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    • 8. 发明授权
    • Pattern formation method and surface treating agent
    • 图案形成方法和表面处理剂
    • US06258972B1
    • 2001-07-10
    • US08691124
    • 1996-08-01
    • Satoko NakaokaMasayuki EndoHiromi OhsakiAkiko Katsuyama
    • Satoko NakaokaMasayuki EndoHiromi OhsakiAkiko Katsuyama
    • C07E708
    • G03F7/0751
    • To the surface of a semiconductor substrate made of silicon, isopropenoxytrimethylsilane is supplied as a surface treating agent to render the surface of the semiconductor substrate hydrophobic and increase adhesion to the semiconductor substrate. Thus, Si(CH3)3 (trimethylsilyl group) is substituted for the hydrogen atom of an OH group on the surface of the semiconductor substrate, resulting in (CH3)2CO (acetone). Subsequently, a chemically amplified resist is applied to the surface of the semiconductor substrate and exposed to light by using a desired mask, followed sequentially by PEB and development for forming a pattern. Since the surface treating agent does not generate ammonia, there can be formed a pattern in excellent configuration with no insoluble skin layer formed thereon.
    • 向由硅制成的半导体衬底的表面提供异丙烯氧基三甲基硅烷作为表面处理剂,使半导体衬底的表面疏水化并增加对半导体衬底的粘合性。 因此,将Si(CH 3)3(三甲基甲硅烷基)取代为半导体衬底的表面上的OH基的氢原子,得到(CH 3)2 CO(丙酮)。 随后,通过使用所需的掩模将化学放大型抗蚀剂施加到半导体衬底的表面并暴露于光,然后依次由PEB和显影形成图案。 由于表面处理剂不产生氨,因此可以形成具有优异构型的图案,其上不形成不溶性表皮层。
    • 9. 发明授权
    • Resist composition and a method for formation of a pattern using the
composition
    • 抗蚀剂组合物和使用该组合物形成图案的方法
    • US6143472A
    • 2000-11-07
    • US195236
    • 1998-11-18
    • Motoshige SuminoAkiko Katsuyama
    • Motoshige SuminoAkiko Katsuyama
    • G03F7/004G03F7/039
    • G03F7/039G03F7/0045
    • This invention relates to a resist composition comprising a polymer containing, as a constituent unit, a monomer unit shown by the general formula [1a] ##STR1## (wherein X is a polycyclic hydrocarbon residue which may have a substituent, Z is a spacer or a direct bond, and R is a substituted alkyl or alkenyl group having one or two protected hydroxyl groups as substituent), a photosensitive compound which can generate an acid upon exposure to light and a solvent which can dissolve the polymer and the photosensitive compound, and a method for formation of a pattern using the said resist composition.The said resist composition shows high sensitivity and high resolution ability in which a polymer having high transmittance against deep-ultraviolet lights having a wavelength of 220 nm or less, particularly ArF excimer laser beams. The said resist composition can remarkably advantageously be used as a resist material for ArF excimer laser beams which has been considered to be a valuable technology for exposure belonging to the coming generation.
    • 本发明涉及一种抗蚀剂组合物,其包含含有由通式[1a]所示的单体单元作为构成单元的聚合物(其中X为可以具有取代基的多环烃残基,Z为间隔基或直接键 R为具有1个或2个被保护的羟基作为取代基的取代的烷基或链烯基),能够在光照下产生酸的光敏化合物和溶解聚合物和感光性化合物的溶剂,以及 使用所述抗蚀剂组合物形成图案。 所述抗蚀剂组合物显示出高灵敏度和高分辨能力,其中对波长为220nm以下的深紫外光具有高透射率的聚合物,特别是ArF准分子激光束。 所述抗蚀剂组合物可以显着有利地用作用于ArF准分子激光束的抗蚀剂材料,其被认为是属于下一代的有意义的曝光技术。