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1. 发明授权

US5214121A Process for manufacturing diols and polyurethanes containing perfluoroalkyl radicals 失效
标题翻译：制备二恶烷和含有全氟烷基基团的聚氨酯的方法
公开(公告)号：US5214121A
公开(公告)日：1993-05-25
申请号：US702800
申请日：1991-05-17
申请人： Franz Mosch , LuSimpert , Michael Bernheim
发明人： Franz Mosch , LuSimpert , Michael Bernheim
IPC分类号： C07C311/04 , C07C317/18 , C07C319/14 , C08G18/30 , C08G18/32 , C08G18/38 , C08G18/50 , C08G18/80 , C08G65/32 , D06M15/576
CPC分类号： C08G18/3855 , C08G18/3812 , C08G18/3825 , C08G18/3861 , C08G18/387
摘要： Diols containing perfluoroalkyl radicals are produced by reacting compounds of the formulaR.sub.f --(E).sub.m --X'--H(R.sub.f =perfluoroalkyl radical, E is an alkylene group optionally interrupted by certain groups and/or substituted at the end, m=0 or 1, X'--H=--CONRH, --SO.sub.2 NRH or --SH) in a first step with diols containing at least 2 halogen atoms. Preferably the obtained products are reacted in a second reaction step with polyvalent isocyanates to prepolymers with free --NCO-- or free --OH--groups and these prepolymers are reacted in a third step with compounds containing isocyanate groups and/or hydroxyl groups. The first reaction step is carried out in an aprotic solvent which is insoluble in water, in the presence of an aqueous solution of an alkali metal carbonate. Intermediate products have not to be isolated.The obtained polyurethanes can be used in form of aqueous dispersions for the oil- and water repellent finishing of textiles.
摘要翻译：含有全氟烷基的二醇通过使式Rf-（E）m-X'-H的化合物（Rf =全氟烷基，E是任选被某些基团间隔的烷基和/或末端取代的m = 0）或1，X'-H = -CONRH，-SO2NRH或-SH）的第二步中，使用含有至少2个卤素原子的二醇。优选地，所得产物在第二反应步骤中与多价异氰酸酯与具有游离-NCO-或游离-OH基团的预聚物反应，并且这些预聚物在第三步骤中与含有异氰酸酯基团和/或羟基的化合物反应。第一反应步骤在碱金属碳酸盐水溶液存在下，在不溶于水的非质子传递溶剂中进行。中间产品没有被隔离。得到的聚氨酯可以以水分散体的形式用于纺织品的防油和防水整理。

2. 发明授权

US5112930A Modified polyurethanes containing perfluoroaliphatic groups and use thereof 失效
标题翻译：含有全氟聚醚的改性聚氨酯及其用途
公开(公告)号：US5112930A
公开(公告)日：1992-05-12
申请号：US667721
申请日：1991-03-11
申请人： Simpert Ludemann , Michael Bernheim , Bernhard Sandner , Erich Rossler , Hans-Burkhardt Vogel
发明人： Simpert Ludemann , Michael Bernheim , Bernhard Sandner , Erich Rossler , Hans-Burkhardt Vogel
IPC分类号： C08G18/08 , C08G18/00 , C08G18/10 , C08G18/38 , C08G18/61 , C08G18/77 , C08G18/83 , C08L75/04 , D06M15/576
CPC分类号： D06M15/576 , C08G18/10 , C08G18/387 , C08G18/837 , C08L75/04 , Y10T442/2172
摘要： Modified polyurethanes containing perfluoroaliphatic groups which are obtained by reacting oligo(poly)urethanes containing free hydroxyl or isocyanate groups and perfluoroaliphatic groups with di/polyfunctional polysiloxanes at elevated temperatures with conversion of all the reactive groups of the urethane are used for the oil- and water-repellent finishing of fiber materials, conferring on these materials thus treated not only laundering- and drycleaning-stable effects but also in particular a very soft, full hand of very good surface smoothness, these excellent hand effects being further optimized by the addition of a polyethylene dispersion and/or of further customary textile assistants, in particular water-repellent fluorocarbon compounds.

3. 发明授权

US4895927A Water soluble, self-crosslinking, polymeric condensation product of amino (meth) acrylate and phosponic acid ester 失效
标题翻译：氨基（甲基）丙烯酸酯和磷酸酯的水溶性，自交联，聚合缩合产物
公开(公告)号：US4895927A
公开(公告)日：1990-01-23
申请号：US172878
申请日：1988-03-25
申请人： Simpert Ludemann , Michael Bernheim
发明人： Simpert Ludemann , Michael Bernheim
IPC分类号： C08F20/34 , C08G79/02 , C08L33/04 , C08L33/06 , D06M13/02 , D06M13/244 , D06M13/282 , D06M13/288 , D06M15/267
CPC分类号： C08G79/02 , Y10T428/31504
摘要： The present invention contains a process for manufacturing a water-soluble, self-crosslinking, polymeric condensation product by reacting 1 mole di-C.sub.1-4 -alkylamino-C.sub.24 alkyl(meth)acrylates with 0.3 to 1.5 mol di-C.sub.1-3 -alkyl-phosphonates in the presence of water under heating up to a remarkable increase of the viscosity.If aqueous solutions of these condensation products are used for the treatment of fibrous materials, a very high antistatic effect is imparted to them with only small changes of shade and a very good dry- and wet rubbing fastness as well as water-fastness. The effects show a good permanency.
摘要翻译：本发明包含一种通过使1摩尔二-C1-4烷基氨基-C24烷基（甲基）丙烯酸酯与0.3-1.5摩尔二-C1-3烷基 - 丙烯酸酯反应制备水溶性自交联聚合缩合产物的方法，在加热的情况下在水存在下使膦酸盐显着增加粘度。如果将这些缩合产物的水溶液用于纤维材料的处理，则仅具有小的变化和非常好的干湿摩擦牢度以及耐水性，赋予它们非常高的抗静电效果。效果显示出良好的永久性。

4. 发明授权

US4735685A Process for sizing paper or cardboard with anionic hydrophobic sizing agents and cationic retention aids 失效
标题翻译：使用阴离子疏水施胶剂和阳离子助留剂调整纸张或纸板的方法
公开(公告)号：US4735685A
公开(公告)日：1988-04-05
申请号：US773705
申请日：1985-09-09
申请人： Michael Bernheim , Hubert Meindl , Peter Rohringer
发明人： Michael Bernheim , Hubert Meindl , Peter Rohringer
IPC分类号： C07D307/89 , D21H17/07 , D21H17/16 , D21H17/56 , D21H3/08
CPC分类号： C07D307/89 , D21H17/07 , D21H17/16
摘要： Anionic sizing agents containing anhydride groups, which are novel compounds and which contain a single N,N-C.sub.6 -C.sub.22 di(alkyl- or alkenyl)amido group, a N-C.sub.6 -C.sub.22 (alkyl- or alkenyl)amido group or a C.sub.6 -C.sub.22 -(alkyl or alkenyl) ester group as hydrophobic substituent, and at least one anionic group in acid or salt form, in particular the anhydride of a N,N-C.sub.6 -C.sub.22 dialkylamido- or N,N-C.sub.6 -C.sub.22 dialkenylamidocarboxylic acid, the anhydride of a N-C.sub.6 -C.sub.22 alkylamido- or N,N-C.sub.6 -C.sub.22 alkenylamidocarboxylic acid, or the C.sub.6 -C.sub.22 alkyl ester or C.sub.6 -C.sub.22 alkenyl ester of an aromatic tetracarboxylic acid anhydride or a salt thereof, are particularly suitable, together with commerically available retention aids, for use in a process for pulp-sizing or surface-sizing paper or cardboard.
摘要翻译：含有酸酐基团的阴离子施胶剂是新型化合物，其含有单个N，N-C 6 -C 22二（烷基 - 或烯基）酰氨基，N-C 6 -C 22（烷基 - 或烯基）酰氨基或C 6 -C 22二 C 22 - （烷基或烯基）酯基作为疏水性取代基，以及至少一种酸或盐形式的阴离子基团，特别是N，N-C6-C22二烷基酰氨基或N，N-C6-C22二烯酰基氨基羧酸的酸酐， N-C6-C22烷基酰氨基或N，N-C6-C22链烯基酰胺羧酸或芳香族四羧酸酐或其盐的C 6 -C 22烷基酯或C 6 -C 22烯基酯的酸酐特别合适，以及商业上可获得的保留辅助材料，用于纸浆尺寸或表面尺寸纸张或纸板的过程中。

5. 发明授权

US5393859A Organopolysiloxanes containing substituted 1,3,5-triazine units 失效
标题翻译：含有取代的1,3,5-三嗪单元的有机聚硅氧烷
公开(公告)号：US5393859A
公开(公告)日：1995-02-28
申请号：US252728
申请日：1994-06-02
申请人： Michael Bernheim , Harald Chrobaczek , Michael Messner
发明人： Michael Bernheim , Harald Chrobaczek , Michael Messner
IPC分类号： C08G77/38 , C08G77/54 , D06M15/643 , D06M15/647 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/16 , D06M101/30 , D06M101/34 , C08G77/40
CPC分类号： D06M15/6436 , C08G77/54
摘要： Organopolysiloxanes in which two polysiloxane chains are bonded via a divalent radical can be obtained by reaction of cyanuric halides with organopolysiloxanes which contain primary amino groups in substituents. The divalent radical contains 1,3,5-triazine rings, to which a halogen atom is still bonded. The organopolysiloxanes thus obtained are suitable for soft handle treatment of fiber materials. In particular, textile sheet-like structures which comprise cellulose fibers can thereby be given a soft handle and improved permanence of the treatment effects with respect to washing processes.
摘要翻译：其中两个聚硅氧烷链通过二价基团键合的有机聚硅氧烷可以通过将氰尿酰卤与在取代基中含有伯氨基的有机聚硅氧烷反应获得。二价基团含有1,3,5-三嗪环，其中卤素原子仍然键合。这样获得的有机聚硅氧烷适用于纤维材料的软处理。特别地，包含纤维素纤维的织物片状结构因此可以被赋予柔软的手感并且改善了洗涤过程中处理效果的持久性。

6. 发明授权

US5021263A Aqueous textile treatment agent and crease resist finishing of textile material 失效
标题翻译：纺织品水性纺织品处理剂和抗皱整理
公开(公告)号：US5021263A
公开(公告)日：1991-06-04
申请号：US526193
申请日：1990-05-21
申请人： Xaver Kastele , Michael Bernheim , Erich Rossler
发明人： Xaver Kastele , Michael Bernheim , Erich Rossler
IPC分类号： D06M15/65 , D06M13/02 , D06M13/148 , D06M13/322 , D06M13/35 , D06M13/352 , D06M13/402 , D06M13/432 , D06M15/423 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08
CPC分类号： D06M13/352 , D06M15/423
摘要： An aqueous textile treatment agent is based on 1,3-dialkyl-4,5-dihydroxy-imidazolidinones and selected polyhydric alcohols, in particular 1,6-hexanediol or 1,1,1-tris(hydroxymethyl)-ethane and is used for the formaldehyde-free finishing of textile material which consists at least partly of cellulose or regenerated cellulose fibers in order to confer crease and shrink resistance thereon, the textile material so treated being notable for appreciably improved whiteness, compared with the prior art, as well as good crease and shrink resistance.
摘要翻译：水性纺织品处理剂基于1,3-二烷基-4,5-二羟基 - 咪唑烷酮和选择的多元醇，特别是1,6-己二醇或1,1,1-三（羟甲基） - 乙烷，用于纺织材料的无甲醛整理，其至少部分由纤维素或再生纤维素纤维组成，以赋予其上的折痕和收缩性能，与现有技术相比，如此处理的纺织材料显着改善白度，良好的折皱和抗收缩性。

7. 发明授权

US4956049A Process for sizing paper with anionic hydrophobic sizing agents and cationic retention aids 失效
标题翻译：用阴离子疏水施胶剂和阳离子助留剂调整纸张的方法
公开(公告)号：US4956049A
公开(公告)日：1990-09-11
申请号：US372217
申请日：1989-06-23
申请人： Michael Bernheim , Dieter Strasilla , Bernardo De Sousa , Peter Rohringer
发明人： Michael Bernheim , Dieter Strasilla , Bernardo De Sousa , Peter Rohringer
IPC分类号： C08L3/00 , C07C275/34 , C07C275/42 , C07C309/51 , C08G73/00 , C08G73/02 , C08L3/04 , C08L77/00 , D21H17/03 , D21H17/46
CPC分类号： D21H17/03 , C07C275/34 , C07C275/42 , C07C309/51
摘要： Sizing agents, some of which are known compounds and some of which are novel aromatic compounds which contain in the aromatic nucleus a single hydrophobic substituent containing at least 5 carbon atoms and at least one anionic group, said hydrophobic substituent being linked to the aromatic nucleus through an ester, amide, urethane or urea bridge, with the CO group of ester and amide bridges being attached to the hydrophobic radical and a methylene group being optionally present between said bridges and the aromatic nucleus, are particularly suitable, together with commercially available retention aids, for use in a process for the mass sizing of paper or cardboard or for the surface sizing of paper.
摘要翻译：上浆剂，其中一些是已知的化合物，其中一些是新颖的芳族化合物，其在芳香核中含有单个含有至少5个碳原子的疏水性取代基和至少一个阴离子基团，所述疏水性取代基通过芳香族核连接酯，酰胺，氨基甲酸酯或尿素桥，酯基和酰胺桥的CO基团连接到疏水基团上，并且任选地存在于所述桥和芳香核之间的亚甲基基团，特别适用于市售的助留剂，用于纸张或纸板的大规模尺寸或纸张表面尺寸的过程。

8. 发明授权

US5310783A Aqueous compositions comprising nitrogen-containing polysiloxanes 失效
标题翻译：包含含氮聚硅氧烷的水性组合物
公开(公告)号：US5310783A
公开(公告)日：1994-05-10
申请号：US954841
申请日：1992-09-30
申请人： Michael Bernheim , Harald Chrobaczek , Gunther Tsuchida
发明人： Michael Bernheim , Harald Chrobaczek , Gunther Tsuchida
IPC分类号： C08J3/03 , C08K5/06 , C08K5/10 , C11D3/37 , D06M13/144 , D06M13/165 , D06M13/224 , D06M13/328 , D06M13/372 , D06M15/643 , C08G77/26
CPC分类号： C08J3/03 , C08K5/06 , C08K5/10 , D06M13/144 , D06M13/165 , D06M13/224 , D06M13/372 , D06M15/6436 , C08J2383/04
摘要： Stable, low-viscosity dispersions of polysiloxanes containing amino or amido groups can be obtained, even at comparatively high concentrations and/or pH values, by adding a product of the formulaR1--CH(X)--Y--O--R2(R1 is H, CH.sub.3 ; X=OH, NH.sub.2 ; R2=C.sub. -C.sub.4 -alkyl, unsubstituted or substituted by OH or OR3; R3=C.sub.1 -C.sub.4 -alkyl, unsubstituted or substituted by OH) to the dispersions.The dispersions are suitable for the treatment of fiber materials, especially textiles, to which a soft handle is thereby imparted.
摘要翻译：通过加入式R 1 -CH（X）-YO-R 2（R 1是H，C 1 -C 6烷基） CH3; X = OH，NH2; R2 =未被取代或被OH或OR3取代的C-C4烷基; R3 =未取代或被OH取代的C1-C4-烷基）。分散体适用于纤维材料，特别是纺织品的处理，由此赋予柔软的手感。

9. 发明授权

US5196260A Process for the treatment of fibrous materials with modified organopolysiloxanes and the materials 失效
标题翻译：用改性有机聚硅氧烷和材料处理纤维材料的方法
公开(公告)号：US5196260A
公开(公告)日：1993-03-23
申请号：US892387
申请日：1992-05-27
申请人： Franz Dirschl , Jurgen Uhl , Michael Bernheim
发明人： Franz Dirschl , Jurgen Uhl , Michael Bernheim
IPC分类号： D06M15/356 , D06N3/12
CPC分类号： D06N3/128 , D06M15/3568 , Y10T428/31663 , Y10T442/218 , Y10T442/223 , Y10T442/2352
摘要： The present invention relates to a process for the treatment of fibrous materials with modified organopolysiloxanes, wherein, in an aqueous medium, an organopolysiloxane copolymer prepared in a first stage from customary cyclic siloxanes (A) and unsaturated silanes (B) in the presence of a crosslinking agent and emulsifier (1) is copolymerized in a second stage with at least one vinyl monomer in the presence of emulsifiers (2), and the resulting dispersion of the modified organopolysiloxane copolymer is applied to the material in the customary manner and the material is dried and subjected to condensation.The process has the advantage that the materials, in particular textiles, treated by the process, above all coated by the process, have very good waterproof properties and at the same time good to very good water repellency. However, the materials are simultaneously distinguished by a pleasant soft handle, without the degree of whiteness thereof being noticeably impaired.
摘要翻译：本发明涉及一种用改性有机聚硅氧烷处理纤维材料的方法，其中在水性介质中，在常规环状硅氧烷（A）和不饱和硅烷（B）的第一阶段中制备的有机聚硅氧烷共聚物在交联剂和乳化剂（1）在乳化剂（2）的存在下在第二阶段与至少一种乙烯基单体共聚，并且将所得改性的有机聚硅氧烷共聚物的分散体以常规方式施加到材料上，并且材料是干燥并冷凝。该方法的优点是，通过该方法处理的材料，特别是纺织品，首先通过该方法涂覆，具有非常好的防水性能，同时具有非常好的防水性。然而，这些材料同时通过舒适的柔软手柄来区分，而白度却明显受损。

10. 发明授权

US5019428A Modified polyurethanes containing perfluoroaliphatic groups and use thereof 失效
标题翻译：含有全氟脂肪族基团的改性聚氨酯及其用途
公开(公告)号：US5019428A
公开(公告)日：1991-05-28
申请号：US301681
申请日：1989-01-25
申请人： Simpert Ludemann , Michael Bernheim , Bernhard Sandner , Erich Rossler , Hans-Burkhardt Vogel
发明人： Simpert Ludemann , Michael Bernheim , Bernhard Sandner , Erich Rossler , Hans-Burkhardt Vogel
IPC分类号： C08G18/08 , C08G18/00 , C08G18/10 , C08G18/38 , C08G18/61 , C08G18/77 , C08G18/83 , C08L75/04 , D06M15/576
CPC分类号： D06M15/576 , C08G18/10 , C08G18/387 , C08G18/837 , C08L75/04 , Y10T442/2172
摘要： Modified polyurethanes containing perfluoroaliphalic groups which are obtained by reacting oligo(poly)urethanes containing free hydroxyl or isocyanate groups and perfluoroaliphatic groups with di/polyfunctional polysiloxanes at elevated temperatures with conversion of all the reactive groups of the urethane are used for the oil- and water-repellent finishing of fiber materials, conferring on these materials thus treated not only laundering- and drycleaning-stable effects but also in particular a very soft, full hand of very good surface smoothness, these excellent hand effects being further optimized by the addition of a polyethylene dispersion and/or of further customary textile assistants, in particular water-repellent fluorocarbon compounds.
摘要翻译：通过使含有游离羟基或异氰酸酯基的低聚（聚）氨基甲酸酯和全氟脂肪族基团与二/多官能聚硅氧烷在高温下与氨基甲酸酯的所有反应性基团的转化反应而获得的改性聚氨酯用于油和水 - 对纤维材料进行精加工，赋予这些材料不仅洗涤和干洗清洁稳定的效果，而且特别是具有非常好的表面光滑度的非常柔软的全手，这些优异的手感通过加入聚乙烯分散体和/或其它常规纺织品助剂，特别是防水氟碳化合物。

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