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1. 发明授权

US06923948B2 Combined heat and power plant and a process for the operation thereof 失效
标题翻译：联合热电厂及其运行过程
公开(公告)号：US06923948B2
公开(公告)日：2005-08-02
申请号：US10109152
申请日：2002-03-27
申请人： Frank Baumann , Stefan Wieland , Peter Britz , Klaus Heikrodt
发明人： Frank Baumann , Stefan Wieland , Peter Britz , Klaus Heikrodt
IPC分类号： C01B3/38 , H01M8/04 , H01M8/06 , C01B3/26
CPC分类号： H01M8/0612 , H01M8/0662 , Y02P70/56
摘要： The invention provides a combined heat and power plant with an integrated gas production system. The combined heat and power plant contains a steam reformer heated with a gas burner which converts a mixture of hydrocarbons and water vapour into a reformate gas stream containing hydrogen and carbon monoxide. The plant further contains a reactor system with several stages for removing carbon monoxide from the reformate gas stream. The plant also contains a heat exchanger for removing heat energy from the reformate gas stream and a fuel cell unit for producing electrical energy by catalytic reaction of the hydrogen contained in the reformate gas with oxygen in the fuel cell, wherein the reformate gas stream is supplied to the anode in the fuel cell unit and the anode waste gas is taken to the gas burner of the steam reformer as fuel, via a gas pipe. The reactor system for removing carbon monoxide from the reformate gas stream contains, according to one embodiment of the invention, a low temperature shift reactor and a downstream methanisation reactor and the heat exchanger for cooling the reformate gas stream leaving the steam reformer to the inlet temperature of the low temperature shift reactor is located in the reformate gas stream between the steam reformer and the low temperature shift reactor. This combined heat and power plant is operated according to the invention in such a way that the reformate gas contains 5 to 10 vol. % of unreformed hydrocarbon which enables the flame in the gas burner to be monitored using an ionisation detector when burning the anode waste gas in the gas burner of the steam reformer.
摘要翻译：本发明提供了一种具有集成气体生产系统的组合式热电厂。组合的热电厂包含用气体燃烧器加热的蒸汽重整器，其将烃和水蒸汽的混合物转化为含有氢和一氧化碳的重整产品气流。该设备还包含一个反应器系统，其具有几个阶段用于从重整产品气流中除去一氧化碳。该设备还包含用于从重整产品气流中除去热能的热交换器和用于通过燃料电池中重整气体中所含的氢气与氧气的催化反应来产生电能的燃料电池单元，其中重整气流被供应到燃料电池单元中的阳极，并且通过气体管将阳极废气作为燃料被带到蒸汽重整器的气体燃烧器。根据本发明的一个实施方案，用于从重整产品气流中除去一氧化碳的反应器系统包含低温变换反应器和下游甲烷化反应器，以及用于将离开蒸汽重整器的重整产品气流冷却至入口温度的热交换器的低温变换反应器位于蒸汽重整器和低温变换反应器之间的重整产品气流中。根据本发明，这种组合的热电厂是以重整气体含有5〜10vol。％的未重整烃，当燃烧蒸汽重整器的气体燃烧器中的阳极废气时，能够使用电离检测器监测气体燃烧器中的火焰。

2. 发明授权

US07150866B2 Catalyst for autothermal reforming of hydrocarbons with increased water gas shift activity 失效
标题翻译：具有增加的水煤气变换活性的烃的自热重整催化剂
公开(公告)号：US07150866B2
公开(公告)日：2006-12-19
申请号：US10644377
申请日：2003-08-20
申请人： Stefan Wieland , Frank Baumann
发明人： Stefan Wieland , Frank Baumann
IPC分类号： C01B3/40 , B01J23/40 , B01J23/42 , B01J23/46
CPC分类号： B01J23/464 , B01J23/40 , B01J37/0244 , C01B3/382 , C01B3/40 , C01B2203/0244 , C01B2203/0283 , C01B2203/0844 , C01B2203/1005 , C01B2203/1047 , C01B2203/1064 , C01B2203/142 , C01B2203/82 , H01M8/0612 , Y02P20/52
摘要： The invention relates to a catalyst and a process for the autothermal, catalytic steam reforming of hydrocarbons using the catalyst. The catalyst has a multilayer structure and comprises a lower catalyst layer located directly on a support body and an upper catalyst layer located on the lower catalyst layer, with the lower catalyst layer preferentially catalysing the partial oxidation and the upper catalyst layer preferentially catalysing steam reforming. In a further embodiment, a three-layer catalyst having a further catalyst layer for the carbon monoxide conversion (water gas shift reaction) is described. Each catalyst layer comprises at least one platinum group metal on an oxidic support material.The steam reforming process is carried out in an adiabatic process by passing a feed mixture of hydrocarbons, oxygen and water or water vapour which has been heated to a preheating temperature over the multilayer catalyst.Catalyst and process are used for producing hydrogen-containing fuel gases in reformer systems, preferably for fuel cells.
摘要翻译：本发明涉及使用催化剂的烃的自热，催化蒸汽重整的催化剂和方法。催化剂具有多层结构，并且包括直接位于支撑体上的下催化剂层和位于下催化剂层上的上催化剂层，下催化剂层优先催化部分氧化，上催化剂层优先催化蒸汽重整。在另一个实施方案中，描述了具有用于一氧化碳转化的另一催化剂层（水煤气变换反应）的三层催化剂。每个催化剂层在氧化载体材料上包含至少一种铂族金属。蒸汽重整过程通过将已被加热到预热温度的烃，氧气和水或水蒸汽的进料混合物通过多层催化剂进行，在绝热过程中进行。催化剂和方法用于在重整器系统中生产含氢燃料气体，优选用于燃料电池。

3. 发明授权

US06949683B2 Process for catalytic autothermal steam reforming of alcohols 失效
标题翻译：醇的催化自热蒸汽重整方法
公开(公告)号：US06949683B2
公开(公告)日：2005-09-27
申请号：US10300173
申请日：2002-11-20
申请人： Stefan Wieland , Frank Baumann
发明人： Stefan Wieland , Frank Baumann
IPC分类号： C01B3/26 , B01J23/63 , C01B3/32 , C01B3/40 , C07C27/16
CPC分类号： C01B3/323 , C01B2203/0244 , C01B2203/0844 , C01B2203/1023 , C01B2203/1029 , C01B2203/1064 , C01B2203/1082 , C01B2203/1217 , C01B2203/1247 , C01B2203/82 , Y02P20/52
摘要： The invention relates to a process for catalytic autothermal steam reforming of alcohols having two or more carbon atoms by directing a preheated educt or reactant mixture of the alcohols, oxygen and water or steam over a catalyst. The process is conducted in an adiabatic manner wherein the catalyst comprises at least one platinum group metal on an oxidic support selected from the group consisting of aluminum oxide, silicon dioxide, titanium dioxide or mixed oxides thereof and zeolites, and that the educt or reactant mixture contains additional hydrocarbons, which are reformed at the same time as the alcohols.
摘要翻译：本发明涉及通过将催化剂上的醇，氧和水或蒸汽的预热的脱水或反应物混合物引入催化剂，从而对具有两个或多个碳原子的醇进行催化自热蒸汽重整的方法。该方法以绝热方式进行，其中催化剂包含选自氧化铝，二氧化硅，二氧化钛或其混合氧化物的氧化物载体上的至少一种铂族金属和沸石，并且所述离子或反应物混合物含有另外的烃，它们与醇同时重整。

4. 发明授权

US06723298B1 Method for catalytic conversion of carbon monoxide in a hydrogen-containing gas mixture 失效
标题翻译：在含氢气体混合物中催化转化一氧化碳的方法
公开(公告)号：US06723298B1
公开(公告)日：2004-04-20
申请号：US09568814
申请日：2000-05-11
申请人： Frank Baumann , Stefan Wieland
发明人： Frank Baumann , Stefan Wieland
IPC分类号： C01B316
CPC分类号： B01J37/0205 , B01J23/894 , B01J35/04 , C01B3/16 , H01M8/0662 , Y02P20/52
摘要： A method for catalytic conversion of carbon monoxide with water to carbon dioxide and water in a hydrogen-containing gas mixture (carbon monoxide conversion) by passing the gas mixture over a shift catalyst that is at an operating temperature for the carbon monoxide conversion. The method is carried out with a shift catalyst based on noble metals that is applied to an inert support element in the form of a coating.
摘要翻译：通过使气体混合物通过在一氧化碳转化的工作温度下的变换催化剂将一氧化碳与水一起在含氢气体混合物（一氧化碳转化）中催化转化为二氧化碳和水的方法。该方法使用基于以涂层形式施加到惰性支撑元件的贵金属的换档催化剂进行。

5. 发明授权

US06413449B1 Method of using catalyst for steam reforming of alcohols 有权
标题翻译：催化剂用于醇的蒸汽重整的方法
公开(公告)号：US06413449B1
公开(公告)日：2002-07-02
申请号：US09413878
申请日：1999-10-07
申请人： Stefan Wieland , Frank Baumann , Frank Adam , Stefan Andersch
发明人： Stefan Wieland , Frank Baumann , Frank Adam , Stefan Andersch
IPC分类号： C07C102
CPC分类号： C01B3/326 , B01J23/60 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , Y02P20/52
摘要： A catalyst is disclosed for the steam reforming of alcohols, which contains a palladium/zinc alloy and zinc oxide as catalytically active components. The alloy catalyst is a catalytically active component deposited on at least one support material which can be aluminum oxide, aluminum silicate, titanium oxide, zirconium oxide, zeoliths and mixtures or mixed oxides thereof.
摘要翻译：公开了一种用于蒸汽重整醇的催化剂，其包含钯/锌合金和氧化锌作为催化活性组分。合金催化剂是沉积在至少一种载体材料上的催化活性组分，其可以是氧化铝，硅酸铝，氧化钛，氧化锆，沸石及其混合物或混合氧化物。

6. 发明授权

US07198862B2 Process for preparing a low-sulfur reformate gas for use in a fuel cell system 失效
标题翻译：制备用于燃料电池系统的低硫重整气体的方法
公开(公告)号：US07198862B2
公开(公告)日：2007-04-03
申请号：US10172570
申请日：2002-06-13
申请人： Frank Baumann , Stefan Wieland
发明人： Frank Baumann , Stefan Wieland
IPC分类号： C01B3/26 , H01M8/04
CPC分类号： B01D53/8603
摘要： The invention provides a multistep process for preparing a low-sulfur reformate gas for use in a fuel cell system. The process comprises catalytic steam reforming of a reactant gas mixture comprising sulfur-containing hydrocarbons and steam in a first step to make a reformate, reducing the carbon monoxide content of the reformate in a second step, passing the reformate over a sulfur absorber either directly after the first step or after passage through the second step, and desorbing the sulfur components optionally absorbed on the catalysts in the reforming and reducing process steps by periodically raising the temperature so as to cause the sulfer components to pass to the absorber, wherein the temperature of the absorber during operation of the process is always kept within a temperature interval which is an optimum for the absorber.
摘要翻译：本发明提供一种制备用于燃料电池系统的低硫重整气体的多步法。该方法包括在第一步骤中包含含硫烃和蒸汽的反应气体混合物的催化蒸汽重整，以制备重整油，在第二步中减少重整产物的一氧化碳含量，使重整产物直接在通过第二步骤的第一步骤或通过第二步骤之后，通过周期性地升高温度以使硫化物组分进入吸收器，在重整和还原过程步骤中任选地吸附在催化剂上的硫组分解吸，其中温度过程运行过程中的吸收器始终保持在吸收器最佳的温度区间内。

7. 发明授权

US06555088B1 Method for catalytic conversion of carbon monoxide in a hydrogen-containing gas mixture with improved cold start behavior 失效
标题翻译：在具有改进的冷启动行为的含氢气体混合物中催化转化一氧化碳的方法
公开(公告)号：US06555088B1
公开(公告)日：2003-04-29
申请号：US09566981
申请日：2000-05-09
申请人： Frank Baumann , Stefan Wieland
发明人： Frank Baumann , Stefan Wieland
IPC分类号： C01B316
CPC分类号： B01J23/56 , B01J23/38 , B01J23/89 , C01B3/16 , Y02P20/52
摘要： A method for conversion of carbon monoxide to carbon dioxide and hydrogen with water in a gas mixture containing hydrogen and other oxidizable components. An oxidation-active noble metal shift catalyst is the catalyst. The necessary operating temperature of the catalyst is established and optionally maintained by partial oxidation of the oxidizable components of the gas mixture.
摘要翻译：一种在含有氢气和其他可氧化组分的气体混合物中将一氧化碳转化为二氧化碳和氢气的方法。氧化活性贵金属转移催化剂是催化剂。催化剂的必要操作温度被建立，并且任选地通过气体混合物的可氧化组分的部分氧化来维持。

8. 发明授权

US07083775B2 Process for the autothermal catalytic steam reforming of hydrocarbons 有权
公开(公告)号：US07083775B2
公开(公告)日：2006-08-01
申请号：US09853902
申请日：2001-05-14
申请人： Stefan Wieland , Frank Baumann , Rainer Ahlborn
发明人： Stefan Wieland , Frank Baumann , Rainer Ahlborn
IPC分类号： C01B3/26
CPC分类号： B01J23/63 , C01B3/382 , C01B3/40 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1094 , C01B2203/142 , C01B2203/82 , Y02P20/52
摘要： A process for autothermal catalytic steam reforming of hydrocarbons by passing a reactant mixture of hydrocarbons, oxygen and water or water vapor, heated to a preheating temperature, over a catalyst. The process is operated adiabatically and the catalyst has a coating of a catalyst material on a support structure, the catalyst material containing at least one platinum group metal on an oxidic support material which can be aluminum oxide, silicon dioxide, titanium dioxide or mixed oxides thereof and zeolites.

9. 发明授权

US06156933A Supercritical hydrogenation 有权
标题翻译：超临界氢化
公开(公告)号：US06156933A
公开(公告)日：2000-12-05
申请号：US155660
申请日：1999-02-18
申请人： Martyn Poliakoff , Thomas M. Swan , Thomas Tacke , Martin G. Hitzler , Stephen K. Ross , Stefan Wieland
发明人： Martyn Poliakoff , Thomas M. Swan , Thomas Tacke , Martin G. Hitzler , Stephen K. Ross , Stefan Wieland
IPC分类号： B01J3/00 , C07B35/02 , C07B43/04 , C07B61/00 , C07C29/132 , C07C29/141 , C07C29/145 , C07C29/20 , C07C45/58 , C07C209/36 , C07D317/66 , C07C209/00 , C07C5/00 , C07C37/00
CPC分类号： C07C29/145 , B01J3/008 , C07B35/02 , C07B43/04 , C07C209/36 , C07C29/132 , C07C29/141 , C07C29/20 , C07C45/58 , C07D317/66 , C07C2101/14 , Y02P20/544
摘要： Process for the selective hydrogenation of alphatic or aromatic substrates under supercritical or near critical conditions. Hydrogenation is effected using a heterogeneous catalyst in a continuous flow reactor containing a supercritical or near critical reaction medium and selectively of product formation is achieved by varying one or more of the temperature, pressure, catalyst and flow rate.
摘要翻译： PCT No.PCT / GB97 / 01014 Sec。 371日期1999年2月18日 102（e）1999年2月18日PCT 1997年4月11日PCT PCT。出版物WO97 / 38955 日期1997年10月23日在超临界或接近临界条件下选择性氢化脂肪或芳香族底物的方法。在包含超临界或近临界反应介质的连续流动反应器中使用非均相催化剂进行氢化，并且通过改变一种或多种温度，压力，催化剂和流速来实现产物形成的选择性。

10. 发明授权

US5922900A Process for producing carboxylic acid esters and catalysts therefor 失效
标题翻译：制备羧酸酯及其催化剂的方法
公开(公告)号：US5922900A
公开(公告)日：1999-07-13
申请号：US922558
申请日：1997-09-03
申请人： Stefan Wieland , Peter Panster
发明人： Stefan Wieland , Peter Panster
IPC分类号： B01J31/06 , C07B61/00 , C07C67/08 , C07C69/14 , C07C69/80 , C07C67/00 , C08G77/00 , C08G79/00
CPC分类号： C07C67/08
摘要： A process for producing carboxylic acid esters by the following steps:a) preparation of a reaction mixture containing an alcohol and a carboxylic acid and/or a carboxylic anhydride and/or a carboxylic acid ester and or a partially esterified carboxylic acid,b) heating of this mixture to the suitable reaction temperature in the presence of a solid polysiloxane insoluble in the reaction medium and having sulphonic acid groups with intensive thorough mixing accompanied by continuous separation of the reaction water which forms, wherein the polysiloxane used as the catalyst in modified by treatment with a soluble aluminum, titanium or zirconium compound, and the spherical particles thereof have a diameter of 0.01 to 3 mm, a specific surface of 0.1 to 1200 m.sup.2 /g, a specific pore volume of 0.01 to 6.0 ml/g and a bulk density of 50 to 1000 g/l.
摘要翻译：一种通过以下步骤制备羧酸酯的方法：a）制备含有醇和羧酸和/或羧酸酐和/或羧酸酯和/或部分酯化的羧酸的反应混合物，b）加热该混合物在不溶于反应介质的固体聚硅氧烷存在下具有适当的反应温度，并且具有强烈浓缩的磺酸基团，伴随着形成的反应水的连续分离，其中用作催化剂的聚硅氧烷被改性为用可溶性铝，钛或锆化合物处理，其球形颗粒的直径为0.01〜3mm，比表面积为0.1〜1200m2 / g，比孔体积为0.01〜6.0ml / g，体积密度为50〜1000g / l。

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