上施加可移除的保护涂层来临时保护基底或制品。基底可以是平的或弯曲的，并且可以具有零个一个或多个功能性涂层。具有本发明的保护涂层的多个基底可以布置在运输容器中，使得保护涂层减少了损坏基底或可选功能性涂层的可能性。在一个实施方案中，保护性涂层是含有聚乙烯醇聚合物的水性涂料组合物的蒸发或反应产物，其可随后通过水洗，热分解或燃烧除去。在另一个实施方案中，通过将基本上碳涂层溅射到基底上而形成保护涂层。随后通过燃烧除去碳涂层。保护涂层可以具有识别材料，例如着色剂或香料，使得可以区分不同类型的基材和/或功能性涂层。此外，临时保护涂层可以改善功能性涂覆的玻璃基板的加热。

6. 发明授权

US06849328B1 Light-transmitting and/or coated article with removable protective coating and methods of making the same 有权
标题翻译：具有可移除保护涂层的透光和/或涂层制品及其制造方法
公开(公告)号：US06849328B1
公开(公告)日：2005-02-01
申请号：US09567934
申请日：2000-05-10
申请人： Paul A. Medwick , Erin Goodreau , Ernest L. Lawton , James J. Finley , George M. Martin , James P. Thiel , Gary J. Marietti , Roger L. Scriven
发明人： Paul A. Medwick , Erin Goodreau , Ernest L. Lawton , James J. Finley , George M. Martin , James P. Thiel , Gary J. Marietti , Roger L. Scriven
IPC分类号： B05D5/00 , B05D7/00 , B32B7/06 , B32B9/00 , B65G49/06 , C03C17/32 , C03C17/38 , C03C17/42 , C09D5/00 , B32B17/10
CPC分类号： C09D5/008 , B65B33/04 , B65G49/069 , C03C17/32 , C03C17/38 , C03C17/42 , C03C2217/475 , C03C2217/485 , C03C2218/328 , C03C2218/355 , Y10T428/273 , Y10T428/30 , Y10T428/31507 , Y10T428/31649 , Y10T428/31681 , Y10T428/31692 , Y10T428/31699 , Y10T428/31703 , Y10T428/31786 , Y10T428/31931 , Y10T428/31935
摘要： A method and coating are provided for temporarily protecting a substrate or article during shipping, handling or storage by applying a removable protective coating over at least a portion of the substrate. The substrate may be flat or curved and may have zero, one or more functional coatings. A plurality of substrates with the protective coating of the invention may be arranged in a shipping container so that the protective coating reduces the possibility of damage to the substrate or optional functional coating. In one embodiment, the protective coating is the evaporation or reaction product of an aqueous coating composition containing a polyvinyl alcohol polymer which may be subsequently removed by aqueous washing, thermal decomposition or combustion. In another embodiment, the protective coating is formed by sputtering a substantially carbon coating onto the substrate. The carbon coating is subsequently removed by combustion. The protective coating may have identification materials, such as colorants or fragrance materials, such that different types of substrates and/or functional coatings can be distinguished from each other. Additionally, the temporary protective coating can improve the heating of a functionally coated glass substrate.
摘要翻译：提供了一种方法和涂层，用于在运输，处理或存储期间通过在基底的至少一部分上施加可移除的保护涂层来临时保护基底或制品。基底可以是平的或弯曲的，并且可以具有零个一个或多个功能性涂层。具有本发明的保护涂层的多个基底可以布置在运输容器中，使得保护涂层减少了损坏基底或可选功能性涂层的可能性。在一个实施方案中，保护性涂层是含有聚乙烯醇聚合物的水性涂料组合物的蒸发或反应产物，其可随后通过水洗，热分解或燃烧除去。在另一个实施方案中，通过将基本上碳涂层溅射到基底上而形成保护涂层。随后通过燃烧除去碳涂层。保护涂层可以具有识别材料，例如着色剂或香料，使得可以区分不同类型的基材和/或功能性涂层。此外，临时保护涂层可以改善功能性涂覆的玻璃基板的加热。

7. 发明授权

US09556071B2 Methods for forming an electrodeposited coating over a coated substrate and articles made thereby 有权
标题翻译：在涂覆的基底上形成电沉积涂层的方法和由此制成的制品
公开(公告)号：US09556071B2
公开(公告)日：2017-01-31
申请号：US11751328
申请日：2007-05-21
申请人： James J. Finley , Donald W. Boyd , Gary J. Marietti
发明人： James J. Finley , Donald W. Boyd , Gary J. Marietti
IPC分类号： C25D13/00 , C03C17/42 , C25D13/20
CPC分类号： C03C17/42 , C03C2218/115 , C03C2218/156 , C25D13/20 , Y10T428/12007
摘要： A coated article includes a non-conductive substrate, such as glass. At least one conductive coating is formed over at least a portion of the substrate, such as by chemical vapor deposition or physical vapor deposition. The conductive coating can be a functional coating and can have a thickness in the range of greater than 0 Å to less than 25,000 Å, such as less than 10,000 Å. At least one polymeric coating is electrodeposited over at least a portion of the conductive coating.
摘要翻译：涂覆制品包括诸如玻璃的非导电基底。在衬底的至少一部分上形成至少一个导电涂层，例如通过化学气相沉积或物理气相沉积。导电涂层可以是功能性涂层，并且可以具有在大于0至小于等于25,000的范围内的厚度，例如小于10,000埃。至少一个聚合物涂层电沉积在至少一部分导电涂层上。

8. 发明申请

US20100173141A1 COATED NON-METALLIC SHEET HAVING A BRUSHED METAL APPEARANCE, AND COATINGS FOR AND METHOD OF MAKING SAME 审中-公开
标题翻译：具有刷毛金属外观的包覆非金属片及其制造方法及其制造方法
公开(公告)号：US20100173141A1
公开(公告)日：2010-07-08
申请号：US12726501
申请日：2010-03-18
申请人： Paul A. Medwick , James P. Thiel , Gary J. Marietti
发明人： Paul A. Medwick , James P. Thiel , Gary J. Marietti
IPC分类号： B32B5/00 , B32B15/04 , B05D3/00 , B05D3/12 , B05D5/00 , C23F1/02
CPC分类号： C03C17/36 , B32B17/10036 , B32B17/10174 , B32B17/10247 , B44F1/06 , C03C17/3613 , C03C17/3615 , C03C17/3639 , C03C17/3642 , C03C17/3644 , C03C17/366 , C03C17/3681 , C03C17/3684 , C03C19/00 , C03C2217/72 , C03C2217/77 , C03C2217/78 , Y10T428/24355 , Y10T428/24364 , Y10T428/24917 , Y10T428/31 , Y10T428/31678 , Y10T428/8305
摘要： A method of making an article that exhibits a metallic appearance includes treating a surface of a non-metallic substrate, e.g. a glass sheet to have a textured surface, and applying an overlay, e.g. a coating over the pattern. The percent of visible light transmittance, and percent visible light reflectance, of the substrate and the overlay is selected such that the pattern is visible when the article is viewed through one of the surfaces of the substrate or overlay. Also provided is a heatable coating having a low emissivity that can be used as the overlay.
摘要翻译：制造具有金属外观的制品的方法包括处理非金属基材的表面，例如，具有纹理表面的玻璃板，以及施加覆盖层，例如，在图案上的涂层。选择基板和覆盖层的可见光透射率和可见光反射率的百分比，使得当通过基板或覆盖层的一个表面观察制品时，该图案是可见的。还提供了可以用作覆盖层的具有低发射率的可加热涂层。

9. 发明申请

US20090233106A1 REFLECTIVE ARTICLE AND METHOD OF MAKING A REFLECTIVE ARTICLE 有权
标题翻译：反思性文章和制作反思性文章的方法
公开(公告)号：US20090233106A1
公开(公告)日：2009-09-17
申请号：US12330618
申请日：2008-12-09
申请人： Paul A. Medwick , Andrew V. Wagner , Gary J. Marietti
发明人： Paul A. Medwick , Andrew V. Wagner , Gary J. Marietti
IPC分类号： B05D5/06 , C23C14/34 , B32B17/06
CPC分类号： G02B1/14 , C03C17/36 , C03C17/3639 , C03C17/3644 , C03C17/3652 , C03C17/3663 , C23C14/185 , F24S23/82 , G02B1/10 , G02B1/105 , G02B5/0858 , Y02E10/40 , Y10T428/23 , Y10T428/24942 , Y10T428/24975 , Y10T428/26
摘要： A reflective article, such as a solar mirror, includes a highly transparent substrate having a first major surface and a second major surface. At least one reflective coating is formed over at least a portion of one of the surfaces, e.g., the second major surface (or, alternatively, the first major surface). The reflective coating includes at least one metallic layer. An encapsulation structure can be formed over at least a portion of the second reflective coating.
摘要翻译：诸如太阳镜的反射制品包括具有第一主表面和第二主表面的高度透明的基材。在一个表面的至少一部分上形成至少一个反射涂层，例如第二主表面（或替代地，第一主表面）。反射涂层包括至少一个金属层。可以在第二反射涂层的至少一部分上形成封装结构。

10. 发明授权

US08445098B2 Reflective article having multiple reflective coatings 有权
公开(公告)号：US08445098B2
公开(公告)日：2013-05-21
申请号：US12330651
申请日：2008-12-09
申请人： Paul A. Medwick , Andrew V. Wagner , Gary J. Marietti
发明人： Paul A. Medwick , Andrew V. Wagner , Gary J. Marietti
IPC分类号： B32B7/02 , B32B9/04 , B32B15/04 , B32B17/06 , B32B15/00 , B32B3/02 , B05D3/02 , C03C17/06
CPC分类号： G02B1/14 , C03C17/36 , C03C17/3639 , C03C17/3644 , C03C17/3652 , C03C17/3663 , C23C14/185 , F24S23/82 , G02B1/10 , G02B1/105 , G02B5/0858 , Y02E10/40 , Y10T428/23 , Y10T428/24942 , Y10T428/24975 , Y10T428/26
摘要： A reflective article, such as a solar mirror, includes a highly transparent substrate having a first major surface and a second major surface. At least one reflective coating is formed over at least a portion of one of the surfaces, e.g., the second major surface (or, alternatively, the first major surface). The reflective coating includes at least one metallic layer. An encapsulation structure can be formed over at least a portion of the second reflective coating.

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