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1. 发明申请

US20160339633A1 FUSED FILAMENT FABRICATION USING MULTI-SEGMENT FILAMENT 审中-公开
标题翻译：使用多部分纤维的熔融纤维制造
公开(公告)号：US20160339633A1
公开(公告)日：2016-11-24
申请号：US15112098
申请日：2015-01-17
申请人： GRAPHENE 3D LAB INC.
发明人： Daniel Stolyarov , Elena Polyakova
IPC分类号： B29C67/00
CPC分类号： B29C67/0055 , B29C48/02 , B29C48/05 , B29C48/2665 , B29C48/865 , B29C48/92 , B29C64/106 , B29C64/20 , B29C2948/92571 , B29C2948/9258 , B29K2023/04 , B29K2025/08 , B29L2009/00 , B33Y10/00 , B33Y30/00 , B33Y70/00
摘要： A thermoplastic filament adapted for use in a fused filament fabrication (FFF) printer which has a plurality of segments wherein each pair of adjacent segments is compositionally different and is arranged in a specific order. Also, a method for printing a three-dimensional (3D) article by printing such a filament in a fused filament fabrication (FFF) printer, wherein the fused filament fabrication (FFF) printer carries out a pattern of printing synchronized with the order of the segments in such a filament. Further, a method and device for fabricating such thermoplastic filaments.
摘要翻译：适用于熔丝制造（FFF）打印机的热塑性长丝，其具有多个段，其中每对相邻的段在组成上是不同的并且以特定顺序排列。另外，一种通过在熔丝制造（FFF）打印机中印刷这种细丝来打印三维（3D）制品的方法，其中熔丝制造（FFF）打印机执行印刷图案，其顺序为在这种细丝中的片段。此外，用于制造这种热塑性长丝的方法和装置。

2. 发明授权

US11097492B2 Thermoplastic composites comprising water-soluble PEO graft polymers useful for 3-dimensional additive manufacturing 有权
公开(公告)号：US11097492B2
公开(公告)日：2021-08-24
申请号：US15555253
申请日：2016-02-29
申请人： GRAPHENE 3D LAB INC.
发明人： Daniel Stolyarov , Irina Pomestchenko
IPC分类号： B29C64/40 , B33Y70/00 , C08J5/04 , C08K3/22 , C08K5/06 , B33Y10/00 , B29C64/112 , B29C64/118 , B29C64/135 , B29K71/00 , B29K105/16 , B29K509/02
摘要： Water-soluble thermoplastic polymer composites of water-soluble thermoplastic polyethylene oxide graft polymers, and nanoscopic particulate processing aids such nanoscopic titanium dioxide powders, or water-soluble polyethylene oxide graft polymers, structural reinforcement materials such as carbon or glass fibers, and plasticizers. These water-soluble thermoplastic polymer composites may be useful in preparing, for example, three-dimensional (3D) sacrificial supports, vapor sensors, as well as other three-dimensional (3D) articles, objects, or parts.

3. 发明授权

US11591467B2 Thermoplastic polymer composites and methods for preparing, collecting, and tempering 3D printable materials and articles from same 有权
公开(公告)号：US11591467B2
公开(公告)日：2023-02-28
申请号：US15748018
申请日：2016-07-22
申请人： GRAPHENE 3D LAB INC.
发明人： Irina Pomestchenko , Daniel Stolyarov , Elena Polyakova , Ivan Stolyarov
IPC分类号： B33Y70/10 , C08L67/04 , C04B24/26 , C04B26/18 , C08K5/00 , C08K3/013 , B29C70/88 , B29C48/05 , C08K3/04 , B29C71/02 , C08J3/215 , C08K3/08 , C08K3/22 , C08K5/11 , C08K5/50 , C08K5/524 , C08K7/06 , C09D11/104 , C09D11/322 , C09D11/52 , C04B111/00 , C04B111/94 , B29B9/06 , B29K67/00 , B29K105/00 , B29K105/16 , B29K509/02
摘要： Electrically conductive thermoplastic polymer composites of particulate thermoplastic polyester polymers, electrically conductive components (carbon nanofibers, graphene nanoplatelets, and/or conductive metal nanoparticulates), processing aids such as plasticizers, thermal stabilizers, etc., as well as nanoscopic particulate fillers such as nanoscopic titanium dioxide, etc., the electrically conductive components being distributed substantially uniformly in the composite to form an electrically conductive network. Also, methods for preparing thermoplastic polymer composites, a system for collecting extruded filaments prepared from thermoplastic polymer composites as a coil of filament, as well as method for tempering articles formed from thermoplastic polymer composites to increase the degree of crystallinity of the thermoplastic polymers and thus their mechanical strength properties.

4. 发明申请

US20180208762A1 THERMOPLASTIC POLYMER COMPOSITES AND METHODS FOR PREPARING, COLLECTING, AND TEMPERING 3D PRINTABLE MATERIALS AND ARTICLES FROM SAME 审中-公开
公开(公告)号：US20180208762A1
公开(公告)日：2018-07-26
申请号：US15748018
申请日：2016-07-22
申请人： GRAPHENE 3D LAB INC.
发明人： Irina Pomestchenko , Daniel Stolyarov , Elena Polyakova , Ivan Stolyarov
IPC分类号： C08L67/04 , C08K3/04 , C08K7/06 , C08K3/08 , C08K3/22 , C08K5/11 , C08K5/524 , C08K5/50 , C08J3/215 , C09D11/52 , C09D11/322 , C09D11/104 , B29C71/02
CPC分类号： C08L67/04 , B29B9/06 , B29C48/05 , B29C70/882 , B29C71/02 , B29C2071/027 , B29K2067/046 , B29K2105/0038 , B29K2105/162 , B29K2509/02 , B29K2995/0005 , B33Y70/00 , C04B24/26 , C04B26/18 , C04B2111/00181 , C04B2111/94 , C08J3/215 , C08J2367/04 , C08K3/013 , C08K3/042 , C08K3/046 , C08K3/08 , C08K3/22 , C08K5/0016 , C08K5/005 , C08K5/11 , C08K5/50 , C08K5/524 , C08K7/06 , C08K2003/0806 , C08K2003/085 , C08K2003/2241 , C08K2201/001 , C08K2201/011 , C08L2201/08 , C09D11/104 , C09D11/322 , C09D11/52 , C04B14/026 , C04B14/042 , C04B14/06 , C04B14/303 , C04B14/304 , C04B14/305 , C04B14/34 , C04B14/386 , C04B2103/30
摘要： Electrically conductive thermoplastic polymer composites of particulate thermoplastic polyester polymers, electrically conductive components (carbon nanofibers, graphene nanoplatelets, and/or conductive metal nanoparticulates), processing aids such as plasticizers, thermal stabilizers, etc., as well as nanoscopic particulate fillers such as nanoscopic titanium dioxide, etc., the electrically conductive components being distributed substantially uniformly in the composite to form an electrically conductive network. Also, methods for preparing thermoplastic polymer composites, a system for collecting extruded filaments prepared from thermoplastic polymer composites as a coil of filament, as well as method for tempering articles formed from thermoplastic polymer composites to increase the degree of crystallinity of the thermoplastic polymers and thus their mechanical strength properties.

5. 发明申请

US20160276056A1 DISPERSIONS FOR NANOPLATELETS OF GRAPHENE-LIKE MATERIALS AND METHODS FOR PREPARING AND USING SAME 审中-公开
标题翻译：类似石墨材料的纳米材料的分散体及其制备和使用方法
公开(公告)号：US20160276056A1
公开(公告)日：2016-09-22
申请号：US14901032
申请日：2014-06-28
申请人： GRAPHENE 3D LAB INC.
发明人： Daniel Stolyarov , Elena Polyakova , Irina Pomestchenko
IPC分类号： H01B1/24 , C08J3/11 , C09D11/38 , B29C67/00
CPC分类号： H01B1/24 , B29C64/165 , B29C64/40 , B29K2105/16 , B33Y10/00 , B33Y40/00 , B33Y70/00 , B33Y80/00 , B82Y30/00 , C08J3/11 , C08J2301/02 , C09D11/38 , H01B1/04
摘要： A dispersion of nanoplatelet graphene-like material, such as graphene nanoplatelets, in a solid or liquid dispersion media wherein the nanoplatelet graphene-like material is dispersed substantially uniformly in the dispersion media with a graphene-like material dispersant. Such dispersions may be used to prepare articles by three-dimensional (3D) printing, as well as to provide electrically conductive inks and coatings, chemical sensors and biosensors, electrodes, energy storage devices, solar cells, etc. Liquid dispersions may be prepared, for example, by sonication of solutions of graphite flakes, dispersant, and liquid dispersion media, while solid dispersions may be prepared, for example, by combining the melted polymer with the liquid dispersion, dissolving the solid polymer in a miscible solvent and then blending with the liquid dispersion, dissolving the solid polymer in the liquid dispersion, or polymerizing one or more monomers in the liquid dispersion to form the solid polymer.
摘要翻译：在固体或液体分散介质中的纳米血小板石墨烯样材料（例如石墨烯纳米片）的分散体，其中纳米血小板石墨烯样材料基本上均匀地分散在具有石墨烯类材料分散剂的分散介质中。这种分散体可用于通过三维（3D）印刷制备制品，以及提供导电油墨和涂层，化学传感器和生物传感器，电极，储能装置，太阳能电池等。可以制备液体分散体，例如通过超声处理石墨薄片，分散剂和液体分散介质的溶液，而固体分散体可以例如通过将熔融的聚合物与液体分散体组合，将固体聚合物溶解在可混溶的溶剂中，然后与液体分散体，将固体聚合物溶解在液体分散体中，或在液体分散体中聚合一种或多种单体以形成固体聚合物。

6. 发明授权

US10727537B2 Electrochemical devices comprising nanoscopic carbon materials made by additive manufacturing 有权
公开(公告)号：US10727537B2
公开(公告)日：2020-07-28
申请号：US15508170
申请日：2015-08-28
申请人： GRAPHENE 3D LAB INC.
发明人： Daniel Stolyarov , Elena Polyakova , Irina Pomestchenko
IPC分类号： H01M4/00 , H01M10/058 , H01G11/36 , H01G11/48 , H01G11/50 , H01G11/86 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/62 , H01M4/04 , H01G11/32 , B33Y80/00 , H01G11/10 , H01G11/40 , H01G11/52 , H01M4/58 , H01M10/0525 , H01M10/0565 , H01M10/052 , H01G11/56 , H01G11/62
摘要： Electrochemical devices, such as batteries, supercapacitors, etc., which may be prepared from nanoscopic electrically conductive carbon materials, and optionally electrochemically active materials. Also, methods for preparing such electrochemical devices, including components, elements, etc., of such devices by using three-dimensional (3D) printing, fused deposition modeling (FDM), selective laser sintering (SLS), etc., techniques.

7. 发明申请

US20180050495A1 THERMOPLASTIC COMPOSITES COMPRISING WATER-SOLUBLE PEO GRAFT POLYMERS USEFUL FOR 3-DIMENSIONAL ADDITIVE MANUFACTURING 审中-公开
公开(公告)号：US20180050495A1
公开(公告)日：2018-02-22
申请号：US15555253
申请日：2016-02-29
申请人： GRAPHENE 3D LAB INC.
发明人： Daniel Stolyarov , Irina Pomestchenko
IPC分类号： B29C64/40 , B33Y70/00 , C08K3/22 , C08K5/06 , C08J5/04
CPC分类号： B29C64/40 , B29C64/112 , B29C64/118 , B29C64/135 , B29K2071/02 , B29K2105/162 , B29K2509/02 , B29K2995/0062 , B29K2995/0088 , B33Y10/00 , B33Y70/00 , C08J5/04 , C08J5/041 , C08J5/042 , C08K3/22 , C08K5/06 , C08K2003/2241
摘要： Water-soluble thermoplastic polymer composites of water-soluble thermoplastic polyethylene oxide graft polymers, and nanoscopic particulate processing aids such nanoscopic titanium dioxide powders, or water-soluble polyethylene oxide graft polymers, structural reinforcement materials such as carbon or glass fibers, and plasticizers. These water-soluble thermoplastic polymer composites may be useful in preparing, for example, three-dimensional (3D) sacrificial supports, vapor sensors, as well as other three-dimensional (3D) articles, objects, or parts.

8. 发明申请

US20170346129A1 ELECTROCHEMICAL DEVICES COMPRISING NANOSCOPIC CARBON MATERIALS MADE BY ADDITIVE MANUFACTURING 审中-公开
公开(公告)号：US20170346129A1
公开(公告)日：2017-11-30
申请号：US15508170
申请日：2015-08-28
申请人： GRAPHENE 3D LAB INC.
发明人： Daniel Stolyarov , Elena Polyakova , Irina Pomestchenko
IPC分类号： H01M10/058 , B33Y80/00 , H01M4/62 , H01M4/58 , H01M4/525 , H01M4/505 , H01M4/485 , H01G11/86 , H01M10/0525 , H01G11/10 , H01G11/36 , H01G11/52 , H01G11/48 , H01G11/40 , H01M10/0565 , H01G11/50 , H01G11/56 , H01G11/62
摘要： Electrochemical devices, such as batteries, supercapacitors, etc., which may be prepared from nanoscopic electrically conductive carbon materials, and optionally electrochemically active materials. Also, methods for preparing such electrochemical devices, including components, elements, etc., of such devices by using three-dimensional (3D) printing, fused deposition modeling (FDM), selective laser sintering (SLS), etc., techniques.

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