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1. 发明授权

US5268499A Preparation of mixtures of 3-aminopropionitrile and ethylene cyanohydrin 失效
标题翻译：制备3-氨基丙腈和乙烯氰醇的混合物
公开(公告)号：US5268499A
公开(公告)日：1993-12-07
申请号：US47303
申请日：1993-04-19
申请人： Franz Merger , Martin Brudermueller , Wolfgang Harder , Juergen Hartig , Dieter Franz
发明人： Franz Merger , Martin Brudermueller , Wolfgang Harder , Juergen Hartig , Dieter Franz
IPC分类号： C07C253/30
CPC分类号： C07C253/30
摘要： A process for preparing mixtures of 3-aminopropionitrile of the formula IH.sub.2 N--CH.sub.2 --CH.sub.2 --CN (I)and ethylene cyanohydrin of the formula IIHO--CH.sub.2 --CH.sub.2 --CN (II)comprises reacting bis(2-cyanoethyl) ether of the formula IIINC--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --CN (III)with ammonia at from 50 to 170.degree. C. and under from 1 to 500 bar thermally or in the presence of a heterogeneous catalyst.
摘要翻译：制备式I H 2 N-CH 2 -CH 2 -N（I）的3-氨基丙腈和式II HO-CH2-CH2-CN（Ⅱ）的乙烯氰醇的混合物的方法包括使双（2-氰乙基）醚式III NC-CH2-CH2-O-CH2-CH2-CN（III）与氨在50至170℃下和在1至500巴下加热或在多相催化剂存在下反应。

2. 发明授权

US5434291A Preparation of aminopropionitriles 失效
标题翻译：氨基丙腈的制备
公开(公告)号：US5434291A
公开(公告)日：1995-07-18
申请号：US251334
申请日：1994-06-01
申请人： Tom Witzel , Rudolf Kummer , Franz Merger , Guido Voit , Martin Brudermueller , Claus-Ulrich Priester , Wolfgang Harder
发明人： Tom Witzel , Rudolf Kummer , Franz Merger , Guido Voit , Martin Brudermueller , Claus-Ulrich Priester , Wolfgang Harder
IPC分类号： C07C253/18 , C07C253/30 , C07C255/24
CPC分类号： C07C253/30 , C07C255/24
摘要： A process for the preparation of aminopropionitriles of the general formula I ##STR1## in which R denotes hydrogen or methyl, wherein ammonia is caused to react with an acrylonitrile of the general formula II ##STR2## In which the substituent has the aforementioned meanings, in a molar ratio of from 1:1 to 500:1 over a heterogenic catalyst at temperatures ranging from 40.degree. to 180.degree. C. and pressures ranging from 10 to 350 bar.
摘要翻译：（I）的氨基丙腈的制备方法，其中R表示氢或甲基，其中使氨与通式II的丙烯腈反应（II）其中取代基具有上述含义，摩尔比为1：1至500：1，相对于异质催化剂，温度范围为40至180℃，压力范围为10至350巴。

3. 发明授权

US5247120A Preparation of aminopropionitriles 失效
标题翻译：氨基丙腈的制备
公开(公告)号：US5247120A
公开(公告)日：1993-09-21
申请号：US921660
申请日：1992-07-30
申请人： Franz Merger , Martin Brudermueller , Claus-Ulrich Priester , Wolfgang Harder , Siegfried Winderl
发明人： Franz Merger , Martin Brudermueller , Claus-Ulrich Priester , Wolfgang Harder , Siegfried Winderl
IPC分类号： C07B61/00 , C07C253/30 , C07C255/24
CPC分类号： C07C253/30
摘要： Abstract of the Disclosure: Aminopropionitriles of the general formula I ##STR1## where R is hydrogen or methyl, wherein ammonia is reacted with an acrylonitrile of the general formula II ##STR2## where the substituents have the abovementioned meanings, in a molar ratio of from 1:1 to 500:1 over a heterogeneous catalyst at from 40.degree. to 180.degree. C. and from 10 to 350 bar.
摘要翻译：公开内容摘要：通式I的氨基丙腈（I）其中R是氢或甲基，其中氨与通式II的丙烯腈（II）反应，其中取代基具有上述含义，摩尔比为1:1至500:1，在40至180℃和10至350巴的多相催化剂上。

4. 发明授权

US4965362A Joint preparation of 3-dialkylaminopropionitriles, bis-(2-cyanoethyl) ether and, if desired, ethylene-cyanohydrin 失效
标题翻译：联合制备3-二烷基氨基丙腈，双（2-氰基乙基）醚和（如果需要）乙烯 - 氰醇
公开(公告)号：US4965362A
公开(公告)日：1990-10-23
申请号：US376373
申请日：1989-07-06
申请人： Franz Merger , Wolfgang Harder , Peter Hettinger , Claus-Ulrich Priester , Dieter Franz , Dieter Voges
发明人： Franz Merger , Wolfgang Harder , Peter Hettinger , Claus-Ulrich Priester , Dieter Franz , Dieter Voges
IPC分类号： C07C253/18 , C07C255/12 , C07C255/13 , C07C255/24
CPC分类号： C07C255/12 , C07C255/13 , C07C255/24
摘要： 3-Dialkylaminopropionitriles ##STR1## where R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.4 -alkyl which may furthermore be bonded to form a 5-membered or 6-membered ring, bis-(2-cyanoethyl) ether IINC--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --CN IIand, if desired, ethylenecyanohydrin IIIHO--CH.sub.2 --CH.sub.2 --CN IIIare prepared jointly by a process in which(a) acrylonitrile and water are reacted in the presence of a base at from 60.degree. to 150.degree. C. to give a mixture of acrylonitrile, water and bis-(2-cyanoethyl) ether II, the base being a mineral base, a quaternary nitrogen base or a mixture of these,(b) this mixture is reacted at about 0.degree.-50.degree. C. with a dialkylamine of the general formula IV ##STR2## to give a mixture of water, a dialkylaminopropionitrile I and bis-(2-cyanoethyl) ether II, and this mixture is separated into its components and(c) if desired, the ether II obtained in proces stage (b) or an aqueous solution of this ether and/or the reacted mixtures containing this ether and obtained from process stage (a) or (b) is allowed to react at from 50.degree. to 150.degree. C. with the dialkylamine IV to give a mixture of a 3-dialkylaminopropionitrile I and ethylenecyanohydrin III, and, if desired, the said mixture is separated into its components.
摘要翻译： 3-二烷基氨基丙腈其中R 1和R 2各自为可以连接形成5元或6元环的C 1 -C 4 - 烷基，双 - （2-氰基乙基）醚II NC-CH 2 -CH 2 - O-CH 2 -CH 2 -CN II和如果需要，乙烯基氰醇III HO-CH 2 -CH 2 -CN III通过以下方法共同制备，其中（a）丙烯腈和水在碱的存在下在60℃至 150℃，得到丙烯腈，水和双 - （2-氰基乙基）醚II的混合物，碱为矿物碱，季氮碱或它们的混合物，（b）该混合物在约0℃ 与二烷基胺（通式IV IV）反应，得到水，二烷基氨基丙腈I和双 - （2-氰基乙基）醚II的混合物，将该混合物分离成其组分，（c ）如果需要，在步骤阶段（b）中获得的醚II或该醚的水溶液和/或含有该醚的反应混合物从工艺步骤（a）或（b）获得，使其与二烷基胺IV在50-150℃下反应，得到3-二烷基氨基丙腈I和乙基烯丙醇III的混合物，如果需要，将所述混合物分离成其组分。

5. 发明授权

US5371292A Preparation of 3-aminomethyl-3,5,5-trimethyl-cyclohexylamine 失效
标题翻译： 3-氨基甲基-3,5,5-三甲基 - 环己胺的制备
公开(公告)号：US5371292A
公开(公告)日：1994-12-06
申请号：US92029
申请日：1993-07-15
申请人： Franz Merger , Claus-Ulrich Priester , Tom Witzel , Gerhard Koppenhoefer , Wolfgang Harder
发明人： Franz Merger , Claus-Ulrich Priester , Tom Witzel , Gerhard Koppenhoefer , Wolfgang Harder
IPC分类号： B01J21/04 , B01J21/06 , B01J23/46 , B01J27/18 , C07B61/00 , C07C209/00 , C07C209/26 , C07C209/48 , C07C209/52 , C07C211/36 , C07C209/24
CPC分类号： C07C209/48 , C07C209/26 , C07C2101/14
摘要： A process for the preparation of 3-aminomethyl-3,5,5-trimethyl-cyclohexylamine from 3-cyano-3,5,5-trimethyl-cyclohexanone, wherein the following stages are carried out in discrete reaction chambers:a) the 3-cyano-3,5,5-trimethyl-cyclohexanone is reacted in a first reaction chamber with excess ammonia over an acidic metal oxide catalyst at a temperature of from 20.degree. to 150.degree. C. and a pressure of from 15 to 500 bar, andb) in a second reaction chamber, the reaction product from stage a) is hydrogenated with hydrogen at a temperature of from 60.degree. to 150.degree. C. and a pressure of from 50 to 300 bar in the presence of excess ammonia over a catalyst containing cobalt, nickel, ruthenium, and/or some other noble metal, which catalyst optionally contains a basic component or is supported by neutral or basic supporting material.
摘要翻译：从3-氰基-3,5,5-三甲基 - 环己酮制备3-氨基甲基-3,5,5-三甲基 - 环己胺的方法，其中以下步骤在离散反应室中进行：a）3 氰基-3,5,5-三甲基 - 环己酮在第一反应室中与过量的氨在酸性金属氧化物催化剂上在20至150℃的温度和15至500巴的压力下反应，和b）在第二反应室中，在过量的氨在催化剂存在下，将氢气从60℃升至150℃，压力为50-300巴，在步骤a）中的反应产物被氢化含有钴，镍，钌和/或一些其它贵金属，该催化剂任选地含有碱性组分或由中性或碱性载体材料负载。

6. 发明授权

US4375000A Process for the preparation of an aryl mono-, di-, and/or polyurethane 失效
标题翻译：芳基单 - ，二 - 和/或聚氨酯的制备方法
公开(公告)号：US4375000A
公开(公告)日：1983-02-22
申请号：US135242
申请日：1980-03-31
申请人： Franz Merger , Friedrich Towae , Wolfgang Harder
发明人： Franz Merger , Friedrich Towae , Wolfgang Harder
IPC分类号： C07C271/06 , C07C125/07 , C07C125/063 , C07C125/077
CPC分类号： C07C271/06
摘要： A process for the preparation of an aryl mono-, di-, and/or polyurethane comprising the steps of A. reacting a primary aromatic mono-, di-, and/or polyamine with an O-alkyl carbamate in the presence of an alcohol at temperatures greater than 160.degree. C., andB. separating the ammonia and other by-products from the aryl mono-, di-, and/or polyurethane.The reaction is preferably carried out in the presence of urea. The aryl mono-, di-, and/or polyurethanes produced are valuable end and intermediate products. They can be transferred into the corresponding isocyanates which can then be used for the preparation of polyurethanes.
摘要翻译：一种制备芳基单 - ，二 - 和/或聚氨酯的方法，包括以下步骤：在醇存在下使主芳族单 - ，二 - 和/或多胺与氨基甲酸O-烷基酯反应在大于160℃的温度下，和B.将氨和其它副产物与芳基单 - ，二 - 和/或聚氨酯分离。反应优选在尿素存在下进行。所生产的芳基单，二和/或聚氨酯是有价值的终端和中间产物。它们可以转移到相应的异氰酸酯中，然后可以用于制备聚氨酯。

7. 发明授权

US4766237A Preparation of 6-aminocaproates 失效
标题翻译： 6-氨基己酸酯的制备
公开(公告)号：US4766237A
公开(公告)日：1988-08-23
申请号：US7578
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz J. Broecker , Franz Merger , Rolf Fischer , Uwe Vagt , Heinz-Walter Schneider , Wolfgang Richter , Wolfgang Harder , Claus-Ulrich Priester
发明人： Hans-Martin Hutmacher , Franz J. Broecker , Franz Merger , Rolf Fischer , Uwe Vagt , Heinz-Walter Schneider , Wolfgang Richter , Wolfgang Harder , Claus-Ulrich Priester
IPC分类号： C07B61/00 , B01J21/16 , B01J23/00 , B01J23/74 , B01J23/755 , B01J25/02 , C07C67/00 , C07C227/00 , C07C227/04 , C07C227/08 , C07C229/08 , C07C67/30
CPC分类号： C07C227/08
摘要： In an improved process for the preparation of 6-aminocaproates by reacting a 5-formylvalerate with ammonia and hydrogen using an alkanol as a solvent in the presence of a hydrogenation catalyst at elevated temperatures and under superatmospheric pressure, the improvement comprises carrying out the reaction at from 40.degree. to 95.degree. C.
摘要翻译：在氢化催化剂存在下，在升高的温度和超大气压下，通过使用烷醇作为溶剂使5-甲酰基戊酸与氨和氢反应制备6-氨基己酸酯的改进方法，其改进包括在从40℃到95℃

8. 发明授权

US5068398A Preparation of 6-aminocaproic esters 失效
标题翻译： 6-氨基磷酸酯的制备
公开(公告)号：US5068398A
公开(公告)日：1991-11-26
申请号：US448900
申请日：1989-12-12
申请人： Franz Merger , Rolf Fischer , Wolfgang Harder , Claus-Ulrich Priester , Uwe Vagt
发明人： Franz Merger , Rolf Fischer , Wolfgang Harder , Claus-Ulrich Priester , Uwe Vagt
IPC分类号： B01J23/46 , C07B61/00 , C07C227/04 , C07C227/08 , C07C229/08
CPC分类号： C07C227/08
摘要： 6-Aminocaproic esters are prepared by reacting alkyl 5-formylvalerates with excess ammonia and hydrogen in the presence of ruthenium catalysts at elevated temperature under superatmospheric pressure in liquid ammonia as reaction medium.
摘要翻译： 6-氨基己酸酯通过在钌催化剂存在下，在高于大气压的高温下在液氨中作为反应介质使5-甲酰基戊酸烷基酯与过量的氨和氢反应来制备。

9. 发明授权

US4349484A Process for the manufacture of mixtures of diphenylmethane diisocyanates and polyphenyl polymethylene polyisocyanates 失效
标题翻译：制备二苯基甲烷二异氰酸酯和聚苯基多亚甲基多异氰酸酯的混合物的方法
公开(公告)号：US4349484A
公开(公告)日：1982-09-14
申请号：US197890
申请日：1980-10-17
申请人： Franz Merger , Gerhard Nestler , Friedrich Towae , Wolfgang Harder
发明人： Franz Merger , Gerhard Nestler , Friedrich Towae , Wolfgang Harder
IPC分类号： C07C67/00 , C07C241/00 , C07C265/12 , C07C265/14 , C07C271/06 , C07C119/048
CPC分类号： C07C263/04 , C07C271/06
摘要： A process for the production of mixtures of diphenylmethane diisocyanates and polyphenyl polymethylene polyisocyanates comprising the steps ofA. reacting aniline and an O-alkyl carbamate to form N-phenylurethanes;B. isolating the N-phenylurethanes;C. condensing, in the presence of an acid, the N-phenylurethanes with formaldehyde or bifunctional compounds having the formulaX--CH.sub.2 --X in which X stands for a RO--, RS-- or ROCO radical and R denotes an alkyl radical, to form mixtures of methylene bis(phenylurethanes) and polymethylene polyphenylurethanes;D. cleaving the mixtures of methylene bis(phenylurethanes) and polymethylene polyphenylurethanes at temperatures of 175.degree. C. to 600.degree. C.; andE. isolating the mixtures of diphenylmethane diisocyanates and polyphenyl polymethylene polyisocyanate resulting from step D.
摘要翻译：制备二苯基甲烷二异氰酸酯和聚苯基多亚甲基多异氰酸酯的混合物的方法，其包括以下步骤：A.使苯胺和氨基甲酸O-烷基酯反应形成N-苯基氨基甲酸酯; B.分离N-苯基氨基甲酸酯; C.在酸存在下，将N-苯基氨基甲酸酯与具有式X-CH 2 -X的甲醛或双官能化合物缩合，其中X代表RO-，RS-或ROCO基团，R表示烷基，至形成亚甲基双（苯基氨基甲酸酯）和多亚甲基多苯基氨基甲酸酯的混合物; D.在175℃至600℃的温度下切割亚甲基双（苯基氨基甲烷）和多亚甲基多苯基氨基甲酸酯的混合物。和E.分离由步骤D得到的二苯基甲烷二异氰酸酯和聚苯基多亚甲基多异氰酸酯的混合物。

10. 发明授权

US5239120A Preparation of 2-(3-aminopropyl)-cycloalkylamines 失效
标题翻译： 2-（3-氨基丙基） - 环丙基胺的制备
公开(公告)号：US5239120A
公开(公告)日：1993-08-24
申请号：US676087
申请日：1991-03-27
申请人： Franz Merger , Claus-Ulrich Priester , Gerhard Koppenhoefer , Wolfgang Harder , Tom Witzel , Helmut Lermer , Ulrich Koehler
发明人： Franz Merger , Claus-Ulrich Priester , Gerhard Koppenhoefer , Wolfgang Harder , Tom Witzel , Helmut Lermer , Ulrich Koehler
IPC分类号： B01J23/40 , B01J23/74 , B01J29/06 , C07B61/00 , C07C209/26 , C07C209/48 , C07C211/36
CPC分类号： C07C209/48 , C07C209/26 , C07C2101/08 , C07C2101/14
摘要： A process for the preparation of a 2-(3-aminopropyl)-cycloalkylamine of the general formula I ##STR1## in which the subscript n is an integer from 1 to 4, from a 2-(2-cyanoethyl)-cycloalkanone of the general formula II ##STR2## in which the subscript n has the meaning stated, wherein the following stages are carried out in discrete reaction chambers:a) the 2-(2-cyanoethyl)-cycloalkanone of formula II is reacted in a first reaction chamber with excess ammonia over an acidic heterogeneous catalyst at a temperature from 20.degree. to 150.degree. C. and a pressure of from 15 to 500 bar, andb) in a second reaction chamber, the reaction product from stage a) is hydrogenated at a temperature of from 60.degree. to 150.degree. C. and a pressure of from 50 to 300 bar in the presence of excess ammonia over a catalyst containing cobalt, nickel, ruthenium, and/or some other noble metal, which catalyst optionally contains a basic component or is supported on neutral or basic supporting material.
摘要翻译： 2-（2-氰基乙基） - （2-氨基丙基） - 环烷基胺的制备方法，其中下标n为1至4的整数，通式I（I）通式II（II）的环烷酮，其中下标n具有所述的含义，其中以下步骤在离散的反应室中进行：a）式II的2-（2-氰基乙基） - 环烷酮是在酸性多相催化剂的第一反应室中，在第二反应室中，在20至150℃的温度和15至500巴的压力下，在第一反应室中与过量的氨反应，和b）在第二反应室中，反应产物从步骤a ）在过量氨的存在下在含有钴，镍，钌和/或一些其它贵金属的催化剂的温度下在60至150℃的温度和50至300巴的压力下氢化，该催化剂可选地含有基本组分或者在中性或基础支撑材料上支撑。

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