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1. 发明授权

US08455707B2 Methane conversion to higher hydrocarbons 有权
公开(公告)号：US08455707B2
公开(公告)日：2013-06-04
申请号：US12886324
申请日：2010-09-20
申请人： Frank Hershkowitz , John Scott Buchanan , Harry W. Deckman , Jeffrey W. Frederick
发明人： Frank Hershkowitz , John Scott Buchanan , Harry W. Deckman , Jeffrey W. Frederick
IPC分类号： C07C5/35
CPC分类号： B01J8/02 , B01F3/02 , B01F5/0603 , B01F2215/0431 , B01J4/002 , B01J8/0278 , B01J8/04 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J8/0496 , B01J19/2485 , B01J19/26 , B01J2208/00132 , B01J2208/00309 , B01J2208/00504 , B01J2208/0053 , B01J2208/00831 , B01J2208/0084 , B01J2208/00849 , B01J2219/0004 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/182 , B01J2219/1943 , C01B3/46 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/0261 , C01B2203/0277 , C01B2203/0811 , C01B2203/0844 , C01B2203/1235 , C01B2203/1241 , C01B2203/142 , C07C2/78 , C07C5/327 , C08G18/10 , C08G18/4825 , C08G18/73 , C08G18/792 , C08G2101/005 , Y02P20/132 , Y10S585/943 , C07C11/24 , C08G18/3203 , C08G18/48
摘要： The present invention provides a process for the manufacture of acetylene and other higher hydrocarbons from methane feed using a reverse-flow reactor system, wherein the reactor system includes (i) a first reactor and (ii) a second reactor, the first and second reactors oriented in a series relationship with respect to each other, the process comprising supplying each of first and second reactant through separate channels in the first reactor bed of a reverse-flow reactor such that both of the first and second reactants serve to quench the first reactor bed, without the first and second reactants substantially reacting with each other until reaching the core of the reactor system.

2. 发明申请

US20110009681A1 Methane Conversion To Higher Hydrocarbons 有权
标题翻译：甲烷转化为高级烃
公开(公告)号：US20110009681A1
公开(公告)日：2011-01-13
申请号：US12886324
申请日：2010-09-20
申请人： Frank Hershkowitz , John Scott Buchanan , Harry W. Deckman , Jeffrey W. Frederick
发明人： Frank Hershkowitz , John Scott Buchanan , Harry W. Deckman , Jeffrey W. Frederick
IPC分类号： C07C5/35
CPC分类号： B01J8/02 , B01F3/02 , B01F5/0603 , B01F2215/0431 , B01J4/002 , B01J8/0278 , B01J8/04 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J8/0496 , B01J19/2485 , B01J19/26 , B01J2208/00132 , B01J2208/00309 , B01J2208/00504 , B01J2208/0053 , B01J2208/00831 , B01J2208/0084 , B01J2208/00849 , B01J2219/0004 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/182 , B01J2219/1943 , C01B3/46 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/0261 , C01B2203/0277 , C01B2203/0811 , C01B2203/0844 , C01B2203/1235 , C01B2203/1241 , C01B2203/142 , C07C2/78 , C07C5/327 , C08G18/10 , C08G18/4825 , C08G18/73 , C08G18/792 , C08G2101/005 , Y02P20/132 , Y10S585/943 , C07C11/24 , C08G18/3203 , C08G18/48
摘要： The present invention provides a process for the manufacture of acetylene and other higher hydrocarbons from methane feed using a reverse-flow reactor system, wherein the reactor system includes (i) a first reactor and (ii) a second reactor, the first and second reactors oriented in a series relationship with respect to each other, the process comprising supplying each of first and second reactant through separate channels in the first reactor bed of a reverse-flow reactor such that both of the first and second reactants serve to quench the first reactor bed, without the first and second reactants substantially reacting with each other until reaching the core of the reactor system.
摘要翻译：本发明提供了使用逆流反应器系统从甲烷进料制造乙炔和其它高级烃的方法，其中反应器系统包括（i）第一反应器和（ii）第二反应器，第一和第二反应器该方法包括通过在逆流反应器的第一反应器床中的单独通道供应第一和第二反应物中的每一个，使得第一和第二反应物都用于使第一反应器骤冷床，没有第一和第二反应物基本上彼此反应直到到达反应器系统的核心。

3. 发明授权

US07943808B2 Methane conversion to higher hydrocarbons 有权
标题翻译：甲烷转化为高级烃
公开(公告)号：US07943808B2
公开(公告)日：2011-05-17
申请号：US11643541
申请日：2006-12-21
申请人： Frank Hershkowitz , John Scott Buchanan , Harry W. Deckman , Jeffrey W. Frederick
发明人： Frank Hershkowitz , John Scott Buchanan , Harry W. Deckman , Jeffrey W. Frederick
IPC分类号： C07C4/02 , C07C11/00 , C07C2/02 , B01J12/00
CPC分类号： B01J8/02 , B01F3/02 , B01F5/0603 , B01F2215/0431 , B01J4/002 , B01J8/0278 , B01J8/04 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J8/0496 , B01J19/2485 , B01J19/26 , B01J2208/00132 , B01J2208/00309 , B01J2208/00504 , B01J2208/0053 , B01J2208/00831 , B01J2208/0084 , B01J2208/00849 , B01J2219/0004 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/182 , B01J2219/1943 , C01B3/46 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/0261 , C01B2203/0277 , C01B2203/0811 , C01B2203/0844 , C01B2203/1235 , C01B2203/1241 , C01B2203/142 , C07C2/78 , C07C5/327 , C08G18/10 , C08G18/4825 , C08G18/73 , C08G18/792 , C08G2101/005 , Y02P20/132 , Y10S585/943 , C07C11/24 , C08G18/3203 , C08G18/48
摘要： The present invention provides a process for the manufacture of acetylene and other higher hydrocarbons from methane feed using a reverse-flow reactor system, wherein the reactor system includes (i) a first reactor and (ii) a second reactor, the first and second reactors oriented in a series relationship with respect to each other, the process comprising supplying each of first and second reactant through separate channels in the first reactor bed of a reverse-flow reactor such that both of the first and second reactants serve to quench the first reactor bed, without the first and second reactants substantially reacting with each other until reaching the core of the reactor system.
摘要翻译：本发明提供了使用逆流反应器系统从甲烷进料制造乙炔和其它高级烃的方法，其中反应器系统包括（i）第一反应器和（ii）第二反应器，第一和第二反应器该方法包括通过在逆流反应器的第一反应器床中的单独通道供应第一和第二反应物中的每一个，使得第一和第二反应物都用于使第一反应器骤冷床，没有第一和第二反应物基本上彼此反应直到到达反应器系统的核心。

4. 发明授权

US08454911B2 Methane conversion to higher hydrocarbons 有权
标题翻译：甲烷转化为高级烃
公开(公告)号：US08454911B2
公开(公告)日：2013-06-04
申请号：US12886336
申请日：2010-09-20
申请人： Frank Hershkowitz , John Scott Buchanan , Harry W. Deckman , Jeffrey W. Frederick
发明人： Frank Hershkowitz , John Scott Buchanan , Harry W. Deckman , Jeffrey W. Frederick
IPC分类号： B01J8/00
CPC分类号： B01J8/02 , B01F3/02 , B01F5/0603 , B01F2215/0431 , B01J4/002 , B01J8/0278 , B01J8/04 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J8/0496 , B01J19/2485 , B01J19/26 , B01J2208/00132 , B01J2208/00309 , B01J2208/00504 , B01J2208/0053 , B01J2208/00831 , B01J2208/0084 , B01J2208/00849 , B01J2219/0004 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/182 , B01J2219/1943 , C01B3/46 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/0261 , C01B2203/0277 , C01B2203/0811 , C01B2203/0844 , C01B2203/1235 , C01B2203/1241 , C01B2203/142 , C07C2/78 , C07C5/327 , C08G18/10 , C08G18/4825 , C08G18/73 , C08G18/792 , C08G2101/005 , Y02P20/132 , Y10S585/943 , C07C11/24 , C08G18/3203 , C08G18/48
摘要： The present invention provides a process for the manufacture of acetylene and other higher hydrocarbons from methane feed using a reverse-flow reactor system, wherein the reactor system includes (i) a first reactor and (ii) a second reactor, the first and second reactors oriented in a series relationship with respect to each other, the process comprising supplying each of first and second reactant through separate channels in the first reactor bed of a reverse-flow reactor such that both of the first and second reactants serve to quench the first reactor bed, without the first and second reactants substantially reacting with each other until reaching the core of the reactor system.
摘要翻译：本发明提供了使用逆流反应器系统从甲烷进料制造乙炔和其它高级烃的方法，其中反应器系统包括（i）第一反应器和（ii）第二反应器，第一和第二反应器该方法包括通过在逆流反应器的第一反应器床中的单独通道供应第一和第二反应物中的每一个，使得第一和第二反应物都用于使第一反应器骤冷床，没有第一和第二反应物基本上彼此反应直到到达反应器系统的核心。

5. 发明申请

US20110008226A1 Methane Conversion To Higher Hydrocarbons 有权
公开(公告)号：US20110008226A1
公开(公告)日：2011-01-13
申请号：US12886336
申请日：2010-09-20
申请人： Frank Hershkowitz , John Scott Buchanan , Harry W. Deckman , Jeffrey W. Frederick
发明人： Frank Hershkowitz , John Scott Buchanan , Harry W. Deckman , Jeffrey W. Frederick
IPC分类号： B01J8/00
CPC分类号： B01J8/02 , B01F3/02 , B01F5/0603 , B01F2215/0431 , B01J4/002 , B01J8/0278 , B01J8/04 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J8/0496 , B01J19/2485 , B01J19/26 , B01J2208/00132 , B01J2208/00309 , B01J2208/00504 , B01J2208/0053 , B01J2208/00831 , B01J2208/0084 , B01J2208/00849 , B01J2219/0004 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/182 , B01J2219/1943 , C01B3/46 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/0261 , C01B2203/0277 , C01B2203/0811 , C01B2203/0844 , C01B2203/1235 , C01B2203/1241 , C01B2203/142 , C07C2/78 , C07C5/327 , C08G18/10 , C08G18/4825 , C08G18/73 , C08G18/792 , C08G2101/005 , Y02P20/132 , Y10S585/943 , C07C11/24 , C08G18/3203 , C08G18/48
摘要： The present invention provides a process for the manufacture of acetylene and other higher hydrocarbons from methane feed using a reverse-flow reactor system, wherein the reactor system includes (i) a first reactor and (ii) a second reactor, the first and second reactors oriented in a series relationship with respect to each other, the process comprising supplying each of first and second reactant through separate channels in the first reactor bed of a reverse-flow reactor such that both of the first and second reactants serve to quench the first reactor bed, without the first and second reactants substantially reacting with each other until reaching the core of the reactor system.

6. 发明申请

US20080314244A1 Temperature swing adsorption of CO2 from flue gas utilizing heat from compression 有权
标题翻译：利用来自压缩的热量从烟道中的二氧化碳的温度变化吸附
公开(公告)号：US20080314244A1
公开(公告)日：2008-12-25
申请号：US12152877
申请日：2008-05-16
申请人： Bruce T. Kelley , Harry W. Deckman , Frank Hershkowitz , Paul S. Northrop , Peter I. Ravikovitch
发明人： Bruce T. Kelley , Harry W. Deckman , Frank Hershkowitz , Paul S. Northrop , Peter I. Ravikovitch
IPC分类号： B01D53/04
CPC分类号： B01D53/0423 , B01D53/02 , B01D53/0462 , B01D2253/108 , B01D2253/311 , B01D2253/342 , B01D2257/504 , B01D2259/4143 , Y02C10/04 , Y02C10/08
摘要： Adsorption of CO2 from flue gas streams using temperature swing adsorption. The resulting CO2 rich stream is compressed for sequestration into a subterranean formation and at least a portion of the heat of compression is used in the desorption step of the temperature swing adsorption process.
摘要翻译：使用变温吸附从烟气流吸附二氧化碳。所得到的富CO 2流被压缩成地下地层，并且在变温吸附过程的解吸步骤中使用至少一部分压缩热。

7. 发明授权

US5883138A Rapid injection catalytic partial oxidation process and apparatus for producing synthesis gas (law 562) 失效
标题翻译：快速注射催化部分氧化工艺和生产合成气的设备（法律562）
公开(公告)号：US5883138A
公开(公告)日：1999-03-16
申请号：US845699
申请日：1997-04-25
申请人： Frank Hershkowitz , Harry W. Deckman , Robert P. Reynolds , Constantine P. Gonatas , John W. Fulton , Leonard Schoenman , Jack I. Ito , Leroy R. Clavenna
发明人： Frank Hershkowitz , Harry W. Deckman , Robert P. Reynolds , Constantine P. Gonatas , John W. Fulton , Leonard Schoenman , Jack I. Ito , Leroy R. Clavenna
IPC分类号： B01F3/02 , B01F5/06 , B01J4/00 , B01J8/02 , B01J12/00 , C01B3/38 , C07C27/00 , C07C1/02
CPC分类号： C01B3/386 , B01F5/0682 , B01J8/0278 , B01F3/02 , C01B2203/0261 , C01B2203/062 , C01B2203/065 , C01B2203/1023 , C01B2203/1052 , C01B2203/1064 , C01B2203/1241 , C01B2203/1276
摘要： A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for recovery and/or subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through an injector means at high velocity into admixture with each other in the desired proportions, at a plurality of mixing nozzles which are open to the catalytic partial oxidation reaction zone of a reactor and are uniformly-spaced over the face of the injector, to form a reactant gaseous premix having a pressure drop through the injector. The gaseous premix is injected in a time period which is less than 5 milliseconds, at a velocity between about 25 to 1000 feet/second, into a reaction zone comprising a catalytic partial oxidation zone so that the gaseous premix reacts in the presence of the fixed catalyst arrangement to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction and form, cool and recover a useful syngas.
摘要翻译：一种新颖的注射器/反应器装置以及用于部分氧化轻质烃气体（例如甲烷）的有效方法，以将这种气体转化成有用的合成气以用于回收和/或随后的烃合成。来自诸如甲烷和氧气或含氧气体的轻质烃气体在多个混合喷嘴处被预热和加压并通过喷射器装置以高速度以相关的比例彼此混合，通向反应器的催化部分氧化反应区，并且在喷射器的表面上均匀间隔开，形成具有通过喷射器的压降的反应物气态预混物。将气态预混物以约25至1000英尺/秒的速度在小于5毫秒的时间内注入到包含催化部分氧化区的反应区中，使得气态预混物在固定的催化剂排列以减少CO 2，H 2 O的量和由部分氧化反应产生的热量并形成，冷却和回收有用的合成气。

8. 发明授权

US5675041A Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene 失效
标题翻译：含有一氧化碳，氢气，乙烯和乙炔的多组分合成气的直接加氢甲酰化
公开(公告)号：US5675041A
公开(公告)日：1997-10-07
申请号：US573052
申请日：1995-12-15
申请人： Gabor Kiss , Frank Hershkowitz , Harry W. Deckman , Michael Gerard Matturro , Istvan T. Horvath , Anthony M. Dean , Raymond A. Cook
发明人： Gabor Kiss , Frank Hershkowitz , Harry W. Deckman , Michael Gerard Matturro , Istvan T. Horvath , Anthony M. Dean , Raymond A. Cook
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , Y02P20/582
摘要： The invention is a process for production of C.sub.3 to C.sub.6 aldehydes by hydroformylating a mixture containing: (a) C.sub.2 to C.sub.5 olefins and mixtures thereof, and (b) (i) C.sub.2 to C.sub.5 alkynes and mixtures thereof or (ii) C.sub.3 to C.sub.5 cumulated dienes and mixtures thereof or (iii) mixtures of (i) and (ii), with CO, H.sub.2 and a solution of a rhodium complex catalyst produced by complexing Rh and an organophosphorus compound at a concentration of Rh in solution from 1 to 1000 ppm by weight. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio of at least 30. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio greater than the value R.sub.L defined by the formula: ##EQU1## in which R.sub.B is the P/Rh ratio sufficient for a catalytically active Rh complex, pKa.sub.TPP is the pKa value for triphenylphosphine, pKa.sub.L is the pKa value for the triorganophosphorus compound, R is the gas constant, and .DELTA.S.sub.B is 35(N-1) cal/mole/.degree.K., N is the number of P-Rh attachments per ligand molecule. The process has utility for the hydroformylation of streams that contain olefins and alkynes.
摘要翻译：本发明是通过加氢甲酰化含有：（a）C 2〜C 5烯烃及其混合物的混合物，和（b）（ⅰ）C2〜C5炔烃及其混合物或（ⅱ）C3〜C5 累积的二烯及其混合物，或（iii）（ⅰ）和（ⅱ）的混合物与CO，H 2和铑络合物催化剂的溶液形成，所述铑配合物催化剂是通过使Rh和溶液中Rh浓度为1〜1000的有机磷化合物重量ppm。或者，铑络合物催化剂的溶液的P / Rh原子比可以至少为30.另外，铑络合物催化剂的溶液可以具有大于由下式定义的值RL的P / Rh原子比：其中RB是催化活性Rh配合物的P / Rh比，pKaTPP是三苯基膦的pKa值，pKaL是三有机磷化合物的pKa值，R是气体常数，DELTA SB是35（N-1 ）cal / mole / DEGK，N是每个配体分子的P-Rh附着物的数目。该方法可用于含有烯烃和炔烃的物流的加氢甲酰化。

9. 发明授权

US07815892B2 Integration of hydrogen and power generation using pressure swing reforming 有权
标题翻译：使用压力摆动重整来整合氢气和发电
公开(公告)号：US07815892B2
公开(公告)日：2010-10-19
申请号：US10912820
申请日：2004-08-06
申请人： Frank Hershkowitz , Harry W. Deckman
发明人： Frank Hershkowitz , Harry W. Deckman
IPC分类号： C01B3/02 , C01B3/24 , C01B3/26
CPC分类号： C01B3/48 , C01B3/38 , C01B3/46 , C01B3/50 , C01B3/56 , C01B2203/00 , C01B2203/0233 , C01B2203/0283 , C01B2203/0288 , C01B2203/0405 , C01B2203/0415 , C01B2203/0425 , C01B2203/043 , C01B2203/046 , C01B2203/0475 , C01B2203/0805 , C01B2203/0811 , C01B2203/0872 , C01B2203/0883 , C01B2203/1041 , C01B2203/1047 , C01B2203/1058 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1235 , C01B2203/1241 , C01B2203/1247 , C01B2203/1288 , C01B2203/1294 , C01B2203/1619 , C01B2203/1623 , C01B2203/1676 , C01B2203/168 , C01B2203/84 , Y02P30/30
摘要： The invention provides a method for generating power with a gas turbine which utilizes pressure swing reforming under conditions that facilitate CO2 capture. First a synthesis gas stream at a first pressure is produced in a pressure swing reformer. Next the synthesis gas stream is subjected to a high temperature water gas shift process to produce a CO2 containing hydrogen enriched stream from which hydrogen and CO2 each are separated. The separated hydrogen in turn is combusted with air to produce a gas turbine and the separated CO2 is easily sequestered.
摘要翻译：本发明提供了一种利用燃气轮机发电的方法，该燃气轮机在促进二氧化碳捕集的条件下利用压力摆动重整。首先，在压力摆动重整器中产生在第一压力下的合成气流。接下来，对合成气流进行高温水煤气变换过程，以产生含有氢的二氧化碳流，每个氢气和二氧化碳都被分离。依次分离的氢气与空气一起燃烧以产生燃气轮机，并且分离的CO 2容易隔离。

10. 发明授权

US06830596B1 Electric power generation with heat exchanged membrane reactor (law 917) 有权
标题翻译：用热交换膜反应堆发电（第917号法律）
公开(公告)号：US06830596B1
公开(公告)日：2004-12-14
申请号：US09606887
申请日：2000-06-29
申请人： Harry W. Deckman , John W. Fulton , Jeffrey M. Grenda , Frank Hershkowitz
发明人： Harry W. Deckman , John W. Fulton , Jeffrey M. Grenda , Frank Hershkowitz
IPC分类号： C10J300
CPC分类号： C01B3/501 , B01J8/009 , B01J12/007 , B01J19/2425 , B01J19/2475 , B01J35/065 , B01J2208/00256 , B01J2208/00309 , B01J2208/0053 , B01J2208/00539 , B01J2219/0002 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0288 , C01B2203/041 , C01B2203/0495 , C01B2203/06 , C01B2203/0805 , C01B2203/0811 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/0883 , C01B2203/1011 , C01B2203/1035 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1205 , C01B2203/1241 , C01B2203/1288 , C01B2203/148 , C01B2203/82 , C01B2203/84 , C01B2203/86 , Y02C10/14 , Y02P20/52 , Y02P30/30
摘要： This invention is directed to a heat exchanged membrane reactor for electric power generation. More specifically, the invention comprises a membrane reactor system that employs catalytic or thermal steam reforming and a water gas shift reaction on one side of the membrane, and hydrogen combustion on the other side of the membrane. Heat of combustion is exchanged through the membrane to heat the hydrocarbon fuel and provide heat for the reforming reaction. In one embodiment, the hydrogen is combusted with compressed air to power a turbine to produce electricity. A carbon dioxide product stream is produced in inherently separated form and at pressure to facilitate injection of the CO2 into a well for the purpose of sequestering carbon from the earth's atmosphere.
摘要翻译：本发明涉及用于发电的热交换膜反应器。更具体地，本发明包括在膜的一侧采用催化或热蒸汽重整和水煤气变换反应的膜反应器系统，并且在膜的另一侧上进行氢燃烧。燃烧热通过膜交换以加热烃燃料并为重整反应提供热量。在一个实施例中，氢气与压缩空气一起燃烧，为涡轮机供电以产生电力。以固有分离的形式和压力产生二氧化碳产物流，以便于将CO 2注入井中，以便从地球大气中隔离碳。

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