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1. 发明申请

US20230091624A1 BIODEGRADABLE POLYESTER SOLUTION AND USE THEREOF 有权
公开(公告)号：US20230091624A1
公开(公告)日：2023-03-23
申请号：US17759544
申请日：2021-01-14
申请人： KANEKA CORPORATION
发明人： Tomoaki HASHIGUCHI
IPC分类号： C08G63/06 , C09J167/04 , C09D11/104
摘要： An object of an embodiment of the present invention is to provide a biodegradable polyester solution that exhibits good solubility in a halogen-free organic solvent and that has sufficient adhesive strength even when aged for a short time. The object is achieved by providing a biodegradable polyester solution containing a poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) copolymer and a solvent, the poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) copolymer having an average content of 16 mol % or more 3-hydroxyhexanoate.

2. 发明授权

US11566146B2 Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof 有权
公开(公告)号：US11566146B2
公开(公告)日：2023-01-31
申请号：US16768329
申请日：2018-11-30
申请人： AXALTA COATING SYSTEMS GMBH
发明人： John R. Moore , Michael R. Koerner , Christian Jackson , Bradley A. Jacobs , Shih-Wa Wang , Matthew Irwin , Matthew Boland , Joanne Hardy , Daniel Naugle , Kevin O'Connor , Barry Snyder
IPC分类号： C09D175/04 , B05C5/02 , B05D1/02 , C09D167/00 , C09D7/43 , B05B12/14 , B05C11/10 , C09D175/06 , C09D11/104 , C09D11/324 , C09D11/328 , B05B1/02 , B41J2/14 , C09D11/102 , C09D11/322 , C09D167/02 , B05D5/06 , C09D5/33 , C08G18/42 , C08G18/44 , C08G18/75 , B05D7/00 , B41M7/00 , C09D7/61 , C09D7/41 , B05D1/26 , C09D7/20 , C09D5/08 , B41M5/00 , C08K3/04 , C08K3/34 , C08K5/3465
摘要： A coating composition for application to a substrate utilizing a high transfer efficiency applicator is provided herein. The coating composition includes monomeric, oligomeric, or polymeric compounds having a number average molecular weight of from about 400 to about 20,000 and having a free-radically polymerizable double bond. The coating composition further includes a photo initiator. The coating composition has an Ohnesorge number (Oh) of from about 0.01 to about 12.6. The coating composition has a Reynolds number (Re) of from about 0.02 to about 6,200. The coating composition has a Deborah number (De) of from greater than 0 to about 1730.

3. 发明授权

US11505712B2 Copper ink 有权
公开(公告)号：US11505712B2
公开(公告)日：2022-11-22
申请号：US16634934
申请日：2018-07-31
申请人： National Research Council of Canada
发明人： Bhavana Deore , Chantal Paquet , Patrick Malenfant
IPC分类号： C09D11/52 , C23C18/14 , B41M1/12 , B41M3/00 , B41M7/00 , C09D11/037 , C09D11/104 , H05K1/09 , H05K3/12
摘要： A copper-based ink contains copper hydroxide and diethanolamine. The ink may be coated on a substrate and decomposed on the substrate to form a conductive copper coating on the substrate. The ink is low cost and micron-thick traces of the ink may be screen printed and thermally sintered in the presence of up to about 500 ppm of oxygen or photo-sintered in air to produce highly conductive copper features. Sintered copper traces produced from the ink have improved air stability compared to traces produced from other copper inks. Sintered copper traces having sheet resistivity of about 20 mΩ/□/mil or less may be obtained for 5-20 mil wide screen-printed lines with excellent resolution.

4. 发明授权

US11485865B2 Thermosetting compositions and forming three-dimensional objects therefrom 有权
公开(公告)号：US11485865B2
公开(公告)日：2022-11-01
申请号：US16344488
申请日：2017-10-30
申请人： Covestro (Netherlands) B.V.
发明人： Paulus Antonius Maria Steeman , Marco Marcus Matheus Driessen
IPC分类号： C09D11/101 , B33Y70/00 , B33Y10/00 , B29C64/124 , C09D11/102 , C08F290/06 , C09D11/104 , C09D11/107 , C09D11/30 , B29C64/153 , G03F7/038
摘要： Thermoset compositions and methods for forming three-dimensional articles via an additive fabrication process, and articles made therefrom are disclosed herein. In an embodiment, a composition comprises a first network-forming component comprising a TPA-based polyester comprising a backbone and having at least 2 polymerizable groups, one or more first network monomers, and a first network initiator. The backbone of the TPA-based polyester comprises the reaction product of a terephthalic acid and a polyol. The composition may further comprise a second network-forming component.

5. 发明申请

US20220282102A1 INKS FOR 3D PRINTING HAVING LOW POLYMERIZATION SHRINKAGE 有权
公开(公告)号：US20220282102A1
公开(公告)日：2022-09-08
申请号：US17825396
申请日：2022-05-26
申请人： 3D SYSTEMS, INC.
发明人： Khalil MOUSSA
IPC分类号： C09D11/101 , B33Y10/00 , B29C64/124 , C08F20/28 , C08F20/36 , C09D11/104
摘要： In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises 20-60 wt. % oligomeric curable material; 10-50 wt. % cyclocarbonate (meth)acrylate monomer; and 0.1-5 wt. % photoinitiator, based on the total weight of the ink. Additionally, in some cases, the ink further comprises one or more additional curable materials differing from the oligomeric curable material and the cyclocarbonate (meth)acrylate monomer. An ink described herein, in some embodiments, also comprises one or more additional component that are non-curable.

6. 发明申请

US20220119664A1 INK SET, INKJET PRINTING APPARATUS, AND INKJET PRINTING METHOD 有权
公开(公告)号：US20220119664A1
公开(公告)日：2022-04-21
申请号：US17482556
申请日：2021-09-23
申请人： Yuusuke Koizuka , Naoto Shimura , Nozomi Terai , Tatsuya Takarada
发明人： Yuusuke Koizuka , Naoto Shimura , Nozomi Terai , Tatsuya Takarada
IPC分类号： C09D11/40 , C09D11/322 , C09D11/104 , C09D11/037 , C09D11/033 , B41M5/00 , B41J2/14
摘要： Provided is an ink set including standard ink and light ink. Standard ink includes cyan, magenta, and yellow inks. Light ink includes a light cyan or light magenta ink, or both. The pigment concentration in cyan ink is 1.9% by mass or greater but 3.6% by mass or less. The pigment concentration in light cyan ink is 0.4% by mass or greater but 1.4% by mass or less. The pigment concentration in magenta ink is 1.9% by mass or greater but 3.6% by mass or less. The pigment concentration in light magenta ink is 0.4% by mass or greater but 1.4% by mass or less. The light ink contains water, organic solvent, and resin. The organic solvent contains amide compound represented by General formula (1). In General formula (1), R1, R2, and R3 each represent a hydrocarbon group containing from 1 through 8 carbon atoms.

7. 发明授权

US11267949B2 (Meth)acrylated compounds based on recycled PET 有权
公开(公告)号：US11267949B2
公开(公告)日：2022-03-08
申请号：US17160771
申请日：2021-01-28
申请人： ALLNEX Belgium S.A.
发明人： Hugues Van Den Bergen , Paul Gevaert , Stephan Peeters
IPC分类号： C08J11/24 , C09D11/104 , C08G63/48 , C09J167/07 , C09D167/07 , C08G63/183 , C08G63/47 , C09D11/101 , C08G63/91 , C07C67/02 , C07C67/03
摘要： The present invention relates to a process for preparing a polyester (meth)acrylate resin (I), said process comprising the steps of: (a) Reacting a thermoplastic polyester with (a1) at least one polyhydric alcohol and, optionally, with (a2) at least one triglyceride, wherein the molar ratio of triglyceride to thermoplastic polyester is between 0 and 0.3, and the molar ratio of polyhydric alcohol to thermoplastic polyester is at most 1.9 to obtain a depolymerization product A that has a hydroxyl number within the range of from 200 to 800 mg KOH/g; (b) Reacting the depolymerization product A with (b1) at least one fatty acid and/or (b2) at least one polybasic carboxylic acid and, optionally, with (b3) at least one polyhydric alcohol to provide a polyester polyol B; (c) Reacting the polyester polyol B with (c) at least one (meth)acrylating compound to provide a (meth)acrylated compound (I), wherein the weight ratio of fatty acid (b1) to the depolymerization product A is between 0 and 0.6, wherein the weight ratio of polybasic carboxylic acid (b2) to the depolymerization product A is less than 0.3, wherein the weight ratio of (meth)acrylating compounds (c) to the depolymerization product A is between 0.1 and 0.8, and wherein the (meth)acrylated compound (I) that is obtained has a number average molecular weight (Mn) of between 500 and 5,000 Dalton. Typically PET is used as starting material. Typically compounds (I) of the invention have a PET content of at least 15 wt %, preferably at least 25 wt %. The present invention also relates to (meth)acrylated compounds (I) thus obtained and to coating compositions and inks based upon these materials. Materials of the invention allow the use of a high amount of PET waste. Inks and coatings prepared from these materials exhibit an excellent pigment wetting and/or ink-water balance.

8. 发明申请

US20220056287A1 ACTIVE ENERGY RAY-CURABLE FLEXOGRAPHIC PRINTING INK COMPOSITION 有权
公开(公告)号：US20220056287A1
公开(公告)日：2022-02-24
申请号：US17416135
申请日：2019-12-18
申请人： SAKATA INX CORPORATION
发明人： Tadashi HIROSE , Takashi ASANO
IPC分类号： C09D11/101 , C09D11/104 , C09D11/12
摘要： An object is to constitute an active energy ray-curable flexographic printing ink composition that uses more biomass-derived components, while still maintaining such basic properties as curability, adhesion, rub resistance, scratch resistance, etc. As a solution, an active energy ray-curable flexographic printing ink composition is provided that contains a plant oil-modified polyfunctional (polyester) oligomer by 20.0 to 70.0% by mass in the ink composition and an acrylamide derivative by 20.0 to 45.0% by mass in the ink composition, and has a viscosity of 300 to 2,000 mPa·s.

9. 发明申请

US20220055378A1 INKJET INK AND INKJET TEXTILE PRINTING METHOD 有权
公开(公告)号：US20220055378A1
公开(公告)日：2022-02-24
申请号：US17403156
申请日：2021-08-16
申请人： KYOCERA Document Solutions Inc.
发明人： Ryotaro KOMADA
IPC分类号： B41J11/00 , C09D11/328 , C09D11/104 , C09D11/033 , C09D11/037 , D06P5/30 , D06P1/16 , D06P1/52 , D06P5/20 , B41J3/407
摘要： An inkjet ink includes an aqueous medium, composite particles, and a cross-linking agent. The composite particles are emulsified particles of a composite of a polyester resin and a disperse dye. The polyester resin includes at least one repeating unit derived from a polyhydric alcohol and at least one repeating unit derived from a polybasic carboxylic acid. The polyester resin is non-crystalline. The polyester resin has a glass transition point of at least 45° C. and no higher than 75° C. The polyester resin has an acid value of at least 10 mgKOH/g and no greater than 70 mgKOH/g. The polyester resin has a hydroxyl value of at least 20 mgKOH/g and no greater than 60 mgKOH/g. The cross-linking agent includes a blocked isocyanate.

10. 发明申请

US20210317325A1 AQUEOUS INK FOR INKJET RECORDING 有权
公开(公告)号：US20210317325A1
公开(公告)日：2021-10-14
申请号：US17266389
申请日：2019-07-26
申请人： KAO CORPORATION
发明人： Tomohiko NAGANO , Teruyuki FUKUDA , Takahiro MAEDA
IPC分类号： C09D11/328 , C09D11/54 , C09D11/104 , B41M5/00
摘要： The present invention relates to [1] an aqueous composition for ink-jet printing, containing a carbodiimide compound, a polyester resin and water; [2] a ink set for ink-jet printing containing an aqueous composition a containing a carbodiimide compound and water, and an aqueous composition b containing a polyester resin; [3] an ink set for ink-jet printing, containing the aforementioned aqueous composition for ink-jet printing and a water-based ink containing a colorant; and [4] an ink-jet printing method including the step 1 of ejecting a carbodiimide compound, a polyester resin, a colorant and water onto a surface of a printing medium by an ink-jetting method to print characters or images thereon; and the step 2 of subjecting the resulting printed characters or images to heat treatment at a temperature of 50 to 200° C. According to the aqueous composition of the present invention, it is possible to obtain a printed material that is excellent in rub fatness.

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